Low Deposition Rate Research Articles

High‐Pressure Cell for In Situ Grazing Incidence XAS Characterization of Model Catalysts on Planar Supports

AbstractThe growing interest in physically deposited model catalysts for uncovering complex structure‐activity relationships is spurred by the possibility of depositing nanoparticles of precise atomic structure and composition using cluster‐beam sources. However, the limitations accompanying these synthesis techniques, such as low deposition rates and flat sample geometry, present a challenge for in situ structural characterization using bulk‐sensitive methods, such as X‐ray absorption spectroscopy (XAS), especially at elevated pressures (1–100 bar). To overcome this challenge, we constructed an in situ XAS cell operating in a grazing incidence (GI) geometry. The GIXAS cell was used to investigate the structure of cluster‐beam‐generated Pd and Au0.3Ag0.7 nanoparticles under CO2‐to‐methanol hydrogenation conditions (230 °C, 20 bar, CO2:H2=1 : 3). These nanoparticles, with metal loading of 0.96–10 μg cm−2, demonstrated stability and resistance to sintering upon activation in H2 at 120 °C and catalytic conditions, revealed by in situ XAS. The promising results from our work will help bridge the gap in the investigation of model catalytic materials produced by gas‐phase cluster deposition at industrially relevant pressures and temperatures, which is vital for a mechanistic understanding of catalytic processes.

Epitaxial RuO2 and IrO2 films by pulsed laser deposition on TiO2(110)

We present a systematic growth study of epitaxial RuO2(110) and IrO2(110) on TiO2(110) substrates by pulsed laser deposition. We describe the main challenges encountered in the growth process, such as a deteriorating material flux due to laser-induced target metallization or the delicate balance of under- vs over-oxidation of the “stubborn” Ru and Ir metals. We identify growth temperatures and oxygen partial pressures of 700 K, 1 × 10−3 mbar for RuO2 and 770 K, 5 × 10−4 mbar for IrO2 to optimally balance between metal oxidation and particle mobility during nucleation. In contrast to IrO2, RuO2 exhibits layer-by-layer growth up to 5 unit cells if grown at high deposition rates. At low deposition rates, the large lattice mismatch between film and substrate fosters initial 3D island growth and cluster formation. In analogy to reports for RuO2 based on physical vapor deposition [He et al., J. Phys. Chem. C 119, 2692 (2015)], we find these islands to eventually merge and grow to continue in a step flow mode, resulting in highly crystalline, flat, stoichiometric films of RuO2(110) (up to 30 nm thickness) and IrO2(110) (up to 13 nm thickness) with well-defined line defects.

Fluidized Bed Chemical Vapor Deposition of Copper on Micronic Alumina Powders

AbstractUniformly coating micronic particles with metals is of main interest for a broad range of applications. This study demonstrates the feasibility of depositing pure copper on the surface of micronic alumina particles by the fluidized bed chemical vapor deposition process from the cheap and nontoxic copper acetylacetonate precursor. Thanks to the development of a preconditioning protocol, a complete fluidization of the particles organized as porous agglomerates was reached. The coating of the individual particles was favored by using conditions involving low deposition rates. The influence of key operating parameters on the process behavior and on the characteristics of the deposit was studied. The deposited copper was of cubic crystal structure without carbon nor oxide contamination.

Simulating the Growth of TATA-Box Binding Protein-Associated Factor 15 Inclusions in Neuron Soma.

To the best of the author's knowledge, this paper presents the first attempt to develop a mathematical model of the formation and growth of inclusions containing misfolded TATA-box binding protein associated factor 15 (TAF15). It has recently been shown that TAF15 inclusions are involved in approximately 10% of cases of frontotemporal lobar degeneration (FTLD). FTLD is the second most common neurodegenerative disease after Alzheimer's disease (AD). It is characterized by a progressive loss of personality, behavioral changes, and a decline in language skills due to the degeneration of the frontal and anterior temporal lobes. The model simulates TAF15 monomer production, nucleation and autocatalytic growth of free TAF15 aggregates, and their deposition into TAF15 inclusions. The accuracy of the numerical solution of the model equations is validated by comparing it with analytical solutions available for limiting cases. Physiologically relevant parameter values were used to predict TAF15 inclusion growth. It is shown that the growth of TAF15 inclusions is influenced by two opposing mechanisms: the rate at which free TAF15 aggregates are deposited into inclusions and the rate of autocatalytic production of free TAF15 aggregates from monomers. A low deposition rate slows inclusion growth, while a high deposition rate hinders the autocatalytic production of new aggregates, thus also slowing inclusion growth. Consequently, the rate of inclusion growth is maximized at an intermediate deposition rate of free TAF15 aggregates into TAF15 inclusions.

