Low Carbon Research Articles

Fully biobased poly(butylene furanate) copolyesters from renewable 2,3-butanediol: Much more than just strengthening and toughening

Making full use of renewable biomass resources to develop biobased polyester plastics with balanced performance is an important part of achieving a low-carbon circular economy. As a representative variety of biobased furan polyesters, the insufficient mechanical properties limit the application of poly(butylene furanate) (PBF) toward sustainable film materials. This study proposes a trade-off strategy by inserting the rigid biobased 2,3-butanediol (2,3-BDO) unit into the PBF molecular chain. The results show that inserting a small amount of 2,3-BDO can simultaneously realize the strengthening and toughening of PBF. When the content of 2,3-BDO reaches only 4 mol%, the copolymer possesses the tensile strength of 67.0 MPa with the elongation at break of 556.2 %. More appealingly, the crystallizability and barrier properties of copolymers can still be maintained to a certain extent. In general, by inserting a small amount of rigid 2,3-BDO unit, the fully biobased copolyesters can achieve a good balance in terms of crystallization, mechanical, and barrier properties, guaranteeing them to meet the requirements where high strength and toughness are needed.

Graphite and multi-layer graphene from a low molecular weight carbon source

While carbonaceous structures formed by pyrolysis of macromolecular carbon sources with silicates are well described in the literature, information on the structure of carbons obtained in the similar way from low molecular weight (LMW) carbon sources is not sufficient. This study is therefore aimed at characterizing the material obtained by pyrolyzing (1300 °C; Ar atmosphere) montmorillonite containing ∼25-50 wt.% LMW cations as a carbon source. Pyrolyzed samples contained ∼5-20 wt.% carbon, and thermogravimetric and elemental analysis showed a higher yield for a higher original amount of the LMW carbon source. In addition to amorphous carbon, graphite was formed during pyrolysis, as confirmed by X-ray diffraction analysis, Raman spectroscopy, and X-ray photoelectron spectroscopy. The presence of graphene-based nanomaterial, specifically multi-layer graphene, was revealed by transmission electron microscopy (TEM). Electrical conductivity of the silicate/carbon material reached ∼35 S·m-1. Raman spectra and TEM images are similar to those from studies describing the use of macromolecular carbon sources. LMW compounds are a sufficient source of carbon for the preparation of electrically conductive materials containing graphite and multi-layer graphene.

Effects of inorganic nitrogen enrichment on soil CH4 and CO2 production in freshwater and mesohaline marshes across six estuaries in China

Eutrophication is an important environmental stressor in coastal wetlands that alters ecosystem processes including primary production and the carbon cycle. However, how different nitrogen eutrophication scenarios may affect CH4 and CO2 production along a salinity gradient in coastal wetlands is poorly known. We collected the surface soil samples from both tidal freshwater and mesohaline Phragmites australis marshes in six main estuaries in China and conducted inorganic nitrogen enrichment anaerobic incubation experiments. Background soil CH4 and CO2 production rates were strongly correlated with total nitrogen but not salinity. On average, nitrate enrichment decreased soil CH4 and CO2 production rates by ca. 20 % in freshwater marsh and 16–43 % in mesohaline marshes, whereas ammonium enrichment decreased CO2 production by ca. 26–30 % but had no effect on CH4 production. Salinity was not an important mitigating factor in either eutrophication scenario. In most cases, nitrogen addition decreased the extracellular enzyme activities of β-1,4-glucosidase and cellobiohydrolase, but increased the activity of β-N-acetyl glucosaminidase, phenol oxidase and peroxidase. Nitrate addition decreased the mcrA gene abundance on average by 34–35 % but ammonium addition had insignificant effect. Total nitrogen availability was an important driver of CH4 and CO2 production rates in these tidally influenced coastal wetlands. Our results showed that tidal marshes with salinity < 15 ppt had similar soil CH4 production rates, and increasing inorganic nitrogen eutrophication might lower soil microbial carbon gas production in both tidal freshwater and mesohaline marshes.

