Low-density Areas Research Articles

Testing spatial transferability of species distribution models reveals differing habitat preferences for an endangered delphinid (Cephalorhynchus hectori) in Aotearoa, New Zealand.

Species distribution models (SDMs) can be used to predict distributions in novel times or space (termed transferability) and fill knowledge gaps for areas that are data poor. In conservation, this can be used to determine the extent of spatial protection required. To understand how well a model transfers spatially, it needs to be independently tested, using data from novel habitats. Here, we test the transferability of SDMs for Hector's dolphin (Cephalorhynchus hectori), a culturally important (taonga) and endangered, coastal delphinid, endemic to Aotearoa New Zealand. We collected summer distribution data from three populations from 2021 to 2023. Using Generalised Additive Models, we built presence/absence SDMs for each population and validated the predictive ability of the top models (with TSS and AUC). Then, we tested the transferability of each top model by predicting the distribution of the remaining two populations. SDMs for two populations showed useful performance within their respective areas (Banks Peninsula and Otago), but when used to predict the two areas outside the models' source data, performance declined markedly. SDMs from the third area (Timaru) performed poorly, both for prediction within the source area and when transferred spatially. When data for model building were combined from two areas, results were mixed. Model interpolation was better when presence/absence data from Otago, an area of low density, were combined with data from areas of higher density, but was otherwise poor. The overall poor transferability of SDMs suggests that habitat preferences of Hector's dolphins vary between areas. For these dolphins, population-specific distribution data should be used for conservation planning. More generally, we demonstrate that a one model fits all approach is not always suitable. When SDMs are used to predict distribution in data-poor areas an assessment of performance in the new habitat is required, and results should be interpreted with caution.

Analysis to determine the domestic water usage in Yolde - Pate Area of Yola South Local Government Area of Adamawa State Nigeria

This research study presents findings of the analysis of determining the domestic water usage in Yolde-Pate area of Yola South LGA of Adamawa State Nigeria. During the recce survey and final survey; the sources of domestic water were identified and mapped out in the study area which include: 127 Industrial borehole, 16 hand-pumps, 6 well water and 1 public tap. Domestic water usage moves in hand with its source and accessibility this is where Nearest Neighbor Analysis NNA was used and its summary depicts the following; z-score of 0.205792265731; which means the pattern does not appear to be significantly different than random; which is fairly recommendable. Mean Distance is 51.1643 Meters, Neighbor Ratio is 1.024, and p-value: 0.836953. This was achieved due to the highly precision DGPS used in determining the spatial positions of each of the 150 XYZ points of each water source location and digitally mapping out the whole study area. Then 600 well-structured questionnaires that were randomly distributed within the study area with the respondent’s responses largely related to the analysis of determining domestic water usage were retrieved and analyzed with the End User Analysis (EUA)Technique. The results show that the total volume of water used daily per house ranges from 52,247 to 78,856 liters for each house hold with a range of 54.53liters to 67.69 liters of water consumption per individual in a day; which fall short of WHO standard of 120 liters. However the EUA based on the population density of the study area reveals: first for the high density areas, which has 3 wards Gadawalowol Yolde Patte ward, Jalingo Yolde Patte ward and Chaka Midari ward with a mean population of 1187, mean household size of 4.67 individuals, 71500 liters as the mean total of consume water daily, 60.35 as the mean per capita water consumption per day individually while standard still remains 120 liters and the mean total of daily demand is 142,440 liters; which shows deficit of what is needed. For the medium density areas with an average population of 1093 which are made up of 2 wards depicts 61100 liters as the mean total of water consumed daily by each household, 55.86 liters was consumed by an individual with a daily mean demand of 131,160 liters. While the low-density areas which mainly is occupied by the Sabonpegi Yolde Patte ward residence has a population of 876, total water consumption per household of 52,247liters, Per Capita Water Consumption (liters per day) is 59,64liters while its water daily demand is 105 120 liters; similarly, a shortage of what is demanded and WHO standard exist also in the medium and low-density areas. Recommendations were then spelt out to improve water consumption and usage with well design accessibility structure to improve well-being of the people in this study area.

