Low Energy Demand Research Articles

CoAl-LDH on ZIF-67 template inserted into the conductive matrix as a high-efficiency composite anode for facilitating phosphorus elimination

Phosphorus pollution can induce water eutrophication and critically threaten the stability of the aquatic ecosystem. Capacitive deionization (CDI) is a potential candidate for controlling phosphorus levels due to its lack of chemical requirements, eco-friendliness, and low energy demand. Herein, a novel ZIF-67-derived CoAl-LDH embedded in conductive carbon skeletons (CoAl-LDH/C) was successfully constructed by a self-sacrificial template strategy. A conductive carbon matrix is incorporated into LDH, which can alleviate the insufficient conductivity and aggregation issues for LDH. The results revealed that CoAl-LDH/C possesses superior phosphorus elimination properties (qm=32.7 mg P/g) at 1.2 V, benefiting from its abundant active sites, large mesoporous diameter, specific surface area, total pore volume, outstanding specific capacitance, and ion diffusion. Meanwhile, the energy consumption of CoAl-LDH/C is merely 3.398 kWh/kg and 0.024 kWh/m3. CoAl-LDH/C also proved flexible for practical applications regarding complex water quality (wide pH range, coexisting substances, natural water) and cyclic utilization. Finally, the potential mechanism illuminated that the phosphorus elimination process in an electric field engages with ligand exchange, anion exchange, electrostatic attraction, and hydrogen bonds. This work paves a promising concept for designing innovative LDH-based electrodes with excellent ion diffusion and superior conductivity to eliminate phosphorus efficiently.

Role of Trapping in Non‐Volatility of Electrochemical Neuromorphic Organic Devices

AbstractArtificial Neural Networks (ANN) require a better platform to reduce their energy consumption and achieve their full potential. Electrochemical devices like the Electrochemical Neuromorphic Organic Device (ENODe) stand out as a potential building block for ANNs, due to their lower energy demand, in addition to their biocompatibility and access to multiple and stable memory levels. However, the non‐volatile effect observed in these devices is not yet fully understood. Hence, here we propose a 2D drift‐diffusion model that is capable to reproduce the device behavior. The model relies on the assumption of trapping sites for cations, which are increasingly filled or emptied during subsequent pre‐synaptic pulses. The model is verified by experiments on devices with varying post‐synaptic dimensions. Overall, the results provide a framework to discuss ENODe operation and design strategies for ENODes with well‐controlled memory states.

The key role of sufficiency for low demand-based carbon neutrality and energy security across Europe

A detailed assessment of a low energy demand, 1.5 ∘C compatible pathway is provided for Europe from a bottom-up, country scale modelling perspective. The level of detail enables a clear representation of the potential of sufficiency measures. Results show that by 2050, 50% final energy demand reduction compared to 2019 is possible in Europe, with at least 40% of it attributable to various sufficiency measures across all sectors. This reduction enables a 77% renewable energy share in 2040 and 100% in 2050, with very limited need for imports from outside of Europe and no carbon sequestration technologies. Sufficiency enables increased fairness between countries through the convergence towards a more equitable share of energy service levels. Here we show, that without sufficiency measures, Europe misses the opportunity to transform energy demand leaving considerable pressure on supply side changes combined with unproven carbon removal technologies.

The role of low-quality calcined clay in enhancing the performance of cement mortar exposed to normal and aggressive media

