Low-salinity Surface Research Articles

Seasonal and Interannual Salinity Variability on the Northeast U.S. Continental Shelf: Insights From Satellite Sea Surface Salinity and Implications for Stratification

AbstractThe Northeast U.S. continental shelf (NEUS) is a highly productive and economically important region that has undergone substantial changes in recent years. Warming exceeds the global average and several episodes of anomalously warm, sustained temperatures have had profound impacts on regional fisheries. A majority of recent research studies focused on the analysis of temperature; however, salinity can serve as a valuable tracer as well. With now more than a decade of remote‐sensing sea surface salinity data, we shed new light onto salinity variability in the region with focus on the Mid‐Atlantic Bight and assess its role for modulating stratification on the shelf using historical hydrographic data. Local river discharge drives decreasing salinities not only in spring and summer on the shelf but also in the Slope Sea. In spring, fresher water aids the build‐up of stratification and a low salinity surface layer extends to the shelf break above the pycnocline by the beginning of summer. An observed salinification in the fall is linked to offshore forcing over the slope associated with the presence of Warm Core Rings. Coherent low‐frequency salinity variability is found over the slope and shelf, highlighting that shelf conditions are significantly impacted by offshore variability. Conditions on the NEUS in 2015 were characterized by anomalously high salinities, associated with a northerly position of the Gulf Stream. A freshening between 2015 and 2021, is in agreement with increased river cumulative discharge as well as lower offshore salinities. Overall, salinity serves as a valuable additional tracer of these multi‐variate processes.

Missing Argo Float Profiles in Highly Stratified Waters of the Amazon River Plume

Abstract In the western tropical Atlantic Ocean close to the Amazon plume, a large loss rate of Argo-float profiles took place, that is, instances of profiles that should have happened but were not transmitted. We find that APEX and SOLO floats were not ascending to the surface in the presence of low surface practical salinity, typically on the order of 32.5 or less, because of limitations on the surface buoyancy range for those floats. This results in an overall loss of profiles from these floats that is on the order of 6% averaged over the year, with a peak of 12% in July. We also find aborted descents/incorrect grounding detections for ARVOR/PROVOR floats when surface salinity is low and the descending float reaches a strong halocline (2.6% of all the profiles in the June–August season). Altogether, the whole Argo set includes a maximum loss rate of roughly 6% in July. We find a pattern of loss that fits the surface salinity seasonal cycle and the occurrence of low surface salinity investigated from a high-resolution daily satellite salinity product in 2010–21. The agreement is even better when considering surface density instead of surface salinity, with the temperature contribution to density inducing a shift in the maximum occurrence of these events by 1 month relative to the cycle of very low salinity events. Because of changes in the float technology, the loss rate that targets the lowest surface salinities was very large until 2010, with an overall decrease afterward. Significance Statement In the western tropical Atlantic Ocean, some Argo floats were not able to ascend or descend with very low surface salinity, because of buoyancy limitations for some float types and false bottom detection on others. In this region, for surface practical salinity smaller than 32.5, this resulted in a loss of close to one-half of the Argo profiles during the last 20 years. Altogether, this undersampling of the lowest surface salinities by Argo floats modifies the upper-ocean salinity seasonal cycle, as well as longer-term trends portrayed in Argo data–based products. Furthermore, in this region, care must be taken when validating satellite salinity data with Argo data or when adjusting satellite sea surface salinity data to in situ data products.

