Low-calcium Pyroxene Research Articles

Lunar rock investigation and tri-aspect characterization of lunar farside regolith by a digital twin

Yutu-2 rover conducted an exciting expedition on the 41st lunar day to investigate a fin-shaped rock at Longji site (45.44°S, 177.56°E) by extending its locomotion margin on perilous peaks. The varied locomotion encountered, especially multi-form wheel slippage, during the journey to the target rock, established unique conditions for a fin-grained lunar regolith analysis regarding bearing, shear and lateral properties based on terramechanics. Here, we show a tri-aspect characterization of lunar regolith and infer the rock’s origin using a digital twin. We estimate internal friction angle within 21.5°−42.0° and associated cohesion of 520-3154 Pa in the Chang’E-4 operational site. These findings suggest shear characteristics similar to Apollo 12 mission samples but notably higher cohesion compared to regolith investigated on most nearside lunar missions. We estimate external friction angle in lateral properties to be within 8.3°−16.5°, which fills the gaps of the lateral property estimation of the lunar farside regolith and serves as a foundational parameter for subsequent engineering verifications. Our in-situ spectral investigations of the target rock unveil its composition of iron/magnesium-rich low-calcium pyroxene, linking it to the Zhinyu crater (45.34°S, 176.15°E) ejecta. Our results indicate that the combination of in-situ measurements with robotics technology in planetary exploration reveal the possibility of additional source regions contributing to the local materials at the Chang’E-4 site, implying a more complicated geological history in the vicinity.

Insight from the Noachian-aged fractured crust to the volcanic evolution of Mars: A case study from the Thaumasia graben and Claritas Fossae

Although most of the large volcanic landforms on Mars have been extensively studied, this is not the case for kilometer-sized landforms whose origin remains uncertain and which might provide important insights into the evolution of Martian volcanism. Previously, different populations of small-scale putative scoria cone volcanoes have been described in Tharsis, specifically in areas where the heavily fractured crust of the Noachian- and Hesperian-age escaped Amazonian resurfacing by younger lava flows. Therefore, we decided to explore a region of old fractured crust in Tharsis, Claritas Fossae, to search for signs of local-scale volcanic activity. Here, we present the results of a mapping campaign focused on the morphological and spectral properties of small-scale constructional mounds in the Noachian-age Claritas Fossae region that was affected by Hesperian- to early Amazonian-aged fracturing. By using data from Context Camera (CTX) and High Resolution Imaging Science Experiment (HiRISE), we mapped 39 mounds superimposed on the ancient crust and determined their morphological and morphometrical properties. The majority of the mounds are elongated (WNW- trending) with steep flanks and without associated flow units. The general appearance of studied edifices is consistent with a volcanic origin and their shapes suggest that they have been emplaced by effusion of viscous, volatile poor lavas incapable of significant flow. In addition, a spectral investigation utilizing the data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) reveal that some of the mounds showed evidence for high concentrations of low-calcium pyroxenes (LCP). Based on the relative stratigraphy, we demonstrate that volcanic activity is responsible for their formation and postdates the main N-S-trending fracturing of the Claritas Fossae, suggesting the formation of a volcanic field in the period spanning through the Late Hesperian and the Early Amazonian. However, morphological evidence such as well-preserved volcanic fissures and fresh-appearing slopes of some of the edifices might suggest even younger age. Among the mapped edifices, we found a well-preserved circular-shaped cone with a short-distance flow-like unit spreading from a caldera-like structure that challenges a scenario in which all the edifices are old. Such relatively young ages of volcanic activity combined with LCP-rich compositions might have critical implications for understanding the temporal evolution of magma compositions on Mars. Moreover, the observed shapes and spectral characteristics of the studied edifices appear to be quite different from other volcanic fields of similar geological settings observed so far on Mars. Therefore, we underline the importance of studying old and heavily fractured terrains that escaped later resurfacing by widespread younger lava flows, in order to search for evidence of small-scale volcanism and better understand local Martian magmatic systems.

