Low Power Conversion Research Articles

Unravelling Structural, Optical, and Band Alignment Properties of Mixed Pb-Sn Metal-Halide Quasi-2D Ruddlesden-Popper Perovskites.

Lead-tin (Pb-Sn) mixed-halide perovskites show potential for single-junction and tandem solar cells due to their adjustable band gaps, flexible composition, and superior environmental stability compared to three-dimensional (3D) perovskites. However, they have lower power conversion efficiencies. Understanding band alignment and charge carrier dynamics is essential for enhancing photovoltaic performance. In this view, herein we have prepared thin films of mixed Pb-Sn-based two dimensional (2D) Ruddlesden-Popper (RP) perovskites BA2FA(Pb1-xSnx)2I7 using a solution-based method. XRD study revealed the formation of orthorhombic phases for pristine (BA2FAPb2I7) and mixed Pb-Sn perovskite thin films. UV-vis analysis showed that different n = 2 and n = 3 phases are present in the pristine sample. In contrast, Pb-Sn-doped samples showed no signature of other phases with a prominent red-shift in the visible spectral region. Cyclic voltammetry showed peaks for electron transfers at the band edges. Additionally, electrochemical and optical band gap matching was observed, along with decreased peak intensity due to less reactant and altered electrolyte-perovskite interface stability. Density functional theory (DFT) calculations revealed that the reduced band gap is due to the alteration of electrostatic interactions and charge distribution within the lattice upon Sn substitution. Low-temperature PL analysis provided insights into charge carrier dynamics with Sn substitution and suggested the suppression of higher n phases and self-trapped excitons/carriers in mixed Pb-Sn quasi-2D RP perovskite thin films. This study sheds light on the electron transfer phenomena between TiO2 and SnO2 layers by estimating band offsets from valence band maximum (VBM) and conduction band minimum (CBM), which is crucial for future applications in fabricating stable and efficient 2D-Pb-Sn mixed perovskites for optoelectronic applications.

Modeling, design and validation of DC-DC landsman converter for low-power electric vehicle battery charging applications

As the world moves towards sustainable development, the reduction of air pollution is considered an important factor. Consequently, the transportation sector is moving from conventional internal combustion engine vehicles to electric vehicles (EVs). To encourage EV usage, governments are working towards installing more public charging systems. These systems invariably use a DC-DC converter to ensure the supply of an appropriate voltage to charge the battery. In developing countries, the majority of users prefer electric bikes and electric rickshaws, which require low power. Therefore, it becomes necessary to use low-power converters suitable to charge these batteries. In such systems, non-isolated DC-DC converters play an important role. This work is intended to explore the use of the Landsman converter for EV battery charging. The motivation behind the work is explained, and the state of the art of EV battery charging research is reviewed to show the research gap. The operation of the proposed converter is explained in detail with its dynamic loop and nodal equations. The gain equation and the memory elements design are detailed with the corresponding equations. The model of the proposed converter is provided with the loss calculation. The system is simulated on MATLAB R2022b software, and the simulation results are provided to show the behavior of voltage and current in each component. To validate the design, a 100 W hardware prototype is implemented using discrete components to supply a resistive load, and to charge a 48 V Li-ion battery. The corresponding results are provided to validate the design and operation. A comparison of the proposed converters’ performance parameters with other non-isolated converters is provided. The topology is seen to provide an instantaneous efficiency of 88% during the prototype testing for resistive load, and an efficiency of 89.6% while charging a 48 V Li-ion battery, wherein, the efficiency magnitudes are the experimental values obtained through real-time measurements on Keysight IntegraVision Power Analyzer PA2203A, during the testing of the hardware prototype, as presented in section . Consequently, Landsman converter is seen to be an attractive converter for EV battery charging applications.

Influence of platform motion on the energy production of a floating wind farm

This study investigates the dynamics of energy production in floating wind farms. Unlike their bottom-fixed counterparts, floating wind turbines experience large-amplitude, low-frequency movements affecting the rotor response and the wake development. We employed the multi-physics simulator FAST.Farm to study a seven-turbine wind farm, comparing conventional monopile foundations with semi-submersibles. Results show that, under undisturbed wind conditions, floating turbines exhibit a lower power-conversion efficiency due to platform tilt and the use of a thrust clipping controller. Conversely, waked turbines in a floating configuration have a higher power output than with a bottom-fixed foundation. This is attributed to the higher wind speed in their wake which is due to the lower thrust set point of the floating controller, the vertical deflection of the wake and the dynamic conditions at rotor created by motion.