The Influence of Freshwater Input on the Evolution of the 1995 Benguela Niño

AbstractBenguela Niño events are characterized by strong warm sea surface temperature (SST) anomalies off the Angolan and Namibian coasts. In 1995, the strongest event in the satellite era took place, impacting fish availability in both Angolan and Namibian waters. In this study, we use direct observations, satellite data, and reanalysis products to investigate the impact that the up‐until‐now unnoticed mechanism of freshwater input from Congo River discharge (CRD) and precipitation had on the evolution of the 1995 Benguela Niño. In the onset phase of the event, anomalous rainfall in November/December 1994 at around 6°S, combined with a high CRD, generated a low salinity plume. The plume was advected into the Angola‐Namibia region in the following February/March 1995 by an anomalously strong poleward surface current generated by the relaxation of the southerly winds and shifts in the coastal wind stress curl. The presence of this low surface salinity anomaly of about −2 psu increased ocean stability by generating barrier layers, thereby reducing the turbulent heat loss, since turbulent mixing acted on a weak vertical temperature gradient. A mixed layer heat budget analysis demonstrates that southward advection of Angolan waters drove the warming at the onset, while reduced mixing played the main role at the event's peak. We conclude that a freshwater input contributed to the SST increase in this exceptionally strong event and suggest that this input can influence the SST variability in Angola‐Namibia waters through a combination of high CRD, precipitation, and the presence of a strong poleward surface current.

Seasonal Water Mass Transformation in the Eastern Indian Ocean from In Situ Observations

The Eastern Indian Ocean (EIO) is one of the eastern boundary areas, which control currents circulation and atmospheric dynamics. This research mainly aimed to identify and analyze the water mass transformation in the EIO. The investigated physical properties of the ocean are the temperature, salinity, seasonal temperature–salinity, and water column stability. An extensive amount of in situ data measurements from 1950 to 2018 was downloaded from the global datasets inventory. The visualization and analysis of the data were defined in monthly spatial and vertical profiles. The result showed the mixed layer is shallower during the northwest monsoon relative to the southwest monsoon. The surface water in the EIO is documented to be warmer due to the interaction with the atmosphere. Furthermore, low-salinity surface water around the Java Seas area is caused by a mixing with fresh water from the eastern Indonesia rivers. The data also confirmed that, at latitude 16° S, the maximum salinity occurred at a depth between 150 and 350 m. There are ten types of water masses found in the EIO, which originate from several regions, including the Indonesia Seas, Pacific Ocean, Indian Ocean, and Antarctic. During the northwest and southeast monsoons, a stable layer is found at a depth of 40 to 150 m and 80 to 150 m, respectively. For further research, it is recommended to focus on the coastal region, particularly the Timor Sea and Northwestern Australia, to investigate the dynamics between the Indonesian Throughflow, Holloway Currents, and Leeuwin Currents. Additionally, deep water observations below 800 m are crucial for a comprehensive understanding of the oceanographic variability in the deep layers of the EIO.

Natural copper-binding ligands in the Arctic Ocean. The influence of the Transpolar Drift (GEOTRACES GN04)

The Arctic Ocean is a unique biogeochemical environment characterized by low salinity surface waters, extensive sea-ice coverage, high riverine inputs, large shelf extension and the long residence time of deep waters. These characteristics determine the distribution of dissolved bio-essential trace metals, such as copper (Cu), and the dissolved organic-binding ligands capable of complexing it. This work reports the concentrations and conditional stability constants of dissolved Cu-binding ligands (LCu and log KcondCu2+L) measured in samples from the Polarstern (PS94) expedition, as part of the international GEOTRACES program (cruise GN04). Full-depth profile stations from the Barents Sea, Nansen Basin, Amundsen Basin and Makarov Basin were analysed by competitive ligand exchange-adsorptive cathodic stripping voltammetry (CLE-AdCSV). The basins and water masses presented a wide range of LCu concentrations (range: 1.40 – 7.91 nM) and log KcondCu2+L values (range: 13.83 – 16.01). The highest variability of Cu-binding ligand concentrations was observed in surface waters (≤200 m), and mean concentrations increased from the Barents Sea and Nansen Basin (2.15 ± 0.31 nM and 1.93 ± 0.35 nM, respectively) to the Amundsen (3.84 ± 1.69 nM) and Makarov Basins (4.40± 2.03 nM). The influence of the Transpolar Drift (TDP) flow path was observed in the Amundsen and Makarov Basins, especially on Cu-binding ligand concentrations (LCu range: 3.96 – 7.91 nM). In contrast, deep waters (>200 m) showed no significant differences between basins and water masses in terms of LCu concentrations (range: 1.45 – 2.78 nM) and log KcondCu2+L (range: 14.02 – 15.46). The presence of strong Cu-binding ligands (log KcondCu2+L>13) in surface waters stabilises the excess of dissolved copper (dCu) transported in the TPD and favours its export to the Fram Strait and Nordic Seas.

