Low Index Polymer Research Articles

Watt-level cladding-pumped bismuth-doped fiber laser operating near 1.31 [formula omitted]m

We report, to the best of our knowledge, the first CW bismuth-doped fiber laser operating at around 1.31 μm with an output power of >1 W utilizing a cladding-pumping configuration with multimode semiconductor laser diodes emitting at a wavelength of 793 nm. The Bi-doped fiber (BDF) serving as an active medium of the laser was based on a pedestal-index design, where P2O5−SiO2 glass core surrounded by P-doped cladding. The BDF construction offers advanced gain characteristics and an increased mode size (∼13 μm). The fiber preform was fabricated by the conventional modified chemical vapor deposition (MCVD) method combined with all gas-phase doping technique. The BDF with low-index polymer coating provided sufficient cladding peak absorption at 750 nm belonging to bismuth active centers associated with phosphorus atoms (BACs-P) that allowed to develop a continuous-wave laser with a linear cavity configuration and enable a maximum slope efficiency of ∼ 4% with respect to the absorbed pump power. In addition, near-field spatial intensity distribution of optical beam has good quality (M2<1.13) and close to Gaussian mode profile in x and y directions. The perspectives for optimization of BDF design and laser system configurations based on such fibers for further power scaling are discussed.

High-directivity far-field radiation of quantum dot-based single-photon emitter coupled to polymeric circular waveguide resonant grating

Solid-state single-photon emitters (SPEs) commonly encounter the limitation of quasi-omnidirectional radiation patterns, which poses challenges in utilizing their emission with conventional optical instruments. In this study, we demonstrate the tailoring of the far-field radiation patterns of SPEs based on colloidal quantum dots (QDs), both theoretically and experimentally, by employing a polymer-based dielectric antenna. We introduce a simple and cost-effective technique, namely low one-photon absorption direct laser writing, to achieve precise coupling of a QD into an all-polymer circular waveguide resonance grating. By optimizing the geometry parameters of the structure using 3D finite-difference time-domain simulations, resonance at the emission wavelength of QDs is achieved in the direction perpendicular to the substrate, resulting in photon streams with remarkably high directivity on both sides of the grating. Theoretical calculations predict beam divergence values below 2°, while experimental measurements using back focal plane imaging yield divergence angles of approximately 8°. Our study contributes to the evaluation of concentric circular grating structures employing low refractive index polymer materials, thereby expanding the possibilities for their application.

Tracking of lineage mass via quantitative phase imaging and confinement in low refractive index microwells.

Measurements of cell lineages are central to a variety of fundamental biological questions, ranging from developmental to cancer biology. However, accurate lineage tracing requires nearly perfect cell tracking, which can be challenging due to cell motion during imaging. Here we demonstrate the integration of microfabrication, imaging, and image processing approaches to demonstrate a platform for cell lineage tracing. We use quantitative phase imaging (QPI), a label-free imaging approach that quantifies cell mass. This gives an additional parameter, cell mass, that can be used to improve tracking accuracy. We confine lineages within microwells fabricated to reduce cell adhesion to sidewalls made of a low refractive index polymer. This also allows the microwells themselves to serve as references for QPI, enabling measurement of cell mass even in confluent microwells. We demonstrate application of this approach to immortalized adherent and nonadherent cell lines as well as stimulated primary B cells cultured ex vivo. Overall, our approach enables lineage tracking, or measurement of lineage mass, in a platform that can be customized to varied cell types.

Ultrahigh Refractive Index Sensitivity With Lossy Mode Resonance in a Side-Polished Low-Index Polymer Optical Fiber

Ultrahigh Refractive Index Sensitivity With Lossy Mode Resonance in a Side-Polished Low-Index Polymer Optical Fiber

Weak optical modes for high-density and low-loss photonic circuits

Dielectric optical waveguides constitute the main building blocks of photonic integrated circuits (PICs). Channels with high refractive index contrast can provide very compact PIC components, whereas structures with lower index exhibit less propagation loss. A hybrid concept that can combine the best of high- and low-index materials is highly required. Here, we devise a new approach to realize compact and low-loss hybrid optical waveguides based on the interaction of weak optical modes. This is a rather universal approach that can be applied to a wide range of optical materials. To prove the principle, the hybrid waveguide structure is formed by combining a low-index polymer and a thin layer of silicon nitride. For this material combination, a minimum bending radius of 90 µm (for a bending loss of 0.005 dB/90°) and a propagation loss of 0.7 dB/cm are achieved. The viability of this platform is demonstrated through a series of high-performance novel PIC components. This hybrid waveguide platform enabled by a powerful and simple design concept holds great promise for high-density and low-loss PICs.