Buckling resistance of ultra-low-density carbon fiber curved-wall honeycomb based on stretching process

Although honeycomb is a kind of lightweight structural material with great potential, its specific strength is not always able to meet the requirements, especially in the weight-sensitive field. Inspired by the bionic idea of cuttlebone, the curved-wall configuration design is proposed to strengthen the buckling impedance of honeycomb, which can effectively prevent the premature occurrence of buckling failure mode induced by thin walls. Compared with the straight-wall honeycomb materials of the same geometric size, the probability of buckling failure in curved-wall honeycomb materials proposed in this paper is reduced by more than 22 %. Moreover, to achieve the preparation of curved-wall configuration, a processing strategy that uses stretching process to prepare ultralight carbon fiber honeycomb (Carbcomb) material is firstly introduced. Compared to the Hexcel Corporation’s aluminum honeycomb with a density of 21 kg/m3, for the Carbcomb, the specific compressive strength and specific shear strength along both the L and W directions respectively improved by 57 %, 61 % and 77 %. In addition, the minimum density of fabricated Carbcomb (14.6 kg/m3) is less than that of the Hexcel's products (16 kg/m3), and the research findings fill the gap of the carbon fiber honeycomb material in low density areas (10 ∼ 30 kg/m3). More importantly, this process which does not require much manual operation can effectively avoid the problems of unstable mechanical properties, difficult mass production and high preparation cost of the existing carbon fiber structural parts. This curved-wall configuration design and fabricated approach widens the potential of carbon fiber honeycomb as a structural material, and makes it possible for lower cost and higher efficiency in aerospace and transportation applications.

Finite element analysis of the impact of bone mass and volume of low-density area under tibial plateau on lower limb alignment

To investigate the impact of the bone mass and volume of the low-density area under the tibial plateau on the lower limb force line by finite element analysis, offering mechanical evidence for preventing internal displacement of the lower limb force line in conjunction with knee varus in patients with knee osteoarthritis (KOA) and reducing bone mass under the tibial plateau. A healthy adult was selected as the study subject, and X-ray film and CT imaging data were acquired. Mimics 21.0 software was utilized to reconstruct the complete knee joint model and three models representing low-density areas under the tibial plateau with equal volume but varying shapes. These models were then imported into Solidworks 2023 software for assembly and verification. Five KOA finite element models with 22%, 33%, 44%, 55%, and 66% bone mass reduction in the low-density area under tibial plateau and 5 KOA finite element models with 81%, 90%, 100%, 110%, and 121% times of the low-density area model with 66% bone mass loss were constructed, respectively. Under physiological loading conditions of the human lower limb, the distal ends of the tibia and fibula were fully immobilized. An axial compressive load of 1 860 N, following the lower limb force line, was applied to the primary load-bearing area on the femoral head surface. The maximum stress within the tibial plateau, as well as the maximum displacements of the tibial cortical bone and tibial subchondral bone, were calculated and analyzed using the finite element analysis software Abaqus 2022. Subsequently, predictions regarding the alteration of the lower limb force line were made based on the analysis results. The constructed KOA model accorded with the normal anatomical structure of lower limbs. Under the same boundary conditions and the same load, the maximum stress of the medial tibial plateau, the maximum displacement of the tibial cortical bone and the maximum displacement of the cancellous bone increased along with the gradual decrease of bone mass in the low-density area under the tibial plateau and the gradual increase in the volume of the low-density area under tibial plateau, with significant differences ( P<0.05). The existence of a low-density area under tibial plateau suggests a heightened likelihood of knee varus and inward movement of the lower limb force line. Both the volume and reduction in bone mass of the low-density area serve as critical initiating factors. This information can provide valuable guidance to clinicians in proactively preventing knee varus and averting its occurrence.

Hydrophobic Modification of Pectin Aerogels via Chemical Vapor Deposition.