Artificial fractures conductivity impairment in gas shale when fracturing with surface water

The shale gas fields are mainly in mountainous areas in China. Surface water is the major source of hydraulic fracturing fluid to develop shale gas. The clay mineral is generally rich in the shale gas reservoir. When encountered with low salinity surface water, the clay minerals are easy to hydrate in the process of fracturing and well shut-in. The hydration of clay minerals would result in the expansion, dispersion, and migration of mineral particles from the fracture surface, changing the structure and space of fractures, thereby affecting fracture conductivity. In this paper, shale artificial fracture core models were developed with rough fracture surfaces. With proppant-supported and self-supported fracture core models, the impact of hydration time, net pressure, and dislocation distance of fracture surfaces on the artificial conductivity were evaluated systematically. The results show that the conductivity of proppant-supported and self-supported fractures decreases by 85.3–95.1% under hydration. The turning point of conductivity is 8.0 hrs. and 4.3 hrs., respectively. At the initial stage of production, the artificial fracture could be protected better if the net pressure on the fracture is maintained from small to large. At the same time, the initial net pressure on fracture should be less than the proppant crushing pressure. Certain dislocation distances of self-supported fractures would augment the conductivity by 6.4–12.8 times. After hydration, illite and montmorillonite in the rock surface expanded and dispersed when encountered with water. The fracture surface strength decreases by 29.8%, while the surface roughness decreases by 46.1–51.6%, and some proppants were crushed. Then the fracture conductivity space was reduced. By adding KCl into the fracturing fluid, hydration can be effectively inhibited, which can increase the proppant-supported and self-supported fracture conductivity by 2.5–3.4 times, compared with fracturing fluid prepared with surface water. This study provides a theoretical basis for the optimization of shale gas reservoir fracturing technology and production strategy.

Strong water stratification provides a refuge for rainbow smelt larvae Osmerus mordax in a sub-arctic estuary (Lake Melville, Labrador)

Estuaries provide nurseries for early life stages of fish that rely on the interaction between fresh- and saltwater. The 250 km long Lake Melville spans 2100 km2 and is the largest estuary of Labrador (northeastern Canada). This sub-arctic fjard hosts freshwater, anadromous, and marine fishes on which depend marine mammals and seabirds, but also coastal communities. Yet, how different fish species and life stages use the estuary as a habitat, in particular the importance of the low salinity surface layer for the development of fish larvae, remains unknown. By pairing seasonal hydroacoustic surveys conducted in summers 2018–2019 and winters 2019–2020 with net sampling and environmental DNA (eDNA) analyses, we test the hypothesis that the strong water stratification prevailing in upper Lake Melville provides a nursery for early life stages of fish, where they are protected from their predators. Ichthyoplankton aggregated just above and at the pycnocline, in the low salinity surface layer down to 25 m. Most adult pelagic fish occupied the bottom waters below the sharp pycnocline, although some ventured in the low salinity surface layer. Ten species of adult fish were captured in gill and fyke nets and 53 species were detected with eDNA. Larvae of rainbow smelt (Osmerus mordax) were ubiquitous in the surface layer in July and August and represented 100% of the ichthyoplankton assemblage sampled during these months. No fish larvae were detected in winter (February). We conclude that the low salinity surface layer provides a refuge for rainbow smelt larvae, a key forage species in the estuary. This study provides baseline information from which to assess future changes in biodiversity and distribution of fish in the Lake Melville estuary. It further supports the use of eDNA as a complementary tool for monitoring fish diversity in sub-arctic estuaries.

Biofilm formation and cell plasticity drive diazotrophy in an anoxygenic phototrophic bacterium.

The contribution of non-cyanobacterial diazotrophs (NCDs) to total N2 fixation in the marine water column is unknown, but their importance is likely constrained by the limited availability of dissolved organic matter and low O2 conditions. Light could support N2 fixation and growth by NCDs, yet no examples from bacterioplankton exist. In this study, we show that the phototrophic NCD, Rhodopseudomonas sp. BAL398, which is a member of the diazotrophic community in the surface waters of the Baltic Sea, can utilize light. Our study highlights the significance of biofilm formation for utilizing light and fixing N2 under oxic conditions and the role of cell plasticity in regulating these processes. Our findings have implications for the general understanding of the ecology and importance of NCDs in marine waters.