A new type of geopolymer with good thickening and strength properties using Na2C2O4+Ca(OH)2 as the activator

Geopolymer materials exhibit excellent resistance to CO2 corrosion and low carbon emission characteristics, which are very suitable for cementing in CCUS/CCS wells. However, it is difficult to control its thickening time, which limits its popularization and application. The substitution of NaOH with Na2C2O4 and Ca(OH)2 to activate geopolymers was tried to investigate their influence on thickening time and strength of the geopolymer. The precursors used were fly ash sinker beads and slag (the mass ratio is 8:2). Results indicate that at 75°C, the thickening time of geopolymers activated by NaOH is difficult to extend with retarders, whereas those activated by Na2C2O4+Ca(OH)2 can be effectively extended using D-Gluconic acid sodium (D-GA) or ethylene diamine tetra methylene phosphonic acid sodium (EDTMPS). Additionally, geopolymers activated by Na2C2O4+Ca(OH)2 exhibit good strength properties, with compressive strengths of 25.3MPa for 24h and 25.6MPa for 48h at 75°C. Furthermore, geopolymer curing next to water-bearing rocks showed that geopolymer can also achieve excellent solidification when surrounded by water-bearing rocks, which is favorable for its application under the well cementing construction.

Carbon isotope composition of biomass and water use efficiency in young plants of Jatropha curcas L. under irrigated or water deficit conditions

Jatropha curcas L. is a non-food crop quoted as a promising natural feedstock for biodiesel production in tropical and subtropical regions. Although an efficient mechanism of drought avoidance through stomatal control of transpiration has been demonstrated in this species, low carbon assimilation and growth rates preclude any advantage of such strategy under water limitation. Two greenhouse experiments were conducted with the objective of investigating varietal differences in water use as the trade-off between carbon isotope composition (δ13C) in different tissues and water use efficiency, in young plants of J. curcas. The first experiment was a survey with seven provenances of J. curcas under non-limiting water availability. There were no significant differences among provenances for leaf gas exchange rates, growth and whole-plant transpiration (T). However, significant effects of provenance and tissue (stem bark or leaf) in δ13C were demonstrated. The provenances CNPAE183 and CNPAE222 were selected for the second experiment, as variations in water use traits and δ13C between the two provenances were observed. Soil water deficit, imposed for 18 days, led to significant physiological, biochemical, and morphological changes. An early and sharp response to water deficit in CNPAE183 as compared to CNPAE222 was observed, as indicated by a 44% higher rate of decrease of T in the former. In addition, water deficit led to increase of δ13C, which was more pronounced in CNPAE222 (13% in young leaves) when compared to CNPAE183 (11% in young leaves). In both provenances, δ13C was less negative in young as compared to mature tissues. Significant and direct correlations between stem bark and leaf δ13C and leaf-level intrinsic water use efficiency were observed. Contrasting results, particularly on T and δ13C, suggest the existence of genetic diversity for water relations and metabolic traits linked to drought tolerance in J. curcas. Using stem bark or leaf δ13C measurements as the basis for large-scale screening of water-use efficient genotypes should be considered.

Bio-organic substitution in tobacco (Nicotiana tabacum L) cultivation: Optimum strategy to lower carbon footprint and boost net ecosystem economic benefit