A diversity baseline of benthic macrofauna along the northwestern slope of Cuba (Gulf of Mexico)

The Gulf of Mexico (GoM) is a unique ecosystem due to its physical characteristics, being influenced by the Mississippi River in the north and the Loop Current from the south, resulting in a gradient of organic to carbonate sediment composition from north to south. The continental slope of the northern and southwestern portions of the GoM are generally well studied; however, less is known about the southeastern GoM along the slope of Cuba. To fill this knowledge gap, sediment cores were collected in 2017 at nine stations (974–1580 m depth) to determine abiotic controls on the deep-sea benthic macrofauna community. Oceanographic data indicated a stratified water column typical of an oligotrophic ocean and no evidence of hypoxia. Sediment texture and composition indicated a west-east gradient likely determined by downslope transport of terrigenous material in the eastern part with a high proportion of carbonate in the west. Heavy metals (Cu, Hg, Pb, and Zn) at concentrations known to cause adverse benthic effects were present in the east near the city of Havana, with the macrofauna community showing characteristics indicative of environmental stress. Overall, this region supported a diverse community of macrofauna families of low abundance, typically only 1–2 animals, and high variability among replicates within stations. Rarefaction curves revealed higher biodiversity per number of individuals in the samples from Cuba compared to those from the nGoM at similar depths, though more samples would be needed to better reveal the true diversity. The major factors influencing macrofauna communities in the continental slope off northwestern Cuba are most likely the lack of organic-rich sediment and low sediment deposition rates, both of which can be attributed to the strong currents and lack of major terrigenous input, along with the regular natural disturbances which prevents domination.

Comparison of Corrosion Behavior of a-C Coatings Deposited by Cathode Vacuum Arc and Filter Cathode Vacuum Arc Techniques

This study explores the utilization of cathodic vacuum arc (CVA) technology to address the limitations of magnetron sputtering technology in preparing amorphous carbon (a-C) coatings, such as having a low ionization rate, low deposition rate, and insufficiently dense structure. Specifically, a-C coatings were prepared by the cathodic vacuum arc (CVA)and the filtered cathodic vacuum arc (FCVA) technology,, one with embedded carbon particles and one without, both having closely related carbon structures. Research is currently underway on bipolar plate coatings for fuel cells. The corrosion behavior of the prepared a-C coatings was examined through Tafel polarization analysis under simulated fuel cell operating conditions as well as potentiostatic analysis at 0.6 V under normal conditions and 1.6 V under start–stop conditions for 7200 s. The coatings before and after corrosion are characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, Raman spectroscopy, and infrared spectroscopy. The results reveal that the incorporation of conductive graphite-like particles in the coatings reduces their contact resistance. However, the gaps between these particles and the coatings act as pathways for corrosive solution, exacerbating the corrosion of the coatings. After corrosion at 0.6 V, both sets of coatings with sp2-hybridized carbon structures are contaminated by elements such as hydrogen and oxygen, leading to an increase in their contact resistance. Under high potential conditions (1.6 V), large corrosion pits and defects appear at the locations of graphite-like carbon particles. Furthermore, both sets of samples exhibit more severe oxygen contamination and a transformation of broken carbon bonds from sp3- to sp2-hybridized forms, irrespective of whether embedded graphite particles are present.

Note on the low deposition rate during reactive magnetron sputtering

Previously published data on the metal partial sputter yield from a poisoned target during reactive magnetron sputtering is confronted with the metal partial sputter yield from the corresponding compound calculated based on an existing semi-empirical model validated with experimental ion beam data. Both yields are linearly correlated but the magnetron based sputter yields are approximately 8 times lower. The lower yield is explained from the formation of an oxygen rich top layer. This hypothesis is verified by binary collision approximation Monte Carlo simulations.

