Low Heavy Rare Earth Research Articles

Geochemical Signatures of Mafic Volcanic Rocks in Modern Oceanic Settings and Implications for Archean Mafic Magmatism

Abstract Greenstone belts are dominated by mafic volcanic rocks with geochemical characteristics that indicate a range of possible geodynamic influences. Many analogies with modern tectonic settings have been suggested. Increasing exploration of the modern oceans and comprehensive sampling of volcanic rocks from the sea floor are now providing unique opportunities to characterize different melt sources and petrogenesis that can be more closely compared to greenstone belts. In this study, we have compiled high-quality geochemical analyses of more than 2,850 unique samples of submarine mafic volcanic rocks (<60 wt % SiO2) from a wide range of settings, including mid-ocean ridges, ridge-hotspot intersections, intraoceanic arc and back-arc spreading centers, and ocean islands. The compiled data show significant geochemical variability spanning the full range of compositions of basalts found in greenstone belts. This diversity is interpreted to be due to variable crustal thickness, dry melting versus wet melting conditions, mantle mixing, and contamination. In particular, different melting conditions have been linked to mantle heterogeneity, complex mantle flow regimes, and short-lived tectonic domains, such as those associated with diffuse spreading, overlapping spreading centers, and triple junctions. These are well documented in the microplate mosaics of the Western Pacific. Systematic differences in mafic volcanic rock compositions in modern oceanic settings are revealed by a combination of principal components analysis and unsupervised hierarchical clustering of the compiled data. Mafic volcanic rocks from most arc-back arc systems have strongly depleted mantle signatures and well-known subduction-related chemistry such as large ion lithophile element (LILE) enrichment in combination with strong negative Nb-Ta anomalies and low heavy rare earth elements (HREEs). This contrasts with mafic volcanic rocks in Archean greenstone belts, which show no, or at least weaker, subduction-related chemistry, a less depleted mantle, less wet melting, and variable crustal contamination. The differences are interpreted to be the result of the lower mantle temperatures, thinner crust, and subduction-related processes of present-day settings. However, mafic rocks that are geochemically identical to those in Archean greenstone belts occur in many modern back-arc basins, including the Lau basin, East Scotia ridge, Bransfield Strait, and Manus basin, which are characterized by fertile mantle sources, high heat flow, and complex spreading regimes typical of small-scale microplate mosaics. These types of settings are recognized as favorable for volcanogenic massive sulfide (VMS) deposits in modern and ancient greenstone belts, and therefore the particular geochemical signatures of the mafic volcanic rocks are potentially important for area selection in base metal exploration.

Late Paleoproterozoic collision-related granitic magmatism in the Cuoke Complex, SW China: New evidence for the early evolution of the Yangtze Block

The Paleoproterozoic tectonic evolution of the southwestern Yangtze Block has been ambiguous due to the scarce preservation of geological records, confusing the history of the entire Yangtze Block in the Nuna supercontinent. We here report an integrated study involving petrology, whole-rock geochemistry, zircon U-Pb geochronology and Hf-Nd isotopes of the recently identified late Paleoproterozoic granitoids from the Cuoke Complex in the southwestern Yangtze Block. LA-ICP-MS zircon U-Pb dating reveals three episodes of granitic magmatism at ca. 1.94 Ga, 1.89 Ga, and 1.85 Ga. Geochemically, the ca. 1.94 Ga albite granites (AGs) and ca. 1.89 Ga and 1.85 Ga monzogranites (MGs) exhibit features of I-type granite, while the ca. 1.85 Ga AGs display characteristics of A-type granite. The zircon εHf(t) values range from −13.0 to −8.1 for the 1.94–1.89 Ga granitoids and from −8.9 to −7.2 for the ca. 1.85 Ga granitoids, with two-stage model ages of 3.3–3.1 Ga and ca. 3.0 Ga, respectively, indicative of their derivation from remelting of Mesoarchean crustal materials. The relatively low heavy rare earth elements (HREEs) (e.g., Yb < 1.9 ppm) and Y (<18 ppm) contents, and moderately negative Eu anomalies of the ca. 1.94–1.89 Ga granitiods suggest they may have been produced in a late collisional or earliest post-collisional setting. The ca. 1.85 Ga AGs and MGs were probably formed in a post-collisional setting indicated by their high HREE (e.g., Yb > 1.9 ppm) and Y (>18 ppm) contents and strongly negative Eu anomalies. Combined with available data, we provisionally divided the tectonic evolution of the southwestern Yangtze Block into four stages: 1) ca. 2.01 Ga subduction, 2) ca. 1.97–1.95 Ga metamorphism associated with collision events, 3) ca. 1.94–1.89 Ga late collisional or earliest post-collisional stage, and 4) ca. 1.85 Ga post-collisional extensional stage. The subduction and collision of the southwestern Yangtze Block initiated slightly later than the northern part, but their near-synchronous tectonic process since ca. 1.97 Ga suggest they may have collaged together at that time. The ca. 1.94–1.89 Ga and ca. 1.85 Ga late collisional to post-collisional granitic magmatism likely recorded the convergence of discrete Archean rock provinces of the Yangtze Block during the Nuna supercontinent assembly.

