Low Levels Of Ozone Research Articles

Impacts of stratosphere-to-troposphere transport on tropospheric ozone in southeastern China: insights from ozonesonde observations

Tropospheric ozone pollution poses a major environmental challenge in China. As its primary natural source, Stratosphere-to-Troposphere Transport (STT) has been recognized as a significant contributor to tropospheric ozone in western, northeastern, and eastern China. However, the extent of STT’s influence on southeastern China has been less studied due to data limitations. Using a recently available one-year dataset of ozonesonde observations from a regional background station, we find that STT contributes significantly to tropospheric and surface ozone elevation in southeastern China. Our results show that STT plays a more substantial role in shaping tropospheric ozone during spring than previously believed, accounting for over 30% of ozone concentrations above 4 km. Without the stratospheric contribution, the spring seasonal peak almost disappears. STT can also significantly influence ozone concentrations at the surface. For example, a distinct ozone profile was observed on 4 May 2022, with a notable increase in tropospheric ozone. This tropospheric ozone increase was caused by a STT event triggered by a robust horizontal trough and subsequent southward movement of subtropical jets in the upper troposphere. According to a stratospheric tracer derived from an atmospheric chemistry model, this STT event contributed to 25%–30% of the surface ozone increase. Overall, this study highlights the important role of STT in driving tropospheric ozone variations, even in regions with comparatively lower ozone levels in southeastern China.

Distribution of ozone, carbon monoxide and oxides of nitrogen over an urban location in the foothills of the North-Western Himalayas

Increasing anthropogenic activities and biomass burning events over the Northern Indian region severely affect the pristine environment of North-Western Himalayas. To investigate their influence in this data sparse region, continuous monitoring of O3, CO and NOx are made during January 2018 to December 2019 over Dehradun, an urban location in the foothills of North-western Himalayas. Ozone shows daytime broad peak and CO and NOx show two peaks during morning and evening hours. The maximum daytime ozone is observed during spring with 58.2 ± 2.0 ppbv (56.2 ± 2.7 ppbv) during 2018 (2019). CO and NOx show maximum value during winter and minimum during summer-monsoon. Their concentrations are found to be influenced from stubble burning and forest fire emissions during late spring. WRF-Chem simulations are made with and without biomass burning emissions to quantify the contribution of these emissions on the variability of these gases over Dehradun. Sensitivity simulations reveal that biomass burning over northern Indian region contributed 43 ppbv, 79 ppbv and 1.2 ppbv increase in O3, CO and NOx mixing ratios over Dehradun. In addition, dust storm event in June 2018 contributed for lower ozone levels in 2018 (16.1 ± 9.3 ppbv) and stratosphere troposphere exchange process enhanced surface ozone in June 2019 (53.6 ± 22.3 ppbv).

Impacts of anthropogenic emissions and meteorology on spring ozone differences in San Antonio, Texas between 2017 and 2021

San Antonio has been designated as ozone nonattainment under the current National Ambient Air Quality Standards (NAAQS). Ozone events in the city typically occur in two peaks, characterized by a pronounced spring peak followed by a late summer peak. Despite higher ozone levels, the spring peak has received less attention than the summer peak. To address this research gap, we used the Weather Research and Forecasting (WRF)-driven GEOS-Chem (WRF-GC) model to simulate San Antonio's ozone changes in the spring month of May from 2017 to 2021 and quantified the respective contributions from changes in anthropogenic emissions and meteorology. In addition to modeling, observations from the San Antonio Field Studies (SAFS), the Texas Commission on Environmental Quality (TCEQ) Continuous Ambient Monitoring Stations (CAMS), and the spaceborne TROPOspheric Monitoring Instrument (TROPOMI) are used to examine and validate changes in ozone and precursors. Results show that the simulated daytime mean surface ozone in May 2021 is 3.8 ± 0.6 ppbv lower than in May 2017, which is slightly less than the observed average differences of −5.3 ppbv at CAMS sites. The model predicted that the anthropogenic emission-induced changes contribute to a 1.4 ± 0.5 ppbv reduction in daytime ozone levels, while the meteorology-induced changes account for a 2.4 ± 0.6 ppbv reduction over 2017–2021. This suggests that meteorology plays a relatively more important role than anthropogenic emissions in explaining the spring ozone differences between the two years. We additionally identified (1) reduced NO2 and HCHO concentrations as chemical reasons, and (2) lower temperature, higher humidity, increased wind speed, and a stronger Bermuda High as meteorological reasons for lower ozone levels in 2021 compared to 2017. The quantification of the different roles of meteorology and ozone precursor concentrations helps understand the cause and variation of ozone changes in San Antonio over recent years.

