Low Penetration Depth Research Articles

Laboratory Liquid-Jet X-ray Microscopy and X-ray Fluorescence Imaging for Biomedical Applications.

Diffraction-limited resolution and low penetration depth are fundamental constraints in optical microscopy and in vivo imaging. Recently, liquid-jet X-ray technology has enabled the generation of X-rays with high-power intensities in laboratory settings. By allowing the observation of cellular processes in their natural state, liquid-jet soft X-ray microscopy (SXM) can provide morphological information on living cells without staining. Furthermore, X-ray fluorescence imaging (XFI) permits the tracking of contrast agents in vivo with high elemental specificity, going beyond attenuation contrast. In this study, we established a methodology to investigate nanoparticle (NP) interactions in vitro and in vivo, solely based on X-ray imaging. We employed soft (0.5 keV) and hard (24 keV) X-rays for cellular studies and preclinical evaluations, respectively. Our results demonstrated the possibility of localizing NPs in the intracellular environment via SXM and evaluating their biodistribution with in vivo multiplexed XFI. We envisage that laboratory liquid-jet X-ray technology will significantly contribute to advancing our understanding of biological systems in the field of nanomedical research.

Time-resolved Laser Speckle Contrast Imaging (TR-LSCI) of Cerebral Blood Flow.

To address many of the deficiencies in optical neuroimaging technologies, such as poor tempo-spatial resolution, low penetration depth, contact-based measurement, and time-consuming image reconstruction, a novel, noncontact, portable, time-resolved laser speckle contrast imaging (TR-LSCI) technique has been developed for continuous, fast, and high-resolution 2D mapping of cerebral blood flow (CBF) at different depths of the head. TR-LSCI illuminates the head with picosecond-pulsed, coherent, widefield near-infrared light and synchronizes a fast, high-resolution, gated single-photon avalanche diode camera to selectively collect diffuse photons with longer pathlengths through the head, thus improving the accuracy of CBF measurement in the deep brain. The reconstruction of a CBF map was dramatically expedited by incorporating convolution functions with parallel computations. The performance of TR-LSCI was evaluated using head-simulating phantoms with known properties and in-vivo rodents with varied hemodynamic challenges to the brain. TR-LSCI enabled mapping CBF variations at different depths with a sampling rate of up to 1 Hz and spatial resolutions ranging from tens/hundreds of micrometers on rodent head surfaces to 1-2 millimeters in deep brains. With additional improvements and validation in larger populations against established methods, we anticipate offering a noncontact, fast, high-resolution, portable, and affordable brain imager for fundamental neuroscience research in animals and for translational studies in humans.

All-visible-light-driven stiff-stilbene photoswitches.

Molecular photoswitches are potent tools to construct dynamic functional systems and responsive materials that can be controlled in a non-invasive manner. As P-type photoswitches, stiff-stilbenes attract increasing interest, owing to their superiority in quantum yield, significant geometric differences between isomers, excellent thermostability and robust switching behavior. Nevertheless, the UV-light-triggered photoisomerization of stiff-stilbenes has been a main drawback for decades as UV light is potentially harmful and has low penetration depth. Here, we provided a series of para-formylated stiff-stilbenes by Rieche ortho-formylation to achieve all-visible-light-responsiveness. Additional phenolic groups provide access to late-stage chemical modification facilitating design of molecules responsive to visible light. Remarkably, the photoisomerization of aldehyde-appended stiff-stilbenes could be fully manipulated using visible light, accompanied by a high photostationary state (PSS) distribution. These features render them excellent candidates for future visible-light-controllable smart materials and dynamic systems.

Near-infrared fluorescence probes based on disassembly-induced emission pyrene derivatives

The fluorescence emission included near infrared and was significantly enhanced (50 times) by co-assembly with cucurbit[8]uril.

Red light activatable photobase generator for rapid thiol-nucleophilic polymerization

Photobase generators (PBGs) are molecules capable of releasing reactive bases when exposed to a photonic field. These compounds have been increasingly used as photolatent catalysts for light-induced polymerization processes such as ionic polymerization and ring opening polymerization. However, most PBGs require UV light trigger, with inherent limitations of low penetration depth, harmful irradiance, and high equipment cost. Herein, we introduce a long-wavelength visible-light responsive PBG based on a tetramethylguanidine (TMG) conjugated with a photoremovable methylene blue moiety. Under irradiation of red light (λmax = 660 nm), TMG is rapidly released, enabling the initiation of thiol nucleophilic addition to a range of electrophilic substrates including (meth)acrylate, propiolate, and glycidyl groups. The photopolymerization was demonstrated by red light-induced crosslinking of resins, prepared by mixing pentaerythritol tetrakis(3-mercaptopropionate) with poly(ethylene glycol) functionalized with electrophilic substrates. We further highlight the advantage of long wavelength visible light initiation by photopolymerization behind a tissue spacer, and fabrication of thick (up to 5 cm) plastic samples.