This study focuses on the role of low-quality calcined Fanja (FNJ) clay in enhancing the behavior of cured cement mortar (CM) and its resistivity to chloride and sulfuric acid attack. Ordinary Portland cement was replaced with different quantities (10%, 25%, 35%, and 50% by weight) of FNJ, which was calcined at different temperatures (620 °C, 760 °C, and 900 °C). After 28 days of curing, all the hardened mortars were immersed in 5% sulfuric acid for up to 12 weeks. Additionally, a rapid chloride permeability test was conducted on the 91-day cured CM and CM-FNJ samples to evaluate the affinity of calcined FNJs to retard the chloride diffusion into CM. The results showed that all samples containing FNJ900 showed better physical and mechanical properties than the control sample, while CM with NFJ760 recorded nearly similar performance as CM-NFJ900. In contrast, the CM-FNJ620 mixtures showed lower properties than those of other mixtures. In addition to the pozzolanic reactivity of the calcined clay, the presence of hematite in the calcined clay strongly contributed to increasing the mechanical properties of the hardened mortar through forming calcium ferrosilicate hydrate binding phase, as confirmed by X-ray diffraction. Moreover, the existence of hematite increased the resistivity of CM against sulfuric acid attack as it acts as a buffer for an acidic medium. Compared with CM-FNJ900, the CM-FNJ760 is recommended for use as it exhibited a higher strength activity index and comparable resistance to accelerated chloride diffusion and sulfuric acid accompanied by lower energy demand and lower CO2 emission, achieving the concept of ‘sustainability’.

Scheme design and assessment of hybrid pump feed system with energy management for throttleable liquid rocket engine

Currently, there is considerable emphasis on the electric pump-fed cycle for liquid engine, primarily due to its design simplicity. However, its development is hindered by the underdeveloped state of power battery technology. Drawing inspiration from hybrid power technology used in electric vehicles and turbochargers, a hybrid pump feed system for throttleable engines is originally proposed as a promising solution. This system integrates the electric motor into the gas generator cycle, with several topologies evaluated. The parallel configuration featuring a mid-motor is selected for its compact structure, efficient power-splitting and energy recovery. Additionally, customized energy management strategies and optimization models are developed to effectively allocate power throughout the operational processes of liquid engines. A comparative analysis of four engine cycles is conducted under the typically variable-thrust mission. The results indicate that attributed to the conservation of turbo-gas and battery energy, the optimized hybrid pump achieves a reduction of 2.39 % compared to the turbopump and 7.15% to the electric pump in total mass. Adaptability assessment further indicates that the mass advantage of the hybrid pump system is more significant during prolonged engine burning and deep throttling. Specific working conditions are found in which the system prefers electric-motor driving or regenerating turbine energy. Although energy-recovery results in the system efficiency decrease, it serves to lower energy demand of battery pack, thus easing the burden on cell thermal management and structural design. This study provides a practical design framework for hybrid pump-fed rocket engines in future variable-thrust missions.

Simultaneous removal of groundwater manganese and ammonia nitrogen based on high-flux gravity driven ceramic membrane (HF-GDCM) coupled with aerated fluidized birnessite

High concentrations of manganese ion (Mn2+) and ammonia nitrogen (NH3-N) in groundwater are indicative of a critical environmental issue that necessitates immediate attention. The gravity-driven ceramic membrane (GDCM) technology has shown great potential for groundwater treatment in rural communities, owing to its low energy demand and user-friendly operation. Active manganese oxide (MnOx) is extensively used for the concurrent removal of Mn2+ and NH3-N, leveraging its large specific surface area and abundant adsorption sites. Our research group has developed a GDCM-MnOx coupled system to address this challenge. However, membrane fouling, manifested as a reduction in flux or an increase in transmembrane pressure, has been a significant barrier to its widespread adoption. To address this challenge, we have implemented a continuous aeration system in conjunction with GDCM to fluidize birnessite to achieve the higher membrane flux, which has also proven effective in mitigating fouling while maintaining high water purification performance. Over a period of 100 days or more, the high membrane flux in the high-flux GDCM system (HF-GDCM) enhanced with aerated fluidized birnessite has been consistently maintained at approximately 34 L/(m2·h) at a water head of 1 m. Moreover, the HF-GDCM system efficiently removed manganese and NH3-N from groundwater under a hydraulic retention time (HRT) of less than 2.5 h, while also improving membrane permeability. The involvement of manganese oxidizing bacteria (MnOB) and ammonium-oxidizing bacteria (AOB) of Hypomicrobium and Nocardioides in the removal processes within the HF-GDCM system was confirmed. Additionally, XPS analysis confirmed the predominant oxidation state of MnOx to be Mn(III). The MnOx, deposited on powdered activated carbon (PAC) particles in a flower-like configuration, progressively formed a birnessite-like functional layer as the manganese ion content increased over time. Consequently, the HF-GDCM coupled with aerated fluidized birnessite is deemed suitable for water purification in small-scale rural or reservoir settings.