Effects of interlayer reflection and interpixel interaction in diffractive optical neural networks.

Multilayer diffractive optical neural networks (DONNs) can perform machine learning (ML) tasks at the speed of light with low energy consumption. Decreasing the number of diffractive layers can reduce inevitable material and diffraction losses to improve system performance, and incorporating compact devices can reduce the system footprint. However, current analytical DONN models cannot accurately describe such physical systems. Here we show the ever-ignored effects of interlayer reflection and interpixel interaction on the deployment performance of DONNs through full-wave electromagnetic simulations and terahertz (THz) experiments. We demonstrate that the drop of handwritten digit classification accuracy due to reflection is negligible with conventional low-index THz polymer materials, while it can be substantial with high-index materials. We further show that one- and few-layer DONN systems can achieve high classification accuracy, but there is a trade-off between accuracy and model-system matching rate because of the fast-varying spatial distribution of optical responses in diffractive masks. Deep DONNs can break down such a trade-off because of reduced mask spatial complexity. Our results suggest that new accurate and trainable DONN models are needed to advance the development and deployment of compact DONN systems for sophisticated ML tasks.

Dual Responsive Dependent Background Color Based on Thermochromic 1D Photonic Crystal Multilayer Films.

In this paper, we present dual responsive one-dimensional (1D) photonic crystal (PC) multilayer films that utilize a high-humidity environment and temperature. Dual responsive 1D PC multilayer films are fabricated on precoated thermochromic film by sequential alternate layer deposition of photo-crosslinkable poly(2-vinylnaphthalene-co-benzophenone acrylate) (P(2VN-co-BPA)) as a high refractive index polymer, and poly(4-vinylpyrollidone-co-benzophenone acrylate) P(4VP-co-BPA) as a low refractive index polymer. The thermochromic film shows a vivid color transition from black to white at 28 °C. Three different colors of thermochromic 1D PC multilayer films are prepared by thickness modulation of P(4VP-co-BPA) layers, and the films on a black background exhibit visible spectrum color only in a high-humidity environment (over 90% relative humidity (RH)). For the three films placed on a hands display, three different composite colors are synthesized by the reflection of light, including yellow, magenta, and cyan, due to the changing of backgrounds from black to white with temperature. Additionally, the films show remarkable color transitions with reliable reversibility. The films can be applied as anti-counterfeiting labels and can be used for smart decoration films. To the best of our knowledge, this is the first report of dual response colorimetric films that change color in various ways depending on temperature and humidity changes, and we believe that it can be applied to various applications.

Excitation of "forbidden" guided-wave plasmon polariton modes via direct reflectance using a low refractive index polymer coupling layer.

A surface plasmon polariton (SPP) is an excitation resulting from the coupling of light to a surface charge oscillation at a metal-dielectric interface. The excitation and detection of SPPs is foundational to the operating mechanism of a number of important technologies, most of which require SPP excitation via direct reflectance, commonly achieved via Attenuated Total Reflection (ATR) using the Kretschmann configuration. As a result, the accessible modes are fundamentally high-loss “leaky modes,” presenting a critical performance barrier. Recently, our group provided the first demonstration of “forbidden,” or guided-wave plasmon polariton modes (GW-PPMs), collective modes of a MIM structure with oscillatory electric field amplitude in the central insulator layer with up to an order of magnitude larger propagation lengths than those of traditional SPPs. However, in that work, GW-PPMs were accessed by indirect reflectance using Otto configuration ATR, making them of limited applied relevance. In this paper, we demonstrate a technique for direct reflectance excitation and detection of GW-PPMs. Specifically, we replace the air gap used in traditional Otto ATR with a low refractive index polymer coupling layer, mirroring a technique previously demonstrated to access Long-Range Surface Plasmon Polariton modes. We fit experimental ATR data using a robust theoretical model to confirm the character of the modes, as well as to explore the potential of this approach to enable advantageous propagation lengths. The ability to excite GW-PPMs using a device configuration that does not require an air gap could potentially enable transformative performance enhancements in a number of critical technologies.