Pectin aerogels, with very low density (around 0.1 g cm-3) and high specific surface area (up to 600 m2 g-1), are excellent thermal insulation materials since their thermal conductivity is below that of air at ambient conditions (0.025 W m-1 K-1). However, due to their intrinsic hydrophilicity, pectin aerogels collapse when in contact with water vapor, losing superinsulating properties. In this work, first, pectin aerogels were made, and the influence of the different process parameters on the materials' structure and properties were studied. All neat pectin aerogels had a low density (0.04-0.11 g cm-1), high specific surface area (308-567 m2 g-1), and very low thermal conductivity (0.015-0.023 W m-1 K-1). Then, pectin aerogels were hydrophobized via the chemical vapor deposition of methyltrimethoxysilane using different reaction durations (2 to 24 h). The influence of hydrophobization on material properties, especially on thermal conductivity, was recorded by conditioning in a climate chamber (25 °C, 80% relative humidity). Hydrophobization resulted in the increase in thermal conductivity compared to that of neat pectin aerogels. MTMS deposition for 16 h was efficient for hydrophobizing pectin aerogels in moist environment (contact angle 115°) and stabilizing material properties with no fluctuation in thermal conductivity (0.030 W m-1 K-1) and density for the testing period of 8 months.

A Simple but Powerful Method to Reduce Background Noise in Celestial Gamma-Ray Images

Reducing background noise is essential for clear data analysis and signal detection. In this study, we introduce a novel denoising algorithm tailored for gamma-ray astronomical data, utilizing local density sampling techniques. The proposed algorithm preferentially amplifies regions of high local density, which are indicative of potential sources, while diminishing the influence of low-density areas. This selective enhancement significantly bolsters the performance of clustering algorithms in pinpointing point sources, effectively minimizing the interference of high-density noise that could be mistaken for genuine sources. We have implemented this algorithm on Fermi Large Area Telescope data, and our results showcase a marked advancement in the clustering algorithm's capacity to discard false sources.

Assessment of Solid Waste Management Practices Following Private Partnership Operations in Zaria Urban Area of Kaduna, Nigeria

The safe disposal of municipal waste is very important in promoting a healthy environment. High-quality public services and promoting competition in the waste management sector leads to the formation of private sector participation (PSP) to handle solid waste management in Kaduna. A multi-stage sampling technique was adopted which involves dividing the local government into localities. Stage two involves the purposive sampling technique which was adopted in selecting locality with high population and low population density areas, a total of 400 households from both strata were interviewed. Descriptive statistics was used to analyse the information from the questionnaires and results were presented using frequency tables and charts. The findings revealed that quality of service among the PSP operators recorded high success in the high-income areas and much less in the low and medium-income areas. On average, industry productivity was 5.63 tonnes per day per vehicle. 12 out of which in the study area were above this average and in meeting increased productivity, year of experience in operations, number of trips made, number of times trucks were serviced, and adhering to regulatory agency requirements were among the factors influencing company’s productivity in the state. It also shows less effectiveness of the system in waste management in the area. The study, therefore, recommends that regulatory agency should be more aggressive in playing their statutory roles of managing the PSP operators.

Spatial diffusion of potentially toxic elements in soils around non-ferrous metal mines

This study focuses on the diffusion patterns of principal ore-forming elements (Pb and Zn) and associated elements (Cd, Cu, Cr, and As) in lead-zinc ore. Sampling points in upwind and downwind directions of lead-zinc ore areas at various densities (1 N/km2 – 4 N/km2) were categorized. This study analyzed the statistical relationship between the content of PTEs in the soil around lead-zinc ore and the source strength and dominant wind direction, constructed one-dimensional and two-dimensional diffusion model, and simulated the EER scope caused by PTEs. The findings indicate that: (1) concerning source strength, the content of PTEs in soils of high-density ore aggregation areas is significantly higher than in low-density ore aggregation areas. However, the impact of source strength decreases with decreasing ore grade, with a difference in Pb content of 1.71 times among principal ore-forming elements and almost consistent Cd content among associated elements. (2) Regarding the transport pathways, for most PTEs, the inverse proportion coefficients downwind are higher than upwind, approximately 1.18–3.63 times, indicating greater migration distances of PTEs downwind due to atmospheric dispersion. (3) By establishing a two-dimensional risk diffusion model, the study simulates the maximum radius of risk diffusion (r = 5.7 km), the 50% probability radius (r = 3.1 km), and the minimum radius (r = 0.8 km) based on the maximum, median, and minimum values statistically obtained from the EER. This study provides a scientific basis for implementing preventive measures for PTEs accumulation in soil within different pollution ranges. Different risk prevention and control measures should be adopted for PTEs accumulation in soil within the three ranges after cutting off pollution sources. Subsequent research should further investigate the impact and contribution of atmospheric transmission and surface runoff on the diffusion of PTEs in areas with high risk near lead-zinc ore.

