Low Carbon Research Articles

Tuning the Electronic Properties of CumAgn Bimetallic Clusters for Enhanced CO2 Activation

The urgent demand for efficient CO2 reduction technologies has driven enormous studies into the enhancement of advanced catalysts. Here, we investigate the electronic properties and CO2 adsorption properties of CumAgn bimetallic clusters, particularly Cu4Ag1, Cu1Ag4, Cu3Ag2, and Cu2Ag3, using generalized gradient approximation (GGA)/density functional theory (DFT). Our results show that the atomic arrangement within these clusters drastically affects their stability, charge transfer, and catalytic performance. The Cu4Ag1 bimetallic cluster emerges as the most stable structure, revealing superior charge transfer and effective chemisorption of CO2, which promotes effective activation of the CO2 molecule. In contrast, the Cu1Ag4 bimetallic cluster, in spite of comparable adsorption energy, indicates insignificant charge transfer, resulting in less pronounced CO2 activation. The Cu3Ag2 and Cu2Ag3 bimetallic clusters also display high adsorption energies with remarkable charge transfer mechanisms, emphasizing the crucial role of metal composition in tuning catalytic characteristics. This thorough examination provides constructive insights into the design of bimetallic clusters for boosted CO2 reduction. These findings could pave the way for the development of cost-effective and efficient catalysts for industrial CO2 reduction, contributing to global efforts in carbon management and climate change mitigation.

Toward Sustainable Utilization and Production of Tartaric Acid

AbstractGlobal efforts toward establishing a circular carbon economy have guided research interests towards exploring renewable technologies that can replace environmentally harmful fossil fuel‐based production routes. In this context, sugar‐based bio‐derived substrates have been identified as renewable molecules for future implementation in chemical industries. Tartaric acid, a special C4 bio‐compound with two hydroxyl and carboxylic groups in the structure, displays great potential for the food, polymer, and pharmaceutical industries due to its unique biological reactivity and performance‐enhancing properties. To this point, there has yet to be a comprehensive literature review and perspective on the applications and synthesis of tartaric acid. As such, we have conducted a detailed and thorough outlook and discussion in terms of biological activity, organic synthesis, catalysis, structural characterization and synthetic routes. Lastly, we provide a critical discussion on the applications and synthesis of tartaric acid to give our insights into developing sustainable chemical technologies for the future.

Assessing the Carbon Intensity of e-fuels Production in European Countries: A Temporal Analysis

The transport sector heavily relies on the use of fossil fuels, which are causing major environmental concerns. Solutions relying on the direct or indirect use of electricity through e-fuel production are emerging to power the transport sector. To ensure environmental benefits are achieved over this transition, an accurate estimation of the impact of the use of electricity is needed. This requires a high temporal resolution to capture the high variability of electricity. This paper presents a previously unseen temporal analysis of the carbon intensity of e-fuels using grid electricity in countries that are members of the European Network of Transmission System Operators (ENTSO-E). It also provides an estimation of the potential load factor for producing low-carbon e-fuels according to the European Union legislative framework. This was achieved by building on top of the existing EcoDynElec tool to develop EcoDynElec_xr, a python tool enabling—with an hourly time resolution—the calculation, visualisation, and analysis of the historical time-series of electricity mixing from the ENTSO-E. The results highlight that, in 2023, very few European countries were reaching low carbon intensity for electricity that enables the use of grid electricity for the production of green electrolytic hydrogen. The methodological assumptions consider the consumption of the electricity mix instead of the production mix, and the considered time step is of paramount importance and drastically impacts the potential load factor of green hydrogen production. The developed tools are released under an open-source license to ensure transparency, result reproducibility, and reuse regarding newer data for other territories or for other purposes.

Zero carbon, some nuisance: Exploring the viewpoints of heat pump owners and their neighbors in Groningen, Netherlands

ABSTRACT The domestic use of natural gas for heating is the prevalent option in the Netherlands. However, heat pumps will be mandatory in most Dutch households by 2026. Therefore, insights are needed in how citizens perceive this technology, by taking into account various societal, technological, economic, environmental, and political aspects. Our research offers a systematic investigation of the multiple viewpoints of heat pump users and their neighbors in Groningen, northern Netherlands. Using Q-methodology, we identified three distinct but interrelated and shared viewpoints: the realistic users, the hesitant neighbors and the enthusiastic advocates. All three shared viewpoints incorporate social influence and cognitive considerations, with the positive environmental impacts of heat pumps being highlighted in unison. Cognitive considerations relate mainly to technical and economic concerns. Social influence considerations often hint at the necessity of making prior agreements with the neighbors. We argue that the findings of this study can support policymakers toward the development of an integrated heat transition strategy.