Exploring the influence of pressure-induced semiconductor-to-metal transition on the physical properties of cubic perovskites FrXCl3 (X = Ge and Sn)

Even though lead halide perovskites have outstanding physiochemical properties and improved power conversion efficiency, most of these compounds threaten their future commercialization because of their instability and highly toxic nature. Thus, it is preferable to use stable alternative elements rather than lead to make environmentally friendly perovskite material that will have comparable optical and electronic properties to those constructed from Pb-based perovskites. However, devices constructed from lead-free perovskites typically display a lower power conversion efficiency. Applying hydrostatic pressure could be deemed an effective method to alter the physical properties of these compounds. This not only improves their performance in application but also reveals significant correlations between structure and properties. This work uses DFT to investigate the structural, electronic, optical, and elastic properties of non-toxic, francium-based halide perovskites FrXCl3 (X = Ge, Sn) at different levels of hydrostatic pressures that vary from 0 to 10 GPa. The estimated structural parameter's strong correlation with the data from earlier studies ensures the accuracy of the current findings. Pressure causes the Fr−Cl and Ge (Sn)–Cl bonds to shorten and become stronger. The electronic property calculations demonstrated that both compounds are direct band-gap semiconductors. The application of pressure leads to a linear reduction in the band gap (semiconducting to metallic state) and raises the electronic density of states around the Fermi level by forcing the valence band electrons upward, indicating that the optoelectronic device's performance can be tuned and improved. The values of the dielectric constant, absorptivity and reflectivity showed an increasing tendency with pressure. As the pressure applied to the compounds increases, the absorption spectra show a redshift. These findings suggested that the FrXCl3 (X = Ge and Sn) compound becomes more appropriate for usage in optoelectronic applications under pressure. Furthermore, our examination of the mechanical properties indicates that both FrGeCl3 and FrSnCl3 exhibit mechanically stability, and ductility. Interestingly, we observe an increase in ductility as pressure levels rise.

Electron injection and defect passivation for high-efficiency mesoporous perovskite solar cells.

Printable mesoscopic perovskite solar cells (p-MPSCs) do not require the added hole-transport layer needed in traditional p-n junctions but have also exhibited lower power conversion efficiencies of about 19%. We performed device simulation and carrier dynamics analysis to design a p-MPSC with mesoporous layers of semiconducting titanium dioxide, insulating zirconium dioxide, and conducting carbon infiltrated with perovskite that enabled three-dimensional injection of photoexcited electrons into titanium dioxide for collection at a transparent conductor layer. Holes underwent long-distance diffusion toward the carbon back electrode, and this carrier separation reduced recombination at the back contact. Nonradiative recombination at the bulk titanium dioxide/perovskite interface was reduced by ammonium phosphate modification. The resulting p-MPSCs achieved a power conversion efficiency of 22.2% and maintained 97% of their initial efficiency after 750 hours of maximum power point tracking at 55 ± 5°C.

A Coordinate Positioning Technique Based on Region Partitioning for EV Wireless Charging System

The performance of wireless charging systems is very sensitive to the relative position of couplers. A small displacement between the transmitting and the receiving coils may lead to severe efficiency drop and degradation in system performance. Therefore, it is necessary to include a positioning-technique-based parking guiding program in EV wireless charging systems. To offer fast and clear location information of the couplers to the driver or automatic parking program, a coordinate positioning technique based on region partitioning for determining the relative position between the transmitting and receiving coils as well as the correct moving direction of the receiving coil is proposed in this paper. Meanwhile, a simple exciting circuit is also proposed to energize the source coil. Therefore, the proposed positioning system consists of the transmitting coil, receiving coil, two auxiliary coils and the corresponding low power converters. With the proposed technique, an EV can move to the near-perfect-coupling zone. Theoretical analysis and experimental verifications are provided.