Surface Activated Si-Si Wafer Bonding Using Different Ion Species

Surface activated bonding (SAB) on wafer level is enabled by the EVG ComBond® system for irradiation with different ion species. In this process, the native oxide of 200 mm Si wafers is sputter-removed, and an amorphous layer is generated. After ion treatment, the wafers are bonded in ultra-high vacuum (UHV) at room temperature. The impact of Ar, Kr and Xe ion irradiation on the amorphous layer thickness (ALT) was investigated with the goal of optimizing the bonding process. This was i.a. motivated by the fact, that the presence of an amorphous layer reduces the electrical conductivity across the wafer interface [1].The ALT of unbonded wafers was evaluated via spectroscopic ellipsometry (SE) for varying ion species, ion energies and angles of incidence. The results show that heavier ions generate a thinner amorphous layer than light ions (see Fig. 1). This is most likely due to the higher scattering cross section of heavy ions resulting in a lower penetration depth. For each ion type there is a minimum in the ALT as a function of the ion energy which can be attributed to sputter-implantation dynamics. Furthermore, the ALT is decreasing with the angle of incidence as the incoming ions are projected into the material.Transmission electron microscopy (TEM) measurements were conducted on bonded wafer pairs and confirm the trend of heavy ions generating a thinner amorphous layer. Moreover, the TEM measurements show that post-bond annealing at 450°C for 5 h reduces the ALT due to recrystallization near the bonding interface.To ensure mechanical stability for further wafer processing and for the final device, bonding energy measurements were conducted via the Maszara method [2]. Although maximum bonding energy can be achieved for specific parameters with each ion species, Xe irradiated samples tend to have a higher overall bonding energy.[1] P.A. Stolk et al., “Contribution of defects to electronic, structural, and thermodynamic properties of amorphous silicon”, in Journal of Applied Physics, vol. 75, no. 11, pp. 7266-7286 (1994).[2] W.P. Maszara et al., “Bonding of silicon wafers for silicon-on-insulator”, in Journal of Applied Physics, vol. 64, no. 10, pp. 4943-4950 (1988). Figure 1

Parameter Optimization in Orbital TIG Welding of SUS 304 Stainless Steel Pipe

The influence of welding angle, welding current, travel speed, pulse time, and torch height on the geometry, macrostructure, and mechanical properties of Tungsten Inert Gas (TIG) orbital welding on an SUS 304 stainless steel pipe is investigated in this study. The results show that an electrode angle of 45° produces better weld joints than angles of 30°, 60°, 90°, and 120°. Furthermore, the electrode angle of 30° results in an acceptable weld width but a low depth of penetration (DOP) value. Welding current and weld speed have a significant impact on heat dispersion during TIG welding of an SUS 304 stainless steel pipe. The high welding current may result in blow-hole flaws, particularly near the conclusion of the welding process when heat is accumulated. A long torch height of 2 mm causes unevenness in the weld joints because the arc may be distorted when compared to shorter torch height cases. The pulse time of 0.2 s is too lengthy for a low-welding current situation because it will generate a small weld pool. As a result, the weld pool solidification process speeds up, and porosity emerges in the weld bead. A pulse time of 0.1 s results in a better weld joint. To avoid blow-hole creation, the welding current should be gradually reduced during the process. In addition, the Taguchi results demonstrate that the welding current has the greatest effect on the ultimate tensile strength (UTS) value, followed by welding speed, pulse time, electrode angle, and torch height. Furthermore, the ideal parameters for the UTS value are an electrode angle of 45°, a torch height of 2.0 mm, a welding current of 174 A, a welding speed of 72 mm/min, and a pulse time of 0.3 s.

Probing molecular arrangements of the organic semiconductor 2,7-Dioctyl[1]benzothieno[3,2- b][1]benzothiophene thin film at the interface by UV Resonant Raman scattering

Raman spectroscopy was employed to investigate nanometric thick films of the organic semiconductor 2,7-Dioctyl[1]benzothieno[3,2-b][1]benzothiophene, following a comprehensive vibrational characterization of the compound condensed phases at various excitation wavelengths. UV Raman excitation enabled the characterization of the thin films, revealing that the molecular orientation at the film/air interface is characterized by a different organization and/or a high degree of disorder compared to the bulk phase. The low penetration depth of the UV Raman excitation allows for the retrieval of this information, unlike the XRD data.