Study on the Comprehensive Assessment of High-Quality Development Performance of Low Carbon Tourism in China's Rizhao City Empowered by New Quality Productivity

With the rapid development of China's urban economy, the new quality productivity empowerment to promote the high-quality development of tourism in Rizhao City has become a new trend, and the vigorous development of tourism has gradually become a new growth point under the influence of a series of policies on low-carbon tourism in Shandong Province. In order to effectively assess the performance of new quality productivity empowerment to promote the high-quality development of low-carbon tourism in Rizhao City, this paper utilizes the basic data of Rizhao City, China, for the period of 2013-2022, and comprehensively assesses the status of the high-quality development performance of low-carbon tourism in Rizhao City by constructing the spatial ecological niche integrated assessment model, and it is found that: the performance of the high-quality development of low-carbon tourism in the city of Rizhao City, China, which is empowered by the new quality productivity, has shown a There are some differences in the assessment results of the three models, the absolute ecological niche suitability model has the largest assessment result, the relative ecological niche suitability model has the smallest assessment result, and the assessment result of the spatial ecological niche suitability model is located in between the assessment results of the other two models with the effect of equalization, and the assessment result of the spatial ecological niche suitability model shows that the high-quality development performance of the target city's low-carbon tourism The assessment result in 2013 is 0.7783, and the quality level of low-carbon tourism high-quality development performance is III, and the assessment result in 2022 rises to 0.8972, and the quality level of low-carbon tourism high-quality development performance is II, which has already reached the edge of I. In terms of the degree of influence of the evaluation indicators, the insufficient strength of new quality productivity empowerment in Rizhao City, China, affects the performance of low-carbon tourism high-quality development, and the second most influential of the other guideline level indicators on the assessment results is the weak effect category.

Impact of plastic waste fiber and treated construction demolition waste on the durability and sustainability of concrete

This study explores the mechanical and durability properties of Plastic-Fibre Reinforced Concrete, incorporating hand-shredded plastic fibers sourced from polyethylene bags and PET bottles. Evaluations, including compressive and split tensile strength tests, were conducted on M40 grade mixes containing plastic fibers and 100% treated Construction and Demolition Waste (CDW), comparing them with conventional concrete. The results demonstrate a significant enhancement in strength properties with the addition of 0.25%, 0.5%, 0.75%, and 1% plastic-fibres, alongside the complete replacement of coarse aggregate with CDW, particularly noticeable at both 7 and 28-day curing ages. Although higher fiber dosages led to a slight reduction in compressive by 7% at the optimum percentage of 0.25% of PE and 0.5% of PET, the flexural strengths and split tensile strength exhibited a proportional increase of 11.7% and 18%. Surface analysis via Scanning Electron Microscopy (SEM) and elemental composition determination using Energy Dispersive Spectroscopy (EDS) revealed minimal fiber damage post-exposure, confirming its efficiency and contribution to higher strength and reduced weight loss in optimum mix. This novel approach combines manually recycled plastic waste as fibers with treated CDW, enhancing concrete properties while promoting sustainability. Sustainability analysis indicates that utilizing 100% CDW and plastic fiber contributes to reduced energy consumption, lower carbon emissions, and economic benefits. These findings underscore the potential of integrating non-degradable plastics into concrete mixtures, combined with treated CDW, offering both environmental sustainability and enhanced performance advantages in construction materials.