A seasonally ice-free Arctic Ocean during the Last Interglacial

AbstractThe extent and seasonality of Arctic sea ice during the Last Interglacial (129,000 to 115,000 years before present) is poorly known. Sediment-based reconstructions have suggested extensive ice cover in summer, while climate model outputs indicate year-round conditions in the Arctic Ocean ranging from ice free to fully ice covered. Here we use microfossil records from across the central Arctic Ocean to show that sea-ice extent was substantially reduced and summers were probably ice free. The evidence comes from high abundances of the subpolar planktic foraminifera Turborotalita quinqueloba in five newly analysed cores. The northern occurrence of this species is incompatible with perennial sea ice, which would be associated with a thick, low-salinity surface water. Instead, T. quinqueloba’s ecological preference implies largely ice-free surface waters with seasonally elevated levels of primary productivity. In the modern ocean, this species thrives in the Fram Strait–Barents Sea ‘Arctic–Atlantic gateway’ region, implying that the necessary Atlantic Ocean-sourced water masses shoaled towards the surface during the Last Interglacial. This process reflects the ongoing Atlantification of the Arctic Ocean, currently restricted to the Eurasian Basin. Our results establish the Last Interglacial as a prime analogue for studying a seasonally ice-free Arctic Ocean, expected to occur this century.

The Bay of Bengal exposes abundant photosynthetic picoplankton and newfound diversity along salinity-driven gradients.

The Bay of Bengal (BoB) is a 2,600,000 km2 expanse in the Indian Ocean upon which many humans rely. However, the primary producers underpinning food chains here remain poorly characterized. We examined phytoplankton abundance and diversity along strong BoB latitudinal and vertical salinity gradients-which have low temperature variation (27-29°C) between the surface and subsurface chlorophyll maximum (SCM). In surface waters, Prochlorococcus averaged 11.7 ± 4.4 × 104 cells ml-1 , predominantly HLII, whereas LLII and 'rare' ecotypes, HLVI and LLVII, dominated in the SCM. Synechococcus averaged 8.4 ± 2.3 × 104 cells ml-1 in the surface, declined rapidly with depth, and population structure of dominant Clade II differed between surface and SCM; Clade X was notable at both depths. Across all sites, Ostreococcus Clade OII dominated SCM eukaryotes whereas communities differentiated strongly moving from Arabian Sea-influenced high salinity (southerly; prasinophytes) to freshwater-influenced low salinity (northerly; stramenopiles, specifically, diatoms, pelagophytes, and dictyochophytes, plus the prasinophyte Micromonas) surface waters. Eukaryotic phytoplankton peaked in the south (1.9 × 104 cells ml-1 , surface) where a novel Ostreococcus was revealed, named here Ostreococcus bengalensis. We expose dominance of a single picoeukaryote and hitherto 'rare' picocyanobacteria at depth in this complex ecosystem where studies suggest picoplankton are replacing larger phytoplankton due to climate change.

Structure of the Ob-Yenisei plume in the Kara Sea shortly before autumn ice formation

The major Siberian rivers form large river plumes in the Arctic Ocean, which govern structure of the sea surface layer at the Arctic shelf. These river plumes were explicitly studied during the warm period in summer and early autumn characterized by high river runoff and ice-free conditions. However, little is known about processes, which occur within these river plumes at the beginning of the cold season, i.e., during late autumn shortly before sea ice formation. In this study, we report in situ measurements performed in the Kara Sea in late October in 2020, 2021, and 2022. We reveal that intense convection occurs in the Ob-Yenisei plume due to heat loss from the surface layer, which is caused by transport of cold air from land to the central part of the Kara Sea. This process induces homogenization of the Ob-Yenisei plume and results in extremely sharp salinity jump (up to 10-12 at vertical distance of 1-2 m) between the plume and the subjacent seawater. This sharp gradient is not formed at the whole area of the plume except, first, at the Ob and Yenisei gulfs due to low surface salinities and the related high temperatures of maximal density and, second, at the lateral boundary of the plume due to intense horizontal mixing across the plume-sea border. As a result, autumn convection significantly modifies vertical structure of the Ob-Yenisei plume that could affect its further spreading below sea ice during winter season.