Lignocellulose nanofiber and starch for surface application on recycled linerboard

In a paper production line, starch is widely used for surface treatment and strengthening of linerboard at a size press. Also, the application of lignocellulose nanofibers (LCNFs) is growing because of its relatively low production energy demand, cost, and less hydrophilic nature in comparison to lignin-free nanofibers. Therefore, the addition of LCNFs to starch for paper surface treatment to reinforce the starch film and improve certain physical and mechanical properties of recycled linerboard was investigated in this work. Various LCNF/starch ratios were homogenized and then applied on the paperboard surface. The results revealed that a low mixing ratio of LCNF (5%) with starch improved the tensile index of the recycled paperboard, and at 50% LCNF content in the surface-treating material, film forming on the linerboard was observed in field emission-scanning electron microscopy images. In the case of 95% LCNF addition to starch, bending stiffness was significantly increased. Additionally, the viscosity of the sizing suspension was studied as a crucial parameter in the process and was found to increase significantly following the addition of LCNF.

Controlled atmosphere as cold chain support for extending postharvest life in cabbage

Postharvest management of cabbage relies on high-intensity cooling to control postharvest physiology, minimising quality loss despite incurring significant energy and environmental costs. As an alternative, we hypothesised that controlled atmosphere (CA) could allow increased storage temperature by supporting physiological regulation, while maintaining quality and reducing energy demand. This study examined the effect CA (1.5 kPa CO2 and 6 kPa O2) at 5 or 10 °C on cabbage quality, with the aim of proposing a more sustainable and resilient supply chain. CA treatment was effective at reducing head respiration at higher temperature, with CA/10 °C treatment achieving lower respiration rates than Control/5 °C. Improved head colour retention and maintenance of stump quality were observed in cabbage under CA conditions. CA effects were seen also at a regulatory level; CA promoted an average of 25.4% reduction in abscisic acid accumulation potentially as part of a wider hypoxia stress response and was successful in decreasing expression of the senescence-coordinating transcription factor BoORE15. This finding was linked with a lower in downstream expression of pheophytinase and subtilisin protease. These results demonstrated that CA treatment fundamentally modified postharvest physiology in cabbage, which can be exploited to enable storage at warmer temperatures, contributing to supply chains with lower energy demand and its associated environmental benefits.

High-Performance Crown Ether-Modified Membranes for Selective Lithium Recovery from High Na+ and Mg2+ Brines Using Electrodialysis

The challenge of efficiently extracting Li+ from brines with high Na+ or Mg2+ concentrations has led to extensive research on developing highly selective separation membranes for electrodialysis. Various studies have demonstrated that nanofiltration membranes or adsorbents modified with crown ethers (CEs) such as 2-OH-12-crown-4-ether (12CE), 2-OH-18-crown-6-ether (18CE), and 2-OH-15-crown-5-ether (15CE) show selectivity for Li+ in brines. This study aims to develop high-performance cation exchange membranes (CEMs) using CEs to enhance Li+ selectivity and to compare the performance of various CE-modified membranes for selective electrodialysis. The novel CEM (CR671) was modified with 12CE, 18CE, and 15CE to identify the optimal CE for efficient Li+ recovery during brine electrodialysis. The modification process included polydopamine (PDA) treatment and the deposition of polyethyleneimine (PEI) complexes with the different CEs via hydrogen bonding. Interfacial polymerization with 1,3,5-benzenetricarbonyl trichloride-crosslinked PEI was used to create specific channels for Li+ transport within the modified membranes (12CE/CR671, 15CE/CR671, and 18CE/CR671). The successful application of CE coatings and Li+ selectivity of the modified membranes were verified through Fourier-transform infrared spectroscopy, zeta-potential measurements, and electrochemical impedance spectroscopy. Bench-scale electrodialysis tests showed significant improvements in permselectivity and Li+ flux for all three modified membranes. In brines with high Na+ and Mg2+ concentrations, the 15CE/CR671 membrane demonstrated more significant improvements in permselectivity compared to the 12CE/CR671 (3.3-fold and 1.7-fold) and the 18CE/CR671 (2.4-fold and 2.6-fold) membranes at current densities of 2.3 mA/cm2 and 2.2 mA/cm2, respectively. At higher current densities of 14.7 mA/cm2 in Mg2+-rich brine and 15.9 mA/cm2 in Na+-rich brine, the 15CE/CR671 membrane showed greater improvements in Li+ flux, approximately 2.1-fold and 2.3-fold, and 3.2-fold and 3.4-fold compared to the 12CE/CR671 and 18CE/CR671 membranes. This study underscores the superior performance of 15CE-modified membranes for efficient Li+ recovery with low energy demand and offers valuable insights for advancing electrodialysis processes in challenging brine environments.