Underwater Acoustic Wave Detection Based on Packaged Optical Microbubble Resonator

We demonstrate an optical underwater acoustic sensor with high sensitivity and broad bandwidth (10 Hz to 100 kHz), based on the packaged optical microbubble whispering gallery mode resonator, for the first time. The underwater acoustic pressure sensitivity level is as high as −159.3 dB re 1 V/μPa at 1 kHz that benefits from the high optical Q-factor and low refractive index (RI) polymer cladding. The corresponding noise equivalent pressure (NEP) is 66.8 dB re 1 μPa/Hz <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">1/2</sup> , which is equivalently 2.2 mPa/Hz <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">1/2</sup> . The sensitivity is hardly affected by the changes of static pressure and temperature in practical applications. The wide underwater acoustic response directivity is measured and the angular responses have – 6 dB angle range of 75.6° and 105.5° in two orthogonal directions, respectively. This work provides a potential miniature optical acoustic sensor for the broadband underwater acoustic wave detection.

Cladding-pumped bismuth-doped fiber laser.

For the first time, to the best of the authors' knowledge, a cladding-pumped bismuth-doped fiber laser (BDFL) is demonstrated. A "home-made" Bi-doped germanosilicate fiber with a 125 µm circular outer cladding made of fused silica and coated by a low refractive index polymer is used as an active medium pumped by commercial multimode laser diodes with a total output power of 25 W at 808 nm. We find that the BDFL with a free-running cavity (when feedback is provided by ≈4% back reflection from two bare right-angle cleaved fiber ends) composed of a 100-m-long bismuth-doped fiber is capable of emitting at a wavelength of 1440 nm. A slope efficiency of 0.5% with respect to the absorbed pump power with a maximum output power of ≈50 mW is obtained in a BDFL with a cavity formed by a highly reflective Bragg grating at 1461 nm and a right-angle cleaved fiber end. The beam quality factors (M2) of the output BDFL in the horizontal and vertical directions are measured to be 1.18 and 1.13, respectively. The processes affecting the efficiency of the BDFLs are also discussed. The possible improvements for the output power scaling and increasing the efficiency of the cladding-pumped BDFLs are proposed.

Toward 3D-Printed Inverse-Designed Metaoptics

Optical metasurfaces have been heralded as the platform to integrate multiple functionalities in a compact form-factor, potentially replacing bulky components. A central stepping stone towards realizing this promise is the demonstration of multifunctionality under several constraints (e.g. at multiple incident wavelengths and/or angles) in a single device -- an achievement being hampered by design limitations inherent to single-layer planar geometries. Here, we propose a general framework for the inverse design of volumetric 3D metaoptics via topology optimization, showing that even few-wavelength thick devices can achieve high-efficiency multifunctionality. We embody our framework in multiple closely-spaced patterned layers of a low-index polymer. We experimentally demonstrate our approach with an inverse-designed 3d-printed light concentrator working at five different non-paraxial angles of incidence. Our framework paves the way towards realizing multifunctional ultra-compact 3D nanophotonic devices.

Photonic multilayers for ultrasensitive millisecond colorimetric discrimination between benzene, toluene, and xylene

Responsive photonic crystals (RPCs) have been used as real-time colorimetric sensors for the detection of various analytes. Herein, reusable one-dimensional photonic crystal (1D PC) polymeric films are used for the ultrafast and distinct colorimetric discrimination between benzene, toluene, and xylene (BTX). The 1D polymeric films are prepared via the alternate spin-coating of photo-cross-linkable poly(para-methyl styrene-co-benzophenone acrylate) (P(MS-co-BPA)) as a high refractive index polymer and poly(methyl acrylate-co-benzophenone acrylate) (P(MA-co-BPA) as a low refractive index polymer onto a glass substrate. Millisecond traffic light discrimination between BTX is achieved when these films are immersed in each BTX solution. The visibility in discrimination is further improved by controlling the thickness and crosslinking density of the P(MA-co-BPA) layers. The high efficiency of the BTX discrimination is attributed to the difference in miscibility between the low-refractive-index polymer and each BTX. This discrimination process is repeated several times, and the reusability of the films over multiple cycles is demonstrated. In addition, the 1D polymeric films are applied to the discrimination of commercial gasolines from adulterated samples, thus demonstrating a practical contribution to environmental protection.