СЕЗОННАЯ ИЗМЕНЧИВОСТЬ ВОДООБМЕНА МЕЖДУ ТИХИМ И ИНДИЙСКИМ ОКЕАНАМИ ПО ДАННЫМ АРГО И ЧИСЛЕННОГО МОДЕЛИРОВАНИЯ

Circulation associated with the Indonesian Troughflow (ITF) is studied using the Argo-based Model for Investigation of the Global Ocean (AMIGO). The model consists of a block for variational interpolation to a regular grid of Argo floats data and a block for model hydrodynamic adjustment of variationally interpolated fields. The seasonal and monthly mean temperature, salinity and velocity fields were calculate for the period of 2005–2014 using such an aproach. The mean ITF mass, heat, and salt transports over a period of 2005–2014 based on the AMIGO data is diagnosed as 15.2 ± 2.3 Sv. The maximum value of mass transport was diagnosed in August as 18.8 ± 1.4 Sv, the minimum value of 11.8 ± 2.1 Sv was found in January. The detailed analisys of seasonal variability of the mass transport through the Makassar Strait (Makassar throughflow or MT), the primary inflow path of Pacific water into the Indonesian Seas, were performed. The maximum and minimum values of MT were also diagnosed in August and January as 22.1 ± 1.2 Sv and 9.8 ± 2.1 Sv respectively. It was found significant changes in the MT sutface layer flow during boreal winter (with total reverse in January) associated with the intrusion of the low surface salinity waters of the Java and South China Seas. These modeling results agree very well with the direct velocity measurements.

Spatial distribution of arctic sand lance in the Chukchi Sea related to the physical environment

Sand lance or sand eels (Ammodytes spp.) are small planktivorous forage fishes that play an integral role in pelagic ecosystems in the Northern Hemisphere. Arctic sand lance (Ammodytes hexapterus) is prevalent in the North Pacific in the Sea of Okhotsk, northern Bering Sea, Chukchi Sea, and Beaufort Sea. Few studies have focused on this species despite its critical position in energy transfer and trophic food webs. Recent surveys in the Chukchi Sea and Beaufort Sea have noted an increase in the prevalence of this species in concert with reduced ice extent. Sand lance are unique among forage species in having close associations with specific water column conditions as well as a reliance on specific sand substrates for burrowing. Life history and habitat dependency is influenced by both dynamic oceanographic conditions and static benthic substrata. This taxa, therefore, provides a unique opportunity to examine the potential expansion of a boreal species into Arctic marine habitats. We use comprehensive surveys conducted throughout the Chukchi Sea shelf over multiple years to evaluate spatial distribution and abundance relative to oceanographic variables in the water column and sediment composition on the seafloor. We applied logistic regression and generalized additive models to investigate presence and relative abundance of Arctic sand lance and to evaluate spatial distribution, as a function of oceanographic and benthic environmental variables. Spatial distribution shifted considerably between years in response to environmental conditions. Arctic sand lance presence was influenced by surface water mass and positively associated with Alaskan Coastal Water. Relative abundance was positively associated with high surface temperature, low surface salinity, and coarser substrates. Evidence is mounting that the distributions of many boreal species are expanding on the margins of the Arctic. Our research reports increased aggregations of Arctic sand lance in the Chukchi Sea and at the highest latitude on record for this species, at the shelf break of the Arctic Basin.