The public-health significance of far-UVC-induced indoor ozone and its associated secondary chemistry.

There has been much recent interest in whole-room far-UVC (wavelength around 222 nm) to markedly and safely reduce overall levels of airborne pathogens in occupied indoor locations. Far-UVC light produces very low levels of ozone-in real-world scenarios induced ozone levels of less than 10 ppb, and much less in moderately or well-ventilated rooms compliant with US far-UVC dose recommendations, and very much less in rooms compliant with international far-UVC dose standards. At these very low ozone levels, there is no epidemiological evidence of increased health risks from any of the very large outdoor ozone studies, whether from ozone alone or from ozone plus associated pollutants. Indoors, at the low ozone concentrations of relevance here, ozone does not react rapidly enough with preexisting airborne volatile organic compounds to compete with even extremely low levels of room ventilation, so significant ozone-induced ultrafine particle production is very unlikely. Direct measurements in real-life room scenarios are consistent with these conclusions. A potential exception is the cleaning material limonene, which has an unusually high ozone interaction cross-section; in the far-UVC context, turning off far-UVC lights during cleaning with limonene products would be reasonable.

Short-term impact of extreme temperatures, relative humidity and air pollution on emergency hospital admissions due to kidney disease and kidney-related conditions in the Greater Madrid area (Spain)

While some studies report a possible association between heat waves and kidney disease and kidney-related conditions, there still is no consistent scientific consensus on the matter or on the role played by other variables, such as air pollution and relative humidity.Ecological retrospective time series study 01-01-2013 to 31-12-2018). Dependent variables: daily emergency hospitalisations due to kidney disease (KD), acute kidney injury (AKI), lithiasis (L), dysnatraemia (DY) and hypovolaemia (HPV). Independent variables: maximum and minimum daily temperature (Tmax, Tmin, °C), and daily relative humidity (RH, %). Other variables were also calculated, such as the daily temperature for risk of kidney disease (Theat, °C) and low daily hazardous relative humidity (HRH%).As variables of air pollution, we used the daily mean concentrations of PM10, PM2.5, NO2 and O3 in μg/m3. Based on these, we then calculated their daily excesses over World Health Organisation (WHO) guideline levels (hPM10, hPM2.5, hNO2 and hO3 respectively). Poisson family generalised linear models (GLMs) (link = log) were used to calculate relative risks (RRs), and attributable risks and attributable admissions. In the models, we controlled for the covariates included: seasonalities, trend, autoregressive component, day of the week, month and year.A statistically significant association was found between Theat and all the dependent variables analysed. The greatest AKI disease burden was attributable to Theat (2.2 % (1.7, 2.6) of attributable hospital admissions), followed by hNO2 (1.7 % (0.9, 3.4)) and HRH (0.8 (0.6, 1.1)). In the case of hypovolaemia and dysnatraemia, the greatest disease burden again corresponded to Theat, with 6.9 % (6.2, 7.6) and 5.7 (4.8, 6.6) of attributable hospital admissions respectively.Episodes of extreme heat exacerbate daily emergency hospital admissions due to kidney disease and kidney-related conditions; and attributable risks are likewise seen for low relative humidity and high ozone levels.