Enhanced antifouling behavior and phosphorus removal in a gravity-driven electrochemical dynamic membrane bioreactor (EDMBR) process: Performance and mechanisms

Gravity-driven dynamic membrane bioreactor (DMBR) process has emerged as a promising wastewater treatment technology. However, long dynamic membrane (DM) formation time, membrane fouling and low phosphorus removal have limited its widespread application. A novel gravity-driven electro-DMBR (EDMBR) using stainless-steel meshes as the anodic membrane and graphite plates as the cathodes was developed for domestic wastewater treatment, with process performance, DM properties and energy consumption compared with a control DMBR without external voltage applied. Electrostatic adsorption between negatively charged foulants and positively charged anodic membrane shortened DM formation time to less than 4 min. Afterwards, electro-oxidation effect and biodegradation effect resulted from the enrichment of electroactive microorganisms (such as Pseudomonas, Acinetobacter, Exiguobacterium) ensured continuous degradation of attached foulants and maintained a thin and well-structured DM layer, showing higher stable flux and reduced cleaning frequency at the voltage of 1.2 V and 1.6 V compared to the control DMBR. The electro-coagulation (EC) effect originated from iron releasing modified the sludge properties and enhanced phosphorus removal (74 %-87 %). Moreover, the EDMBR with higher permeability and treatment capacity resulted in lower energy consumption (0.41–0.44 kWh/m3) compared to the DMBR (0.50 kWh/m3). The results provide new insights into sustainable operation of the EDMBR process towards lower energy demand and less maintenance requirement.

Thermal performance and energy efficacy of membrane-assisted radiant cooling outdoors

Membrane-assisted radiant cooling systems offer a promising solution for directly cooling human bodies in outdoor settings. In this study a prototype system is experimentally assessed, which comprised of two wall-mounted panels and one ceiling-mounted panel with the cooling provided by a water chiller system. Three different radiant panel surface temperatures (Tsur =14.3°C, 17.8°C, 21.9°C) were tested to observe possible condensation and to measure the heat flux, and a thermal comfort survey was conducted in combination to analyze the system energy efficacy. The results indicate that selecting appropriate panel surface temperatures under different ambient universal thermal climate index (UTCI) conditions can not only effectively avoid energy surplus but also improve thermal comfort for people. When the ambient UTCI is 38.1°C, the panel surface temperature needs to be lowered to 14.3°C to achieve neutral thermal sensation while 333.7 W of cooling energy is required; but when the ambient UTCI is 29.9°C, a panel surface temperature of 21.9°C would suffice with a much lower energy demand. It is also concluded that the surface condensation may occur but can be controlled. This experimental study provides solid data for the further development of radiant cooling technology for open-space applications.