The partial substitution of organic manure for chemical nitrogen fertilizers, known as organic substitution, is widely regarded as a cleaner and more sustainable production strategy. However, few studies have quantified greenhouse gas emissions, product income and net ecosystem economic benefit (NEEB) using a life cycle assessment (LCA) approach, particularly for typical tobacco (Nicotiana tabacum L.) production. Here, we quantified the yield and quality of a typical tobacco production in Qujing, Yunnan, China, through field experiments and calculated its carbon footprint and NEEB using the LCA approach. Four organic substitution strategies were established with equal nitrogen inputs, including synthesized chemical fertilizer (SN), farmyard organic manure (NF), commercial organic manure (NC), and bio-organic (Trichoderma viride Pers.) manure (NT), each substituting 15% of synthesized nitrogen fertilizer. Compared to the SN strategy, the NT strategy significantly increased yield and income by 10.3% and 9.6%, respectively. In contrast, the NF strategy significantly reduced income, while the NC strategy showed no significant difference. Both the NC and NT strategies significantly reduced N2O cumulative emissions (by 15.9% and 8.0%, respectively), increased δSOC (by 38.4% and 15.0%, respectively), and decreased carbon footprint compared to the SN strategy. However, the NF strategy significantly increased the income-scaled carbon footprint, even though it also notably reduced N2O cumulative emissions (by 22.6%) and increased δSOC (by 7.9%). The NT strategy achieved a win-win scenario of low environmental risk and high economic returns of tobacco production with significantly increased NEEB (by 10.6%) compared to the SN strategy (37.60 × 103 CNY yr−1). This suggests that the bio-organic Trichoderma manure substituting 15% synthesized nitrogen fertilizer is the best organic substitution strategy for sustainable tobacco production.

Lithium‑sulfur batteries for next-generation automotive power batteries carbon emission assessment and sustainability study in China

The rise of electric vehicles has ushered in a revolution in the automotive industry, propelling the global automotive sector towards sustainable development. However, considerable controversy persists regarding the comprehensive performance of electric vehicle batteries and their environmental impact. The development of next-generation power batteries, aimed at enhancing energy storage performance while mitigating environmental consequences, has become a focal point of research in this field. Lithium‑sulfur batteries (LSBs), with their innovative structural design and environmentally friendly materials, not only enhance energy storage performance but also harbor significant environmental potential. When coupled with an all-solid-state battery structure, the all-solid-state lithium‑sulfur battery (A-LSB) demonstrates even more superior performance. This combination represents an ideal next-generation power battery for automotive applications, offering heightened efficiency and environmental sustainability. This study conducts a prospective life cycle assessment (LCA) to examine the environmental performance, particularly carbon emissions, during the production processes of LSBs and A-LSBs in the Chinese region. The primary objective is to uncover the potential for sustainable development in the future of lithium‑sulfur battery technologies. During the research process, we conducted comparative validation by comparing with traditional ternary lithium-ion batteries (NCM) and lithium iron phosphate batteries (LFP). Experimental setups were designed to simulate both laboratory and industrial production scenarios, with a primary focus on analyzing the sustainable performance of LSB and A-LSB. The results indicate that, compared to traditional lithium-ion batteries, both LSB and A-LSB exhibit lower carbon emissions and superior environmental performance, with A-LSB showing particular promise. However, A-LSB demonstrates higher sensitivity to environmental impacts, displaying significant variations before and after industrial production. Additionally, it exhibits a greater dependency on regional resources and energy structures. In contrast, LSB displays better regional adaptability.

Evaluating the effectiveness of climate change policies and initiatives in the United States: A comprehensive review

Climate change presents profound challenges, demanding effective policies to mitigate its impacts. This paper reviews the effectiveness of climate policies in the United States, analyzing scholarly articles, government reports, and relevant literature. The review covers diverse policies such as greenhouse gas regulations, renewable energy initiatives, energy efficiency programs, and adaptation measures. It assesses their success in reducing carbon emissions, advancing a low-carbon economy, and enhancing resilience to climate impacts. Key findings highlight significant successes, such as the rise in renewable energy due to renewable portfolio standards and reduced emissions from vehicle fuel efficiency standards. State-level initiatives, like carbon pricing and renewable energy targets, also show promising outcomes. However, the review identifies substantial challenges, including political and economic obstacles, inconsistent policies across states, and the need for better federal-state-local collaboration. Additionally, disparities in policy benefits, with marginalized communities facing greater burdens and limited access to renewable resources, are significant concerns. To enhance the effectiveness of climate policies, the study recommends fostering coherent policies across all government levels, promoting equitable and inclusive climate solutions, raising public awareness, and supporting innovation in clean technologies. This comprehensive review provides valuable insights for policymakers and stakeholders to develop strategies that effectively address climate change, promote sustainability, and ensure a fair transition to a low-carbon future.