Ozone therapy in the treatment of the elderly

Aging is a universal process of constant reducing of the functioning of a complex system over time, affecting all levels of its organization that impede self-renewal processes. In the structure of the geroprotective therapeutic effect, the main role is given to combat oxidative stress. The most important natural remedy without drugs with this property is the ozoneoxygen mixture, whose effect on the human body is verified by studies conducted both nationally and internationally. 119 patients who underwent outpatient treatment at the Ozone Center in Nizhny Novgorod, Russia, were examined, the basic diagnosis was coronary heart disease, stable angina CF II-III. Parenteral administration of ozonated saline normalizes the pro- and antioxidant serum balance of elderly patients with coronary heart disease. After a course of ozone therapy, there is a decrease in the level of lipid metabolism - total cholesterol, LDL-C, triglycerides. Intravenous administration of low ozone levels improves endothelial function by lowering high levels of nitric oxide and endothelin. Ozone therapy reduces the ability of platelets to aggregate and improves the rheological properties of the blood of elderly patients with coronary heart disease.

Low-to-moderate atmospheric ozone levels are negatively correlated with hospital visits by asthma patients.

Asthma is a chronic illness of the airways that affects approximately 300 million individuals worldwide. While it is commonly accepted that high ozone levels exacerbate asthma symptoms, the impact of low to moderate ozone levels on asthma symptoms has received little attention. The purpose of this research was to determine the relationship between hospital visits by asthma patients showing the severity of their symptoms and moderate ozone levels. Statistical analyses were performed on hospital visit big data for asthma patients in Seoul, Korea, collected between 2013 and 2017. The data set includes outpatient hospital visits (n = 17,787,982), hospital admissions (n = 215,696), and emergency department visits (n = 85,482). The frequency of hospital visits by asthma patients was evaluated in relation to low ozone levels (< 0.03 ppm) and moderate ozone levels (0.03-0.06 ppm) in the Seoul environment. In comparison to low ozone levels, moderate ozone levels resulted in a reduction in outpatient hospital visits (t = 7.052, P < .001). When ozone levels were low to moderate, there was a negative correlation between ozone levels and outpatient visits (r = -0.281, 95% CI: -0.331 to -0.228). Negative associations were also identified between ozone levels and new hospital admissions (t = 2.909, P < .01; r = -0.125, 95% CI: -0.179 to -0.070) and emergency treatments (t = 2.679, P < .01; r = -0.132, 95% CI: -0.186 to -0.076). Additionally, it was verified that moderate ozone levels one day before the visits resulted in a reduction in outpatient visits (t = 5.614, P < .001; r = -0.207, 95% CI: -0.259 to -0.153). A strong relationship was identified between moderate atmospheric ozone levels and a reduction in asthma patient hospital visits.

Effects of ozone addition and octane sensitivity on combustion characteristics of gasoline compression ignition engines

Gasoline compression ignition (GCI) is one of the promising technologies that can achieve high efficiency and clean combustion. However, GCI engines often suffer from ignition instabilities at low loads with poor intake conditions. Various physical methods such as intake preheating are often employed to improve combustion instabilities, while the approaches based on chemical perspectives are not fully considered. In this work, the effect of ozone addition and octane sensitivity on GCI combustion was investigated based on a single-cylinder engine fueled with Toluene Primary Reference Fuels (TPRF). Four octane sensitivities (i.e., 0, 3.6, 5.3, and 7.2) at a research octane number of 75 and six levels of ozone seeding (i.e., 0, 5, 10, 30, 60, and 90 ppm) were considered. Pressure characteristics and combustion evolutions were compared and interpreted and underlying reasons for distinct combustion behaviors were clarified. The results show that both ozone seeding and octane sensitivity has a pronounced influence on the combustion characteristics of GCI engines. Specifically, with the increase of octane sensitivity, both low- and high-temperature combustion phasing is advanced, indicating the improvement in chemical reactivity during GCI combustion. Ozone seeding shows similar influences on GCI combustion and can reduce the disparities of combustion characteristics under various octane sensitivity conditions. Meanwhile, low concentrations of ozone seeding can exhibit significance in the promotion of GCI combustion while it becomes minimal when beyond a critical level. Chemical kinetic analysis shows that the introduction of ozone seeding promotes the production of reactive free radicals, which accelerates the oxidation of fuel molecules and then improves combustion at both low and high temperatures. The current work demonstrates the potential of higher octane-sensitivity fuel combined with low levels of ozone seeding in improving the combustion instability of GCI engines at low loads.