Mechanical performance of liquid cold-poured interlayer adhesives in comparison to PVB, EVA, and ionomers

AbstractCurrently, liquid cold-poured adhesives are infrequently used as interlayers of laminated or laminated safety glass in structural glass applications, despite their inherent benefits. The potential advantages of these materials are characterized by easy handling, rapid curing devoid of elevated temperature or pressure requirements, and consequently, a comparatively low energy demand. Despite the prolonged availability of certain products in the market, comprehensive scientific inquiry into their mechanical and thermal material characteristics remains limited. In this paper, two specific liquid cold-poured interlayer adhesives are investigated for their mechanical material properties in an extensive test regime. To be able to classify the characteristic values of the adhesives within a correct framework, the materials currently holding the largest market share, including Polyvinyl Butyral (PVB), Ionomers, and Ethylene Vinyl Acetate (EVA), are also subjected to the experimental program. The temperature dependence of the material behavior is explored through Dynamic Mechanical Thermal Analysis (DMTA) experiments. Furthermore, the time-dependent material behavior at large deformations is scrutinized using various methodologies, such as tensile tests at different strain rates, cyclic tests, creep tests, and relaxation tests, all conducted in uniaxial tension mode. The outcomes of all tests led to promising results for one of the adhesives with advantages over those of PVB and EVA.

Assessment of the Potential of Electrochemical Steps in Direct Air Capture through Techno-Economic Analysis.

Direct air capture (DAC) technologies are proposed to reduce the atmospheric CO2 concentration to mitigate climate change and simultaneously provide carbon as a feedstock independent of fossil resources. The currently high energy demand and cost of DAC technologies are challenging and could limit the significance of DAC processes. The present work estimates the potential energy demand and the levelized cost of capture (LCOC) of liquid solvent absorption and solid adsorption DAC processes in the long term. A consistent framework is applied to compare nonelectrochemical to electrochemical DAC processes and estimate the LCOC depending on the electricity price. We determine the equivalent cell voltage needed for the electrochemical steps to achieve comparable or lower energy demand than nonelectrochemical processes. The capital expenses (CapEx) of the electrochemical steps are estimated using analogies to processes that are similar in function. The results are calculated for a range of initial data of CapEx and energy demand to include uncertainties in the data.

Assessing the Carbon Footprint of Viticultural Production in Central European Conditions

A number of factors will increasingly play a role in the sustainability of wine production in the coming period. The current situation suggests that the analysis of energy consumption and greenhouse gas (GHG) emissions will play a particularly important role. The so-called carbon footprint, expressed in CO₂ equivalents, is used to express the sum of GHG emissions. This study presents an analysis of vine cultivation in a particular Central European region, with the main focus on quantifying the inputs, yield, fuel consumption, and GHG emissions. The emphasis was placed on conventional, integrated, and ecological production systems of growing, evaluated with the help of the developed AGROTEKIS version 5 software. A total of 30 wine-grower entities in the Morava wine-growing region, the subregion Velké Pavlovice, in the Czech Republic weather climate, were included in the input data survey. By analyzing the aggregated values, the real savings in energy and curbing of CO2 emissions of vineyards could be observed, relating to individual work procedures with lower energy demand used in the vineyard treatment as well as the amounts and doses of agrochemicals used. The average values of the total impacts did not show any statistically significant differences between the conventional (971 ± 78 kg CO2eq·ha−1·year−1) and integrated production systems (930 ± 62 kg CO2eq·ha−1·year−1), whereas the values for the ecological production system were significantly higher (1479 ± 40 kg CO2eq·ha−1·year−1). The results show that growing vines under ecological production conditions generates a higher proportion of the carbon footprint than under conventional production conditions. Overall, the best results can be achieved in an integrated production system.