Regulating the Quantum Dots Integration to Improve the Performance of Tin–Lead Perovskite Solar Cells

AbstractDespite their advantageous attributes, such as a narrow bandgap and reduced toxicity, tin–lead halide perovskites (TLHPs) have received limited attention due to their lower power conversion efficiency (PCE) relative to lead‐only variants. In this study, a transformative approach is introduced that leverages perovskite quantum dots (PQDs) to optimize TLHP solar cells. While conventional oleyl‐capped PQDs enhance the open circuit voltage (VOC), the long‐chain ligands hinder charge transport. To overcome this limitation, a post‐treatment with isopropyl alcohol effectively dissociates these ligands and PQD crystals, resulting in reduced defect density, improved charge transfer, and elevated quasi‐Fermi level splitting in the TLHP device. Consequently, the PCE of the device is notably increased from 19.0% to 23.74% and elevated the VOC from 0.78 to 0.87 V, without compromising the photocurrent or fill factor. The findings highlight PQD modification as a compelling avenue for TLHP solar cell enhancement, particularly in boosting VOC.

An Energy-based Analysis of High Voltage Resonant-based Pulsed Low Power Converter for Water Treatment Application

An Energy-based Analysis of High Voltage Resonant-based Pulsed Low Power Converter for Water Treatment Application

Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells

Compared with the n-i-p structure, inverted (p-i-n) perovskite solar cells (PSCs) promise increased operating stability, but these photovoltaic cells often exhibit lower power conversion efficiencies (PCEs) because of nonradiative recombination losses, particularly at the perovskite/C 60 interface. We passivated surface defects and enabled reflection of minority carriers from the interface into the bulk using two types of functional molecules. We used sulfur-modified methylthio molecules to passivate surface defects and suppress recombination through strong coordination and hydrogen bonding, along with diammonium molecules to repel minority carriers and reduce contact-induced interface recombination achieved through field-effect passivation. This approach led to a fivefold longer carrier lifetime and one-third the photoluminescence quantum yield loss and enabled a certified quasi-steady-state PCE of 25.1% for inverted PSCs with stable operation at 65°C for >2000 hours in ambient air. We also fabricated monolithic all-perovskite tandem solar cells with 28.1% PCE.

Isomeric Effect of a π Bridge in an IDT-Based Nonfused Electron Photovoltaic Acceptor.

A pair of isomers, IDT-BOF containing S⋅⋅⋅O/F⋅⋅⋅H noncovalently configurational locks and IDT-BFO containing F⋅⋅⋅H/O⋅⋅⋅H noncovalently configurational locks, with an acceptor-π-donor-π-acceptor (A-π-D-π-A) structure have been designed and synthesized by choosing 4,9-dihydro-s-indaceno[1,2-b : 5,6-b']dithiophene (IDT) as the D unit, an F/n-hexyloxy substituted phenyl ring as π bridge, and 3-(dicyanomethylidene)indan-1-one as the A unit. Owing to the S⋅⋅⋅O/F⋅⋅⋅H or F⋅⋅⋅H/O⋅⋅⋅H noncovalently configurational locks, both IDT-BOF and IDT-BFO have a completely planar structure. IDT-BOF exhibits a similar LUMO to IDT-BFO, but higher HOMO energy levels, leading to a smaller optical bandgap and red-shifted absorption. However, IDT-BOF-based bulk-heterojunction organic solar cells (BHJ-OSCs) coupled with PBDB-T, and PCE-10 as donor materials both exhibited a lower PCE than that of IDT-BFO (PBDB-T: 5.2 vs. 6.1 %; PCE-10: 1.7 vs. 3.2 %). Comprehensively comparing and investigating IDT-BOF : PBDB-T and IDT-BFO : PBDB-T OSCs suggested that the large phase separation and serious charge recombination of IDT-BOF-based OSCs contributed to its lower power conversion efficiency. Importantly, ternary solar cells based on PBDB-T : Y5 as control devices with an additional 10 % IDT-BFO exhibited a 5 % enhancement in the PCE compared to the control device (14.3 vs. 13.46 %).

An Extraordinary Antisolvent Ethyl Cyanoformate for Achieving High Efficiency and Stability P3HT‐Based CsPbI3 Perovskite Solar Cells

