In this work, the environmental fracture behavior of marine steel and its welding joint were compared in artificial seawater. The electrochemical measurement, slow strain rate tensile test, and low-frequency cyclic loading test were conducted. The results showed that the corrosion current density and stress corrosion cracking susceptibility of welding joints were higher than those of base metal, caused by high dislocation density and residual stress in the heat-affected zone. The acidification and ion concentration occurred at the crack tip of the welding joint and basic metal. pH value and Cl− concentration at the crack tip reached 4.1 and 3.8 mol/L, respectively. The crack growth rate of the welding joint was higher than that of base metal. The crack growth behavior was controlled by the mechano-electrochemical effect at the crack tip, and hydrogen embrittlement was the main factor.