Grazing disturbance reduces biocrust-related cyanobacteria and N-fixer abundance but increases bacterial diversity: Implications for biocrust restoration in degraded drylands

Overgrazing is a major driver of dryland degradation, however, so far, there is limited understanding on how this process affects biocrust-related microbial community, and especially how the key groups respond to grazing disturbance. In this study, quantitative polymerase chain reaction (qPCR) and high throughout sequencing technologies were used to investigate the bacterial community abundance and diversity in the Horqin Sandland (China) experiencing different livestock grazing disturbances, in order to examine whether a shift in bacterial community (in particular the key biocrust components, cyanobacteria) was involved, and how this was related to biocrust development and altered soil carbon and nitrogen level. Our results revealed that a clear heterogeneous soil bacterial community was associated with grazing disturbance, which inhibited biocrust development. The decreased photosynthetic cyanobacterial abundance (81.81 % in relative abundance and 98.83 % in absolute abundance) and nitrogen-fixing genes (87.72 %), associated with the lower total carbon and nitrogen content (P<0.05), illustrated a low soil carbon and nitrogen-fixing capability and nutrient level in the grazing-disturbed soils. In particular, a switch of nitrogen-fixing dominance from cyanobacteria to proteobacteria was induced by the grazing disturbance. Compared to the grazing-disturbed soils, higher dominant cyanobacterial operational taxonomic units (OTUs) (especially the species of Nostoc and Scytonema) and lower bacterial diversity (e.g., Shannon, Ace, and Chao index) were observed in the undisturbed biocrust soils, highlighting that the dominants rather than diversity played more important roles in biocrust development. Collectively, our results demonstrate that cyanobacteria are very sensitive (even more than others, e.g., proteobacteria and actinobacteria) to grazing disturbance, therefore, we propose that cyanobacterial inoculation is likely an effective approach to supplement soil cyanobacterial abundance, which is expected to induce biocrust development and increase carbon and nitrogen level in the disturbed drylands.

Development Strategy of Carbon Finance in China Under the Low Carbon Economy Context

Development Strategy of Carbon Finance in China Under the Low Carbon Economy Context

Greenhouse-gas abatement on Australian dairy farms: what are the options?

The Australian dairy industry contributes significantly to the rural economy, but must reduce its greenhouse-gas emissions to remain competitive in a global market that is starting to prioritise a low carbon footprint. Demand for improved environmental, social and governance performance from supply chains creates an imperative for research to deliver options for farmers to make reductions in their environmental footprint. Given the rapidly evolving nature of greenhouse-gas abatement research, this critical review provides an update on the state of the research relevant to Australian dairy systems and identifies research gaps that must be addressed if there is to be widespread on-farm adoption. Current research suggests that Australian dairy farms could theoretically abate enteric methane by 40–50%, with about another 5–10% reduction in whole-farm greenhouse-gas emissions being possible by flocculating or covering stored effluent. Fertiliser- and urine-patch management strategies could substantially reduce direct and indirect nitrous oxide emissions, but by variable amounts subject to local conditions. However, few abatement options are currently cost-effective for farmers. Significantly more research investment is required to facilitate the on-farm adoption of strategies, particularly to reduce enteric methane and improve the efficiency of nitrogen cycling. Improved understanding is required of the influences on each strategy’s abatement potential and interactions with economically important traits in grazing systems, the effect of combining abatement strategies, and systems by which strategies can be implemented cost-effectively on farms. The challenge for research is to consider how the implementation of cost-effective abatement options can be refined for grazing dairy systems to maintain the position of Australian dairy in the global market.

Innovation and future development direction of hydrogen fuel cell vehicles

With the increasing problem of global climate change, reducing greenhouse gas emissions has become an urgent issue for all countries to solve. The pollution of the Earth is gradually becoming severe. The extensive use of fossil fuels is a major cause of this problem. In this critical situation, energy with the least carbon emissions should be used to minimize air pollution and the harm caused by it. Hydrogen energy is currently a clean energy alternative that can achieve low carbon emissions. As a new energy vehicle, hydrogen fuel cell vehicles have the advantages of being clean, efficient, and environmentally friendly. Compared with traditional fuel vehicles, hydrogen fuel cell vehicles only produce water and a small amount of oxygen during operation, and do not emit harmful substances such as carbon dioxide, which helps to significantly reduce carbon emissions in the transportation sector. So, hydrogen fuel cell vehicles are a viable and clean solution. In this paper, the performance evaluation, cost analysis, and future impact of hydrogen-powered vehicles are analyzed, and the future development trend of hydrogen energy battery vehicles is discussed. As a new energy vehicle, hydrogen fuel cell vehicles have important strategic significance and market prospects. The purpose of this paper is to provide a useful reference for the development of China's new energy vehicle industry through the study of hydrogen fuel cell vehicles.