Crust-Mantle Interaction Controls the Formation of High-Mg Adakitic Rocks: Evidence from Early Cretaceous Intrusive Complexes in Luxi Terrane, North China Craton

AbstractHigh-Mg adakite rocks preserve crucial information about the crust-mantle interactions during the magma evolution. The Luxi Terrane, southeastern North China Craton, stores a set of Early Cretaceous high-Mg adakite rocks; nevertheless, their petrogenesis remains controversial. In this study, we present new whole-rock geochemistry, zircon U-Pb-Hf isotopes in the Tiezhai, Jinxingtou, and Sanshanyu complexes which are composed of gabbroic diorite, diorites, syenites, and monzonites. Field observations and zircon U-Pb dating indicate that all of the rock units crystallized contemporaneously at ca. 125–120 Ma. They are characterized by high Al2O3 and Sr contents, and low MgO, Y, Yb, and heavy rare earth elements contents, coupled with high Sr/Y values (42–163), showing adakitic affinities. The magma mixing process is supported by the following ample evidence: (1) the disequilibrium mineral textures and mafic enclaves; (2) high Mg# values (37–69, Mean = 58); and (3) widely zircons εHf(t) values (−25.6 to +7.8). The signature geochemical characteristics support that the adakites were generated by magma mixing of ancient crust-derived melts and relatively mafic melts from metasomatized mantle source. In combined with regional geology, the Early Cretaceous high-Mg adakites in Luxi Terrane represent the magmatic response of intensive crust-mantle interaction caused by the underplating of voluminous mantle-derived magma in an extension intracontinental setting.

Effect of diffusing TbH3 on magnetic, corrosion and mechanical properties of NdFeB magnet

Grain boundary diffusion can enhance the coercivity of NdFeB magnets with low consumption of heavy rare earths Dy/Tb. This work systematically studied the effects of diffusing TbH3 on the magnetic, corrosion and mechanical properties of NdFeB magnet. The results show that the remanence Br and maximum energy product (BH)max of magnets slightly decreased after diffusion, while coercivity increased from 14.47 kOe to 22.08 kOe with 0.20 wt% Tb usage. The formation of Tb-rich shell and RE-(FeO) metallic-type grain boundary phases attribute to the enhancement of coercivity. The fracture and corrosion behavior of NdFeB magnet are discussed before and after diffusion. This study provides an experiment and theoretical basis for the industry fabrication of high-performance magnet with low heavy rare earth.

Ancient Metasomatism in the Lithospheric Mantle, Eastern North China Craton: Insights from In-Situ Major and Trace Elements in Garnet Xenocrysts, Mengyin District

Mantle metasomatism refers to the interaction between mantle melt, fluid, and mantle rock. It not only affects the physical and chemical properties of the lithospheric mantle but also plays an important role in the process of metal and gem mineralization. In order to explore the nature and evolution of metasomatism in the lithospheric mantle of the Mengyin area in the eastern part of the North China Craton, this paper combines the previous data of garnet inclusions in diamonds and analyzes the major and trace elements of garnet xenocrysts in the Shengli No. 1 kimberlite pipe from the EPMA and LA-ICP-MS experiments. The experiments show that the garnet xenocrysts of the Shengli No. 1 kimberlite pipe are mainly lherzolitic and harzburgitic garnets. The content of Zr and TiO2 in some garnets are low, which are the characteristics of depleted garnets. Conversely, another group of garnets display high Zr and TiO2 contents, indicative of high-temperature melt metasomatism. When comparing the Ti/Eu ratio of the depleted garnets to that of the primary mantle, a significantly lower value is observed. Additionally, the (Sm/Er)N value undergoes minimal changes, while the Zr/Hf value exceeds that of the primary mantle. These characteristics are indicators of carbonatite melt metasomatism. Garnets that are affected by high-temperature melt metasomatism exhibit low (Sm/Er)N content, a significant variation in the Ti/Eu ratio, and a Zr/Hf value greater than that of the primary mantle. These characteristics indicate the influence of kimberlite melt metasomatism. Garnets impacted by carbonatite melt metasomatism display a strong sinusoidal distribution pattern of rare earth elements (REE) and are often found as lherzolitic garnet xenocrysts and garnet inclusions in diamond. On the other hand, garnets influenced by kimberlite melt metasomatism exhibit a slight sinusoidal REE distribution pattern in harzburgitic garnets and a slight sinusoidal REE distribution or a flat pattern from medium rare earth elements (MREEs) to heavy rare earth elements (HREEs) in lherzolitic garnet xenocrysts. Based on these findings, it is evident that there are at least two types of metasomatism occurring in the lithospheric mantle of the Mengyin area in the eastern part of the North China Craton. The first type involves the metasomatism of early carbonatite melt to the mantle peridotite. Garnets formed under this condition exhibit high Sr and LREE contents, as well as low Zr, Hf, Ti, Y, and HREE contents, indicating depletion characteristics. The second type entails the metasomatism of late kimberlite melts affecting the mantle peridotite. Garnets formed under this process display high Zr, Hf, Ti, Y, and HREE contents.