Deposition Kinetics and Characteristics of Peald Igzo Films Using Tetrahydrofuran-Adducted in & Ga Precursors

As the down-scaling of semiconductor materials, silicon compatible emerging materials have extensively researched for next generation display and 3D structured devices. In particular, oxide semiconductors are considered a promising candidate for backplane applications in display. Among them, indium-gallium-zinc oxide (IGZO) using plasma enhanced atomic layer deposition (PEALD) has excellent properties, like high mobility, low leakage current, high transparecy and low temperature processablility. However, conventional precursors for IGZO still have some prolems to solve such as low deposition rate, low thermal stability and high price. In this study, we developed indium precursor (Trimethylindium Tetrahydrofuran, DIP-4) and gallium precursor (Trimethylgallium Tetrahydrofuran, DGP-2) to overcome the shortcomings of the conventional In & Ga precursors. ALD characteristics of the films deposited using the newly developed the precursors were confirmed through the source feeding time saturation and linearity. Furthermore, the incubation time of In, Ga and Zn oxide films according to the different bottom layer was respectively verified and calculated using the developed DIP-4, DGP-2 and commercially used DEZn. In order form a multilayer IGZO thin film, application of the incubation factors at IGZO process were experimentally demonstrated. Thickness of the IGZO films can be easily controlled through modulation of the incubation factors. The physical and chemical properties of the films were analyzed by X-ray diffraction, X-ray reflectrometer, X-ray photoelectron spectroscopy, transmission electron microscope. Figure 1

Progress in Additive Manufacturing of Magnesium Alloys: A Review.

Magnesium alloys, renowned for their lightweight yet high-strength characteristics, with exceptional mechanical properties, are highly coveted for numerous applications. The emergence of magnesium alloy additive manufacturing (Mg AM) has further propelled their popularity, offering advantages such as unparalleled precision, swift production rates, enhanced design freedom, and optimized material utilization. This technology holds immense potential in fabricating intricate geometries, complex internal structures, and performance-tailored microstructures, enabling groundbreaking applications. In this paper, we delve into the core processes and pivotal influencing factors of the current techniques employed in Mg AM, including selective laser melting (SLM), electron beam melting (EBM), wire arc additive manufacturing (WAAM), binder jetting (BJ), friction stir additive manufacturing (FSAM), and indirect additive manufacturing (I-AM). Laser powder bed fusion (LPBF) excels in precision but is limited by a low deposition rate and chamber size; WAAM offers cost-effectiveness, high efficiency, and scalability for large components; BJ enables precise material deposition for customized parts with environmental benefits; FSAM achieves fine grain sizes, low defect rates, and potential for precision products; and I-AM boasts a high build rate and industrial adaptability but is less studied recently. This paper attempts to explore the possibilities and challenges for future research in AM. Among them, two issues are how to mix different AM applications and how to use the integration of Internet technologies, machine learning, and process modeling with AM, which are innovative breakthroughs in AM.

Microstructure, mechanical, and tribological properties of transition metal (Nb, V, W) nitride coating on AISI-1045 steel by cathodic cage plasma deposition

AISI-1045 steel is a medium-carbon, medium-strength steel that usually requires surface engineering to be usable in industrial applications. Using the cathodic cage plasma deposition technique, transition metal (Nb, V, W) nitride coating is deposited on this steel using cathodic cage lids of these metals. The hardness of untreated steel (1.8 GPa) is upgraded to 11.2, 12.2, and 9.7 GPa for niobium nitride, vanadium nitride, and tungsten nitride coating, respectively. The elastic modulus, the ratio of hardness-elastic modulus (H/E, H2/E, and H3/E2), and the plasticity factor depict the improvement in mechanical and elastic properties. The sample treated with a niobium cage lid exhibits the Nb4N5 phase, the vanadium cage lid shows the VN phase (along with the Fe4N phase), and the tungsten cage lid consists of W2N3, WFeN2, and Fe4N phases. Among these coatings, the thickness of niobium nitride coating is maximum (1.87 μm), and a low deposition rate is obtained for tungsten nitride coating (0.83 μm). In addition to this coating, a nitrogen diffusion zone (∼60 μm) is also formed beneath the coating, which creates a hardness gradient between the coating and the substrate. The ball-on-disc wear tester shows that niobium nitride coating deposition reduces the wear rate from 19.5 × 10−3 to 8.8 × 10−3 mm3/N m and exhibits excellent wear performance.