Role of energy value chain in carbon neutrality: A review

Value chain analysis is an important tool for optimizing operations and decision-making in enterprises. As the concept of sustainable development gains recognition worldwide, research on value chains is increasingly focused on sustainability. Traditionally, energy management and value management have operated in parallel with limited intersections. However, after the 2015 Paris Agreement set the goal of achieving net-zero emissions, carbon management has become integral to national strategies, necessitating a re-evaluation of traditional value chains. In this paper, the “energy value chain” is introduced, a novel concept that integrates energy consumption with value creation and carbon emissions, emphasizing the coupling relationships among “energy flow”, “value flow”, and “carbon flow.” From a review of current value chains in the power, steel, petroleum, and transportation industries, the specific energy value chain for each industry is defined and its rationale and effectiveness are discussed. This integrated analytical method provides a strategic tool for industries or enterprises to optimize energy consumption, reduce carbon emissions, and enhance competitive advantage.

Effect of hot coil immersion cooling process on microstructure and properties of strip steel and oxide scales

ABSTRACT Coils obtained at the end of hot rolling of four different low carbon steels (DX54D, HX180YD, DX51D and HCT590X) were subjected to immersion in water for cooling (IC) as against the normal natural cooling (NC). IC produces significant improvements in the microstructure, scale formation, distribution of mechanical properties and surface quality. A model developed to simulate thermal history in the hot coil being cooled indicates that the 0.1°C/min core cooling rate in NC increased by over 7 times in IC, thereby decreasing the temper softening effects. Results of the tests performed exhibit a greater uniformity in the longitudinal properties and a 30–50% reduction in the band spread. The volume fraction of carbide on the DX54D steel is reduced by 20–30%, and the yield platform length is increased from 2.6 to 3.4%. The IC process was observed to significantly inhibit the formation of the banded structure in the HCT590X steel and the average yield strength of the coil increased by ∼30 MPa. The thickness of the oxide scale in all the steels decreased by 30–40% and the FeO content in the scale increased by 10–20%.

A Newly Bio-Based Material for the Construction Industry Using Gypsum Binder and Rice Straw Waste (Oryza sativa)

Construction is one of the economic sectors with the greatest influence on climate change. In addition to working procedures, the primary carbon footprint is attributed to the choice of materials and the energy required for their manufacturing. The underlying idea of this study is to minimize the effects and offer new solutions to emerging problems in the quest for materials that can be deemed as natural, such as gypsum (calcium sulphate dihydrate) and rice straw (Oryza sativa). The acquisition of these materials involves a lower carbon footprint compared to the conventional materials. It is well known since ancient times that gypsum and cereal straw can be used in construction, with numerous examples still available. Cereal straw is one of the oldest construction materials, traditionally combined with earth and occasionally with certain binders, with it continuing to be employed in construction in many countries to this day. This work showcases the feasibility of producing stable prefabricated elements from straw waste with construction gypsum, addressing a significant environmental concern posed by the alternative of having to burn such materials. In this study, for the proposed bio-based material, specific tests, such as thermal conductivity, flexural and compressive strength, and fire resistance, were carried out to evaluate the principal physical and mechanical characteristics for different compositions of water, gypsum, and straw fiber samples. The results highlighted the good performance of the proposed materials in order to spread their use in the green building industry. The addition of straw fibers improved, in different ways, some important physical characteristics of these components so as to diminish environmental pollution and to obtain better material performance. The tests highlighted the different behaviors of the proposed material with respect to the different cuts of the straw and as well as the water/gypsum ratio; this is not very well understood and probably depends on the micro structure of the straw fibers. The blocks with raw straw showed a significant improvement in the breaking mechanism (1775.42 N) compared to the blocks with cut straw (712.26 N) when subjected to bending tests, and their performance in compression tests was also acceptable. Additionally, a very interesting reduction in thermal conductivity was achieved by incorporating rice straw (0.233 W/mK), and high fire exposure times were obtained, with gypsum preventing the spread of ignition in any type of fiber.