Soil organic carbon stocks as driven by land use in Mato Grosso State: the Brazilian Cerrado agricultural frontier

To address national and global demand for agro-based products, agricultural expansion has rapidly become a norm in Brazil since 1950s to date. In recent decades, agricultural expansion and technological advancement have placed the country among the top producers and exporters of agricultural products. The paradigm shifts in farming system from conventional to integrated approach has brought significant changes in land use, which consequently influenced carbon sequestration and soil organic carbon (SOC). This is more prevalent in the State of Mato Grosso, one of the most producers of food in Brazil. On this background, we hypothesized that though forests have potential for SOC stock, which decreases due to conversion to cropland but in longer-term with sustainable management, carbon might accrual significantly in cropland. Therefore, this paper aimed to unveil the nexus between long term land use and carbon stock changes and estimate future SOC stocks in Mato Grosso State of Brazil. To achieve this aim, a hybridization of machine learning and the InVEST prediction models was applied to estimate the land use changes and the SOC stocks between 1990 and 2020 and estimate for 2050. The study revealed that between 1990, 2020, and 2050, croplands increased significantly by at least 78%, pastures decreased by 32%, while forests decreased marginally by about 4% due to agricultural expansions. However, in 1990 and 2020, the SOC stock was slightly up to 147.34 Mg ha−1, it recorded an increase after a longer-time (i.e., in 2050). This increase was substantially under the forests, and marginally in the croplands. Climate-smart agricultural systems such as crop-livestock forest, integrated crop-livestock, and other conservation agricultural practices have great potential to contribute to sustainable development by increasing the levels of carbon in agricultural soils especially, after a longer period. Therefore, agricultural policies geared towards low carbon agriculture should be fully integrated into the various government decision making processes as this will guarantee food security and maximize soil carbon sequestration and stocks in the long term. Simultaneously, it is crucial to promote the dissemination of best practices for implementing and sustaining conservation efforts, thereby safeguarding the carbon stocks established to prevent their depletion. This will also support the Brazilian government in achieving its Nationally determined contributions (NDCs) through agricultural soils.

Experimental study on buildability and mechanical properties of 3D printing cob

The application of 3D printing technology to earth buildings conforms to the development concept of low carbon, green and intelligent construction. The key issue lies in the development of earth material with both favorable buildability and sufficient mechanical properties. In this study, the printing parameters of mixture for 3D printing with different water contents were optimized. The optimum water content of 3D printing cob was determined based on the buildability. The result shows that when the flow spreading diameter is between 140 mm and 160 mm, 3D printing cob has good buildability performance. The optimum water content is 24.6 %. In addition, anisotropic performance was analyzed by compressive strength tests from three orthogonal directions. In particular, according to the test results of single printing limit height and yield stress, the buildability of 3D printing cob wall was analyzed. The building strategy of the printing divided into multiple times was obtained.

The Concept of Implementing Net Zero Carbon Emission with a Cluster Approach. Case Study: Central Java Province Projection to 2030

The Concept of Implementing Net Zero Carbon Emission with a Cluster Approach. Case Study: Central Java Province Projection to 2030

Renewable Solar Energy Facilities in South America—The Road to a Low-Carbon Sustainable Energy Matrix: A Systematic Review

South America is a place on the planet that stands out with enormous potential linked to renewable energies. Countries in this region have developed private investment projects to carry out an energy transition from fossil energies to clean energies and contribute to climate change mitigation. The sun resource is one of the more abundant sources of renewable energies that stands out in South America, especially in the Atacama Desert. In this context, South American countries are developing sustainable actions/strategies linked to implementing solar photovoltaic (PV) and concentrated solar power (CSP) facilities and achieving carbon neutrality for the year 2050. As a result, this systematic review presents the progress, new trends, and the road to a sustainable paradigm with disruptive innovations like artificial intelligence, robots, and unmanned aerial vehicles (UAVs) for solar energy facilities in the region. According to the findings, solar energy infrastructure was applied in South America during the global climate change crisis era. Different levels of implementation in solar photovoltaic (PV) facilities have been reached in each country, with the region being a worldwide research and development (R&amp;D) hotspot. Also, high potential exists for concentrated solar power (CSP) facilities considering the technology evolution, and for the implementation of the hybridization of solar photovoltaic (PV) facilities with onshore wind farm infrastructures, decreasing the capital/operation costs of the projects. Finally, synergy between solar energy infrastructures with emerging technologies linked with low-carbon economies like battery energy storage systems (BESSs) and the use of floating solar PV plants looks like a promising sustainable solution.