Evaluation of Thermal Stability and Its Effect on the Corrosion Behaviour of Mg-RE Alloys Processed by High-Pressure Torsion

The evolutions of microstructure and texture and the corrosion behaviour of low light rare-earth containing Mg-1.4Nd and low heavy rare-earth containing Mg-0.6Gd and Mg-0.4Dy (wt.%) were evaluated and compared after processing by high-pressure torsion (HPT) and isochronal annealing at 250 and 450 °C for 1 h using electron backscatter diffraction (EBSD) and electrochemical tests in a 3.5% (wt.%) NaCl solution. The EBSD results show that dynamic recrystallisation (DRX) was restricted in the Mg-1.4Nd alloy which led to a heterogenous deformation microstructure whereas the Mg-0.6Gd and Mg-0.4Dy alloys exhibited a homogenous deformation microstructure formed mostly of equiaxed dynamically recrystallised DRX grains. The HPT processing caused the development of a deviated basal texture in the three alloys. A good thermal stability of the three alloys was noticed after annealing at 250 °C. By contrast, annealing at 450 °C led to a homogenous equiaxed microstructure and weakening of texture for the Mg-1.4Nd alloy and a heterogenous bimodal microstructure with a stable basal texture for the Mg-0.6Gd and Mg-0.4Dy alloys. The HPT-processed Mg–RE alloys exhibited an improved corrosion resistance due to grain refinement. Thereafter, the corrosion resistance of the Mg-0.6Gd and Mg-0.4Dy alloys decreased with increasing annealing temperature due to an increase in grain size while the corrosion resistance of the Mg-1.4Nd alloy was improved after annealing at 450 °C due to precipitation and texture weakening.

Geochemical Signatures of Felsic Volcanic Rocks in Modern Oceanic Settings and Implications for Archean Greenstone Belts

Abstract Felsic volcanic rocks are abundant in ancient greenstone belts and important host rocks for volcanogenic massive sulfide (VMS) deposits. About half of all VMS deposits are hosted by dacite or rhyolite, an association that reflects anomalous heat flow during rifting, partial melting of basaltic crust, and fractional crystallization in high-level magma chambers. For over 30 years, geochemical signatures of these rocks (e.g., F classification of Archean rhyolites) have been widely used to identify possible hosts for VMS deposits in ancient greenstone belts. However, comparisons with modern oceanic settings have been limited, owing to a lack of samples of felsic volcanic rocks from the sea floor. This is changing with increasing exploration of the oceans. In this study, we have compiled high-quality geochemical analyses of more than 2,200 unique samples of submarine felsic volcanic rocks (&amp;gt;60 wt % SiO2) from a wide range of settings, including mid-ocean ridges, ridge-hot-spot intersections, intraoceanic arc and back-arc spreading centers, and ocean islands. The compiled data show significant geochemical diversity spanning the full range of compositions of rhyolites found in ancient greenstone belts. This diversity is interpreted to reflect variations in crustal thickness, the presence or absence of slab-derived fluids (dry melting versus wet melting), and mantle anomalies. Highly variable melting conditions are thought to be related to short-lived microplate domains, such as those caused by diffuse spreading and multiple overlapping spreading centers. Systematic differences in the compositions of felsic volcanic rocks in the modern oceanic settings are revealed by a combination of principal components analysis, unsupervised hierarchical clustering, and supervised random forest classification of the compiled data. Dacites and rhyolites from midocean ridge settings have moderately depleted mantle signatures, whereas rocks from ridge-hot-spot intersections and ocean islands reflect enriched mantle sources. Felsic volcanic rocks from arc-back-arc systems have strongly depleted mantle signatures and well-known subduction-related chemistry (strong large ion lithophile element enrichment in combination with strong negative Nb-Ta anomalies and low heavy rare earth elements [HREEs]). This contrasts with felsic volcanic rocks in Archean greenstone belts, which show high field strength element and HREE enrichment (so-called FIIIb-type) due to a less depleted mantle, a lack of wet melting, and variable crustal contamination. The differences between modern and ancient volcanic rocks are interpreted to reflect the lower mantle temperatures, thinner crust, and subduction-related processes in present-day settings. We suggest that the abundance of FIIIb-type felsic volcanic rocks in Archean greenstone belts is related to buoyant microplate domains with thickened oceanic crust that were better preserved on emerging Archean cratons, whereas in post-Archean tectonic settings most of these rocks are subducted.