Construction of a dual-core hollow waveguide for visible and mid-infrared light transmission based on PTFE tubing and UV gel

This work proposes a facile approach to fabricate a dual-core hollow waveguide based on two common and low-cost raw materials, namely polytetrafluoroethylene (PTFE) tube and ultraviolet (UV) gel. A silica glass tube is nested inside a heat-shrinkable PTFE tube. After heat treatment at 350 °C, the PTFE tube shrinks and then transforms into the low-index polymer on the outside of the silica tube. The PTFE-coated silica glass tubing is filled with UV gel followed by inserting a typical Ag/AgI mid-infrared (IR) hollow optical fiber. The UV gel is cured by UV radiation, forming a solid low-index layer between the PTFE-coated silica glass tubing and the Ag/AgI hollow optical fiber. A visible laser beam can be transmitted at a loss of 0.4 dB/m through the silica annulus between the low-index PTFE and UV gel layer. A 10.6-μm-wavelength CO2 laser beam is delivered through the Ag/AgI hollow optical fiber (core size 530 μm) and the transmission loss goes up from 1.63 to 3.22 dB/m as the bending angle increases from 0° to 90°.

Experimental demonstration of 3D printed terahertz polarization-insensitive flat devices based on low-index meta-gratings

Dielectric meta-gratings have achieved tremendous success in realizing high-efficiency wavefront control in terahertz range. Here, several efficient, polarization-insensitive, low-cost devices are investigated numerically and experimentally. First, an anomalous deflector based on a low-index polymer acrylonitrile butadiene styrene meta-grating is designed and measured around 0.1 THz. By breaking the distance limitation between the fixed bars and bending the terahertz beam into the T−1 diffraction order through the optimization of quadrumer unit cell, the efficiencies for 37° deflection under normal excitation reach 67.1% (56.4%) with the S-(P-) polarized terahertz wave, which are in good agreement with the simulated 71.8% (63.7%). Next, with regard to the concept of bending light by the proposed meta-grating array, a method for designing a terahertz flat lens is proposed and experimentally demonstrated with long focal length and polarization insensitivity. The proposed flat lens can achieve the measured numerical aperture of 0.604 (collection angle of 37.2°.) and focusing efficiency of 50.3% with normal incident of linear polarized terahertz wave at 0.1 THz. Also, a focal spot with the focusing distance of 65.9 mm is achieved. These designs can be manufactured by 3D printing at low cost, and provide promising applications in imaging, communication, information processing and materials science.

An Optimization of Two-Dimensional Photonic Crystals at Low Refractive Index Material

Photonic crystal (PC) is usually realized in materials with high refractive indices contrast to achieve a photonic bandgap (PBG). In this work, we demonstrated an optimization of two-dimensional PCs using a low refractive index polymer material. An original idea of assembly of polymeric multiple rings in a hexagonal configuration allowed us to obtain a circular-like structure with higher symmetry, resulting in a larger PBG at a low refractive index of 1.6. The optical properties of such newly proposed structure are numerically calculated by using finite-difference time-domain (FDTD) method. The proposed structures were realized experimentally by using a direct laser writing technique based on low one-photon absorption method.

Active beam steering and afocal zooming by nematic liquid crystal-infiltrated graded index photonic structures