Cardiopulmonary exercise testing in long-term calcium channel blockers responders, does it normalize in the same way as pulmonary vascular resistance?

Abstract Background and aims Long-term calcium channel blockers (CCB) responders represent &amp;lt;10% of pulmonary arterial hypertension (PAH) patients and are known to have an excellent prognosis on high dose CCB. The few reports of lung histology of these patients suggest a predominant muscular thickening of the precapillary arterioles. Nevertheless, the classic intimal proliferation characteristic of PAH has also been reported, although to a lesser extent. Hence, we hypothesized that long-term CCB responders are likely to exhibit some degree of ventilatory inefficiency as a result of their impaired alveolo-capillary membrane. In this study, we aimed to evaluate the exercise performance of a contemporary cohort of long-term responders to CCB in terms of both exercise capacity and ventilatory efficiency, and whether there are differences depending on the haemodynamic severity. Methods We evaluated all long-term CCB responders with regular follow-up at our institution between 1996 to 2024 with at least one cardiopulmonary exercise test (CPET) and a right heart catheterization (RHC) within a three-year period, provided they had remained clinically stable without changes in pulmonary vasodilator treatment. Patients with additional PAH specific treatment were excluded. For data analysis purposes, the population was divided into 2 groups according to pulmonary vascular resistance (PVR). The cut-off point for PVR was set at ≥3. Results Twenty-four patients (91,6% female) with complete data were retrospectively enrolled. Baseline characteristics were as follows: median age 45.5 years (59-33) median mean pulmonary artery pressure of 26 mmHg (29-24) and median PVR of 3 WU (3-2.6). Regarding the whole cohort, peak oxygen consumption (pVO2) revealed mild impairment of functional capacity (mean pVO2: 1281 ± 245 ml/kg – 75 ± 15% of predicted). Ventilatory efficiency parameters were also mildy affected with low end-tidal carbon dioxide pressure at the anaerobic threshold (PETCO2@AT) (33.7±3.6mmHg), and increased minute ventilation (VE)/carbon dioxide output (VCO2) slope (33.5±4.5). The subgroup analysis depending on PVR showed no significant differences between groups in terms of pVO2 (1291.9 ±240 Vs. 1150 ±350 ml/kg, p:0.29 / 79%±16 vs 67%±12, p:0.8), VE/VCO2 slope (33 Vs. 34, p:0.21), or PETC02@AT (35 Vs. 33 mmHg, p:0.25). All CPET parameters by subgroups are displayed in Table 1. Conclusions Long-term CCB responders exhibit mildly reduced functional capacity. Moreover, they often fail to normalize the ventilatory efficiency parameters in most of the cases, even when PVR reaches close to normal values, suggesting persistent endothelial impairment.Results according to PVR

Improvement of N-type carbon nanotube field effect transistor performance using the combination of yttrium diffusion layer in HfO2 dielectrics and metal contacts.

In this paper, we obtained n-type top-gate carbon nanotube thin film field effect transistors (CNTFET) with source/drain extensions structure through dielectrics optimization strategy, combining the yttrium layer with HfO2 dielectric argon annealing process and metal contacts. The mechanism for enhanced n-type conduction was explained as being due to the vertical diffusion of yttrium to the HfO2 dielectric during argon annealing. This diffusion causes abending of the energy band, which results in more positive fixed charges and a reduction in the electron injection barrier between the low work function source-drain Cr electrode and carbon nanotube. The optimized technology has great prospects for the low cost, large scale and high performance n-type CNTFET to be used in integrated electronic devices.&#xD.

Taming CO2•- via Synergistic Triple Catalysis in Anti-Markovnikov Hydrocarboxylation of Alkenes.