AbstractSurface defects are always a severe problem in inorganic perovskite, superadding the mismatch of energy level between Poly(3‐hexylthiophene) (P3HT) hole transport layer (HTL) and CsPbI3 perovskite. All these issues result in large losses in open‐circuit voltage (Voc) and fill factor (FF), and thus, CsPbI3 perovskites solar cells (PSCs) based on P3HT HTL commonly show a lower power conversion efficiency (PCE). Herein, an extraordinary antisolvent engineering is proposed by ethyl cyanoformate (EC), that regulates the crystallization progress to improve the quality of CsPbI3 perovskite film. Concomitantly, residual EC passivates the uncoordinated Pb2+ defects by synergistical chemical interaction of C≡N and C═O groups, and energy level arrangement at the CsPbI3/P3HT interface is also optimized. As a result, the PCE of P3HT‐based CsPbI3 PSC is improved to 18.46% from 17.33% of the control device. The unencapsulated CsPbI3 PSCs show enhanced moisture stability and fine operational stability. The work reveals that EC is an extraordinary antisolvent, exhibiting a synergistic strategy in many aspects for obtaining high‐performance P3HT‐based CsPbI3 PSCs. Furthermore, P3HT is doped with a small amount of 4‐Cyano‐4′‐pentylbipheny (5CB), and thus the PCE of PSC is increased to 19.15% and its humidity stability is significantly improved.

Photosensitivity reversal in solution-processed Copper Zinc Tin Sulphide/Cadmium Sulphide superstrate junction

Inverse photosensitivity is a sought-after property for the development of photonic devices and non-volatile memories with low power conversion. Herein, we report on the development of a superstrate-type thin film junction exhibiting inverse photosensitivity which does not involve the use of a pricy transparent conducting oxide layer, providing a method for engineering low-cost thin film devices. Sequential ionic layer adsorption reaction (SILAR) was used to grow Copper Zinc Tin Sulphide (CZTS) and Cadmium sulphide (CdS) large area thin film p-n diode junction. Uniform CZTS thin films with an area of ∼10 cm2 which were free of pin holes or voids could be deposited using an optimized SILAR process recipe. The grown CZTS films exhibited an electrical resistivity of 4.4 × 10−4 Ωm using silver (Ag) electrodes. CdS thin films were sub-sequentially grown over the CZTS layer to form a p-n junction. A knee voltage of 0.2 V in the device configuration “glass/CZTS/CdS/Ag” was observed in the current voltage characteristics. The as-prepared and the vacuum-annealed p-n junction exhibited negative photosensitivity of magnitude 0.21 and 0.16 respectively. The air-annealed device structure exhibited photosensitivity of 216.

Study of the Heat‐Induced Degradation Mechanism in PbI2‐Excess Perovskite Solar Cells

The photodecomposition of PbI2 in the perovskite halide structure has been identified as a primary reason for the rapid degradation of metal halide perovskite solar cells (PSCs) under continuous illumination. In particular, excess PbI2 on the surface of perovskite films reduces the stability of PSCs via several mechanisms that are still unelucidated. Herein, the influence of excess PbI2 on PSCs is investigated by varying the Au deposition rate, which results in different temperatures during the fabrication of PSCs, and then they are compared with stoichiometric PSCs. It is demonstrated that the anion exchange of Br− in perovskite and I− in excess PbI2 occurs at the grain boundary and interface of the perovskite layers induced by the high heating temperature, leading to a photoluminescence peak redshift and lower power conversion efficiency. Light illumination accelerates the exchange of Br− and I− between the perovskite layer and excess PbI2 induced by carrier accumulation at the interface and grain boundary, leading to the poor stability of the PSCs.

(Invited) Molecular Reaction Imaging of Charge Transport in MoS2 Nanoflake Photoelectrodes

Transition metal dichalcogenides (TMD) such as WSe2 and MoS2 are highly efficient and stable light absorbers in TMD∣I−,I3 −∣Pt liquid junction solar cells. It is generally accepted that TMD crystals with a large fraction of exposed edge sites exhibit lower power conversion efficiencies (PCEs) than apparently smooth crystals. However, one open question is why does the PCE vary significantly from one crystal to another? Answering this critical question could lead to robust syntheses for high quality and uniform TMD samples. In this work, we apply nanoscale photoelectrochemical microscopy techniques to study n-type TMD nano flake∣I−,I3 −∣Pt cells. Using a combination of near-diffraction-limited photocurrent mapping and molecular reaction imaging techniques, we reveal a previously hidden surface recombination process: photogenerated holes in hidden p-type domains travel micron-scale distances parallel to the solid/liquid interface and preferentially react with iodide at step-edges. The overall efficiency of the nanoflake, as evidenced from whole nanoflake-level photoelectrochemical measurements, is dictated by the size, efficiency, and location of n- and p-type domains. These results provide a unifying view of efficiency losses in smooth TMD photoelectrodes and open the possibility to design electrode architectures that leverage the long-range lateral charge transport property for photoelectrocatalysis.