Spectral unmixing analysis for the lunar surface mineralogy using Chandrayaan-2 IIRS imagery

Hyperspectral imagery (HSI) in the visible to near-infrared wavelength region has a high potential for deciphering mineral compositions of terrestrial and planetary surfaces. Thus, ISRO's Imaging Infrared Spectrometer (IIRS) sensor onboard Chandrayaan-2 (Ch-2) orbiter provides an opportunity to utilise the hyperspectral observations to characterise the lunar surface minerals and composition significantly. Hence, a sensitivity study of hyperspectral observations of the IIRS sensor was carried out for the detection and mapping of various lunar minerals using spectral unmixing analysis. A common region within the hyperspectral image obtained from Chandrayaan-1's (Ch-1) Moon Mineralogy Mapper (M3) sensor and Ch-2 IIRS sensor has been identified in the South-East of the Taurus-Littrow valley nearby Gardner crater for comparison and validation purposes. Ch-2 IIRS is an advanced hyperspectral imaging spectrometer capable of collecting spectra over a wider spectral range (800 ​nm ​− ​5000 ​nm) with high spatial (~80 m) and spectral resolution (20 n m ​− ​25 ​n m ). To examine spectral unmixing analysis, an electromagnetic range (800 ​nm ​− ​2500 ​nm) in the near-infrared region was chosen for the Ch-2 IIRS sensor. An L 1 ​− ​ norm based denoising algorithm is used for mixed noise removal from both the IIRS and M3 reflectance datasets. Endmember extraction and fractional abundance estimation are carried out using the N-Findr algorithm and the fully-constrained least square method, respectively. Our results reveal different minerals such as high-calcium pyroxene (Clinopyroxene), low-calcium pyroxene (Orthopyroxene), and regolith surface (matured and younger). The results obtained from the IIRS and M3 observations are in strong agreement. Hence, the hyperspectral observations made by the IIRS sensor are extremely effective for describing the mineral and chemical compositions of the lunar surface. • Spectral unmixing analysis is executed to determine lunar surface mineralogy and their abundance using Hyperspectral data. • For comparative analysis, co-located datasets from Chandrayaan-2 (Ch-2) IIRS and Chandrayaan-1(Ch-1) M3 are investigated. • An L1-norm-based denoising algorithm is introduced to significantly improve the data quality by removing the complex noise. • The methodology can be automated to develop the lunar mineralogical and chemical map in a time-efficient and systematic way.

Compositional Maps of the Lunar Polar Regions Derived from the Kaguya Spectral Profiler and the Lunar Orbiter Laser Altimeter Data

Abstract Due to the challenging illumination conditions of the lunar polar regions, mineralogic maps have generally been constrained to within 0°–70°N/S. Here we generate a gridded reflectance data cube from the Kaguya Spectral Profiler measurements for each polar region and calibrate it to absolute reflectance using data from the Lunar Orbiter Laser Altimeter. We use this data set to derive the first quantitative mineral maps of iron oxide (FeO), the optical maturity parameter (OMAT), and nanophase iron poleward of 50°N/S at a spatial resolution of 1 km pixel–1. We evaluate potential latitudinal trends in space weathering and optical maturity and characterize the polar geology, with an emphasis on the Artemis region (84°–90°S). The maps of FeO are in excellent agreement with the abundances measured by the Lunar Prospector and provide an increased level of detail, such as the excavation of high- and low-FeO material by De Forest crater. The OMAT maps offer a fantastic view of both polar regions. They highlight small fresh craters, walls, and central peaks, as well as rays extending through multiple degrees of latitude, such as those from Tycho and De Forest, which extend into the Artemis region. Both polar regions are characterized by the ubiquitous presence of noritic anorthosites and anorthositic norite. Low-calcium pyroxene is largely the dominant mafic mineral present. The Artemis region has relatively homogeneous FeO and plagioclase content at the observed spatial resolution. The lowest FeO values are found near Shackleton, between Shoemaker and Faustini, and on the central peak of Amundsen crater.

Occurrence of secondary minerals at Tharsis Montes of Mars: A critical assessment

Identification of phyllosilicates on Mars suggests the existence of an aqueous environment, indicating an active period in its evolutionary history. This study analysed the surface mineralogy of caldera and flank regions of Tharsis Montes using remote spectral analysis. Though a thick layer of dust obscures the surface of Tharsis volcanic province, relatively lesser dust regions provide a unique window for exploration. The reflectance data obtained from CRISM onboard Mars Reconnaissance Orbiter in the visible-infrared region is used for the mineralogical study. Spectral parameter indices were used to identify the distribution of minerals over the caldera and flank regions of Tharsis Montes. The spectral characterisation indicates the well-distributed presence of mafic minerals such as olivine with low-calcium pyroxene and plagioclase with the sparse presence of high-calcium pyroxene in the region. The dusty region, typically with a high TES DCI index and low thermal inertia values in the Tharsis Montes, shows a high concentration of olivine. Few regions identified as comparatively dust-free at the caldera and flank show the presence of secondary mafic minerals like FeMg bearing phyllosilicates. Our spectral analysis using nonlinear mixing models with the MICA spectral library indicates the occurrence of absorption features characteristic of hydrated minerals. The occurrence of the secondary mafic minerals, especially the phyllosilicates on Tharsis Montes suggest active weathering or hydrothermal alteration from episodic volcanic activity over time.

