The constant temperature rise on the solar panel surface causes a deterioration of electrical power generation. This article is provided with the performance of photovoltaic thermal (PVT) collector through cerium oxide with water as a base fluid. A small percentage of incoming radiation is transformed into electricity and rest of them is wasted as hot energy, the panel surface temperature will confine the performance of PV module. The research's objectives were to develop and construct a photovoltaic/thermal collector and evaluate its thermal and electrical energy as an output. The experimental investigation of PVT collector with two different concentration of cerium oxide 0.5 and 1.0 LPM (litres per minute). As per the investigations on the PVT collector results were obtained as electrical performance of collector was attained about 18.56 %, 19.12 % for the flow rate of 0.5 and 1.0 LPM. Similarly, thermal performance was achieved 48.38 %, 54.03 % for the flow rate of 0.5 and 1.0 LPM. Thermal conductivity of cerium oxide nano fluid was much better than the air and water. It was observed that employing a nano fluid to the receiver might increase the efficiency around 5–10 %, compared to utilising water as a base fluid, water can only generate 3–7 %. As a cooling medium, air has a relatively low production capacity between 2 and 3 %.
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