Numerical simulation of dust deposition characteristics of photovoltaic arrays taking into account the effect of the row spacing of photovoltaic modules

Dust deposition on the surfaces of Photovoltaic (PV) arrays during their operation markedly affects their power generation efficiency. Previous research has overlooked the impact of the row spacing of PV modules on the actual dust deposition on PV arrays. This study investigates the dust deposition process and its behavior on PV arrays considering variations in row spacings, inlet wind speeds, dust particle sizes, and dust particle counts. By employing commercial Computational Fluid Dynamics (CFD) software, incorporating the SST k-ω turbulence model and discrete particle model, numerical simulations were performed to analyze the airflow field, dust particle trajectories, dust deposition patterns, and deposition rates on the PV array through grid-independent verification and numerical validation. At the same time, we performed a comparative analysis of the deposition rate considering the rebound of dust particles on the PV module surface versus the case where rebound is not considered. Results revealed that the maximum dust deposition rates at different inlet wind speeds were 6.84 %, 8.84 %, 11.0 %, and 14.6 %, corresponding to dust sizes of 50 μm, 100 μm, 120 μm, and 300 μm, respectively. Smaller dust particles exhibited lower deposition rates, while larger particles were influenced more by mass inertia and gravity, leading to predominant deposition on the front row of PV modules. Larger dust particles are more likely to deposit primarily on the front row of PV modules in a PV array. The tilt angles of 30°, 45°, and 60° were chosen to study the effects of different tilt angles on the dust deposition of PV arrays, and the results show that the dust deposition rate decreases as the tilt angle increases, and it is worth noting that the larger the tilt angle, the larger the dust deposition rate is when the dust particles are especially small as 5 μm. When wind speeds are low and dust particles are small, the dust deposition rate gradually rises as the row spacing increases. However, at higher wind speeds with small dust particles, the row spacing has minimal impact on the dust deposition rate. Conversely, with larger dust particles, increasing the row spacing results in a lower dust deposition rate. These findings underscore the significance of optimizing PV array design for enhanced power generation efficiency.

Influence of agricultural activity in corn farming on airborne microplastic in surrounding elementary school

Microplastics (MPs) have been widely detected in agricultural soils, and agricultural activities have been identified as an important factor influencing the abundance of MPs in the air. However, no studies have investigated whether agricultural activities are contributors to airborne MPs in buildings near farms. We collected airborne MP samples using an active sampling method from an elementary school near corn farms during different cultivation stages to assess the impact of agricultural activities on MPs in the study school near farms. Our data showed that the predominant shapes, sizes, colors, and polymer compositions were fragments, 2–50 μm, black or grey, and polyethylene terephthalate, respectively, during all cultivation stages. The highest and lowest MP concentrations were recorded during the land preparation (56.8 ± 7.4 particles/m3, August 2022) and growth (2.5 ± 1.8 particles/m3, February 2022) stages, respectively. A multiple-path particle dosimetry model revealed that the deposition fractions of MPs in humans were highest in the head; the highest and lowest deposition rates and fluxes of MPs in the airway were found during the land preparation and growth stages, respectively. The concentration of MPs did not present a positive correlation with potassium or crustal elemental concentration; however, it did show a positive association with temperature value. Therefore, our data did not show that corn cultivation influences MP concentrations in the study school near corn farms; instead, temperature was an important influencing factor.

A Microporous Channel Copper Immersion Layer Promotes the Rapid Ni-P Electroless Plating Process on Aluminum Alloys at Medium and Low Temperatures

Electroless plating is a commonly used method to enhance the corrosion resistance, wear resistance, and decorative performance of aluminum alloys. However, in electroless plating processes, it is customary to maintain the solution temperature at levels exceeding 85 °C, a critical condition that ensures a sufficiently rapid deposition rate and thereby fosters the formation of high-performance coatings. Conventional immersion pretreatments with zinc and palladium result in lower deposition rates at low temperatures. This study shows that a copper immersion layer with microporous channels can facilitate the electroless plating process for aluminum alloys at lower temperatures. Through a redox reaction in a Cu2+-containing solution at 70 °C, a copper immersion layer with a microporous structure could be created on an aluminum alloy. The microporous channels between the copper immersion layer and the aluminum alloy create electrochemical corrosion cells in the plating solution, accelerating the electroless plating process. The Ni-P coating obtained after pretreatment by copper immersion has a higher hardness (578 HV) and a lower corrosion current density (0.55 μA cm−2). This work provides a practical method to rapidly fabricate high-performance Ni-P coatings at intermediate temperatures (70 °C–75 °C).