The direct utilization of carbon dioxide as an ideal one-carbon source in value-added chemical synthesis has garnered significant attention from the standpoint of global sustainability. In this regard, the photo/electrochemical reduction of CO2 into useful fuels and chemical feedstocks could offer a great promise for the transition to a carbon-neutral economy. However, challenges in product selectivity continue to limit the practical application of these systems. A robust and general method for the conversion of CO2 to the polarity-reversed carbon dioxide radical anion, a C1 synthon, is critical for the successful valorization of CO2 to selective carboxylation reactions. We demonstrate herein a hydride and hydrogen atom transfer synergy driven general catalytic platform involving CO2•- for highly selective anti-Markovnikov hydrocarboxylation of alkenes via triple photoredox, hydride, and hydrogen atom transfer catalysis. Mechanistic studies suggest that the synergistic operation of the triple catalytic cycle ensures a low-steady-state concentration of CO2•- in the reaction medium. This method using a renewable light energy source is mild, robust, selective, and capable of accommodating a wide range of activated and unactivated alkenes. The highly selective nature of the transformation has been revealed through the synthesis of hydrocarboxylic acids from the substrates bearing a hydrogen atom available for intramolecular 1,n-HAT process as well as diastereoselective synthesis. This technology represents a general strategy for the merger of in situ formate generation with a synergistic photoredox and HAA catalytic cycle to provide CO2•- for selective chemical transformations.

Experimental Study on Enhancement in the Tribological Behaviour of Military Grade Lubricant Using Titanium Dioxide Nanoadditives for Aerospace Applications

ABSTRACTThe coefficient of friction of low carbon chromium alloy steel with military grade lubricant was high, resulting in increased heat generation and temperature rise of the lubricant in the aircraft power transmission units such as engine gearbox, accessory gearbox and so on. To address this, the current research proposes the addition of TiO2 nanoparticles to MIL grade lubricant as an additive to enhance the tribological performance. In this experimental study, TiO2 nanolubricant was prepared using various surfactants for better suspension of TiO2 nanoparticles, and properties were evaluated for both base lubricant and nanolubricant. The tribological experiments were conducted using a four ball tester, a shear stability tester and a reichert tester. In a four ball test, TiO2 nanolubricant resulted in a 27.3% reduction in wear scar diameter by the addition of TiO2 nanoparticles to the base lubricant. In a shear stability test, TiO2 nanolubricant showed 80% better shear stability than the base lubricant. In the reichert test, the coefficient of friction was reduced by 13% with the TiO2 nanolubricant. The experimental findings demonstrated that the TiO2 nanoparticles, as an additive to a military grade lubricant, have superior tribological properties for aerospace applications.

ASSESSING PROGRESS TOWARDS A CIRCULAR CARBON ECONOMY IN THE G20 COUNTRIES

As cornerstones of worldwide sustainable development, the circular economy and the circular carbon economy are profoundly interrelated. However, opinions differ on how to optimize the circular economy towards reducing carbon dioxide emissions. This article aims to investigate the different levels of readiness for the circular carbon economy within G20 member countries in the domain of economic efficiency. In that regard, a selection of circular carbon economy sub-indicators has been analysed. Through the use of secondary data, tendencies towards change in this variability were found. The degree of adoption of a circular carbon economy differs among the G20 economies. In terms of the various factors considered in the G20 member countries, the current analysis has determined that there continue to be substantial differences between the best performers and their enabling factors.