Super-high coercivity NdFeB magnet fabricated with double Tb-rich/lean shells by double alloy method and grain boundary diffusion

In this work, the high performance NdFeB magnet were fabricated by double alloy method and grain boundary diffusion Tb70Cu20Ga10 alloys. The maximum energy product (BH)max and coercivity Hcj of the magnet are 45.33 MGOe and 35.46 kOe, respectively. The reversible temperature coefficients of coercivity of the diffusion magnets improve from − 0.456%/°C to − 0.412%/°C at the range of 22 °C −180 °C. The magnetostatic loss of NdFeB magnet was analyzed in high temperature applications by general finite element method (FEM). The RE-(Fe,CuGaO) grain boundary phases and double Tb-rich/lean shells improve the utilization rate of heavy rare earths and coercivity of magnets after diffusion. The magnetization reversal mechanism of double core-shell microstructures had been discussed. This work may shed light on developing coercivity above 30 kOe of NdFeB magnet with low heavy rare earth through modified microstructure.

The geochronology, geochemistry and petrogenesis of ca. 2.65 Ga tonalites and ca. 2.61 Ga amphibolites in the Jiefangyingzi area: Implications for the northern boundary of the North China craton

The Bayan Obo–Duolun–Chifeng–Kaiyuan (BDCK) Fault is considered the boundary between the North China Craton (NCC) and Central Asian Orogenic Belt (CAOB). However, the site of this boundary from Duolun to Chifeng and Kaiyuan remains highly controversial. Here, we present an integrated study of petrology, whole‐rock geochemistry, and zircon U–Pb and Sr–Nd–Hf isotope compositions for tonalites and amphibolites in the Bainaimiao arc belt (BAB) to better constrain the northern NCC margin. The tonalites are similar to NCC tonalite–trondhjemite–granodiorites (TTGs), characterized by relatively high Na2O/K2O and Sr/Y ratios and fractionated rare earth element (REE) patterns, with high light REE (LREE) but low heavy REE (HREE) concentrations. Laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) zircon U–Pb dating yields formation ages of 2599–2674 Ma, with a weighted average of 2649.6 ± 3.7 Ma. The εHf(t) values (3.5–7.5), two‐stage model ages (2673–2793 Ma), whole‐rock positive εNd(t) values (1.3–1.9), and two‐stage model ages (2841–2880 Ma) suggest that the Neoarchean tonalites likely originated from remelting of thickened Meso‐Neoarchean mafic crust. LA–ICP–MS U–Pb isotope data reveal that the amphibolites formed at ~2610 Ma. They have high‐Fe tholeiitic compositions and are close to normal mid‐ocean ridge basalt (N‐MORB)‐like rocks, indicating that they were generated from partial melting of the depleted mantle. The existence of Neoarchean basement rocks, combined with seismic and isotope data, suggests that the Jiefangyingzi area is part of the Trans‐North China Orogen (TNCO) in the NCC rather than part of the CAOB and that the northern boundary of the NCC in Chifeng is located north to the Jiefangyingzi area.

The Ouarzazate Supergroup and its plutonic keel: the relicts of an Ediacaran silicic large igneous province in North Africa

Ouarzazate igneous rocks from Sidi Ifni, SW Morocco, define a &gt;3 km thick pile of mostly pyroclastic falls and flows of rhyolitic and dacitic ignimbrite and tuff, underlain by co-magmatic granitoid plutons. These rocks formed during two closely spaced periods of magmatism dated to c. 595–585 and 575–560 Ma, with the majority of rocks comprised of ferroan alkali feldspar rhyolite, syenorhyolite or monzorhyolite. They can be divided into high and low heavy rare earth element types that discriminate as both volcanic arc and within-plate magma types. Coeval, but less common, mafic rocks consist of olivine-normative trachybasalt and basaltic trachyandesite. Temporal and compositional equivalents of the Ouarzazate volcanic and intrusive rocks crop out widely across North Africa and extend into the previously contiguous regions of NE North America. Collectively, these erupted/shallowly emplaced Ouarzazate-like rocks represent asthenospheric partial melts that are variably hybridized by additions from the lithospheric mantle and crust. The root cause of asthenospheric upwelling remains unknown, although the foundering of pre-collison subducted oceanic lithosphere may provide a plausible explanation. The vast geographical extent over which Ouarzazate-like igneous rocks are found, together with their composition and intra-plate setting, support the conclusion that these rocks represent the remnants of a late Ediacaran silicic large igneous province. Supplementary material: A tabulation of the geochronologic and geochemical datasets from Sidi Ifni is available at https://doi.org/10.6084/m9.figshare.c.5945756

Diffusion behavior and coercivity enhancement of Tb-containing NdFeB magnet by dip-coating TbH3

There is a growing demand for high coercivity of NdFeB magnets with low heavy rare earth in the emerging applications. In this work, dip-coating 0.02 g and 0.09 g TbH3 on the Tb-containing NdFeB magnet enhance coercivity at room temperature，respectively. The highest coercivity achieve about 30 kOe at room temperature after diffusion, which can apply to traction motors of electric vehicles. The magnetic field intensity distribution of magnet was analyzed by finite element method. Microstructures show TbH3 coat contents and original composition of NdFeB magnet influences the formation of Tb-rich shell and grain boundary phase, and determine finally diffusion depth and Tb concentration. The Tb atoms diffuse into the interior of the magnet, forming a network Tb-rich shell existed around Nd2Fe14B grains, resulting in the coercivity enhancement.