Assessment Impacts of Ozone on Salmonella Typhimurium and Escherichia coli O157:H7 in Liquid Dairy Waste

Liquid dairy manure, which is produced in enormous quantities in flush dairy manure management systems, is commonly used as an alternative to chemical fertilizers. It provides nutrient benefits to crops and soils. While dairy waste is a well-accepted and widely used fertilizer, the presence of indicator organisms and human pathogens in manure may lead to pathogen contamination in crops and soils. This study is focused on the examination of ozone gas-based sterilization. In the past, ozone (O3) has been used for sanitizing various foods and solid surfaces, but the potential of O3 for eliminating human pathogens in liquid dairy waste is not studied yet. Pathogens such as Salmonella Typhimurium and Escherichia coli O157:H7 are reported to be present in liquid dairy manure, and this research evaluated the effects of various levels of ozone on the survival of these two pathogens. We designed a continuous type O3 treatment system that has four major components: (1) ozone generator using oxygen; (2) ozone concentration control by mixing with pure air; (3) continuous monitoring of ozone concentrations; and (4) ozone experiment chambers. Various levels of ozone (43.26, 87.40, and 132.46 mg·L−1) were produced in the ozone system, and subsequently, ozone was diffused through liquid manure. Liquid manure was exposed to ozone for multiple durations (30, 60, and 120 min). To determine the effectiveness of O3 in eliminating pathogens, time-series samples were collected and analyzed for determining the levels of S. typhimurium and E. coli O157:H7. Preliminary results showed that ozone concentrations of 132.46 mg/L, and exposure time of 120 min resulted in the reduced levels of E. coli and Salmonella. Low levels of ozone and limited exposure time were found to be less effective in pathogen removal potentially due to high solid contents. Additional studies carrying out experiments to evaluate the impacts of solids in combination with ozone concentrations will provide further insights into developing full-scale ozone-based treatment systems.

Chemistry and human exposure implications of secondary organic aerosol production from indoor terpene ozonolysis.

Surface cleaning using commercial disinfectants, which has recently increased during the coronavirus disease 2019 pandemic, can generate secondary indoor pollutants both in gas and aerosol phases. It can also affect indoor air quality and health, especially for workers repeatedly exposed to disinfectants. Here, we cleaned the floor of a mechanically ventilated office room using a commercial cleaner while concurrently measuring gas-phase precursors, oxidants, radicals, secondary oxidation products, and aerosols in real-time; these were detected within minutes after cleaner application. During cleaning, indoor monoterpene concentrations exceeded outdoor concentrations by two orders of magnitude, increasing the rate of ozonolysis under low (<10 ppb) ozone levels. High number concentrations of freshly nucleated sub–10-nm particles (≥105 cm−3) resulted in respiratory tract deposited dose rates comparable to or exceeding that of inhalation of vehicle-associated aerosols.

Evaluating health outcome metrics and their connections to air pollution and vulnerability in Southern California's Coachella Valley

