Gamma radiation from the 46Ca(n, γ) 47Ca and 40Ca(n, γ) 41Ca reactions was measured with Ge(Li) detectors. The 47Ca γ-rays observed can be placed in a decay scheme with levels at 2013.62±0.20, 2875.27±0.25, 4057.9±0.3, 4809.2±0.3 and 5503.4±0.3 keV. The neutron binding energy of 47Ca is 7276.0±0.5 keV. The primary γ-ray intensities populating intermediate 1 2 − and 3 2 − states are found to be strongly correlated with l n = 1 transitions in 46Ca (d, p) 47Ca studies, which is consistent with the common unique parent assumption and suggests a direct process (channel capture) in the (n, γ) reaction. The decay of the low-lying negative parity states is consistent with their shell-model interpretation as 2 p 1 2 and 2 p 3 2 one-particle two-hole excitations in the 41Ca inert core. Energies of the previous established levels in 48Ca are 1942.69±0.14, 2009.88±0.24, 2462.15±0.17, 2669.82±0.18, 3400.08±0.26, 3613.42±0.17, 3944.20±0.25, 4603.7±0.7 and 4752.6±0.2 keV. The neutron binding energy of 41Ca is 8363.1±0.5 keV.