The Early Cretaceous tectonic evolution of the Neo-Tethys: constraints from zircon U–Pb geochronology and geochemistry of the Liuqiong adakite, Gongga, Tibet

AbstractThe subduction model of the Neo-Tethys during the Early Cretaceous has always been a controversial topic, and the scarcity of Early Cretaceous magmatic rocks in the southern part of the Gangdese batholith is the main cause of this debate. To address this issue, this article presents new zircon U–Pb chronology, zircon Hf isotope, whole-rock geochemistry and Sr–Nd isotope data for the Early Cretaceous quartz diorite dykes with adakite affinity in Liuqiong, Gongga. Zircon U–Pb dating of three samples yielded ages of c. 141–137 Ma, indicating that the Liuqiong quartz diorite was emplaced in the Early Cretaceous. The whole-rock geochemical analysis shows that the Liuqiong quartz diorite is enriched in large-ion lithophile elements (LILEs) and light rare-earth elements (LREEs) and is depleted in high-field-strength elements (HFSEs), which are related to slab subduction. Additionally, the Liuqiong quartz diorite has high SiO2, Al2O3 and Sr contents, high Sr/Y ratios and low heavy rare-earth element (HREE) and Y contents, which are compatible with typical adakite signatures. The initial 87Sr/86Sr values of the Liuqiong adakite range from 0.705617 to 0.705853, and the whole-rock ϵNd(t) values vary between +5.78 and +6.24. The zircon ϵHf(t) values vary from +11.5 to +16.4. Our results show that the Liuqiong adakite magma was derived from partial melting of the Neo-Tethyan oceanic plate (mid-ocean ridge basalt (MORB) + sediment + fluid), with some degree of subsequent peridotite interaction within the overlying mantle wedge. Combining regional data, we favour the interpretation that the Neo-Tethyan oceanic crust was subducted at a low angle beneath the Gangdese during the Early Cretaceous.

Origin of low-MgO primitive intraplate alkaline basalts from partial melting of carbonate-bearing eclogite sources

Alkaline basalts occur widely in intraplate settings and carbonate-bearing mantle sources such as carbonated peridotites are increasingly regarded to play a key role in their formation. Carbonated eclogites, most likely the products of subducted carbonate-bearing altered oceanic crust, are probable alternative ingredients in the mantle sources of many intraplate alkaline basalts, highlighting the importance of the subduction-driven deep carbon cycle. However, this widely proposed hypothesis remains enigmatic because the recognition of low-MgO primitive alkaline basalts predicted by experiments is scarce. Here we show that Cenozoic continental intraplate alkaline basalts occurring above the stagnant oceanic slab in the mantle transition zone beneath the Hannuoba region, eastern China, display geochemical features consistent with their origin as low-degree partial melts of carbonate-bearing eclogites. Their MgO contents correlate positively with CaO, Ba/Th and Ti/Eu, but negatively with Dy/Yb and εNd. Remarkably, the most primitive alkaline basalts are characterized by low MgO (<5.25 wt.%), low heavy rare earth elements and Sc contents, low CaO/Al2O3 (<0.41), low Ti/Eu (<3380), but Dy/Yb (>7.1) higher than those of ocean island basalts (OIBs). These features cannot be ascribed to differentiation from high-MgO alkaline basalts because significant amounts of crystallization of clinopyroxene and garnet did not occur during ascent. Differentiation also cannot account for the correlations of time-integrated Sr-Nd isotopes with MgO, Dy/Yb and Ba/Th. Instead, the linear correlations mainly reflect strong interaction between ascending primitive alkaline melts and the lithospheric mantle. The compositions of primitive alkaline basalts reflect the key control of garnet and clinopyroxene in the mantle residue (eclogites), and the Ti, Zr and Hf anomalies further indicate the critical effect of carbonates in the eclogite source. Partial melting of the carbonate-bearing eclogites likely occurred in the uppermost asthenosphere. The production of alkaline basalts with low MgO contents by partial melting of carbonate-bearing eclogite below the peridotite solidus in an intraplate setting has been overlooked and the magmas were instead often considered to be highly evolved. Recycled altered oceanic crust thus may not only cause metasomatism of the deep mantle but may also serve as a direct source of mafic melts. These results on natural rocks support the experiment-based model for subducted altered oceanic crustal material and also indicate its diverse fate in the mantle.