The ongoing desiccation of California's Salton Sea has led to increasing concerns about air quality and health for its surrounding communities, including the nearby Coachella Valley – a region already experiencing severe air quality and health disparities. Here we explore spatial air pollution and human health disparities in the Coachella Valley with particular attention to disparities arising across population characteristics including both socioeconomic and demographic vulnerabilities. We use two different measures of respiratory and cardiovascular health outcomes at the individual and census tract levels – one measure based on a randomly sampled telephone survey and the other measure based on emergency room visitation data – to investigate the degree to which these health outcomes are connected to air pollution and socioeconomic metrics. We further investigate biases and differences between the health outcome metrics themselves and suggest opportunities to address them in future analyses and survey efforts. We find that more vulnerable communities are associated with higher levels of fine particulates, but lower levels of ozone. While emergency visit rates show a significant positive correlation with both pollutants, no such association is found when using surveyed health outcome data. The ratio of emergency visits versus survey rates shows a positive relationship with socioeconomic and demographic vulnerability, indicating that vulnerable communities are less likely to self-report diagnoses despite higher rates of respiratory or cardiovascular hospitalization. Additionally, survey respondents tend to show less vulnerability relative to their surrounding census-based demographics. These findings suggest the need for greater attention to health issues specifically within disadvantaged communities in the Coachella Valley, building upon and working within existing community networks and local resources, to better address current and projected health needs. Our findings also highlight disparities in air pollution exposure, health outcomes, and population characteristics in the Coachella Valley, providing context for crucial pollution reduction efforts in the face of increasing environmental threats.

Personal ozone exposure and stress hormones in the hypothalamus-pituitary-adrenal and sympathetic-adrenal-medullary axes.

The effect of ozone exposure on neuroendocrine responses in humans has not been fully studied. We conducted a longitudinal panel study with four rounds of visits among 43 college students in Shanghai, China, from May to October 2016. For each visit, we monitored personal real-time ozone exposure for consecutive 3days (from 8:00 a.m. to 6:00p.m. each day), followed by blood sample collection. We measured serum levels of three hormones in the hypothalamus-pituitaryadrenal (HPA) axis, including corticotropin releasing hormone (CRH), adrenocorticotropic hormone (ACTH), and cortisol, and three catacholamines indicating sympathetic-adrenal-medullary (SAM) axis activation, including adrenaline, noradrenaline, and dopamine. We applied linear mixed-effect models to evaluate the associations between ozone exposure and these neurohormones and further compared models using personal and fixed-site ozone measurements. At lag 0-8h, personal ozone exposure ranged from 4.5ppb to 104.3ppb with an average of 21.0±14.7ppb, which was approximately half of the ambient ozone concentration. Per 10-ppb increase in personal ozone exposure (lag 0-8h) was associated with increases of 5.60% [95% confidence interval (CI): 2.30%, 9.01%] in CRH, 5.91% (95% CI: 0.55%, 11.56%) in cortisol, and 10.13% (95% CI: 2.75%, 18.05%) in noradrenaline, whereas associated with a 12.15% (95% CI: 1.23%, 21.87%) decrease in dopamine. Overall, models using personal ozone measurements yielded larger effect estimates and better model fits than models using fixed-site measurements. Short-term exposure to low levels of ozone may lead to activation of the HPA and SAM axes.

A novel dual-scale ensemble learning paradigm with error correction for predicting daily ozone concentration based on multi-decomposition process and intelligent algorithm optimization, and its application in heavily polluted regions of China

Accurate prediction of daily ozone concentration is imperative to prevent and control photochemical pollution in China. A novel ensemble learning paradigm is proposed in this paper to perform high-precision ozone concentrations prediction, including model preprocess, optimized dual-scale prediction, and error correction. Firstly, the original ozone series is decomposed into two detailed sequences and two approximate sequences by wavelet packet decomposition (WPD). The detailed sequences are reconstructed into several new subsequences by complementary ensemble empirical mode decomposition (CEEMD) and fuzzy entropy (FE). Secondly, the extreme learning machine (ELM) and the support vector machine (SVM) are both optimized by the bald eagle search (BES) algorithm to carry out dual-scale parallel prediction. Finally, the error series is decomposed and predicted by the variational mode decomposition (VMD) and the optimized ELM to correct the previously predicted ozone and obtain the final ozone prediction. The actual ozone data from two typical cities in China are collected as the inputs of the model for empirical analysis under two scenarios, and one-day ahead prediction results show that: the RMSE values of the proposed model are 2.5319 and 3.2069 at Taiyuan and Shanghai sites when predicting low levels of ozone, respectively, while the RMSE values of the proposed model are 2.8451 and 3.8702 at two sites when predicting high levels of ozone, respectively; the proposed model outperforms the comparison models and four existing models under each scenario, demonstrating its robustness and serviceability. The results of this study can provide a valuable reference for analyzing the tendency of pollution.