Not only in the crowd: Benthic litter characterization in a low population density area still reveals widespread pollution and local malpractices

Various anthropogenic activities affect marine coastal habitats, leading to heavy litter pollution. However, whilst high litter concentrations are nowadays common in the proximity of metropolises, few studies investigated the magnitude of this phenomenon around coastal villages and small towns. We hereby characterized the benthic litter occurring in the trawlable grounds of the Gulf of Policastro (Tyrrhenian Sea, central-western Mediterranean), a low population density area that becomes a popular tourist destination during summer. We furthermore tested differences between two depths (∼100–200 and ∼500–600 m) and the impact of tourism on the shallower waters. The area was characterized by a litter abundance of 651.12 ± 130.61 item/km2, with plastic being almost totalitarian (93%). The shallower waters hosted two-thirds of the litter found. Almost all (∼95%) the litter items had a land-based origin, while the sea-based litter was mostly found at higher depths. About 14% of the litter was found to be fouled, with the development of litter-associated communities that somehow mimic the natural ones living on hard substrates. The higher litter presence noticed during the touristic peak (July–August) suggests that tourism is an important source of local litter, although it contributed to the local accumulation in a synergic way with other factors. The majority of the litter items presumably originated from the nearby coastline, while the deeper waters were or are used as a dumping site by the local trawling fleet. The discovery of such a critical waste accumulation and management in a somehow remote area contributes to widen the perspectives on the presence of benthic litter mostly in territories characterized by wide anthropization. Moreover, it confirms that appropriate local policies and communication plans are urged even at a regional level to stimulate citizen consciousness and mitigate the ever growing litter pollution.

Optimized Low-powered Wide Area Network within Internet of Things

The Internet of Things is rapidly becoming an integral part of everyday life. Low-powered wide area network are capable of providing reliable connectivity even in low-density areas and device consuming low amount of energy. The exponential increase in the use of Internet of things application across the globe will continue to generate more and more data traffic within the Internet of Things network. Thus, End device within Internet of Things network in the near future will rise up to billions of device operating across Internet of Things network, generating a necessity for more correct and reliable energy conservation Internet of things technology. This prompted the research work on optimized low-powered wide area network. The experiment has been carried out in various stages: firstly running of simulation over wireless sensor network without optimization using MATLAB Simulink and obtained the following result of 6.3997e-17 joules power consumption, secondly, the authors test the network with power optimization using particle swarm optimization algorithms and obtained a better result of 2.5230e-17 joules. The Long Range energy consumption is reduced by 60%. Lastly, different simulation test of Long Range Wide Area Network protocols with respect to some network communication parameters such as throughput, packet loss, delay, data transmission, buffer size, and network density.

Ageing in Place: Older People Identify Barriers to Remaining in Low-Density Areas

AbstractStudies involving older people as co-investigators are limited in Portugal. The main objectives of this article are: (I) Analyze the barriers identified by older people living in low-density territories that pose a challenge to ageing in place. (ii) Understand the co-research methodology as an appropriate instrument for increasing the participatory capacity of older people and improving the conditions for ageing in place. (iii) Assess the role of social networks and community support in providing informal assistance to older people in low-density territories. The study involved 14 co-researchers, who had a balanced gender representation and an average age of 64.5 years. All the co-researchers were residents of the study location and volunteered for the research. They were provided training in interview techniques and active listening, prior to the study. A total of three interviews and 23 photographs were analyzed and discussed in five focus group meetings. The participants agreed upon four types of unmet needs and developed proposals to increase their negotiating power, thereby mitigating barriers to their permanence. The co-researchers presented their proposals at two public meetings with decision-makers, managers, and members of the municipal council. The findings were a significant addition to the promotion of the co-research approach and the engagement of older adults in detecting the obstacles that hinder their secure and independent aging in their living environment.