Felsic Igneous Rocks in the Hua'aobaote Pb‐Zn‐Ag Polymetallic Orefield, Southern Great Xing'an Range: Genesis, Metallogenetic and Tectonic Significance

AbstractThe Hua'aobaote Pb‐Zn‐Ag Polymetallic orefield is situated in the southern section of the Great Xing'an Range (GXAR), which has experienced extensive magmatism. Since the Paleozoic, there are two stages of magmatism in Hua'aobaote orefield occurred in the Paleozoic and Mesozoic. The Mesozoic magmatism is of great significance for the Pb‐Zn‐Ag Polymetallic mineralization in Hua'aobaote orefield. In this study, new geochemical data was obtained to discuss the timing and petrogenesis of the magmatic rocks and its geodynamic and metallogenic significance. Zircon U‐Pb ages reveal that the felsic igneous rocks from the Hua'aobaote orefield were formed in the Early Permian (294.8 ± 3.2 Ma) and Early Cretaceous (132.6 ± 1.4 Ma). Geochemically, the Early Permian granodiorite porphyrite is characterized by high Sr/Y (42–63) ratios and Mg#(62.24–70.74) values and low heavy rare earth element (HREE) (5.09–6.79 ppm) contents. The granodiorite porphyrite is also characterized by depleted Sr–Nd initial isotopic signatures [∊Nd(t) = 5.91–7.59, (87Sr/86Sr)i= 0.7029–0.7030], exhibiting adakitic characteristics. The Early Cretaceous granite porphyry and rhyolite are A‐type felsic igneous rocks, and demonstrate high SiO2, Na2O + K2O and rare earth element (REE) contents, low CaO and MgO contents, low (87Sr/86Sr)iratios (0.7044–0.7058), and positive∊Nd(t) values (2.57–4.65). Whole‐rock Pb isotopic compositions in granodiorite porphyrite are:206Pb/204Pb = 17.631–18.149,207Pb/204Pb = 15.422–15.450, and208Pb/204Pb = 37.325–37.729. The granite porphyry and rhyolite have initial206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.106–19.309, 15.489–15.539, and 37.821–38.05, respectively. Sr‐Nd‐Pb isotopic evidence suggests that the Early Permian granodiorite porphyrite is likely to derive from slab melts and modified by peridotitic mantle wedge in the subduction tectonic setting of the Paleo‐Asian Ocean. The Early Cretaceous A‐type felsic igneous rocks were derived from juvenile lower crust, accompanied by limited crustal contamination and various degree of fractional crystallisation during magma emplacement. The Early Cretaceous magmatism and related mineralization were formed in a post‐orogenic tectonic setting that attributed to the closure of the Mongol–Okhotsk Ocean. Pb isotopic data for the various rock units in the study area indicate that the Mesozoic magma source contributed substantial Pb, Zn, and Ag to the Hua'aobaote deposit.

Coercivity and thermal stability enhancement of NdFeB magnet by grain boundary diffusion Tb80Al20 alloys

Grain boundary diffusion of Tb and Al elements can improve the coercivity and optimize grain boundary of NdFeB magnets. In this paper, we investigated magnetic property and microstructure evolution of sintered NdFeB magnets by grain boundary diffusion Tb80Al20 alloys. The coercivity and thermal stability of the magnets were effectively improved. Microstructural analysis confirmed the formation of Tb-rich shells and continuous grain boundary, contributing to coercivity enhancement of magnet. The element distribution and diffusion mechanism of the magnets have been disused. This work may shed light on developing low heavy rare earth sintered NdFeB magnets.

When did the final closure occur of the eastern Paleo-Asian Ocean: Constraints from the latest Early–Middle Triassic adakitic granites in the southeastern Central Asian Orogenic Belt

There is a broad consensus that the Solonker suture zone marked the final closure of the eastern Paleo-Asian Ocean, which led to the formation of the eastern segment of the Central Asian Orogenic Belt (CAOB). However, when and how the final closure occurred still remained controversial. Located in a key position in the southeastern CAOB, the Early Mesozoic magmatic rocks along the northern margin of the North China Craton provide a crucial window to evaluate the subduction and final closure processes of the eastern Paleo-Asian Ocean. To address these issues, data on geochronological, whole-rock geochemical, whole-rock Sr-Nd and in situ zircon Hf isotopic study of the Early Mesozoic granites, as well as major-trace elements compositions of the apatites are reported here. Zircon U-Pb dating results showed that our studied granites were emplaced in the Middle Triassic (243.1–242.6 Ma). These granites have high Sr (250–652 ppm) contents, low heavy rare earth elements (HREEs), Yb (0.46–0.77 ppm) and Y (4.48–8.15 ppm) contents, and show high Sr/Y and (La/Yb)N signatures (36–108 and 21–35, respectively), with negligibly negative to moderately positive Eu anomalies (δEu = 0.80–1.36), indicating adakite-like affinities. Most of these granite samples are characterized by high K2O contents (3.30–4.83 wt%), and belong to the high-K calc-alkaline and shoshonitic series, with peraluminous affinities (A/CNK = 1.02–1.28). Besides, their low MgO (0.10–0.34 wt%), Cr (0.99–3.50 ppm), and Ni (0.96–2.40 ppm) contents indicate a thickened continent crustal origin, rather than subducting slab-derived or delaminated lower crust-derived melts. Analyzed granite samples yielded in situ zircon εHf (t) values (–8.3 to + 5.8) and whole-rock εNd (t) values (–4.38 to –5.69), with predominately negative values, indicating mixture sources of major recycled old components and limited juvenile crustal materials. Their parental magma was originated by partial melting of thickened lower crust, under garnet amphibolite facies conditions. Thickened crust in the southeastern CAOB yielded crustal thickness of ~54–64 km estimated from (La/Yb)N ratios of these lower crust-derived granites. These constraints, in conjunction with the E-W trending collision-related adakitic granitoids (250–243 Ma) along the southeastern CAOB, and other geological evidence, recorded a tectonic transition from this prolonged subduction to final closure of the eastern Paleo-Asian Ocean.