Compositional and morphological analysis of Gassendi crater

Gassendi impact crater is located on the western side of the visible lunar hemisphere just north of Mare Humorum. It has a diameter of 110 km, and it is a Floor Fractured Crater (FFC) belonging to Class-3 type that exhibits a wide annular depression or moat. Is Gassendi crater formed due to igneous intrusion or viscous relaxation? To investigate this, the analysis explores the compositional and morphological dimensions of the crater. The area studied has been found to contain various minerals such as LCP (Low Calcium Pyroxene), HCP (High Calcium Pyroxene), olivine, plagioclase, and mixtures of pyroxene and plagioclase. To differentiate between similar spectral profiles, Integrated Band Depth map (IBD) and Band Depth Parameter (BD) maps are generated using the M3 data. Features such as central peak complex, isolated mound, fractures, rimae, wall terraces, wall slumps, etc., have been identified and marked in the morphological map. We have also studied the morphometrical aspects of all the morphological features. Another impact crater just on the northern rim of Gassendi, Gassendi A crater shows the presence of LCP and olivine mineral along with extensive slumping, melt pool, and distorted northern rim. We have mapped the three mare regions towards the south of the crater floor and estimated their ages by using the CSFD technique. The present appearance of the Gassendi crater is mostly due to past volcanic activities rather than the result of the impact event.

Evidence for fluvial and glacial activities within impact craters that excavated into a Noachian volcanic dome on Mars

Impact craters on Mars preserve diverse records of volcanic, fluvial, and glacial activities. Enigmatically, the preservation of these major activities or records altogether within impact craters is rare. We report one such new observation of impact craters that formed on a volcanic dome studied using data from the Mars Reconnaissance Orbiter's (MRO) Context Camera (CTX), High-Resolution Imaging Science Experiment (HiRISE), and Compact Reconnaissance Imaging Spectrometer for Mars (CRISM), Mars Global Surveyor's Mars Orbiter Laser Altimeter (MOLA), and Mars Express' High-Resolution Stereo Camera (HRSC). A ~ 20 km diameter impact crater, informally named as Degana-A, is formed within the ~50 km diameter impact crater Degana. Mineralogical analysis reveals exposures of low-calcium pyroxene and olivine deposits, which occupy Degana-A's eastern walls, leading to the idea that pristine Noachian bedrocks might be exposed from beneath the volcanic dome. Degana-A floor is completely covered by alluvial fans from all sides with distributaries. Within Degana crater, multiple fans are observed along its eastern to southern side only. The most likely source of water was the accumulation of snow on Degana crater walls, which possibly melted as a result of the impact of Degana-A. We observed a ~ 1 km wide breach on the eastern wall of Degana-A and the estimated maximum flow velocity is ~2 m/s and a run-off ~2.25 mm/h. Over the south-facing walls, multiple moraine-like ridges superposed the fans, which suggests overprinting by glacial activities. The presence of fans and superposed moraine-like ridges located at the mid-latitudes (~23°S) implies atmosphere-derived snow/ice precipitation was possible. Chronologically, the dome is of Noachian age, whereas Degana crater formed in the Hesperian period and crater retention on the fans indicates late Hesperian to Amazonian ages. Overall, the preserved Noachian crustal material underneath a volcanic dome is rarely exposed in its pristine context, which offers a rare window into early igneous processes. This intriguing location also witnessed a climatic transition as implied by water/ice derived landforms formed by non-coeval events.

Impactite dykes in impact crater central uplifts: Insights from Negril crater, Mars

Negril crater is a 52 km complex crater located north of Syrtis Major, Mars. The central uplift of Negril crater is remarkably well-exposed and contains one of the best examples of dykes associated with a Martian crater. This study aims to characterize the dykes within the central uplift and determine if they are impactite dykes that formed as a part of the impact process or whether they are pre-existing mineral veins or volcanic dykes that were uplifted. This study also attempts to put the geology of the uplift into the proper stratigraphic context of the regional geology in the vicinity of Jezero crater. The uplift consists of two major geomorphologic units: the uplifted fractured and brecciated massive bedrock crosscut by linear ridges and dykes, and a dark-toned clast-rich to clast-poor unit that coats the central uplift and crater floor, interpreted as impact melt rock. The uplift is quite diverse with respect to its morphology and spectral characteristics, exhibiting bedrock with spectral signatures consistent with a low-calcium pyroxene, Fe/Mg-bearing phyllosilicates and a few occurrences of a plagioclase feldspar, dykes with an olivine-bearing signature, and additional Fe/Mg-bearing phyllosilicates associated with pervasive light-toned ridges and mounds. The ridges crosscut the impact melt rock and are consistent with impact-generated hydrothermal alteration. Two varieties of dykes occurring within the uplift that have a complex cross-cutting relationship, indicating they formed syngenetically with respect to each other. The morphology, orientation and composition of the dykes suggest they may represent impact melt dykes rather than pre-existing dykes that were uplifted. This interpretation is also based on comparisons made with terrestrial observations. Finally, the uplifted fractured bedrock is potentially related to the extensive Fe/Mg phyllosilicate-bearing basement units in the Nili Fossae region that may be related to the formation and evolution of the Isidis Basin.