Distrust and reflexive impotence in the net zero transition: findings from a longitudinal deliberative mini-public

Responding to climate change requires that people engage in different forms of climate citizenship. These span from individual consumption choices, to taking part in forms of collective action to steer the behaviour of governments and in the private sector. Here we analyse data from the Net Zero Diaries project to explore how attitudes to different forms of climate citizenship develop as people become more aware about the scale of societal change required to reach net zero carbon emissions by 2050. The Net Zero Diaries project was a deliberative mini-public, composed of 41 citizens broadly representative of the UK adult population, which convened over five months between 2021 and 2022 to debate the UK policies for reaching net zero emissions by 2050. We show that people identify government as the prime actor needed to drive the transition, but doubt that they will act due to a range of constraints vis-à-vis the public and private sector. This tension provides a novel explanation for why some people prioritise forms of individual and consumption focused climate citizenship, whilst also doubting the efficacy of such actions. We conclude by suggesting that efforts to drive more engaged forms of climate citizenship need to attend to underlying feelings about state efficacy, rather than focus on just how the issue of climate change is framed.

Development of a deep learning-based object recognition system for pre-stage separation to improve the recycling rate of major general-purpose plastics

ABSTRACT The generation of plastic waste has been increasing annually, necessitating various recycling methods. Among these, material recycling with low carbon emissions should be prioritized. This study aims to enhance the material recycling rate by developing a separation system using deep learning-based object recognition. To improve labeling efficiency, image data were acquired for each material type, and the performance of different labeling methods was evaluated. The average precision (AP) values for the single-material learning model using hybrid labeling (manual + automatic) were 0.947 for PET, 0.951 for PP, 0.892 for PE, and 0.896 for PS, demonstrating superior performance compared to other methods. An integrated learning model was also developed for composite materials, achieving AP values of 0.972 for PET, 0.976 for PP, 0.963 for PE, and 0.961 for PS. These results demonstrate the model’s strong applicability for plastic waste recognition.

On‐Purpose Production of Light Olefins Through Oxidative Dehydrogenation: An Overview of Recent Developments

AbstractProducts made from light olefins play an important role in our daily lives. Traditional light olefins production based on steam cracking and fluid catalytic cracking suffer from high energy consumption and CO2 emissions. Thereby, the continually increasing demand for light olefins needs to be met through more environmentally sustainable procedures. On‐purpose production routes are preferred choice among petrochemicals manufacturers, being energy efficient and having lower carbon footprint. Among them, oxidative dehydrogenation (ODH) of light paraffins is a thermodynamically favourable exothermic process as compared to non‐oxidative routes. They can be operated at lower temperatures and have propensity of low coke deposition on catalyst, thereby resisting rapid catalyst deactivation. Herein, we have analysed various catalytic systems utilised in the oxidative dehydrogenation process. We have reviewed role of support, chemical composition of catalyst, presence of dopant, oxidation state of active metal, controlled surface modification by oxidative and reductive pretreatments, and reaction factors for each system. The performance of various catalytic systems for ODH of ethane, propane and butane in the presence of O2, CO2, N2O and special oxidants have been reviewed. A short critical overview on emerging on‐purpose routes for the production of renewable 1,3 butadiene has also been discussed.

Low-Carbon Rural Areas: How Are Polish Municipalities Financing the Green Future?

The main aim of the research was to assess Polish rural municipalities’ investment activity connected with the development of a low-carbon economy, supported with EU funds in the 2007–2013 and 2014–2020 financial frameworks. The empirical study was based on data from Poland’s Ministry of Development Funds and Regional Policy, Ministry of Finance, and Statistics Poland, analysed through basic descriptive statistics and a logistic model to identify key factors influencing investment activity. The study showed that the greatest number of agreements on funding were, in fact, signed by rural municipalities in the period under analysis. The predominant measures undertaken during this time were the promotion of renewable energy sources and the improvement in energy efficiency. In the earlier financial framework, low-carbon economy projects in rural areas were more often implemented by municipalities with developing demographic potential, including those characterised by a higher level of enterprise development. In the subsequent financial framework, human capital turned out to be of key importance for the investment activity of rural municipalities. Experience gained from 2007–2013 positively influenced fund absorption in 2014–2020, improving project value, number, and support. The study confirmed that rural municipalities play a vital role in advancing a low-carbon economy, as local actions are key to achieving sustainable development and reducing greenhouse gas emissions.