Multi-stage garnet formation and destruction in Kimberley harzburgitic xenoliths, South Africa

Thirty-nine garnet harzburgites from Kimberley in the Kaapvaal Craton (South Africa) were studied to constrain the origin, age and evolution of sub-cratonic lithospheric mantle (SCLM). In order to avoid chemical overprinting by recent metasomatism, only garnet harzburgites that appeared clinopyroxene-free to the naked eye were sampled. The majority of garnets were, however, in equilibrium with clinopyroxene (24 of 39). Whole rock and mineral major–trace element geochemistry and garnet Sr–Nd–Hf isotope data are presented. Equilibration pressures range from 3.8–6.1 GPa, indicating the harzburgites were derived from a large portion of the SCLM (~115–185 km). High olivine Mg# (~93.4, n = 39) and low whole rock heavy rare earth elements (HREE) contents are consistent with large degrees of partial melting (>45%) and garnet exhaustion leaving a dunitic residue with olivine ≥90%, orthopyroxene ≤10% and HREE <0.01 times chondrite. Mineral modes, whole rock Al2O3 (0.5–3.2 wt%) and SiO2 (43.1–49.1 wt%), however, indicate heterogeneous re-introduction of garnet (≤13%) and orthopyroxene (≤50%). Harzburgites with high garnet and relatively low orthopyroxene modes (mostly ~7–13% and ~ 9–30%; n = 6) are characterised by mildly sinusoidal garnet REE patterns (Tb-Dy minimum and high HREE) and Archaean depleted Hf TDM ages (2.7–3.3 Ga; εHfe: +190 to +709). In contrast, harzburgites with high orthopyroxene and relatively low garnet and modes (~1.5–7.5% and ~ 25–50%; n = 19) are characterised by highly sinuous REE patterns (Ho-Yb minimum and low HREE) and Proterozoic enriched Hf TDM ages (0.7–1.6 Ga; εHfe: −16 to +6). It is inferred that Archaean G10 garnet re-introduction caused a significant increase in HREE, making melt depletion models based on HREE inaccurate. Orthopyroxene addition, a few hundred million years later, most likely at ~2.7 Ga and associated with Ventersdorp magmatic activity, caused partial consumption of garnet and olivine, and changed garnet compositions leading to: 1) Cr/Al ratio increase; 2) HREE decrease; 3) more sinusoidal REE patterns; and 4) un-radiogenic 176Hf/177Hf. Garnets define a Lu-Hf isochron age of 2702 ± 64 Ma (εHfi = +44, n = 31), which is interpreted as a consequence of partial isotopic equilibrium within the SCLM and mixing of the garnet- and orthopyroxene-rich metasomatic components. The low LILE contents and absence of Nb-Ta anomalies are consistent with modal metasomatism caused by intra-plate magmatism. In addition, the REE signatures of metasomatic agents in equilibrium with the garnets suggest that carbonatitic melts and SiO2-rich hydrous melts were responsible for re-introduction of garnet and orthopyroxene, respectively. Sr-Nd isotope systematics were disrupted associated with kimberlite magmatism (Nd isochron: 217 ± 58 Ma, εNdi = +4; n = 34), consistent with recent G10 garnet transformation into G9 garnets (Ca + Fe-enriched). This event may have caused garnet addition (up to 1%), suggesting that garnet was formed or destroyed in at least 4 different events: i) initial extensive polybaric melting, ii) asthenospheric melts re-introducing the bulk of the garnet, iii) orthopyroxene addition and garnet loss, all in the Archaean, and iv) minor garnet addition possibly related to recent kimberlite magmatism prior to eruption.

Transition in tectonic regime from the Paleo-Asian Ocean to Paleo-Pacific Ocean: constraints from the Jurassic adakitic and I-type granites, and calc-alkaline diorites at the northern margin of the North China Craton