Diverse rock types detected in the lunar South Pole–Aitken Basin by the Chang’E-4 lunar mission

Abstract The South Pole–Aitken (SPA) basin, located between the South Pole and Aitken crater on the far side of the Moon, is the largest confirmed lunar impact structure. The pre-Nectarian SPA basin is a 2400 × 2050 km elliptical structure centered at 53°S, 191°E, which should have exposed lower crust and upper mantle due to the enormous excavation depth. Olivine, the dominant mineral in Earth’s mantle, has only been identified in small and localized exposures in the margins of the SPA basin, and the dominant mafic component is, instead, pyroxene. These mineralogical characteristics could be explained by the recent hypothesis that the lunar upper mantle is dominated by low-calcium pyroxene, not olivine. Here, we present observations from imaging and spectral data from China’s Chang’E-4 (CE-4) lunar mission in the first 4 synodic days, especially the first in situ visible/near-infrared spectrometer observations of an exposed boulder. We identified a variety of rock types, but not the recently reported olivine-rich materials in the landing region. The results are consistent with orbital observations. The obtained mineralogical information provides a better understanding of the nature and origin of SPA materials.

Overview of the Latest Scientific Results of China's Lunar Exploration Program

China's Chang'E-4 probe successfully landed on 3 January 2019 in Von Kármán crater within the South Pole-Aitken (SPA) basin on the lunar far side. Based on the data acquired by the scientific payloads onboard the lander and the rover, the researchers obtained the related information such as the geologic and tectonic setting of the landing area, compositional characteristics of the landing surface materials, dielectric permittivity and density of the lunar soil. The experiments confirmed the existence of materials dominated by olivine and low-calcium pyroxene in the SPA basin on the lunar far side, which preliminary revealed the geological evolution history of the SPA basin and even that of the early time lunar crust, as well as the tectonic setting and formation mechanism of the materials in the lunar interior. The researchers also inves-tigated the particle radiation, Linear Energy Transaction (LET) spectrum, and so forth on the lunar surface. The low-frequency radio observations were carried out on the lunar far side for the first time as well. This article summarizes the latest scientific results in the past years, focusing on the Chang'E-4 mission. Key words CLEP, Chang'E-4, Scientific objectives, Scientific payloads, Scientific results

Aqueous alteration of pyroxene in sulfate, chloride, and perchlorate brines: Implications for post-Noachian aqueous alteration on Mars

Abstract Both high and low calcium pyroxene minerals have been detected over large portions of the martian surface in addition to widespread salts in martian soils and dust. Calcium pyroxenes in martian meteorites are associated with secondary evaporite phases, including sulfates, chlorides, and perchlorates, suggesting the pyroxene may have been altered in saline solutions. Therefore, understanding pyroxene mineral weathering in high salinity brines may provide insight into past aqueous alteration on Mars. This study examines both solute-based dissolution rates and qualitative assessments of weathering textures developed during pyroxene-brine alteration experiments to link dissolution rates and textures and aid in interpreting weathering features observed in Mars meteorites and future pyroxene samples returned from Mars. Batch reactor dissolution experiments were conducted at 298 K to compare diopside (a high Ca-pyroxene) dissolution rates in water (18 MΩ cm−1 ultrapure water (UPW); activity of water (ɑH2O) = 1.0), 0.35 mol kg−1 NaCl (ɑH2O = 0.99), 0.35 mol kg−1 Na2SO4 (ɑH2O = 0.98), 2 mol kg−1 NaClO4 (ɑH2O = 0.90), 2.5 mol kg−1 Na2SO4 (ɑH2O = 0.95), 5.7 mol kg−1 NaCl (ɑH2O = 0.75), and 9 mol kg−1 CaCl2 (ɑH2O = 0.35) brines at pH 5–6.6 to determine how changing solution chemistry and activity of water influence pyroxene dissolution. Aqueous Si release rates and qualitative textural analyses indicate diopside dissolution rates are influenced by both solution chemistry and activity of water, with diopside weathering increasing along a trend from: 9 mol kg−1 CaCl2

Chang'E-4 initial spectroscopic identification of lunar far-side mantle-derived materials.