Ultraviolet light and ozone controls Cryptocaryon irritans infection in factory aquaculture

Cryptocaryon irritans is a pathogenic ectoparasitic ciliate that infects marine teleosts, causing massive mortality and economic losses in aquaculture. Ultraviolet light (UV) and ozone (O3) are commonly used for disinfection in factory aquaculture; however, the efficacy of neither method against C. irritans had been evaluated. This study aimed to evaluate the efficacy of UV and ozone in destroying C. irritans. UV or ozone treatment changed or ruptured the shape of C. irritans theronts, although C. irritans tomonts showed some resistance. The minimum in vitro lethal doses of UV and ozone against theronts were 2.88× 105 μWs/cm2 and 0.15 mg/L, respectively. In vivo, UV and ozone-treated theronts lost their ability to infect pompano (Trachinotus ovatus) when exposed to doses above 1.84 × 105 μWs/cm2 and 0.10 mg/L, respectively. Unexpectedly, exposure to low ozone levels (< 0.04 mg/L) enhanced theronts infecting ability. These results provide a reference for C. irritans theronts disinfection in factory aquaculture and further studies on C. irritans.

The effect of ambient ozone on glucose-homoeostasis: A prospective study of non-diabetic older adults in Beijing

BACKGROUND AND AIM: Limited evidence on O3 and glucose association among older, non-diabetic adults. To investigate potential effects of short- and medium-term exposure to low levels of ozone (O3) on glucose-homeostasis in non-diabetic older adults. METHODS: 166 non-diabetic, older participants in Beijing were deemed eligible to partake in this longitudinal population-based study. Observations were recorded on three separate occasions from November 2016 up until January 2018. Concentrations of outdoor O3 were monitored throughout the study period. Biomarkers indicative of glucose-homeostasis, including fasting blood glucose, insulin, HbAlc, glycated albumin percentage (glycated albumin/albumin), HOMA-IR and HOMA-B were measured at 3 sessions. A linear mixed effects model with random effects was adopted to quantify the effect of O3 across a comprehensive set of glucose-homeostasis markers. RESULTS:Short-term O3 exposure positively associated with increased fasting blood glucose, insulin, HOMA-IR and HOMA-B. The effect on glucose occurred at 3-, 5-, 6- and 7-days, although the largest effect manifested on 6-days (5.6%, 95%CI: 1.4, 9.9). Significant associations with both insulin and HOMA-IR were observed on the 3- and 4-days. For HOMA-B, positive associations were identified from 3- to 7-days with estimates ranging from 40.0% (95%CI: 2.3, 91.5) to 83.1% (95%CI: 25.3, 167.5). Stratification suggests that women may be more susceptible to short-term O3 exposure. There does not appear to be a significant association between O3 and glucose-homeostasis in medium-term exposures. CONCLUSIONS:In this study, we found that O3 exposure is at least partially associated with type II diabetes in older adults with no prior history of this condition. O3 therefore appears to be a potential risk factor, which is a particular concern when we consider the rise in global concentrations. Evidence also suggests that women may be more susceptible to short-term O3 exposure although we are not quite sure why. Future research may look to investigate this phenomenon further. KEYWORDS: Glucose homeostasis, Glucose metabolism disorder, Longitudinal study, O3

Seed-borne fungal endophytes constrain reproductive success of host plants under ozone pollution