ABSTRACT There is a broad consensus that subduction of the Paleo-Pacific oceanic plate has caused extensive magmatism, lithospheric deformation, and metal mineralization in the eastern margin of the Eurasian continent during the Late Mesozoic. However, the onset and extent of subduction of the Paleo-Pacific Ocean, especially the timing of the transition in tectonic regime from the Paleo-Asian Ocean to Paleo-Pacific, and extent of the subduction of the Paleo-Pacific Ocean remain poorly constrained. To address these key issues, we present regional geological observations, zircon U–Pb dating, whole-rock geochemistry, and Hf isotopic compositions of the Jurassic intrusions at the northern margin of the North China Craton, with the aim of constraining their petrogenesis and the tectono-magmatic events related to subduction of the Paleo-Pacific Ocean. The geochronological and geochemical results indicate that these intrusions were emplaced between 177 and 155 Ma, with distinct geochemical features. The Huajianggou pluton (HJG), Tongjiatun pluton (TJT), and Haoguantun pluton (HGT) are characterized by high Al2O3 and Sr contents, and low MgO, TFe2O3, Y, Yb, and heavy rare earth elements (HREEs) contents, coupled with high Sr/Y values (34.10–94.36), showing adakitic affinities. Based on these geochemical characteristics, we suggest that these adakitic magmas (i.e. the HJG, TJT, and HGT plutons) were produced by partial melting of thickened lower crust in response to earlier subduction of the Paleo-Pacific oceanic plate beneath the northern margin of the North China Craton. In contrast, the Baijiagou pluton (BJG) and Sheshangou pluton (SSG) are high-K calc-alkaline rocks with low Sr/Y ratios (0.80–17.77), and they exhibit petrological and geochemical characteristics of I-type granites, indicating an origin from the lower crust, with variable degrees of fractional crystallization. In addition, the Bakeshu pluton (BKS) is mainly comprised of diorite that displays high SiO2, low MgO, Cr, and Ni contents, with Mg# of 39.8–42.9, indicating a lower crustal origin. Despite the range in ages of these intrusions, all the Jurassic calc-alkaline intrusions show typical geochemical characteristics of active continental margins, such as enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depletion in high field strength elements (HFSEs). Combined with spatial-temporal variations of coeval magmatic rocks along the northern margin of the North China Craton, we suggest that the transition in tectonic regime from the Paleo-Asian Ocean to Paleo-Pacific Ocean was initiated in the Early Jurassic. These Jurassic intrusions formed in an active continental margin setting, related to westward subduction of the Paleo-Pacific oceanic plate. Importantly, the Early Jurassic subduction-related calc-alkaline magmatic rocks in northeast (NE) China constitute a NE-trending magmatic arc belt, which is best explained as continental magmatism triggered by the westward subduction of the Paleo-Pacific oceanic plate.

Sintered NdFeB magnets with Tb - Dy double-layer core/shell structure were fabricated by double alloy method and grain boundary diffusion

The high magnetocrystalline anisotropy of the Dy or Tb core shell structure formation can greatly improve the coercivity of sintered NdFeB magnets. In this work, we fabricated the base NdFeB magnet with Dy core-shell structure by double alloy method, and then diffusion TbH2 on the base NdFeB magnet. The result showed that compared with the base magnets, the coercivity of diffusion magnet increased by 7.6 kOe with a slight reduction in remanence. The thermal stability and the microstructure of the diffused magnet improved significantly. Microstructure analysis found that a Tb - Dy double-layer core-shell structure formed around Nd2Fe14B grains after diffusion. The double-layer core-shell structure can effectively prevent the reversed magnetic domain nucleation, and improve the utilization of heavy rare earths. This work may shed light on developing low heavy rare earth NdFeB magnets with high coercivity through controlling core-shell structure.

Recycling of granulitic lower crust into the mantle

Foundering of eclogitic lower crust into the convecting mantle is a well-recognized process invoked to explain the relatively evolved chemical composition of Earth's continental crust. However, it remains unclear the extent to which the foundering could control the newly-made lowermost crust, and whether mafic granulite in a thickened eclogitic-granulitic lower continental section is effectively removable. Here we report a geochemical study of zoned clinopyroxene phenocrysts in Early Cretaceous high-Mg, Eu-depleted andesites (adakite-like intermediate lavas with high La/Yb and Sr/Y ratios and low heavy rare-earth element and Y contents) from the eastern North China craton (NCC), which suggests crust-to-mantle recycling of plagioclase-rich lithologies. Three types of zoned clinopyroxenes are recognized. The type I and II zoned clinopyroxenes show normal- and reverse-zonation, respectively, and both are featured by clear negative Eu anomalies in their cores. The type III zoned clinopyroxene is poikilitic with a high-Mg# core but no Eu anomaly, and enclosing low-Mg#, partially resorbed olivine grain. We therefore propose that these high-Mg andesites were derived from the partial melting of recycled plagioclase- and garnet-bearing granulitic lower crust, which have interacted with refractory peridotites at spinel-facies depth. Owning to mafic plagioclase- and garnet-bearing granulite with density higher and viscosity lower than refractory peridotite at the same temperature, the subcontinental granulitic lower crust could be preferentially recycled into the mantle through delamination. This correlates well with the continental Moho depth, as lower crustal xenolithes and geophysical studies in the eastern NCC revealed the existence of a granulite-facies rather than eclogite-facies lowermost crust residue (present-day ~30-km-thickness) with a pronounced Eu depletion (Eu/Eu* = ~0.8). Consequently, our preferred model has important implications for the compositional evolution of the Earth's continental crust, and offers new constraints on the scale and timing of lithosphere removal beneath the eastern NCC.