Over 60 years of spacecraft exploration has revealed that the Earth's Moon is characterized by a lunar crust1 dominated by the mineral plagioclase, overlying a more mafic (richer in iron and magnesium) mantle of uncertain composition. Both crust and mantle formed during the earliest stages of lunar evolution when late-stage accretional energy caused a molten rock (magma) ocean, flotation of the light plagioclase, sinking of the denser iron-rich minerals, such as olivine and pyroxene, and eventually solidification2. Very large impact craters can potentially penetrate through the crust and sample the lunar mantle. The largest of these craters is the approximately 2,500-kilometre-diameter South Pole-Aitken (SPA) basin3 on the lunar far side. Evidence obtained from orbiting spacecraft shows that the floor of the SPA basin is rich in mafic minerals4, but their mantle origin is controversial and their in situ geologic settings are poorly known. China's Chang'E-4 lunar far-side lander recently touched down in the Von Kármán crater5,6 to explore the floor of the huge SPA basin and deployed its rover, Yutu-2. Here we report on the initial spectral observations of the Visible and Near Infrared Spectrometer (VNIS)7 onboard Yutu-2, which we interpret to represent the presence of low-calcium (ortho)pyroxene and olivine, materials that may originate from the lunar mantle. Geological context6 suggests that these materials were excavated from below the SPA floor by the nearby 72-km-diameter Finsen impact crater event, and transported to the landing site. Continued exploration by Yutu-2 will target these materials on the floor of the Von Kármán crater to understand their geologic context, origin and abundance, and to assess the possibility of sample-return scenarios.

Assessing martian bedrock mineralogy through “windows” in the dust using near-infrared and thermal infrared remote sensing

Much of Mars' surface is mantled by bright dust, which masks the spectral features used to interpret the mineralogy of the underlying bedrock. Despite the wealth of near-infrared (NIR) and thermal infrared (TIR) data returned from orbiting spacecraft in recent decades, the detailed bedrock composition of approximately half of the Martian surface remains relatively unknown due to dust cover. To address this issue, and to help gain a better understanding of the bedrock mineralogy in dusty regions, Dust Cover Index results from the Mars Global Surveyor Thermal Emission Spectrometer (TES) and analysis of images from the Mars Reconnaissance Orbiter Mars Color Imager (MARCI) were used to identify 63 small localized areas within the classical bright dusty regions of Arabia Terra, Elysium Planitia, and Tharsis Montes as potential “windows” through the dust; that is, areas where the dust cover is thin enough to permit infrared remote sensing of the underlying materials. The mineralogy of each candidate window was inferred using spectra from the Mars Express Observatoire pour la Mineralogie, l'Eau, les Glaces et l'Activité (OMEGA) NIR spectrometer and, where possible, TES. Twelve areas of interest returned spectra that are consistent with mineral species expected to be present at the regional scale, such as high- and low-calcium pyroxene, olivine, and iron-bearing glass. Distribution maps were created using previously defined index parameters for each species present within an area. High-quality TES spectra, if present within an area of interest, were deconvolved to estimate modal mineralogy and to support NIR interpretations. OMEGA data from Arabia Terra and Elysium Planitia are largely similar and indicate the presence of high-calcium pyroxene with significant contributions of glass and olivine, while TES data suggest an intermediate between the established compositions of the southern highlands and Syrtis Major. Limited data from Tharsis are consistent with low-calcium pyroxene mixed with lesser amounts of glass and high-calcium pyroxene. TES data from southern Tharsis correlate well with the previously inferred compositions of the Aonium and Mare Sirenum highlands immediately to the south. Of particular note is the detection of iron-bearing glass as a significant component of all three analyzed regions, especially in Tharsis. Overall, the underlying compositions of the classically dust-covered regions of Mars appear consistent with the compositions of adjacent and other low-albedo (not dust covered) regions of the planet identified in previous studies, with the noted contribution from iron-bearing glass.