Structure and mechanical properties of TiAlTaN thin films deposited by dcMS, HiPIMS, and hybrid dcMS/HiPIMS

The quaternary Ti1-x-yAlxTayN system exhibits superior thin film properties compared to Ti1-xAlxN. Apart from the Ta content, the sputtering method has a crucial effect on the structural and mechanical properties. High power impulse magnetron sputtering (HiPIMS) produces denser thin films with improved hardness compared to direct current magnetron sputtering (dcMS), but at lower deposition rates. However, a hybrid dcMS/HiPIMS process combines the advantages of dcMS and HiPIMS and is, therefore, a suitable method to synthetize Ti1-x-yAlxTayN thin films. To analyze the effect of the sputtering technique on the structural and mechanical properties, Ti1-x-yAlxTayN is sputtered from TiAlTa compound targets with Ta fractions up to 0.2 by dcMS, HiPIMS, and dcMS/HiPIMS.The Ta metal fraction within Ti1-x-yAlxTayN steadily increased up to y ≈ 0.25, while the Al content notably decreased at higher Ta levels. This reduction was most pronounced in HiPIMS, resulting in an order of decreasing Al content as dcMS, dcMS/HiPIMS, and HiPIMS. All thin films exhibit a Ti1-x-yAlxTayN substitutional solid solution with a linearly increasing lattice parameter corresponding to higher Ta contents. At similar Ta contents, HiPIMS-Ti1-x-yAlxTayN and dcMS/HiPIMS-Ti1-x-yAlxTayN show larger out-of-plane lattice parameters compared to dcMS/HiPIMS-Ti1-x-yAlxTayN, indicating elevated compressive stresses within the thin films. The Ti1-x-yAlxTayN thin films show a column-like structure, with HiPIMS promoting the formation of a denser morphology with less columns. The HiPIMS-Ti1-x-yAlxTayN with H = 41 GPa and dcMS/HiPIMS-Ti1-x-yAlxTayN with H = 40 GPa achieve their peak hardness at a lower Ta metal fraction of y ≈ 0.12–0.13, in contrast to dcMS-Ti1-x-yAlxTayN, which reaches H = 38 GPa at y ≈ 0.25. The shift to lower Ta contents for the maximum hardness in HiPIMS-Ti1-x-yAlxTayN and dcMS/HiPIMS-Ti1-x-yAlxTayN is due to higher compressive stresses and smaller crystallite sizes in these films at low Ta metal fractions. The H/E and H3/E2 ratios of the HiPIMS-Ti1-x-yAlxTayN and dcMS/HiPIMS-Ti1-x-yAlxTayN exhibited a similar trend of increasing values, reaching a maximum, and then decreasing with higher Ta content. Consequently, the hybrid dcMS/HiPIMS process produces Ti1-x-yAlxTayN thin films with mechanical properties comparable to pure HiPIMS, making it a suitable sputtering method for the synthesis of Ti1-x-yAlxTayN.

Segregation effects of doped VN and ZrN on magnetic and microstructural characteristics of FePt-based films

