This paper is a companion to a paper by Liang et al. (2011) which reports a causal connection between the intensification of electrostatic ECH waves and the postmidnight diffuse auroral activity in the absence of whistler mode chorus waves at L = 11.5 on the basis of simultaneous observations from THEMIS spacecraft and NORSTAR optical instruments during 8–9 UT on February 5, 2009. In this paper, we use the THEMIS particle and wave measurements together with the magnetically conjugate auroral observations for this event to illustrate an example where electrostatic electron cyclotron harmonic (ECH) waves are the main contributor to the diffuse auroral precipitation. We use the wave and particle data to perform a comprehensive theoretical and numerical analysis of ECH wave driven resonant scattering rates. We find that the observed ECH wave activity can cause intense pitch angle scattering of plasma sheet electrons between 100 eV and 5 keV at a rate of >10−4 s−1 for equatorial pitch angles αeq < 30°. The scattering approaches the strong diffusion limit in the realistic ambient magnetic field to produce efficient precipitation loss of <∼5 keV electrons on a timescale of a few hours or less. Using the electron differential energy flux inside the loss cone estimated based upon the energy‐dependent efficiency of ECH wave scattering for an 8‐s interval with high resolution wave data available, the auroral electron transport model developed by Lummerzheim (1987) produced an intensity of ∼2.3 kR for the green‐line diffuse aurora. Separately, Maxwellian fitting to the electron differential flux spectrum produced a green‐line auroral intensity of ∼2.6 kR. This is in good agreement with the ∼2.4 kR green‐line auroral intensity observed simultaneously at the magnetic foot point (as inferred using the event‐adaptive model of Kubyshkina et al. (2009, 2011)) of the location where the in situ observations were obtained. Our results support the scenario that enhanced ECH emissions in the central plasma sheet (CPS) can be an important or even dominant driver of diffuse auroral precipitation in the outer magnetosphere. This paper is an important compliment to recent work that has shown lower band and upper band chorus to be mainly responsible for the occurrences of diffuse aurora in the inner magnetosphere.