Global classification of lunar reflectance spectra obtained by Kaguya (SELENE): Implication for hidden basaltic materials

A global classification map of lunar absorption spectra is developed under unified classification criteria by applying the K-means and ISODATA unsupervised classification methods. The spectra were obtained by the Spectral Profiler (SP) onboard the Kaguya (SELENE) lunar orbiter spacecraft. The spectra are mostly categorized into seven spectral groups by the K-means method: K1, K2, K3, K4, K5, K6, and K7. Then, each K-means group is divided into 66 total classes by the ISODATA method. The K1 and K3 groups are classified into 21 and 14 classes, respectively, for which the average spectra are high-calcium pyroxene (HCP)-abundant compared to the other groups. Both groups are mainly located on maria and pyroclastic deposits. However, while the K1 group can be found primarily near the center of large maria, the K3 group can be found mainly at small maria and the margins of large maria. The K2 group contains eight classes and shows average spectra, such as low-calcium pyroxene (LCP), in abundance, which are found mainly on the South Pole-Aitken (SPA) basin and on the coast of Mare Frigoris. The K5 (eight classes), K6 (two classes) and K7 (three classes) groups indicate average spectra with shallower absorption (between 0.9 µm and 1.2 µm wavelength) than those of the K1, K2, and K3 groups. These groups are located in highland regions, and the K5 group is located in high-albedo regions, such as fresh craters. The K6 group is found on nearside highland areas and the K7 group is found on farside highland areas. The K4 group with nine classes shows average spectra, such as mixtures of K1/K2/K3 and K5/K6/K7, and these classes are located around boundaries between mare/SPA and highland. In addition, one class is independently defined without using K-means and ISODATA because its spectra are unsuitable for automatic unsupervised classification. However, this class is still geologically meaningful.The average spectra of the ISODATA classes show not only the characteristics of the major host material belonging to a spectral group, but they also show the small influence of materials from other groups in nearby regions on that host material. This influence is considered to be caused by horizontal material mixing of materials in that location with the ejecta from nearby regions. However, occasionally the ISODATA classes of the K4, K5, and K6 groups influenced by the K1/K3 groups are clustered geographically in regions far from the K1/K3 regions. Some locations of the clusters correspond to locations of the well-known cryptomaria and small pyroclastic deposits. On the other hand, some locations of them also contain candidates of hidden subterranean basaltic materials, such as undiscovered cryptomare, dike, and sill estimated based on recent lunar gravitational anomalies. This agreement suggests to be appeared hidden basaltic materials by the material mixing occurring vertically. The total area of the clusters except for known cryptomaria is approximately two times larger than that of the known cryptomaria, and this area reaches approximately 20% of the total area of exposed maria. The total volume of hidden basaltic materials, except for the known cryptomaria, is estimated to be 104 to 106 km3, depending on assumptions of the relative abundance between cryptomare and dike/sill. This volume is comparable to that of the known cryptomaria and approximately 10% of that of the exposed mare.

The compositions of the lunar crust and upper mantle: Spectral analysis of the inner rings of lunar impact basins

The innermost ring in impact basins exposes material originating from various depths, and can be used to study the composition of the lunar crust with depth. In this study, we conduct quantitative mineralogical analyses of the innermost ring in 13 lunar impact basins using reflectance data from the Kaguya Multiband Imager and radiative transfer modeling. We use results from recent hydrocode modeling to calculate the depth of origin of the material exposed by the innermost rings. We find that the most abundant rock type on the innermost ring of most basins is anorthosite. The mafic assemblages are dominated by olivine in some cases, but most often by pyroxene. The impact modeling suggests that the innermost ring material was excavated from a wide range of depths. Here we focus on two mean depths: a crustal component and a mantle component. The crustal component largely dominates the innermost ring material, and the mantle component is present on the innermost ring of 9 of the basins we studied. On these 9 rings, the abundance of low-calcium pyroxene decreases with the proportion of crustal component, suggesting a dominantly mantle origin. However, as we do not detect exposures of ultramafic material, such mantle material is possibly present at the sub-pixel scale (<62 m). This quantitative study reassesses the composition of the lunar crust and upper mantle, which is of great importance for understanding the formation of the Moon.

The central uplift of Elorza Crater: Insights into its geology and possible relationships to the Valles Marineris and Tharsis regions