Low signs of territorial behavior in the Eurasian otter during low-water conditions in a Mediterranean river

The Eurasian otter Lutra lutra is a territorial semi-aquatic carnivore usually found at low densities in rivers, coastal areas, and wetlands. Its diet is based on prey associated with aquatic environments. Mediterranean rivers are highly seasonal, and suffer reduced flow during the summer, resulting in isolated river sections (pools) that sometimes can be left with a minimal amount of water, leading to concentrations of food for otters. To our knowledge, this process, which was known to field naturalists, has not been accurately described, nor have otter densities been estimated under these conditions. In this study, we describe the population size and movements of an aggregation of otters in an isolated pool in the Guadiana River in the Tablas de Daimiel National Park (central Spain), which progressively dried out during the spring–summer of 2022, in a context of low connectivity due to the absence of circulating water in the Guadiana and Gigüela rivers. Using non-invasive genetic sampling of 120 spraints collected along 79.4 km of sampling transects and spatial capture-recapture methods, we estimated the otter density at 1.71 individuals/km of river channel length (4.21 individuals/km2) in a progressively drying river pool, up to five times higher than previously described in the Iberian Peninsula. The movement patterns obtained with the spatial capture-recapture model are not quite different from those described in low density, which seems to indicate a wide home range overlap, with low signs of territoriality.

Powder-bed 3D printing by selective activation of magnesium phosphate cement: Determining significant processing parameters and their effect on mechanical strength

The present work addresses powder bed binder jetting additive manufacturing by selective magnesium phosphate cement activation. Despite the potential of this technology to aid the digitalization of the construction industry, the effect of processing parameters on the mechanical performance of printed materials has not yet been studied to generate a guideline for the further development of the technology. Statistical methodologies were used to screen the effect of four printing process parameters (printing speed, layer thickness, raster angle, and build direction on flexural and compressive strength). As the exploited technology works with constant fluid pressure, the physical interpretation of the effect of each factor can be considered taking into account the interactions between the binder materials in the powder bed. Analysis of variance (ANOVA) indicated that printing speed and layer thickness significantly affect mechanical performances. Furthermore, the layout of samples for the printing process is preferable to be parallel the printhead movement. An anisotropic behavior was observed, and the samples subjected to compressive forces parallel to the layer plane possessed lower strength values. This effect can be interpreted as a result of a weak area of low density in between layers, leading to a pronounced delamination under compression.Even though the strength of the printed material is not suitable for a structural concrete, it can be marginally improved by design of experiment and optimized for non-structural applications, such as for porous artificial stone. Design of experiment coupled with ANOVA methods can be used in the future to support the development of novel material mixtures, thus expanding the fields of application of this novel additive manufacturing technology.

Osseodensification: An Innovative Technique With Manifold Gains.

Prosthodontics, which isremovable and fixed, is the branch dealing with the replacement of missing teeth. Implant therapy is the popular treatment modality and commonly preferred treatment option by many patients and clinicians for missing teeth in recent years. Primary implant stability (PIS) is one of the crucial factors for osseointegration. It has been considered a crucial factor in the success of implants. Moreover, several factors influence PIS. On the other hand, both secondary implant stability and osseointegrationare influenced by the PIS. Bone density, bone volume, bone-to-implant contact, and other factors that enhance or degrade the primary stability. Certain host sites such as the maxillary posterior region demand more dense bone to achieve desired results as they are the low-density areas of the jaw. So, a new promising and growing innovative concept of osseodensification (OD) offers a great solution with multiple benefits and desirable results. This review article aims to enlighten the multiple benefits of OD technique and their mechanism of action.