Efficient removal of micropollutants from low-conductance surface water using an electrochemical Janus ceramic membrane filtration system

Electrochemical membrane filtration (EMF) technology is effective to remove the micropollutant in the wastewater but its efficacy is drastically compromised in treating the surface water having a typically low conductivity. In this work, a Janus Fe-Pt electrochemical ceramic membrane (ECM) was fabricated by depositing a thin Fe layer on the side of a ceramic membrane facing feed (cathode) and Pt layer on the other side facing permeate (anode). The low Fe-Pt electrode distance (∼1 mm) ensured a decent conductance of the EMF system even in the low-salinity surface water and thereby maintained the removal efficiency of the micropollutant. It was identified that hydroxyl radicals (•OH) generated via anodic water oxidation and cathodic heterogenous Fenton process on bilateral sides of ECM were the dominant reactive oxygen species. The EMF system not only achieved 74% removal of atrazine (ATZ) from the low-conductance synthetic surface water with a low energy consumption (3.6 Wh per gATZ or 7.2 Wh m − 3), but also realized a stable removal of ATZ from real surface water over a continuous filtration experiment of 168 h. The theoretical computations and experimental analysis identified the degradation pathway, i.e., the dechlorination and dealkylation of ATZ in the EMF system. This study highlights the great potential of the Janus ECM in removing micropollutants from low-conductance surface water and wastewater.

Distributions and Influencing Factors of Dissolved Manganese in Kongsfjorden and Ny-Ålesund, Svalbard

The contributions of polar glaciers to the global distribution of trace metals have attracted an increasing amount of attention due to global warming. To better understand the distributions and influencing factors of dissolved manganese (dMn) in the Arctic, samples were collected in Ny-Ålesund and Kongsfjorden in Svalbard in August 2013. dMn concentrations in the drainage basin of the Bayelva River, of which the average value was 216.4 ± 54.2 nM (n = 16) and higher than that in other polar rivers and lakes, showed no significant differences from upstream to downstream in August. dMn varied differently at certain stations in the mainstream of Bayelva River on different days due to complex factors in the polar region, e.g., topography, tributaries, groundwater, organic matter content, and runoff fluxes. It was estimated that the scale length (distance from the initial concentration to 1/e) of dMn in the coastal area of the Bayelva River was 1050 m, indicating that the influence of Bayelva River on the distributions of dMn in Kongsfjorden was insignificant. Affected by high-dMn concentration tidewater glacier meltwater (∼581.1 nM) in the inner fjord, dMn showed an increasing trend from the fjord entrance to the inner zone in the surface layer of Kongsfjorden. Furthermore, the longer scale length (4.25 km) and overlying relatively large discharge suggested a higher incidence of tidewater glaciers in Kongsfjorden. The vertical distributions of dMn presented obvious stratification, with higher dMn at the surface (80.9 ± 53.7 nM, n = 21) and lower dMn below the surface (12.6 ± 2.4 nM, n = 11). Combined with the water mass properties and flow field, the distributions of dMn in Kongsfjorden were mainly controlled by relatively high dMn concentrations, low-salinity surface water, relatively low dMn concentrations, and high-salinity Atlantic water mixing. The dMn concentrations in Ny-Ålesund and Kongsfjorden were significantly higher than those in the North Atlantic Ocean and Arctic Ocean around Svalbard. Tidewater glaciers (Kongsvegen, Kronebreen, and Kongsbreen) and glaciers of Svalbard were estimated to export 0.46 and 74 Mmol/year of dMn, which was comparable to other sources to the Arctic Ocean. The contributions of glaciers to the distributions of dMn in the Arctic and global Ocean were expected to be increasingly significant considering the increasing amount of glacier meltwater in the context of global warming.

Freshening of Great Barrier Reef waters is deleterious for larval crown-of-thorns starfish, counter to the terrestrial runoff hypothesis

Outbreak populations of crown-of-thorns starfish (COTS; Acanthaster spp.) cause widespread coral mortality. High nutrient river runoff generates phytoplankton blooms that potentially enhance larval food levels and success leading to outbreaks, a link posited by the terrestrial runoff hypothesis (TRH). Runoff plumes also lower salinity, although the parallel and potentially negative effects of freshening on COTS larvae have not been considered. The impact of decreased salinity across a range of food levels on larval development and survival was investigated in context with the TRH. Larval survival and incidence of bipinnaria larvae with normal morphology in 6-7 salinities and 3 food treatments were quantified, at 4 time points, to generate salinity performance curves. Salinity was the major factor determining bipinnaria larval survival. At 24 h of exposure, the optimal salinity (Sopt) (≥90% larval survival) was ~26-34‰, and the salinity with 50% mortality (LS50) was 21.8‰. By 168 h, the LS50 was 27.3‰, showing a narrowing of salinity tolerance over time. Low salinity impaired swimming, resulting in larvae sinking at <25-30‰. This was not due to halted ciliary beating and may be a mechanism to escape deleterious low-salinity surface water. The sharp onset of deleterious effects at 22-25‰ is commensurate with salinity levels that larvae would experience in runoff plumes. Counter to the hypothesis of eutrophic enhancement of larval success and outbreaks, a paradigm that has driven management regulations for decades, runoff plumes are likely to be deleterious for COTS bipinnaria larvae.