The majority of hydrated silicate occurrences on Mars are associated with impact craters (Ehlmann et al., 2011; Carter et al., 2013). Three formation mechanisms have been suggested to account for this correlation: (1) aqueous alteration occurred pre-impact, and was subsequently exposed via the impact (pre-impact; Bibring et al., 2006; Ehlmann et al., 2011), (2) heat generated from the impact facilitated the formation of a hydrothermal system, leading to alteration products (syn-impact; e.g. Marzo et al., 2010; Osinski et al., 2013), and/or (3) altered materials were deposited after crater formation, or formed within the crater well after the impact had taken place (post-impact). In this study, we analyze the central uplift of Elorza Crater, a ∼40km diameter impact crater located ∼300km north of Valles Marineris. To determine whether hydrated minerals found within the uplift were generated pre-, syn-, or post-impact, we used a data synthesis approach, utilizing High Resolution Imaging Science Experiment (HiRISE), Compact Reconnaissance Imaging Spectrometer for Mars (CRISM), Context Camera (CTX), and Thermal Emission Imaging System (THEMIS) imagery. Opaline silica is observed in two locations on the southwestern side of the uplift and is interpreted to have been pre-existing or formed via hydrothermal alteration due to stratigraphic relationships with the overlying impact melt unit. Both Fe/Mg smectite and low-calcium pyroxene (LCP) are found throughout the uplift. Bedrock exposures on the northern wall of Coprates Chasma containing Fe/Mg smectite and LCP suggest an uplifted origin for these units. In all cases, although a pre-existing origin is probable, it is difficult to rule out the possibility of an impact-generated hydrothermal origin. Using the observed stratigraphy exposed in Coprates Chasma and bedrock exposures analyzed in nearby craters, we were able to constrain the pre-impact stratigraphy around Elorza. The near-subsurface consists of Hesperian-aged, discontinuous lava/ash deposits that may be interposed with opaline silica-bearing deposits, overlying Noachian basement consisting of smectite-bearing bedrock and LCP- bearing light-toned fractured bedrock.

The role of particle size in the laboratory reflectance spectra of pyroxenes: The case of the 670-nm minor feature

Reflectance spectroscopy is a very helpful tool for remote sensing investigations and has been widely used in terrestrial as well as planetary observations to study the surface composition. From this perspective, the visible (Vis) and near-infrared (NIR) regions of the spectrum, where several diagnostic absorption features of minerals are located, are well suited for the identification of such materials, in particular of rock-forming silicates. Among them, pyroxenes, which have been discovered on the surface of a number of different solar system bodies, play an important role.Up to now, both laboratory and remote sensing spectroscopic studies have been focused mainly on the two major bands at about 1 and 2µm (the so-called Band I and Band II, respectively), while little attention has been paid to the minor bands falling in the visible range. One of the most important of them, present in many pyroxenes as well as in olivines, is the weak feature (reflectance minimum) near 670nm, generally characterized by its variable wings (reflectance maxima) at about 570nm and 720nm. The intensity and the exact position of this feature depend on the type of pyroxene as well as on the grain size of the particles under consideration.In this work we present the Vis/NIR experimental reflectance spectra concerning enstatite and diopside, which are excellent representative of Low Calcium Pyroxenes (typically orthopyroxenes), and High Calcium Pyroxenes (typically clinopyroxenes) respectively. The results are very interesting and show a good correlation between the grain size of our samples and the relative intensities of the reflectance maxima occurring on both sides of the 670nm feature. A similar study performed on Acfer 353, a pyroxene-rich eucritic meteorite of the Howardite–Eucrite–Diogenite family, of putative Vestan origin, shows that also in this case the variability in the Vis region of the spectra is linked to the grain size of the meteoritic particles. The connection between grain size and the behavior of the 670nm feature can potentially be used to derive the average dimension of the regolith existing on the surface of planets and minor bodies.Both laboratory and observational study of the minor features, frequently ignored in the interpretation of the spectra acquired in remote sensing, can give complementary and useful information and thus can definitely contribute to a better knowledge of the mineralogy of planetary and asteroidal surfaces.

The central uplift of Ritchey crater, Mars

Ritchey crater is a ∼79km diameter complex crater near the boundary between Hesperian ridged plains and Noachian highland terrain on Mars (28.8°S, 309.0°E) that formed after the Noachian. High Resolution Imaging Science Experiment (HiRISE) images of the central peak reveal fractured massive bedrock and megabreccia with large clasts. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) spectral analysis reveals low calcium pyroxene (LCP), olivine (OL), hydrated silicates (phyllosilicates) and a possible identification of plagioclase bedrock. We mapped the Ritchey crater central uplift into ten units, with 4 main groups from oldest and originally deepest to youngest: (1) megabreccia with large clasts rich in LCP and OL, and with alteration to phyllosilicates; (2) massive bedrock with bright and dark regions rich in LCP or OL, respectively; (3) LCP and OL-rich impactites draped over the central uplift; and (4) aeolian deposits. We interpret the primitive martian crust as igneous rocks rich in LCP, OL, and probably plagioclase, as previously observed in eastern Valles Marineris. We do not observe high-calcium pyroxene (HCP) rich bedrock as seen in Argyre or western Valles Marineris. The association of phyllosilicates with deep megabreccia could be from impact-induced alteration, either as a result of the Richey impact, or alteration of pre-existing impactites from Argyre basin and other large impacts that preceded the Ritchey impact, or both.