Role of zeolite and palm fiber in modifying the strength of cement-treated soil.

This paper aimed to research the role of zeolite and palm fiber in changing strength of cement-treated soil. The unconfined compressive strength (UCS) testwas mainly used to study the changes of strength of cement-treated soil by varied content of cement, zeolite, palm fiber under different curing period. The optimum substitution rate of zeolite for cement was researched for the purpose of increasing of strength of cement-treated soil and low carbon and environment protection, while the optimum content of palm fiber was explored for improving of strength and ductility of cement-treated soil by means of analytic software. Finally, the multiple regression technology was used to try to capture the relationship between strength of cement-treated soil and content of zeolite and palm fiber. The results show that the cement, zeolite, palm fiber and curing age have strong effect on the UCS of cement-treated soil.

Selective Oxidation of Polyesters via PdCu-TiO2 Photocatalysts in Flow.

Catalytic upcycling of plastic wastes offers a sustainable circular economy. Selective conversion of the most widely used polyester, polyethylene terephthalate (PET), under ambient conditions is practically attractive because of low energy consumption and carbon footprint. Here, we report selective, aerobic conversion of PET in a flow reactor using TiO2 photocatalyst modified with atomic Pd and metallic PdCu (Pd1Cu0.4-TiO2) under ambient conditions. We demonstrate that atomically synergistic Pd1Cu0.4-TiO2 exhibits a formate evolution of 4707 μmol g-1 h-1 with a selectivity of 92.3% together with trace COx released. Importantly, we show that this corresponds to 10-103 times greater activity than reported photocatalytic systems. We confirm that synergy between atomic Pd and metallic PdCu boosts directional charge transfer and oxygen-induced C-C cleavage and inhibits product decomposition. We conclude that photocatalytic waste plastic-to-chemical conversion is sustainable via targeted engineering of atomically synergistic catalysts and reaction systems.

Russian exports amid geopolitical instability: The case of physical and transitional climate risks

The paper examines the impact of physical and transitional climate risks, which to some extend shape the geopolitical situation in the world, on Russian exports. The gravity model of international trade was employed to model the existing relationship. Estimation of the gravity equation by means of the Poisson Pseudo Maximum Likelihood (PPML) method using data on Russian export flows to 72 countries over the period 2010—2021 revealed that climate change and the ambitions of trading partner states towards low-carbon development determine the dynamics of Russian exports. In particular, national physical climate risks have a detrimental impact on Russia’s exports due to the destruction of infrastructure, loss of capital, reduced quality and availability of natural resources, and increased social tensions. Extreme climatic events and climate change measures in trading partner countries spur the development of Russian exports. Namely, physical climate risks of importing countries may increase the demand for key Russian goods for economic recovery purposes. Changes during the transition to a low-carbon economy in trading partner countries also generate opportunities for Russian export growth due to the country’s role as a major supplier of energy and mineral products, as well as technologies for the alternative energy production and electrification of transport

Performance of Molasses Waste as a Cement Replacement to Study Concrete Compressive Strength

To reduce the negative environmental impact of cement production and preserve natural resources, an experimental investigation was conducted to study the performance of concrete specimens at different curing ages and to determine the compressive strength of these specimens by replacing cement with molasses. Experimentation was carried out on the concrete specimens at a temperature range of 25 °C to 30 °C; six specimens were cast for each replacement ratio, except for 0.75% wt. of cement (86.55 g) and 1% wt. of cement (113.6 g), where five samples were considered for each ratio. The average 28-day compressive strength of the conventional concrete specimens came out to be 29 MPa, but increased to 40 MPa with the addition of 0.25% wt. of cement molasses (28.85 g). It was observed that as the percentage of molasses waste in the concrete mix was further increased by replacing the cement, the compressive strength of the concrete specimens increased gradually and then significantly decreased. The findings shed light on the prospect of using molasses waste instead of cement in the concrete mix. Also, it is worth mentioning that about 30% of the cost–benefit was obtained with reference to that of conventional admixtures available in the market for the production of concrete. However, it is notable that a long-term durability study needs to be conducted before making it viable. This work not only addresses a sustainable and innovative method of waste management (SDG12), but also contributes to low carbon emissions (SDG13). The novelty of this work lies in the fact that no such kind of study has been conducted in Pakistan so far, in addition to the very limited international literature available, and, in particular, no evidence on the compressive strength results at higher molasses dosages, i.e., 1% wt. of cement (113.6 g) and 2% wt. of cement (230.8 g).