Interannual Variability of Surface Salinity and Ekman Pumping in the Canada Basin During Summertime of 2003–2017

AbstractThe Canada Basin (CB) is undergoing significant changes due to long‐term global climate change, and other shorter time‐scale processes that are still not well understood. Based on the in‐situ and satellite observations and atmospheric reanalysis data, interannual variabilities of sea surface salinity and Ekman pumping in the CB are investigated in the summertime of 2003–2017. This study reveals strong surface salinity reduction and Ekman downwelling enhancement during 2006–2012 compared with the remaining years. The surface 20‐m salinity averaged in 2006–2012 decreases by 1.26 PSU relative to the other years. The results suggest that the lower surface salinity is correlated to enhanced sea ice melt and Ekman convergence in the CB. Enhanced downward solar radiation accounts for the accelerated sea ice melt over the southeast CB, leading to the surface salinity decrease. Strengthened anticyclonic wind circulation over the CB not only enhances sea ice melt via strengthening offshore Ekman transport over the Chukchi Sea slope, but also favors freshwater accumulation in the CB through strengthening the horizontal convergence. The sea ice melt is estimated to account for 54% of the surface freshening, and the horizontal convergence is believed to play an important role in the remaining 46%. During the freshening years in the CB, the Ekman downwelling enhancement is mainly attributed to variations of wind stress curl, sea ice concentration, and ice‐ocean stress curl, and their relative contributions are estimated on the basis of on a linearized model as 72%, 12%, and 10%, respectively.

Subpolar Gyre – AMOC – Atmosphere Interactions on Multidecadal Timescales in a Version of the Kiel Climate Model

AbstractThere is a controversy about the nature of multidecadal climate variability in the North Atlantic (NA) region, concerning the roles of ocean circulation and atmosphere-ocean coupling. Here we describe NA multidecadal variability from a version of the Kiel Climate Model, in which both subpolar gyre (SPG)-Atlantic Meridional Overturning Circulation (AMOC) and atmosphere-ocean coupling are essential. The oceanic barotropic and meridional overturning streamfunctions, and sea level pressure are jointly analyzed to derive the leading mode of Atlantic sector variability. This mode accounting for 23.7 % of the total combined variance is oscillatory with an irregular periodicity of 25-50 years and an e-folding time of about a decade. SPG and AMOC mutually influence each other and together provide the delayed negative feedback necessary for maintaining the oscillation. An anomalously strong SPG, for example, drives higher surface salinity and density in the NA’s sinking region. In response, oceanic deep convection and AMOC intensify, which, with a time delay of about a decade, reduces SPG strength by enhancing upper-ocean heat content. The weaker gyre leads to lower surface salinity and density in the sinking region, which reduces deep convection and eventually AMOC strength. There is a positive ocean-atmosphere feedback between the sea surface temperature and low-level atmospheric circulation over the Southern Greenland area, with related wind stress changes reinforcing SPG changes, thereby maintaining the (damped) multidecadal oscillation against dissipation. Stochastic surface heat-flux forcing associated with the North Atlantic Oscillation drives the eigenmode.