Modal mineralogy of the surface of Vesta: Evidence for ubiquitous olivine and identification of meteorite analogue

The observations of the surface of 4 Vesta by the Visible and Infrared Mapping Spectrometer (VIR) onboard the Dawn spacecraft reveals that its composition is dominated by pyroxenes with olivine in very localized spots. To derive new constraints on the surface composition of the asteroid, we apply a scattering model to VIR reflectance spectra. The model is first calibrated by performing a non-linear deconvolution of laboratory spectra of mineral mixtures and howardite, eucrite, diogenite (HED) meteorites. Abundance estimates of minerals are accurate to within 15–25% for the analyzed samples, while the estimated particle sizes are within the intervals of actual sizes. Grain size effects complicate spectral deconvolution and estimation of modal abundances of samples (both HED and mineral mixtures) that contain olivine. The magnesium-rich olivine detection threshold is 10–20% for large grain sizes (100sμm) and several 10s% for small grain sizes (<50μm). Major expected minerals (low-calcium pyroxenes, high-calcium pyroxenes, plagioclase and olivine) can provide satisfactory fits of VIR spectra with excellent residuals ⩽1%. Terrains with the strongest low-calcium pyroxene signatures are well representative of diogenites. The best fits of any unit are obtained by including Fo70 olivine at an abundance level of 10–20%, with an uncertainty of ∼10%. Olivine is therefore likely to be ubiquitous over the whole surface of Vesta. Olivine is coarser grained (a few hundred μm) than other minerals such as orthopyroxene and clinopyroxene (grain sizes typically smaller than 100μm). Both the grain size variance and the modal mineralogy are consistent with the lithologic size and mineral distributions of howardites containing olivine phenocryst-bearing melt. These howardites are the best petrologic analogues of Vesta. Such a surface assemblage could be the result of successive melting and mixing processes due to impacts. The compositional view confirms that Vesta underwent major homogenization processes, resulting in a relatively uniform modal mineralogy and explaining the lack of specific olivine enrichment in the Rheasilvia ejecta.

Valles Marineris dune fields as compared with other martian populations: Diversity of dune compositions, morphologies, and thermophysical properties

Planetary dune field properties and their bulk bedform morphologies relate to regional wind patterns, sediment supply, climate, and topography. On Mars, major occurrences of spatially contiguous low-albedo sand dunes are primarily found in three major topographic settings: impact craters, high-latitude basins, and linear troughs or valleys, the largest being the Valles Marineris (VM) rift system. As one of the primary present day martian sediment sinks, VM holds nearly a third of the non-polar dune area on Mars. Moreover, VM differs from other regions due to its unusual geologic, topographic, and atmospheric setting. Herein, we test the overarching hypothesis that VM dune fields are compositionally, morphologically, and thermophysically distinct from other low- and mid-latitude (50°N–50°S latitude) dune fields. Topographic measurements of dune fields and their underlying terrains indicate slopes, roughnesses, and reliefs to be notably greater for those in VM. Variable VM dune morphologies are shown with topographically-related duneforms (climbing, falling, and echo dunes) located among spur-and-gully wall, landslide, and chaotic terrains, contrasting most martian dunes found in more topographically benign locations (e.g., craters, basins). VM dune fields superposed on Late Amazonian landslides are constrained to have formed and/or migrated over >10s of kilometers in the last 50My to 1Gy. Diversity of detected dune sand compositions, including unaltered ultramafic minerals and glasses (e.g., high and low-calcium pyroxene, olivine, Fe-bearing glass), and alteration products (hydrated sulfates, weathered Fe-bearing glass), is more pronounced in VM. Observations show heterogeneous sand compositions exist at the regional-, basinal-, dune field-, and dune-scales. Although not substantially greater than elsewhere, unambiguous evidence for recent dune activity in VM is indicated from pairs of high-resolution images that include: dune deflation, dune migration, slip face modification (e.g., alcoves), and ripple modification or migration, at varying scales (10s–100sm2). We conclude that VM dune fields are qualitatively and quantitatively distinct from other low- and mid-latitude dune fields, most readily attributable to the rift’s unusual setting. Moreover, results imply dune field properties and aeolian processes on Mars can be largely influenced by regional environment, which may have their own distinctive set of boundary conditions, rather than a globally homogenous collection of aeolian sediment and bedforms.