This study presents active beam steering and afocal zooming of light by incorporating liquid crystals (LCs) with graded index photonic crystals (GRIN PCs). The GRIN PC structures are composed of low refractive index polymer annular rods with holes of gradually varying radii. To actively manipulate incident light, the annular rods are infiltrated with nematic LCs. By applying an external voltage to the infiltrated LCs, the effective index profile of the low-index GRIN PC structure is modulated without introducing any mechanical movement. The incident beam deflection and corresponding focal distance modulation are tuned only by controlling the applied bias voltage. In the present work, the hyperbolic secant refractive index profile is chosen to design GRIN PC structures. To design a GRIN PC structure with annular PCs, the Maxwell–Garnett effective medium approximation is employed. We analytically express the relation between infiltrated LCs and the gradient parameter to show the physical background of the tuning ability of the proposed devices. Beam steering and afocal zooming devices are analytically investigated via geometrical optics, and numerically realized with the help of a finite-difference time-domain method. A beam deflection with an angle change of Δθout = 44° and a light magnification with maximum ×2.15 are obtained within operating frequencies of a/λ = [0.10–0.15] and a/λ = [0.15–0.25], respectively, where ‘a’ is the lattice constant and λ is the incident wavelength. The corresponding operating frequency bandwidths are calculated as 40% and 50% for the beam steering and afocal zooming applications, respectively. LCs are inexpensive materials and work under low voltage/power conditions. This feature can be used for designing an electro–optic GRIN PC device that has the potential for use in a wide variety of optical applications.

Effect of bending on emission characteristics of large core Yb/Al doped optical fiber with depressed cladding structure

The large core Yb/Al doped optical fiber with depressed cladding structure for fiber laser applications was fabricated. The measured bending loss was found to increase to 0.11 dB m−1 with the decrease of bending diameter to 60 mm and then increase sharply to 1.25 dB m−1 down to 10 mm. The broad emission band appeared from 1000 nm to 1100 nm upon pumping with the 976 nm laser diode. When the light pumping with launching onto the place between the depressed cladding and the low-index polymer coating, the emission of ~4.50 dB increased at the bending diameter of 60 mm, the optimum bending diameter for an efficient pumping.

Highly sensitive surface plasmon resonance biosensor based on a low-index polymer optical fiber.

A highly sensitive refractive index sensor based on surface plasmon resonance in a side-polished low-index polymer optical fiber is proposed for biosensing. Benefitting from the low refractive index of the fiber core, the sensitivity of the device can reach ~44567 nm/RIU theoretically for aqueous solutions, at the expense of a lowered upper detection limit that is down to ~1.340. The sensor is fabricated by coating 55-nm-thick Au-film on the polished surface of a graded-index perfluorinated polymer optical fiber. Results show that the sensor exhibits a sensitivity of ~22779 nm/RIU at 1.335 with a figure of merit of 61.2. When employed for glucose sensing, the sensor presents an averaged sensitivity of 24.50 nm/wt%, or 0.46 nm/mM. This device is expected to have potential applications in cost-effective bio- and chemical-sensing.

Investigation of Temperature Sensitivity of a Polymer-Overlaid Microfiber Mach-Zehnder Interferometer.

The temperature sensitivity of the free spectral range (FSR) for a polymer-overlaid microfiber Mach-Zehnder interferometer (MZI) is investigated both theoretically and experimentally. The waist diameter of the optical microfiber can be controlled to alter the thermal expansion and optic properties of the polymer-coated MZI. Inserting an optical microfiber with a strong evanescent field into the MZI, a low index polymer with high thermal characteristics is deposited on the surface of the microfibers to realize a polymer-overlaid microfiber MZI. It was found that the thermal expansion factor in the proposed MZI plays an important role in the temperature sensitivity of the FSR. The temperature sensitivity of the polymer-overlaid microfiber MZI is improved, which is measured to be −8.29 nm/°C at 25 °C. The optical transmission spectrum of the polymer-overlaid microfiber MZI is converted to the spatial frequency spectrum via fast Fourier transform. The temperature sensitivity of the spatial frequency in the proposed polymer-overlaid MZI is estimated to be 18.31 pm−1 °C−1, which is 17 times higher than that of the microfiber MZI without polymer coating (1.04 pm−1 °C−1).

Raman lasing and Fano lineshapes in a packaged fiber-coupled whispering-gallery-mode microresonator

We report Raman lasing and the optical analog of electromagnetically-induced-transparency (EIT) in a whispering-gallery-mode (WGM) microtoroid resonator embedded in a low refractive index polymer matrix together with a tapered fiber coupler. The microtoroid resonator supports both single mode and multimode Raman lasing with low power thresholds. Observations of Fano and EIT-like phenomena in a packaged microresonator will enable high resolution sensors and can be used in networks where slow-light effect is needed. These results will open up new possibilities for portable, robust, and stable WGM microlasers and resonator-based sensors for applications in various environments.