Tuning Band Alignment at Grain Boundaries for Efficiency Enhancement in Cu2ZnSnS4 Solar Cells.

Conducting atomic force microscopy has been performed for a fundamental understanding of the mechanism responsible for the lower power conversion efficiency (PCE) of Cu2ZnSnS4 (CZTS) solar cells than that of CuIn1-xGaxSe2 (CIGS) solar cells. The difference in efficiency is partly attributed to the distinctly different band alignment between the grain boundaries (GBs) and grain interior (GI) for the two materials. While CIGS shows type-II band alignment, CZTS was discovered to demonstrate type-I band alignment with the conduction band shifting downward while the valence band shifting upward at the GBs. The type-I band alignment in CZTS leads to both electron and hole trapping, enhancing their recombination, and lowers the PEC. Band engineering was realized by moderate oxidative annealing of CZTS. The preferential GB oxidation changes the band alignment into inverse type-I (i.e., the conduction band upward bending and valence band downward bending at GBs). The blocking of carrier recombination at GBs leads to 30% enhancement in PCE. Our work reveals the critical role that band alignment between the grain boundary and interior plays in polycrystalline thin film solar cells and suggests band alignment engineering as a practical approach to enhance PCE. Furthermore, conducting AFM has been shown to be a powerful tool for qualitative and semiquantitative characterization of band alignment in polycrystalline films.

High-Performance Semi-Transparent Perovskite Solar Cells with over 22% Visible Transparency: Pushing the Limit through MXene Interface Engineering.

Semi-transparent perovskite solar cells (ST-PSCs) have attracted enormous attention recently due to their potential in building-integrated photovoltaic. To obtain adequate average visible transmittance (AVT), a thin perovskite is commonly employed in ST-PSCs. While the thinner perovskite layer has higher transparency, its light absorption efficiency is reduced, and the device shows lower power conversion efficiency (PCE). In this work, a combination of high-quality transparent conducting layers and surface engineering using 2D-MXene results in a superior PCE. In situ high-temperature X-ray diffraction provides direct evidence that the MXene interlayer retards the perovskite crystallization process and leads to larger perovskite grains with fewer grain boundaries, which are favorable for carrier transport. The interfacial carrier recombination is decreased due to fewer defects in the perovskite. Consequently, the current density of the devices with MXene increased significantly. Also, optimized indium tin oxide provides appreciable transparency and conductivity as the top electrode. The semi-transparent device with a PCE of 14.78% and AVT of over 26.7% (400-800 nm) was successfully obtained, outperforming most reported ST-PSCs. The unencapsulated device maintained 85.58% of its original efficiency after over 1000 h under ambient conditions. This work provides a new strategy to prepare high-efficiency ST-PSCs with remarkable AVT and extended stability.

Design and Implementation of a Low-Cost and Low-Power Converter to Drive a Single-Phase Motor

This research introduces a cost-effective converter for single-phase machines, aiming to enhance efficiency and reduce energy consumption in retrofit applications. Single-phase motors commonly found in household appliances often suffer from low efficiency, resulting in wasted energy. To tackle this problem, a dedicated converter was proposed to replace the existing capacitors and improve the motor performance. This study presents a proof of concept for retrofit applications, discussing the converter design methodology and prototype evaluation. Additionally, a cost analysis comparing single-phase and three-phase motors is included. It aims to demonstrate the long-term cost savings and improved energy efficiency of the proposed converter. The findings highlight the converter’s potential as a promising solution for enhancing energy efficiency and decreasing costs in single-phase motor applications.

Exploring the Effect of Kesterites and Zinc‐Based Charge Transport Materials on the Device Performance and Optoelectronic Properties of FAPbI3Perovskite Solar Cells

Formamidinium lead triiodide (FAPbI3)‐based perovskite solar cells (PSCs) have shown greater structural stability but lower power conversion efficiency (PCE) than other established perovskites. The efficiency of the PSC can be improved by identifying suitable charge transport layers for FAPbI3, having good conductivity, and wide bandgap. Kesterite materials belonging to the adamantine family of chalcogenides are quaternary compounds with high conductivity and tunable bandgap. They have shown excellent results when employed in thin films and hence have emerged as an alternate option to be used for the hole transport layers (HTL). Similarly, zinc‐based materials have remarkable properties in terms of their wide bandgap, inability to oxidize, and abundance, making them a viable option to be explored as electron transport layers (ETL). Herein, six different kesterits are used as HTL to simulate FAPbI3PSC with four different zinc‐based ETL. Henceforth, a total of 24 structures is modeled and optimized using SCAPS‐1D. The effect of these materials on the optical absorption, quantum efficiency, electric field,I–Vcharacteristics, and recombination is studied. Among all the structures, CBTS/FAPbI3/CdZnS is found to be the best‐performing PSC structure with PCE of 28.55%, short‐circuit current of 26.8 mA cm−2, open‐circuit voltage of 1.19 V, and fill factor of 88.93%.