Copper isotope evidence of particulate shuttle dynamics in the Late Pennsylvanian North American Midcontinent Sea, with implications for glacio-eustatic magnitude

The North American Midcontinent Sea (NAMS) covered a vast area during Late Pennsylvanian glacio-eustatic highstands, providing a laboratory for analysis of the internal watermass dynamics of large cratonic seas (of which few exist in the Recent). In this study, a novel proxy, copper (Cu) isotopes, was used to gain a better understanding of NAMS watermass dynamics. We analyzed the 63-cm-thick Stark Shale (Dennis Formation, Missourian Stage, Upper Pennsylvanian) in the Iowa Riverton core (IRC) at a centimeter scale in order to reconstruct secular variations in Cu-isotopic compositions (δ65Cu) and other geochemical proxies. The gray shale facies yielded δ65Cu of +0.02 ± 0.06‰ (2σ, n = 14), similar to detrital Cu in modern marine sediments (δ65Cu = +0.08 ± 0.20‰; 2σ, n = 42). In contrast, the black shale facies, in which the proportion of authigenic Cu hosted by the organic fraction is 50–100% of total Cu content, exhibits heavier δ65Cuauth values, mostly between +0.09 and +0.43‰. In modern marine systems, one of the main processes leading to 65Cu-enriched sediment compositions is adsorption of aqueous Cu onto Fe-Mn particulates. The black shale facies of the Stark Shale exhibits four peaks in Mo/U ratios that are indicative of an active particulate shuttle because of the tendency of Mo to adsorb more strongly than U to Fe-Mn particulates. The Sr/Ba ratio, a paleosalinity proxy, shows correlated variations, with high values (indicative of more fully marine conditions) linked to low Mo/U and light δ65Cu, and low values (indicative of brackish conditions) linked to high Mo/U and heavy δ65Cu. These considerations suggest that the flux of isotopically heavy Cu to the sediment–water interface via Fe-Mn cycling was enhanced during brackish intervals, with subsequent reductive dissolution of Fe-Mn particulates allowing transfer of hydrogenous Cu to the organic fraction of the sediment. Control of δ65Cu by Fe-Mn cycling is supported by the results of a sequential extraction experiment showing that organic δ65Cu is positively correlated with Mo/U. These findings provide evidence of large fluctuations in watermass salinity and sea-level elevation within the NAMS at timescales of ∼104 yr during core shale deposition, as previously inferred but not conclusively demonstrated until now. The dynamics of particulate shuttle operation suggest that sea-level fluctuations must have had amplitudes of at least a few tens of meters. These fluctuations ended during the final stages of black shale deposition, probably owing to overall sea-level fall and permanent shallowing of the study site into the oxic, low-salinity surface layer of the NAMS.

Solar radiation and solar radiation driven cycles in warming and freshwater discharge control seasonal and inter‐annual phytoplankton chlorophyll a and taxonomic composition in a high Arctic fjord (Kongsfjorden, Spitsbergen)

AbstractFjords on the west coast of Spitsbergen experience variable Arctic and Atlantic climate signals that drive seasonal and inter‐annual variability of phytoplankton productivity and composition, by mechanisms that are not fully resolved. To this end, a time series (2013–2018) of Kongsfjorden (N 78°54.2, E 11°54.0) phytoplankton pigments, ocean physics, nutrient concentrations, and microbial abundances was investigated. Kongsfjorden phytoplankton dynamics were predominantly governed by solar radiation and cycles of warming and freshwater discharge that caused pronounced changes in light and nutrient availability. Phytoplankton growth after the polar night commenced in March in a mixed, nutrient loaded water column, and accelerated in April after weak thermal stratification. Spring (weeks 10–22) showed high diatom relative abundance that ceased when silicic acid and nitrate reached limiting concentrations. Summer (weeks 23–35) was characterized by sixfold stronger stratification due to increased freshwater discharge and continued ocean heating. This caused a warm, low salinity surface layer with low nutrient concentrations. Small and diverse flagellates, together with high bacterial and viral abundances, thrived in this regenerative, N or P‐limited system. Elevated late summer chlorophyll a (Chl a), and ammonium suggested increased regeneration and nutrient pulses by glacial upwelling. Fall (weeks 36–48) caused rapidly declining Chl a and increasing diatom relative abundance, which persisted throughout the polar night, causing high diatom relative abundance during spring. Despite inter‐annual variability in ocean temperature and salinity we observed relatively stable seasonal phytoplankton taxonomic composition and Chl a.