Visualization of photothermal therapy by semiconducting polymer dots mediated photoacoustic detection in NIR II

Visualization of photothermal therapy mediated by photothermal transduction agents (PTAs) is important to promote individual treatment of patients with low side effects. Photoacoustic detection has emerged as a promising noninvasive method for the visualization of PTAs distribution but still has limitations in temperature measurement, including poor measurement accuracy and low tissue penetration depth. In this study, we developed biocompatible semiconducting polymer dots (SPD) for in situ coupling of photothermal and photoacoustic detection in the near-infrared II window. SPD has dual photostability under pulsed laser and continuous-wave laser irradiation with a photothermal conversion efficiency of 42.77%. Meanwhile, a strong correlation between the photoacoustic signal and the actual temperature of SPD can be observed. The standard deviation of SPD-mediated photoacoustic thermometry can reach 0.13 °C when the penetration depth of gelatin phantom is 9.49 mm. Preliminary experimental results in vivo show that SPD-mediated photoacoustic signal has a high signal-to-noise ratio, as well as good performance in temperature response and tumor enrichment. Such a study not only offers a new nanomaterial for the visualization of photothermal therapy but will also promote the theranostic platform for clinical applications.

A comprehensive analysis of time-dependent performance of a solar chimney power plant equipped with a thermal energy storage system

Solar Chimney Power Plants (SCPP) are among the promising solar thermal electricity generation technologies. Equipped with a Thermal Energy Storage (TES) system, such technologies can overcome variations in the main driving factors such as solar radiation and ambient air temperature. This article presents a comprehensive semi-analytical model of a TES to predict the time-dependent performance of an SCPP. By introducing a Quality Factor of power generation (QF) that includes energy conversion efficiency and capacity factor, the effects of 15 TES materials have been studied on the plant performance. Results indicate no significant difference between water TES and clay or soil type, and water-filled bags or tubes are relatively ineffective in improving performance compared to them. Among the various TES materials analyzed, a type of wet soil, i.e., the specific wet mixture of clay, sand, and silt in closed and dark-colored bags, show excellent performance in both QF enhancement and having low Heat Penetration Depth (HPD) simultaneously. The QF and HPD are directly affected by thermal effusivity and thermal diffusivity, respectively. Implementing wet soil TES for the studied power plant (Manzanares) enhances the QF from 7.46 % (for limestone soil) to 10.95 %. Water-filled bags demonstrate a heat penetration depth of 0.4 m, while wet soil exhibits a slightly greater depth of 0.5 m. Furthermore, water-filled bags experience a broader temperature range of 40 °C, whereas wet soil undergoes a comparatively smaller temperature variation of 26 °C. Furthermore, the capacity factor raises from 41.18 % to 61.07 % when utilizing wet soil TES compared to water-filled bags.

Surface Conditions after LASER Shock Peening of Steel and Aluminum Alloys Using Ultrafast Laser Pulses.

Laser shock peening (LSP) is a mechanical surface treatment process to modify near-surface material properties. Compared to conventional shot peening (SP) the process parameters can be finely adjusted with greater precision and a higher penetration depth of compressive residual stresses could be reached. However, high process times of LSP leads to high production costs. In this study, ultrafast LSP (U-LSP) with an ultrafast laser source (pulse time in the picosecond range) was applied on specimens made of X5CrNiCu15-5 and AlZnMgCu1.5. The surface characteristics (surface roughness) and surface-near properties (microstructure, residual stresses, and phase composition) were compared to the as-delivered condition, to conventional laser shock peening (C-LSP), and to SP, whereas metallographic analyses and X-ray and synchrotron radiation techniques were used. The process time was significantly lower via U-LSP compared to C-LSP. For X5CrNiCu15-5, no significant compressive residual stresses were induced via U-LSP. However, for AlZnMgCu1.5, similar compressive residual stresses were reached via C-LSP and U-LSP; however, with a lower penetration depth. A change in the phase portions in the surface layer of X5CrNiCu15-5 after C-LSP compared to SP were determined.