Pre-sizing of a modular high power density DC/DC converter with GaN components

Finding the most appropriate architecture to achieve a function is a major engineering challenge. In the power conversion context, the question that arises is: what is the best trade-off between an architecture based on a single high-power converter and another based on the combination of multiple low-power converters? This article aims to answer this question in the specific case of the isolated interface between the low voltage (28VDC) and high voltage (±270VDC) buses of an aircraft. Towards this goal, the targeted power electronics converter is carefully modeled in order to obtain an accurate and fast computing model. A technological database of the different usable components is then used to feed an optimization algorithm. The execution of the latter achieves an attractive and robust result showing an excellent performance in terms of power-to-weight ratio, which is the key index of this study. The precision and speed of this computer-aided design is based on analytical models that are quick to run and therefore enable exploring almost exhaustively the search space. More specifically, the high-frequency transformer has a large relative mass and generates significant losses that are difficult to assess. A major modeling effort has been undertaken and has been enabled to define a simplified but convincing and accurate model (successfully assessed on a wide bandwidth using an experimental setup). It was used for the first time in this optimization process. According to the targeted aeronautical specifications, the two best solutions would make it possible to achieve a mass power density of 4.5kW/kg, i.e. twice as high as traditional solutions. This result very clearly shows that the appropriate use of the new GaN transistors makes it possible to make a technological breakthrough. Considering the voltage and current ratings of these components, this shows that the combination of multiple partial converters is very promising and will make it possible in the future to achieve a significant increase in the compactness of electrical power conversion functions. This sizing study therefore clearly shows the potential of the standardized design of power electronics converters and the search for the best combinations (series, parallel) to meet any specific specifications. Additionally, the developed approach, based on a modeling effort, especially as far as the high-frequency transformer is concerned, and collection of manufacturer data, also makes it possible to limit the implementations and associated tests.Hence, the main contributions of this article are (i) the assembly of the analytical models of the various components constituting an isolated DC–DC power supply, (ii) the simplification of an analytical model of the planar HF transformer, its experimental validation and its first use in a loop of optimization, (iii) the fact of showing supporting figures that GaN technology enables technological breakthroughs to achieve high power density, which opens the way to modular architectures based on partial converters of electrical power, (iv) the comprehensive description of a powerful pre-study design tool enabling to greatly reduce power converters’ time to market.

High‐Efficiency All‐Small‐Molecule Organic Solar Cells Based on New Molecule Donors with Conjugated Symmetric/Asymmetric Hybrid Cyclopentyl‐Hexyl Side Chains

AbstractAll small molecule organic solar cells (ASM‐OSCs) have numerous advantages but lower power conversion efficiencies (PCEs) than their polymer equivalents, which is largely due to the suboptimal nanoscale network structure in a bulk heterojunction (BHJ). Herein, new small molecule donors with symmetric/asymmetric hybrid cyclopentyl‐hexyl side chains are designed, accounting for manipulated intermolecular interactions and BHJ morphology. Theoretical and experimental results reveal that the asymmetric cyclopentyl‐hexyl side chains modification has a significant influence on potential energy surface and intermolecular interaction that can ensure preferable molecular assembly and regulate the D/A interfacial energetics, thus boosting the exciton dissociation and charge transport when pairing with a wide‐used acceptor L8‐BO. Concurrently, a nanoscale bicontinuous interpenetrating network with optimal domain size can be fully evolved in the BHJ layer. As a consequence, the As‐TCp‐based binary device achieves a superior PCE of 16.46% in comparison to that of the controlled symmetric counterparts S‐BF (14.92%) and A‐TCp (15.77%), and ranks one of best performance among ASM‐OSCs. This study demonstrates that precise manipulation of the cyclo‐alkyl chain in combination with the asymmetric 2D side chain strategy is an effective synergistic approach to control intermolecular interaction and nanoscale bicontinuous phase separation for achieving high‐performance ASM‐OSCs.