The Effect of Cryogenic Treatment on a High Co Bearing DIN 1.2888 Steel Used as Die in Hot Forging Process

Abstract Hot work steels used as dies in metal forming processes must endure harsh conditions, typically achieved through a martensitic structure. However, retained austenite can persist after martensitic transformation, negatively impacting mechanical properties. Cryogenic treatment (CT) refines martensite, reduces retained austenite, and increases fine carbide density, thus enhancing performance. DIN 1.2888, a hot work tool steel with high cobalt content (~10%) and low carbon content (~0.2%), is less studied concerning the effects of CT. The objective of this study was to investigate how cryogenic treatment affects the mechanical and microstructural properties of DIN 1.2888 steel. Samples underwent conventional heat treatment (HT) and CT at -100, -140, and -180°C for 6 hours, followed by double tempering. Various analytical methods, including X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), and Vickers Microhardness tests, were used to examine the samples. Wear mechanisms were evaluated through pin-on-disc tests under different loads, and impact toughness was measured both at room temperature and the working temperature of dies (350°C). Results indicated that lowering the cryogenic treatment temperature resulted in a slight increase in hardness values from 507HV for the heat-treated sample to 529HV for the sample treated at -180°C. Additionally, the impact toughness improved significantly, with values rising from 12.35J for the heat-treated sample to 23.44J at 350°C for the cryogenically treated sample at -180°C. Wear rates also decreased by approximately 50%, particularly at higher cryogenic treatment temperatures. The improvement in wear resistance was attributed to finer carbide precipitation and a more homogeneous distribution of carbides. These findings suggest that deep cryogenic treatment has a positive effect on DIN 1.2888 steel by decreasing retained austenite and increasing fine carbide density, leading to enhanced mechanical properties and extending the lifespan of the steel in die applications.

A Study on the Spatiotemporal Dynamics of Land Cover Change and Carbon Storage in the Northern Gulf Economic Zone of Guangxi Based on the InVEST Model

In recent years, the international community has increasingly focused on the “dual carbon” issue, as human-induced land use changes significantly impact ecosystem structure and carbon cycling. This study analyzes land use changes in the economic zone of the northern Gulf of Guangxi from 1980 to 2020, utilizing the InVEST model to simulate spatiotemporal changes in carbon storage and conducting zoning studies through spatial analysis. The findings reveal that ① forest land and arable land dominate the northern Gulf of Guangxi’s land use, with notable changes observed in forest land, unused land, and construction land areas. Forest land and construction land have increased by 1761.5 km2 and 1001.19 km2, respectively, while unused land has decreased by 1881.18 km2 from 2000 to 2020. ② The total carbon storage values in the northern Gulf of Guangxi in 1980, 2000, and 2020 were, respectively, 504.91 × 106/t, 487.29 × 106/t, and 500.31 × 106/t, with the expansion of construction land and conversion of forest land being the main reasons for the decrease in carbon storage. ③ In the northern Gulf of Guangxi, there is a slight upward trend in total carbon storage values over time. Spatially, higher carbon storage values are observed in mountainous and hilly areas at high altitudes, while the central and southern coastal areas exhibit lower carbon storage values. ④ The local spatial autocorrelation results reveal that Pu Bei County exhibits high–high clustering of carbon storage, while He Pu County undergoes a transition from high–low to low–low clustering, and several other administrative areas in Beihai demonstrates low–low clustering. Due to the imperative of economic development, the expansion of urban construction land encroaches upon ecological land, resulting in a decline in carbon storage. Therefore, in the Northern Gulf of Guangxi, it is essential to implement measures such as reforestation and establish ecological protection areas such as forests, grasslands, and wetlands to develop effective carbon sequestration methods and compensate for the carbon loss caused by the expansion of construction land.