Numerical investigation on spray and flow field characteristics of elliptical nozzle in supersonic crossflow

ABSTRACT It has been suggested that using an elliptical nozzle could enhance the atomization and mixture quality. In order to explore the elliptical liquid jet on spray and flow field characteristics in supersonic airflow, the VOF-Spray one-way coupling model was adopted to study the nozzle exit patterns, size, and velocity distribution of droplets. The research also compared the flow field characteristics in Mach 2.85 air crossflow under the application of different orifices. The numerical results showed that elliptical 4 nozzle (Aspect ratio of 4) had better flow performance than circular nozzle. The cavitation area and turbulent disturbance of elliptical 4 nozzle were mainly concentrated in the major axis direction. The elliptical 4 jet always had a lower penetration depth than circular jet. At the flow range of 0 ~ 50 mm, the penetration depth of elliptical 4 jet is roughly 12% less than that of circular jet. Another finding was that the spanwise extension range of elliptical 4 spray was larger than the circular spray. The spanwise extension range of elliptical 4 spray increased by about 19.4% at most in the flow range of 0 ~ 50 mm. Additionally, the elliptical 4 spray had the smallest Santer Mean Diameter (SMD). The elliptical 4 jet had a 2.9% smaller Santer Mean Diameter than the circular jet. Due to the greater windward surface area of the elliptical 4 orifice, the gas streamwise velocity near the bottom wall was reduced. A reverse vortex pair with distinct characteristics could be observed under the application of elliptical 4 orifice. Furthermore, compared with the circular orifice, the shock wave angle generated by elliptical 4 orifice reduced by 9.7%, and the total pressure recovery coefficient rose by 2.3%.

Dual-Mode Gold Nanocluster-Based Nanoprobe Platform for Two-Photon Fluorescence Imaging and Fluorescence Lifetime Imaging of Intracellular Endogenous miRNA.

Bioimaging is widely used in various fields of modern medicine. Fluorescence imaging has the advantages of high sensitivity, high selectivity, noninvasiveness, in situ imaging, and so on. However, one-photon (OP) fluorescence imaging has problems, such as low tissue penetration depth and low spatiotemporal resolution. These disadvantages can be solved by two-photon (TP) fluorescence imaging. However, TP imaging still uses fluorescence intensity as a signal. The complexity of organisms will inevitably affect the change of fluorescence intensity, cause false-positive signals, and affect the accuracy of the results obtained. Fluorescence lifetime imaging (FLIM) is different from other kinds of fluorescence imaging, which is an intrinsic property of the material and independent of the material concentration and fluorescence intensity. FLIM can effectively avoid the fluctuation of TP imaging based on fluorescence intensity and the interference of autofluorescence. Therefore, based on silica-coated gold nanoclusters (AuNCs@SiO2) combined with nucleic acid probes, the dual-mode nanoprobe platform was constructed for TP and FLIM imaging of intracellular endogenous miRNA-21 for the first time. First, the dual-mode nanoprobe used a dual fluorescence quencher of BHQ2 and graphene oxide (GO), which has a high signal-to-noise ratio and anti-interference. Second, the dual-mode nanoprobe can detect miR-21 with high sensitivity and selectivity in vitro, with a detection limit of 0.91 nM. Finally, the dual-mode nanoprobes performed satisfactory TP fluorescence imaging (330.0 μm penetration depth) and FLIM (τave = 50.0 ns) of endogenous miR-21 in living cells and tissues. The dual-mode platforms have promising applications in miRNA-based early detection and therapy and hold much promise for improving clinical efficacy.

A NIR-Activated and Mild-Temperature-Sensitive Nanoplatform with an HSP90 Inhibitor for Combinatory Chemotherapy and Mild Photothermal Therapy in Cancel Cells.

Mild photothermal therapy (PTT) shows great potential to treat cancers while avoiding unwanted damage to surrounding normal cells. However, the efficacy of mild PTT is normally moderate because of the low hyperthermia temperature and limited light penetration depth. Chemotherapy has unlimited penetration but often suffers from unsatisfactory efficacy in view of the occurrence of drug resistance, suboptimal drug delivery and release profile. As a result, the combinatory of chemotherapy and mild PTT would integrate their advantages and overcome the shortcomings. Herein, we synthesized an NIR-activatable and mild-temperature-sensitive nanoplatform (BDPII-gel@TSL) composed of temperature-sensitive liposomes (TSL), heat shock protein 90 (HSP90) inhibitor (geldanamycin) and photothermal agent (BDPII), for dual chemotherapy and mild PTT in cancer cells. BDPII, constructed with donor-acceptor moieties, acts as an excellent near-infrared (NIR) photothermal agent (PTA) with a high photothermal conversion efficiency (80.75%). BDPII-containing TSLs efficiently produce a mild hyperthermia effect (42 °C) under laser irradiation (808 nm, 0.5 W cm-2). Importantly, the phase transformation of TSL leads to burst release of geldanamycin from BDPII-gel@TSL, and this contributes to down-regulation of the overexpression of HSP90, ensuring efficient inhibition of cancer cell growth. This research provides a dual-sensitive synergistic therapeutic strategy for cancer cell treatment.

