This study aims to explore the influence of control parameters from the perspective of the amorphous ceramic coating formation process. Three preparation processes were preferred based on the thickness, appearance and corrosion resistance of the coatings by orthogonal experiment. The surface morphology, cross-sectional structure, phase composition and micro-hardness of PEO coatings were examined using scanning electron microscopy (SEM)/Energy dispersive X-ray spectroscopy (EDS), X-ray diffractometry (XRD) and hardness measurement techniques. Findings indicate that voltage exerts the most significant impact on coating thickness and appearance, whereas the influence of other parameters becomes more pronounced as the voltage increases. Three amorphous ceramic coatings prepared in 20 min with thicknesses of 27.4 μm, 83.2 μm and 193.3 μm increased the surface hardness of 6061 aluminium alloy by 6–8 times, and decreased the corrosion current density of 6061 aluminium alloy by 3 orders of magnitude in 1 mol L−1 HCl solution. Moreover, the thickening of the coating primarily occurs within a few minutes after the voltage reaches its peak, and high frequency and low duty ratio are prerequisites for better appearance under higher voltage conditions.
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