High crystalline polyethylene terephthalate (PET) microfibres were irradiated (at low energy density regime, De ~10 23 eV/cm) with 2.4 MeV proton beam at 3 different fluences: 1×10 p/cm,1×10 p/cm and 1×10 p/cm. Because of irradiation, the fibre gets amorphized from its highly crystalline state after passing through an intermediate mesophase stage. The mesophase of polymers is well studied using wide-angle X-ray scattering, small-angle X-ray scattering, FTRaman scattering and nuclear magnetic resonance techniques. In the present paper, ion (proton) induced mesophase structure of PET was observed. X-ray fiber diffraction was carried out by adopting a special fiber mounting technique and using a diffractometer having Bragg-Brentano parafocusing optics. The sample irradiated at the lowest fluence showed the maximum percentage (7.05%) of mesophase.
Read full abstract