Tropospheric ozone is among the global change factors that pose a threat to plants and microorganisms. Symbiotic microorganisms can assist plants to cope with stress, but their role in the tolerance of plants to ozone is poorly understood. Here, we subjected endophyte-symbiotic and non-symbiotic plants of Lolium multiflorum, an annual species widely distributed in temperate grasslands, to high and low (i.e., charcoal-filtered air) ozone levels at vegetative and reproductive phases. Exposure to high ozone reduced leaf photochemical efficiency and greenness in both symbiotic and non-symbiotic plants. However, ozone-induced oxidative damage at biochemical level (i.e., lipid peroxidation) was mostly detected in symbiotic plants. Ozone exposure at the vegetative phase did not affect the reproductive investment in seeds, indicating full recovery from stress. Ozone exposure at the reproductive phase reduced biomass and seed production only in symbiotic plants indicating a symbiont-associated cost. At low ozone, endophyte-symbiotic plants showed a steeper slope in the relationship between seed number and seed weight (i.e., a number-weight trade-off) compared to non-symbiotic plants. However, when plants were treated at the reproductive phase, ozone increased the imbalance between seed number and seed weight in both endophyte-symbiotic and non-symbiotic plants. Plants with endophytes at the reproductive stage produced fewer seeds, which were not compensated by increased seed weight. Thus, fungal mycelium growing within ovaries or ozone-induced antioxidant systems may result in costs that finally depress the fitness of plants. Despite ozone pollution could destabilize plant-endophyte mutualisms and render them dysfunctional, other endophyte-mediated benefits (e.g., resistance to herbivory, tolerance to drought) could over-compensate these losses and explain the high incidence of the symbiosis in nature.

Analysis of Arctic Spring Ozone Anomaly in the Phases of QBO and 11-Year Solar Cycle for 1979–2017

Arctic ozone amount in winter to spring shows large year-to-year variation. This study investigates Arctic spring ozone in relation to the phase of quasi-biennial oscillation (QBO)/the 11-year solar cycle, using satellite observations, reanalysis data, and outputs of a chemistry climate model (CCM) during the period of 1979–2017. For this duration, we found that the composite mean of the Northern Hemisphere high-latitude total ozone in the QBO-westerly (QBO-W)/solar minimum (Smin) phase is slightly smaller than those averaged for the QBO-W/Smax and QBO-E/Smax years in March. An analysis of a passive ozone tracer in the CCM simulation indicates that this negative anomaly is primarily caused by transport. The negative anomaly is consistent with a weakening of the residual mean downward motion in the polar lower stratosphere. The contribution of chemical processes estimated using the column amount difference between ozone and the passive ozone tracer is between 10–20% of the total anomaly in March. The lower ozone levels in the Arctic spring during the QBO-W/Smin years are associated with a stronger Arctic polar vortex from late winter to early spring, which is linked to the reduced occurrence of sudden stratospheric warming in the winter during the QBO-W/Smin years.

The impact of Los Angeles Basin pollution and stratospheric intrusions on the surrounding San Gabriel Mountains as seen by surface measurements, lidar, and numerical models

Abstract. In this work, the impact of Los Angeles Basin pollution transport and stratospheric intrusions on the surface ozone levels observed in the San Gabriel Mountains is investigated based on a combination of surface and lidar measurements as well as WRF-Chem (Weather Research and Forecasting with Chemistry) and WACCM (Whole Atmosphere Community Climate Model) runs. The number of days with observed surface ozone levels exceeding the National Ambient Air Quality Standards exhibit a clear seasonal pattern, with a maximum during summer, when models suggest a minimum influence of stratospheric intrusions and the largest impact from Los Angeles Basin pollution transport. Additionally, measured and modeled surface ozone and PM10 were analyzed as a function of season, time of the day, and wind direction. Measurements and models are in good qualitative agreement, with maximum surface ozone observed for southwest and west winds. For the prevailing summer wind direction, slightly south of the ozone maximum and corresponding to south-southwest winds, lower ozone levels were observed. Back trajectories suggest that this is associated with transport from the central Los Angeles Basin, where titration limits the amount of surface ozone. A quantitative comparison of the lidar profiles with WRF-Chem and WACCM models revealed good agreement near the surface, with models showing an increasing positive bias as function of altitude, reaching 75 % at 15 km above sea level. Finally, three selected case studies covering the different mechanisms affecting the near-surface ozone concentration over the San Gabriel Mountains, namely stratospheric intrusions and pollution transport, are analyzed based on surface and ozone lidar measurements, as well as co-located ceilometer measurements and models.