Novel Strategy to Evaluate Platinum Photocatalysts for Hydrosilation-Curable Silicones

UV-activated catalytic hydrosilation is a low-temperature crosslinking process that has attracted attention for its high efficiency and lower energy demand relative to thermal curing. In this study, formulations comprising industrially relevant model silanes and Pt photocatalysts trimethyl(methylcyclopentadienyl)platinum(IV) and trimethyl(pentamethylcyclopentadienyl)platinum(IV) (MeCpPtMe3 and Cp*PtMe3, respectively) were prepared with and without a photosensitizer (PS) and assessed for catalytic performance by a novel strategy. Photopolymerizations were initiated using different wavelengths from LEDs and monitored in real-time using an Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) “well” strategy to track the degree of cure in ultra-thin films by consumption of hydride via the disappearance of the Si-H bending absorption band at 915 cm−1. Irradiation of formulations with 365 nm excitation showed higher conversions relative to 400 nm light and improvements to calculated initial reaction rates by incorporation of a PS suggested increased sensitization to 365 nm irradiation. To the best of our knowledge, this is the first study to report catalytic performance, electronic absorption spectroscopic data, and the crystal structure of Cp*PtMe3.

Emerging Advances around Nanofluidic Transport and Mass Separation under Confinement in Atomically Thin Nanoporous Graphene.

Membrane separation stands as an environmentally friendly, high permeance and selectivity, low energy demand process that deserves scientific investigation and industrialization. To address intensive demand, seeking appropriate membrane materials to surpass trade-off between permeability and selectivity and improve stability is on the schedule. 2Dmaterials offer transformational opportunities and a revolutionary platform for researching membrane separation process. Especially, the atomically thin graphene with controllable porosity and structure, as well as unique properties, is widely considered as a candidate for membrane materials aiming to provide extreme stability, exponentially large selectivity combined with high permeability. Currently, it has shown promising opportunities to develop separation membranes to tackle bottlenecks of traditional membranes, and it has been of great interest for tremendously versatile applications such as separation, energy harvesting, and sensing. In this review, starting from transport mechanisms of separation, the material selection bank is narrowed down to nanoporous graphene. The study presents an enlightening overview of very recent developments in the preparation of atomically thin nanoporous graphene and correlates surface properties of such 2D nanoporous materials to their performance in critical separation applications. Finally, challenges related to modulation and manufacturing as well as potential avenues for performance improvements are also pointed out.

Ensuring Sustainable Grid Stability through Effective EV Charging Management: A Time and Energy-Based Approach

The rise of electric vehicles (EVs) has significantly transformed transportation, offering environmental advantages by curbing greenhouse gas emissions and fossil fuel dependency. However, their increasing adoption poses challenges for power systems, especially distribution systems, due to the direct connection of EVs with them. It requires robust infrastructure development, smart grid integration, and effective charging solutions to mitigate issues like overloading and peak demand to ensure grid stability, reliability, and sustainability. To prevent local equipment overloading during peak load intervals, the management of EV charging demand is carried out in this study, considering both the time to deadline and the energy demand of EVs. Initially, EVs are prioritized based on these two factors (time and energy)—those with shorter deadlines and lower energy demands receive higher rankings. This prioritization aims to maximize the number of EVs with their energy demands met. Subsequently, energy allocation to EVs is determined by their rankings while adhering to the transformer’s capacity limits. The process begins with the highest-ranked EV and continues until the transformer nears its limit. To this end, an index is proposed to evaluate the performance of the proposed method in terms of unserved EVs during various peak load intervals. Comparative analysis against the earliest deadline first approach demonstrates the superior ability of the proposed method to fulfill the energy demand of a larger number of EVs. By ensuring sustainable energy management, the proposed method supports the widespread adoption of EVs and the transition to a cleaner, more sustainable transportation system. Comparative analysis shows that the proposed method fulfills the energy needs of up to 33% more EVs compared to the earliest deadline method, highlighting its superior performance in managing network loads.