Numerical and experimental investigation of impact strength and fracture mechanism of Kevlar and Hemp elastomeric thin biocomposite laminate under high-velocity impact: A comparative study

Thin composite structures reinforced with woven fabrics are widely used in many industrial sectors due to their lightweight, easy access, and high specific performance. Due to safety, the study of fracture mechanisms and energy absorption of thin composite structures is significant. In this study, Kevlar and Hemp elastomeric thin biocomposite laminates with an elastomeric matrix filled with natural lignin filler with a low carbon footprint and with the aim of the sustainability concept of environmental protection have been designed experimentally and numerically for testing under high-velocity impact. The impact resistance of elastomeric composites reinforced with natural fillers is less reported. Good interaction of lignin-filled elastomeric matrix with woven hemp fabric is expected to show impact performance comparable to Kevlar-reinforced composites. For this purpose, Kevlar and hemp thin elastomeric biocomposites are tested under high-velocity impact with almost the same surface density. Also, tensile and dynamic compression tests (Hopkinson test) were performed to check the mechanical properties of the elastomer layer. The proposed laminates' penetration resistance and fracture behavior during an impact according to the Kevlar and hemp fabric constituent material model and the user-defined material model (VUMAT) for the nonlinear behavior of elastomeric materials considering the damage criterion in ABAQUS/Explicit confirmed. The results show, In the thin elastomeric hemp biocomposites, the tensile failure and stress transfer to the surrounding bundles cause more yarns to participate in the load-carrying process. As a result, the low penetration depth and more significant protection margin in fully green hemp composites provide impact performance comparable to Kevlar elastomeric composites.

Palladium Nanocapsules for Photothermal Therapy in the Near-Infrared II Biological Window.

Recent developments in nanomaterials with programmable optical responses and their capacity to modulate the photothermal effect induced by an extrinsic source of light have elevated plasmonic photothermal therapy (PPTT) to the status of a favored treatment for a variety of malignancies. However, the low penetration depth of near-infrared-I (NIR-I) lights and the need to expose the human body to a high laser power density in PPTT have restricted its clinical translation for cancer therapy. Most nanostructures reported to date exhibit limited performance due to (i) activity only in the NIR-I region, (ii) the use of intense laser, (iii) need of large concentration of nanomaterials, or (iv) prolonged exposure times to achieve the optimal hyperthermia state for cancer phototherapy. To overcome these shortcomings in plasmonic nanomaterials, we report a bimetallic palladium nanocapsule (Pd Ncap)─with a solid gold bead as its core and a thin, perforated palladium shell─with extinction both in the NIR-I as well as the NIR-II region for PPTT applications toward cancer therapy. The Pd Ncap demonstrated exceptional photothermal stability with a photothermal conversion efficiency of ∼49% at the NIR-II (1064 nm) wavelength region at a very low laser power density of 0.5 W/cm2. The nanocapsules were further surface-functionalized with Herceptin (Pd Ncap-Her) to target the breast cancer cell line SK-BR-3 and exploited for in vitro PPTT applications using NIR-II light. Pd Ncap-Her caused more than 98% cell death at a concentration of just 50 μg/mL and a laser power density of 0.5 W/cm2 with an output power of only 100 mW. Flow cytometric and microscopic analyses revealed that Pd Ncap-Her-induced apoptosis in the treated cancer cells during PPTT. Additionally, Pd Ncaps were found to have reactive oxygen species (ROS) scavenging ability, which can potentially reduce the damage to cells or tissues from ROS produced during PPTT. Also, Pd Ncap demonstrated excellent in vivo biocompatibility and was highly efficient in photothermally ablating tumors in mice. With a high photothermal conversion and killing efficiency at very low nanoparticle concentrations and laser power densities, the current nanostructure can operate as an effective phototherapeutic agent for the treatment of different cancers with ROS-protecting ability.

