The synthesized (Y0.5Sb0.5)xTi1-xO2 (YSTO) ceramics (x=0.005 and 0.05) were investigated for their potential application in humidity sensors. The rutile phase of TiO2 for YSTO ceramics was confirmed. SEM images revealed dense microstructures, with relative densities and average grain sizes decreasing with doping concentrations. YSTO ceramics exhibited outstanding dielectric constants (ε′∼ 6.617.31×104) and low loss tangents (tanδ∼0.0190.067) at 25°C and 1 kHz. Capacitive humidity sensing properties demonstrated significant increases in capacitance with rising relative humidity (%RH) levels, with sensitivities of 165 and 386 pF/%RH. Hysteresis analysis showed narrow loops with low hysteresis error (γH∼1.4 and 2.0 %). Rapid response (∼9 s) and recovery (∼7 and 4 s) times, with stable repeatability, were observed. The presence of VO•• and SbTi• was confirmed, enhancing humidity sensing through chemical absorption reactions. This analysis underscores the potential of YSTO ceramics for humidity sensors, emphasizing the role of microstructural characteristics and induced defects in sensor performance, which is vital for the development of advanced sensing technology.
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