The effect of ambient ozone on glucose-homoeostasis: A prospective study of non-diabetic older adults in Beijing

ObjectiveTo investigate potential effects of short- and medium-term exposure to low levels of ozone (O3) on glucose-homeostasis in non-diabetic older adults. Methods166 non-diabetic, older participants in Beijing were deemed eligible to partake in this longitudinal population-based study. Observations were recorded on three separate occasions from November 2016 up until January 2018. Concentrations of outdoor O3 were monitored throughout the study period. Biomarkers indicative of glucose-homeostasis, including fasting blood glucose, insulin, HbAlc, glycated albumin percentage (glycated albumin/albumin), HOMA-IR and HOMA-B were measured at 3 sessions. A linear mixed effects model with random effects was adopted to quantify the effect of O3 across a comprehensive set of glucose-homeostasis markers. ResultsShort-term O3 exposure positively associated with increased fasting blood glucose, insulin, HOMA-IR and HOMA-B. The effect on glucose occurred at 3-, 5-, 6- and 7-days, although the largest effect manifested on 6-days (5.6%, 95% CI: 1.4, 9.9). Significant associations with both insulin and HOMA-IR were observed on the 3- and 4-days. For HOMA-B, positive associations were identified from 3- to 7-days with estimates ranging from 40.0% (95% CI: 2.3, 91.5) to 83.1% (95% CI: 25.3, 167.5). Stratification suggests that women may be more susceptible to short-term O3 exposure. There does not appear to be a significant association between O3 and glucose-homeostasis in medium-term exposures. ConclusionsIn this study, we found that O3 exposure is at least partially associated with type II diabetes in older adults with no prior history of this condition. O3 therefore appears to be a potential risk factor, which is a particular concern when we consider the rise in global concentrations. Evidence also suggests that women may be more susceptible to short-term O3 exposure although we are not quite sure why. Future research may look to investigate this phenomenon further.

The effect of ambient ozone on glucose-homoeostasis: A prospective study of non-diabetic older adults in Beijing

Objective: To investigate potential effects of short- and medium-term exposure to low levels of ozone (O3) on glucose-homeostasis in non-diabetic older adults. Methods: 166 non-diabetic, older participants in Beijing were deemed eligible to partake in this longitudinal population-based study. Observations were recorded on three separate occasions from November 2016 up until January 2018. Concentrations of outdoor O3 were monitored throughout the study period. Biomarkers indicative of glucose-homeostasis, including fasting blood glucose, insulin, hemoglobin A1c (HbAlc), glycated albumin percentage, Homeostatic Model Assessment of Insulin Resistance (HOMA-IR) and Homeostatic Model Assessment of Beta cell function (HOMA-B) were measured at 3 sessions. A linear mixed effects model with random effects was adopted to quantify the effect of O3 across a comprehensive set of glucose-homeostasis markers. Results: short-term O3 exposure positively associated with increased fasting blood glucose, insulin, HOMA-IR and HOMA-B. The effect on glucose occurred at 3-, 5-, 6- and 7-days, although the largest effect manifested on 6-days (5.6%, 95%CI: 1.4, 9.9). Significant associations with both insulin and HOMA-IR were observed on the 3- and 4-days, although the largest effect consistently occured on 4-days with estimations of 90.0% (95%CI: 19.0, 203.4) and 96.5% (95%CI: 14.9, 235.9), respectively. For HOMA-B, positive associations were identified from 3- to 7-days with estimates ranging from 40.0% (95%CI: 2.3, 91.5) to 83.1% (95%CI: 25.3, 167.5). Stratification suggests that women may be more susceptible to short-term O3 exposure with positive associations observed at 1-, 2-, 5-, 6-, and 7-days in both insulin and HOMA-IR. Conclusions: In this study, we found that O3 exposure is at least partially related to the onset of type II diabetes in older adults with no prior history of this condition. O3 therefore acts as a kind of catalyst for metabolic disorders, which is a particular concern when we consider the rise in global concentrations.