Abstract. An analysis of modern capital construction state shows that the material and technical base of the construction industry does not allow the production of effective building materials and products in the required quantity without due consideration of the economic burden on the environment, and now significant financial costs are required to restore the ecological balance of the natural zone. Power plant fly ash is a man-made raw material for many industries, which is utilized up to 92% in dry form and is of practical interest in the production of effective thermal insulation building materials and products as a filler and an aggregate. In view of the instability of the chemical and mineralogical composition, the content of raw fuel, as well as the pozzolanic activity, the study of the profitability of the production of pozzolanic cements and concretes based on them was carried out, with an increase in sulfate resistance, corrosion resistance of the aggregate while preventing thermal cracking. The expediency of autoclaved gas-ash-slag concretes production with the use of cement with high content of highly basic minerals ‒ alite and tricalcium aluminate is proved. The technology of obtaining ash-alkaline cellular concrete using ash-removal and alkaline component is given. The economic efficiency of cellular ash-containing concretes is justified by the replacement of sand with ash, a 1.2-1.5-fold reduction in lime consumption compared to lime-sand concrete and a reduction of approximately 2 times the capital costs for extraction and processing of raw materials. Comparative physical and mechanical parameters of autoclave and non-autoclave aerated concrete products are given. The process of manufacturing products by vibro-vacuuming and vibratory compaction of ash concrete is presented. The strength data of vacuum concrete are given, which are 30-40% higher than that of vibro- compacted concrete from a rigid mixture. The investigated value of shrinkage as a result of the water-reducing effect of ash, provides a decrease in the water-cement ratio of concrete. Autoclaved and non-autoclaved aerated concrete can compete with such an effective thermal insulation material as mineral wool. They are more effective materials for low-rise and frame housing construction than traditional brick and concrete.