Segregants are essential materials for forming the complexation or granular microstructure in thin films for magnetic recording media. One such film, FePt-BN, has a metallic L10 FePt main phase as its matrix, in addition to having BN and C segregants at the grain boundaries. Amorphous BN has sufficient mechanical strength to support the columnar growth of FePt grains, however, it has a lower deposition rate resulting in columnar grains with a nonuniform aspect ratio. Moreover, some B diffuses in the interstitial site of FePt lattices. To overcome these limitations, this study added the transition nitride VN and ZrN with equal volume percentages to replace some BN segregants in FePt(BN, Ag, C) films: substantially different segregation behaviors were observed. Microstructural imaging mapping revealed that although VN segregated the FePt grains boundary, ZrN was diffused in the lattice. The FePt-BN-ZrN film thus had more disordered grains contributing to a higher in-plane magnetization and wider hard axis magnetic hysteresis loops than did FePt-BN-VN. The FePt-BN-VN film has the highest perpendicular magnetic anisotropy constant (Ku= 2.17 × 106 J/m3) and coercivity (Hc= 4 T); moreover, parallel remanence magnetization was minimal with a linear in-plane magnetization loop. The FePt-BN-VN film was sputtered directly on MgO(100) but depositing the FePt-BN-ZrN film required a 2-nm-thick FePt nucleation layer. The high atomic number of Zr and high sputter yield ratio (YN/Ymetal) of ZrN may increase the sites occupied by N, potentially affecting ZrN segregation.

Enhanced ferroelectric and piezoelectric properties of SrBi2Ta2O9 thin films through crystalline orientation

This study investigates how variations in substrate temperatures and deposition rates during pulsed laser deposition on Nb-doped SrTiO3 substrates affect the crystallinity, and consequently, the ferroelectric and piezoelectric properties of SrBi2Ta2O9 (SBT) thin films. The SBT thin film developed at 850 °C with a deposition rate of 0.34 nm/pulse showed lower remanent polarization and piezoelectric coefficients, a result of its c-oriented crystallinity. In contrast, SBT thin films produced at 750 °C with deposition rates of 0.37 nm/pulse demonstrated enhanced ferroelectric and piezoelectric responses due to mixed a-oriented crystallinity. In particular, the SBT thin film, fabricated at 750 °C with a lower deposition rate of 0.04 nm/pulse, demonstrated the most enhanced ferroelectric and piezoelectric properties due to its highly refined a-oriented crystallinity. Our findings illuminate the relationship between the characteristics of the crystals and functional properties in SBT thin films, highlighting the integration of a-domains within c-domains as a key strategy for optimizing SBT film performance and opening avenues for designing specialized Bi-layered perovskite thin films.

Microstructural characteristics and properties of wire arc additive manufactured 304L austenitic stainless steel cylindrical components by different arc welding processes

Wire arc additive manufacturing (WAAM) is an advanced additive manufacturing (AM) technology that offers low cost and high deposition rates, making it suitable for building large metal parts for structural engineering applications. However, various welding procedures result in differing heat inputs and repetitive heating treatments throughout the deposition process, which can affect the microstructural and mechanical characteristics of the parts. In the current study, cylindrical parts made of 304L austenitic stainless steel (ASS) were manufactured using the WAAM technique, employing both gas metal arc welding (GMAW) and cold metal transfer (CMT) processes. This study explores the correlation between WAAM techniques and their effects on the bead geometry, microstructure and mechanical properties. The microstructure of the cylinders consisted of vertically growing austenite dendrites with residual ferrite (δ) within the austenite (γ) matrix. Compared to the bottom region (region ①), the top region (region ②) contained more residual ferrite. Although the microstructural characteristics from region ① to region ② are similar, they exhibit different ferrite morphologies. The rapid cooling rate in the CMT-AM process resulted in finer structures and a greater presence of ferrite phases in both regions compared to the GMAW-AM method. Cylinders produced by the CMT process displayed nearly uniform properties across both regions and demonstrated superior tensile properties, hardness, and impact toughness relative to those made using the GMAW technique. The WAAM 304L ASS cylinders also showed enhanced performance compared to stainless steel manufactured using traditional industrial forging standards, indicating that WAAM-processed 304L ASS cylinders are suitable for industrial applications.

Sedimentary Paleoenvironment and Organic Matter Enrichment Characteristics of Lacustrine Shahezi Shale in Songliao Basin: Insights from the Continental Scientific Drilling.