Self-powered electrochromic smart window helps net-zero energy buildings

Net-zero energy buildings are becoming an important energy-saving and low-carbon technology for global environmental protection and resource conservation. As the least energy-efficient building components, windows have promoted the development of electrochemically light/thermal management, where smart windows without external electrical supplies are highly desired for net-zero energy buildings. Here, we develop a self-powered electrochromic smart window system to regulate solar radiation transmittance, constructed by a triboelectric nanogenerator (TENG) and a high-performance electrochromic device. The visible–near-infrared (VIS-NIR) dual-band electrochromic device is well-designed based on an eco-friendly low-energy demand phenothiazine redox ionic liquid, demonstrating a fast switching response of ﹤1.9 s, a large transmittance modulation of >51.8 %, and outstanding electrochemical durability (5.5 % attenuation after 4000 cycles). Upon continuous pressing/releasing motions, the integrated TENG-powered electrochromic smart window (TECSW) displays a prompt light/thermal management behavior with desirable privacy preservation performance (transmittance modulation of 51 % in the visible region) and excellent thermal management property (12.3 °C reducti°n). The whole-building energy simulations show that TECSW can save 347.79 MJ/m2yr (amounting to 96.60 kWh/m2yr) of operational Heating Ventilation Air Conditioning (HVAC) warming/cooling energy consumption among 34 cities in China, accounting for 17.25 % of the total energy consumption. This research provides new insight into designing green and energy-efficient smart windows for net-zero energy buildings.

Comparing genome-scale metabolic models of the non-resistant Enterococcus faecalis ATCC 19433 and the multi-resistant Enterococcus faecalis V583

Enterococcus faecalis is a versatile lactic acid bacterium with a large variety of implications for humans. While some strains of this species are pathobionts being resistant against most of the common antibiotics, other strains are regarded as biological protectants or even probiotics. Accordingly, E. faecalis strains largely differ in the size and content of their accessory genome. In this study, we describe the genome-scale metabolic network reconstruction of E. faecalis ATCC 19433, a non-resistant human-associated strain. A comparison of the genome-scale metabolic model (GSM) of E. faecalis ATCC 19433 with a previously published GSM of the multi-resistant pathobiontic E. faecalis V583 reveals high similarities in the central metabolic abilities of these two human associated strains. This is reflected, e.g., in the identical amino acid auxotrophies. The ATCC 19433 strain, however, has a 14.1 % smaller genome than V583 and lacks the multiple antibiotic resistance genes and genes involved in capsule formation. Based on the measured metabolic fluxes at different growth rates, the energy demand at zero growth was calculated to be about 40 % lower for the ATCC 19433 strain compared to V583. Furthermore, the ATCC 19433 strain seems less prone to the depletion of amino acids utilizable for energy metabolism. This might hint at a lower overall energy demand of the ATCC 19433 strain as compared to V583.

Enhancing Thermal and Daylight Performance of Historic Buildings with Passive Modifications; A Tropical Case Study

Historical buildings worldwide hold immense potential for adaptive reuse within the framework of the circular economy, a concept gaining traction in the building construction industry for its role in reducing carbon emissions. Many of these structures boast passive building design strategies, which inherently lower energy demands. Among these, thermal mass and daylight harvesting emerge as pivotal strategies for achieving indoor thermal and visual comfort, respectively. However, with the advent of significant climate change and evolving built environments, the efficacy of these historical passive strategies is subject to debate. This study focuses on a residential building constructed in the 17th century by Dutch settlers in Galle, Sri Lanka, serving as a case study. The research targets improvements in both thermal and visual comfort. Thermal performance analysis was conducted through air temperature measurements, revealing a notable 3-hour time lag and a 2.5°C reduction in peak air temperature during the day. Conversely, nighttime measurements indicated a rise in indoor temperature compared to ambient conditions. Using Design Builder software, the building was modelled to assess its daylighting conditions. Drawing upon thermodynamic principles and daylight harvesting techniques, the study proposes building envelope interventions and ventilation strategies to address nighttime overheating and enhance daylight utilization. The results demonstrate that these modifications can potentially reduce nighttime heat by 2-3°C, while also decreasing the energy requirement for lighting comfort from 51.10 kWh/m² per annum to 44.84 kWh/m² per annum. This research showcases the effectiveness of judiciously implemented interventions in historical buildings, illustrating tangible improvements in both thermal/visual performance and energy efficiency. Leveraging inherent qualities of historical structures and integrating modern design strategies to these buildings can play a vital role in sustainable urban development and energy conservation efforts.