Understanding land take by low-density residential areas: An institutionalist perspective on local planning authorities, developers and households

Using a case study design, the study focuses on identifying the institutional configuration that determines land take by low-density residential areas. Methodologically, it combines geospatial approaches and new institutionalism to capture and understand residential development, taking into account the interests, constraints and agency of local planning authorities, developers and households. The geospatial analysis shows that land take in the case study regions is primarily the result of low-density residential areas. We find that the combination of rural housing ideals, municipal policy objectives, municipalities' disengagement from spatial development and private sector interests are the main drivers for this kind of residential development. As the interests and constraints apply to all case study regions, the identified institutional configuration has high power in explaining low-density residential development. Our study thus uncovers a close link between the interests and constraints of actors, which on the one hand explains the limited impact of existing and new planning instruments on reducing land take, and on the other hand fosters path dependency in the development of low-density residential areas. Although there is some potential for change, breaking path dependency requires significant behavioural change among local planning authorities, developers and households.

Investigating the Impact of Various Vegetation Scenarios on Outdoor Thermal Comfort in Low-Density Residential Areas of Hot Arid Regions

In hot, arid regions, outdoor spaces suffer from intense heat. This study explores how vegetation can improve outdoor thermal performance for pedestrians in low-density residential areas. Specifically, it seeks to identify the best combination of grass and trees for optimal comfort. Four scenarios were simulated using ENVI-met software, varying the proportions of grass and three tree types: 50% grass, 50% grass with 25% trees, 50% grass with 50% trees, and 50% grass with 75% trees. A reference scenario with no vegetation was also investigated. The simulated outputs encompassed air temperature (Ta), mean radiant temperature (Tmrt), relative humidity (RH), and physiologically equivalent temperature (PET). The findings show that scenarios with a higher percentage of trees exhibited the best reduction in air temperature, ranging from 0.2 k to 0.92 k. Additionally, the inclusion of trees and grass in the scenarios resulted in a substantial improvement in thermal performance, with an average reduction of 7.5 degrees in PET. Among the evaluated scenarios, the one comprising 75% trees and 50% grass exhibits the most noteworthy enhancement. This study underscores the significance of strategically positioning vegetation to coincide with prevailing wind patterns, thereby enhancing convective cooling mechanisms and improving overall thermal comfort levels. These insights offer valuable implications for urban planning and the development of sustainable design strategies.

Influence of prey availability on the movement pattern of breeding saker falcons (Falco cherrug) in Mongolia

Abstract As an apex predator in arid steppe, saker falcon plays a crucial role in maintaining ecosystem balance. Understanding their movement patterns concerning conspecific competition and prey availability is important for their conservation. We aim to understand how movement pattern of breeding saker falcons relates to prey availability. Twelve adult sakers were tracked during the breeding seasons, using satellite transmitters. Throughout the breeding season, sakers exhibited territorial behaviour, with minimal overlap in range use among neighbouring conspecifics. Males occupied larger areas (mean = 2,397 ha, median = 1,221 ha), compared to females (mean = 1,241 ha, median = 554 ha), and it remained consistent throughout breeding season. Female home range size increased notably during late nestling stage and post-fledging dependence periods, indicating release from brooding constraints. Notably, we found a negative relationship between male home range size and prey availability. In high rodent density areas, males occupied smaller areas (mean = 1,135 ha, median = 1,034 ha), contrasting with low rodent density areas (mean = 6,815 ha, median = 6,516 ha). However, no significant relationship was observed between female home range size and prey availability. We also noted instances of nest abandonment and early dispersal behaviour in some females, potentially influenced by a handicapping effect of tagging. Our findings offer valuable insight into how prey availability shapes saker falcon space use and defines their spatial requirements for successful breeding. This knowledge is crucial for the conservation and management of globally endangered saker falcons, informing targeted habitat protection and resource management strategies.

Open-source data pipeline for street-view images: A case study on community mobility during COVID-19 pandemic.