The lacustrine shale of the Shahezi Formation in the Songliao Basin has obvious organic matter enrichment characteristics and great potential for oil and gas resources. At present, the understanding of the sedimentary paleoenvironment and organic matter enrichment characteristics of the lacustrine shale of the Shahezi Formation is relatively weak. Therefore, taking the international continental scientific drilling Program (ICDP) borehole Songke-2 (SK-2) with continuous and whole Shahezi cores as the research object, combined with organic geochemistry, elemental geochemistry, and logging data, the sedimentary paleoenvironment and organic matter enrichment mechanism were studied. The results show that the organic matter of Shahezi shale is generally in the high to over mature stage. The kerogen type of organic matter is mainly II2-III. The organic matter is mainly derived from the lake basin's own algae and terrestrial higher plants. The total organic carbon (TOC) content of Shahezi shale is relatively high, and the TOC is mainly distributed between 1% and 2%. The Shahezi Formation is dominated by clay shale and siliceous shale, and experienced moderate chemical weathering during deposition. According to the analysis of organic geochemistry and elemental geochemistry data, the paleoenvironment of organic matter deposition in Shahezi shale was dominated by warm and humid climate in the early stage, and then experienced multiple cooling and arid periods. The climate type turned to semihumid-semiarid, with stable terrigenous debris input, low deposition rate, brackish water salinity and oxygen-rich-oxygen-poor water environment. The sedimentary period of Shahezi Formation is in the Cretaceous oceanic anoxic Aptian-Albian stage. During the oceanic anoxic event, the anoxic sedimentary environment and the frequent volcanic activity have an important impact on the organic matter enrichment. The oceanic anoxic event and volcanic activity are the main causes of water body hypoxia in the lake basin. The nutrients brought by volcanic activity are also one of the reasons for promoting the growth of lake basin organisms, creating good conditions for organic matter enrichment. The enrichment of organic matter in Shahezi Formation is the result of the interaction and coupling of various factors such as paleoclimate, paleoenvironment, paleoproductivity, water environment, terrestrial input, and major geological events. And, the organic matter enrichment model of Shahezi Formation shale is established.

Impact of deposition rate on structural, morphological and optical properties of E-beam evaporated chromium thin film

The structural, morphological and optical properties of thin chromium film are investigated on the dependency of deposition rate with characterization by X-ray Diffraction, SEM-EDS, AFM and UV–Visible spectroscopy. A high vacuum E-Beam vacuum coating device fabricates thin chromium film at different deposition rates on borosilicate glass. XRD diffractogram reveals that film is in amorphous nature at low deposition rate. The crystallite size is increases with increases the deposition rate but strain is in opposite nature. It is decreases as deposition rate increases indicate no peak shifting. AFM demonstrates that smoother surfaces with higher deposition rates reduce scattering losses i.e., from 0.016 to 0.006 nm. SEM-EDS spectra gives information about pure chromium is deposited on substrate without any oxides and sulphides formation. Optical analysis depicts that transmittance is decreases with deposition rate and uniform in visible range. As the rate of deposition rises, the extinction coefficient and absorption coefficient drop.

Observation of an abrupt 3D-2D morphological transition in thin Al layers grown by MBE on InGaAs surface

Among superconductor/semiconductor hybrid structures, in situ aluminum (Al) grown on InGaAs/InAs is widely pursued for the experimental realization of Majorana Zero Mode quasiparticles. This is due to the high carrier mobility, low effective mass, and large Landé g-factor of InAs, coupled with the relatively high value of the in-plane critical magnetic field in thin Al films. However, growing a thin, continuous Al layer using the molecular beam epitaxy (MBE) is challenging due to aluminum's high surface mobility and tendency for 3D nucleation on semiconductor surfaces. A study of epitaxial Al thin film growth on In0.75Ga0.25As with MBE is presented, focusing on the effects of the Al growth rate and substrate temperature on the nucleation of Al layers. We find that for low deposition rates, 0.1 and 0.5 Å/s, the growth continues in 3D mode during the deposition of the nominal 100 Å of Al, resulting in isolated Al islands. However, for growth rates of 1.5 Å/s and above, the 3D growth mode quickly transitions into island coalescence, leading to a uniform 2D Al layer. Moreover, this transition is very abrupt, happening over an Al flux increase of less than 1%. We discuss the growth mechanisms explaining these observations. The results give new insights into the kinetics of Al deposition and show that with sufficiently high Al flux, a 2D growth on substrates at close to room temperature can be achieved already within the first few Al monolayers. This eliminates the need for complex cryogenic substrate cooling and paves the way for the development of high-quality superconductor-semiconductor interfaces in standard MBE systems.