Greener and more mechanically robust 3D acrylate composites with added tannin

Greener and more mechanically robust 3D-printed structures were obtained by adding tannin to acrylate resin. Mimosa tannin particles (5–25 wt %) were incorporated into an acrylate resin formulated and 3D-printed to fabricate tannin-reinforced composites using stereolithography. FTIR spectroscopy and printing parameters highlighted the photoblocking behavior of the tannin particles by adsorption in the UV range and a reddening phenomenon characteristic of phenolic compounds. Tannin-containing samples showed a low penetration depth (from 322 to 127 µm), thus improving the resolution control in the resin tank. The glass transition temperature decreased with the incorporation of stiff tannin microparticle, evidencing change in relaxation time, while mechanical properties improved with increasing tannin content. For instance, the inclusion of 10 wt % tannin improved tensile strength, ductility, and Young’s modulus by 110 %, 80 %, and 32 %, respectively. The high resolution and improved mechanical performance demonstrate the promising use of tannin as a bio-based ingredient to produce accurate and reinforced structures.

Progress and Perspectives of Mid-Infrared Photoacoustic Spectroscopy for Non-Invasive Glucose Detection.

The prevalence of diabetes is rapidly increasing worldwide and can lead to a range of severe health complications that have the potential to be life-threatening. Patients need to monitor and control blood glucose levels as it has no cure. The development of non-invasive techniques for the measurement of blood glucose based on photoacoustic spectroscopy (PAS) has advanced tremendously in the last couple of years. Among them, PAS in the mid-infrared (MIR) region shows great promise as it shows the distinct fingerprint region for glucose. However, two problems are generally encountered when it is applied to monitor real samples for in vivo measurements in this MIR spectral range: (i) low penetration depth of MIR light into the human skin, and (ii) the effect of other interfering components in blood, which affects the selectivity of the detection system. This review paper systematically describes the basics of PAS in the MIR region, along with recent developments, technical challenges, and data analysis strategies, and proposes improvements for the detection sensitivity of glucose concentration in human bodies. It also highlights the recent trends of incorporating machine learning (ML) to enhance the detection sensitivity of the overall system. With further optimization of the experimental setup and incorporation of ML, this PAS in the MIR spectral region could be a viable solution for the non-invasive measurement of blood glucose in the near future.

About the assessment of sampling error and representative sample in X-ray fluorescence analysis of mineral powders

The assessment of laboratory sampling errors in X-ray fluorescence analysis (XRF) of mineral powders ground to a particle size less than 75 μm is important when analyzing specimen portions less than 100–300 mg. The sampling error can be found from Poisson statistics, which allows one to estimate the variations in the number of mineral grains containing an analyte in a powder sample of a fixed mass. However, the absorption of X-ray radiation in the sample imposes a limitation on the analyzed mass due to the low penetration depth of X-rays, especially in the energy region below 4 keV.In this paper, we propose the sampling error estimation based on Poisson statistics taking into account the size of powder particles in comparison with the penetration depth of X-rays. Two limiting cases are considered, when the penetration depth is greater or less than the size of the grains containing the analyte. Zircon, ilmenite, and quartz were considered as grains containing the analyte, and boric acid and clay were taken as matrices. Measurements were carried out with wavelength dispersive XRF spectrometer. It was shown that the sampling errors obtained experimentally for different model mixtures are close to the sampling errors calculated using Poisson statistics. The described model of quartz inclusions in clay matrix was used to explain the relatively low sampling error in determining the main components Al2O3, SiO2, K2O in course-grain Neolithic ceramics.

Effect of microwave-assisted acidification on the microstructure of coal: XRD, 1H-NMR, and SEM studies

Microwave heating contributes to coal fracturing and gas desorption. However, problems of low penetration depth, local overheating and fracture closure exist. Coal demineralisation by acids has advantages in coal unblocking and permeability improvement, while it is difficult for acid to enter microcracks. Microwave-asisted acidification may offer an alternative. In this work, XRD, 1H-NMR, and SEM were used to evaluate the effect of microwave-assisted acidification on the microstructure of coal. Results show that kaolinite, calcite, and dolomite can be dissolved by acid. After microwave irradiation, the graphitization of microcrystalline structure of carbon improves. Microwave-assisted acidification erodes minerals in coal and enhances the graphitization degree of microcrystalline structure. Compared to individual microwave irradiation or acidification, the pore volume and pore connectivity can be greatly enhanced by microwave-assisted acidification. The NMR permeability of coal increased by 28.05%. This study demonstrates the potential of microwave-assisted acidification for coalbed methane recovery.