Street View Images (SVI) are a common source of valuable data for researchers. Researchers have used SVI data for estimating pedestrian volumes, demographic surveillance, and to better understand built and natural environments in cityscapes. However, the most common source of publicly available SVI data is Google Street View. Google Street View images are collected infrequently, making temporal analysis challenging, especially in low population density areas. Our main contribution is the development of an open-source data pipeline for processing 360-degree video recorded from a car-mounted camera. The video data is used to generate SVIs, which then can be used as an input for longitudinal analysis. We demonstrate the use of the pipeline by collecting an SVI dataset over a 38-month longitudinal survey of Seattle, WA, USA during the COVID-19 pandemic. The output of our pipeline is validated through statistical analyses of pedestrian traffic in the images. We confirm known results in the literature and provide new insights into outdoor pedestrian traffic patterns. This study demonstrates the feasibility and value of collecting and using SVI for research purposes beyond what is possible with currently available SVI data. Our methods and dataset represent a first of its kind longitudinal collection and application of SVI data for research purposes. Limitations and future improvements to the data pipeline and case study are also discussed.

Investigation of Li accumulations in LLZO based solid state batteries via operando neutron imaging and ex-situ correlative structural and chemical analysis

In this study, we present a comprehensive analysis of lithium dendrite formation in half-cells with lithium garnet-type solid-state electrolyte Li7La3Zr2O12 (LLZO) utilizing operando neutron imaging and subsequent ex-situ correlative structural and chemical analysis. The operando experiment involves cycling a solid-state symmetric half-cell (Li|LLZO|Li) until short-circuit failure, all while being irradiated with neutrons, providing invaluable insights into the dynamic processes within the symmetric half-cell. Post-mortem investigations were carried out, comprising two techniques: 1) secondary electron imaging for structural analysis and 2) secondary ion mass spectrometry (SIMS) for chemical mapping. This multifaceted approach creates complementary datasets, bridging the gap between neutron radiography, known for its quantitative transmission capabilities, and high-resolution, high-sensitivity structural and chemical imaging via scanning electron microscopy (SEM) and SIMS.Central to our investigation is the design and development of an operando neutron imaging approach, enabling the study of lithium penetration during the electrochemical cycling. Furthermore, structural, and chemical analyses through correlative SEM/SIMS unveil various morphologies of lithium accumulations. Specifically, regions with dense LLZO reveal intergranular lithium accumulations, while low-density areas within the LLZO pellet, such as pores and cracks, exhibit distinct types of lithium accumulations (e.g. whiskers).Notably, neutron analysis reveals an accumulation of lithium in selected regions, with a maximum increase of up to 3.6 vol.-%. These regions primarily correspond to the roughened LLZO/Li interface, as observed through neutron imaging, although the SEM/SIMS analysis unequivocally confirms the presence of lithium dendrites (with sizes at or below the resolution limit of neutron imaging) also within the bulk of LLZO.This work offers a comprehensive examination of the intricate dynamics of lithium dendrite formation and behaviour in LLZO-based solid-state half-cells, emphasizing the potential of operando techniques to advance our understanding of critical issues (e.g. degradation, dendrite formation, …) in battery research.

Simulating the land use change effects on non-point source pollution in the Duliujian River Basin.

The uncertainty in the generation and formation of non-point source pollution makes it challenging to monitor and control this type of pollution. The SWAT model is frequently used to simulate non-point source pollution in watersheds and is mainly applied to natural watersheds that are less affected by human activities. This study focuses on the Duliujian River Basin (Xiqing section), which is characterized by a dense population and rapid urbanization. Based on the calibrated SWAT model, this study analyzed the effects of land use change on non-point source pollution both temporally and spatially. It was found that nitrogen and phosphorus non-point source pollution load losses were closely related to land use type, with agricultural land and high-density urban land (including rural settlements) being the main contributors to riverine nitrogen and phosphorus pollution. This indicates the necessity of analyzing the impact of land use changes on non-point source pollution loads by identifying critical source areas and altering the land use types that contribute heavily to pollution in these areas. The simulation results of land use type changes in these critical source areas showed that the reduction effect on non-point source pollution load is in the order of forest land > grassland > low-density residential area. To effectively curb surface source pollution in the study area, strategies such as modifying urban land use types, increasing vegetation cover and ground infiltration rate, and strictly controlling the discharge of domestic waste and sewage from urban areas can be implemented.