Reflection Loss Research Articles

Electromagnetic Absorption Mechanism of TPMS‐Based Metastructures: Synergy Between Materials and Structures

Abstract3D metastructure absorbers have gained attention for their lightweight, load‐bearing capabilities, and superior electromagnetic wave absorption. However, the complex interplay between unit cell geometry, material properties, and electromagnetic response is not well understood, hindering the design of high‐performance devices. A multi‐scale model, validated is presented by simulations and experiments, that clarify the relationship between materials, structures, and electromagnetic behavior in 3D metastructures. By systematically investigating strut‐based and sheet‐based structures, volume fraction, unit size, crystal lattice orientation, and density gradient within TPMS‐based unit cells, it is revealed that unit geometry significantly influences electromagnetic field propagation and reflection loss. Specifically, under the same unit size, sheet‐based TPMS metastructures exhibit stronger reflectivity than strut‐based ones, while multilayer structures show the opposite trend. The direct correlation is also further confirmed between geometric symmetry and polarization insensitivity, with orthogonal isotropic superstructures displaying excellent polarization‐insensitive properties. This finding provides a new design principle for achieving robust, angle‐independent absorption in these materials. This work enhances understanding of the structure‐electromagnetic behavior interplay, guiding the design of next‐generation broadband, wide‐angle, and polarization‐insensitive devices.

Initial Performance Outlook on the Sliding Particle Receiver (SlideRec)

The next generation of central receivers is expected to reach high outlet temperatures of 800 °C and above, maintain stable operation and react to a varying incoming flux magnitude caused by hourly and seasonal variations, endure high-temperature operation, and remain cost-effective. Particle-based central receivers are being considered due to their high-temperature durability and favorable thermal properties of particle materials such as bauxite particles. This paper describes a new particle-based central receiver concept and provides an initial exploration of its performance in comparison with the existing CentRec® technology. Discrete Element Method (DEM) simulations demonstrated that a stable falling and sliding particle film can be achieved inside the SlideRec. The residence time of particle flow within the SlideRec is estimated to be higher than a falling particle receiver and similar to that of an obstructed-flow receiver. The results of the thermal model (incorporating reflective, radiative, convective and conductive heat losses) indicate that the SlideRec demonstrates a higher thermal efficiency than the CentRec® under an incoming aperture flux of between 0.1 MW/m2 and 1.7 MW/m2. The concept therefore is promising and is recommended for further experimental exploration.

Plasma-Driven Conversion of 2D Graphene into 3D Pouch for Improved Electromagnetic Absorption Performance.

Graphene-based materials are ideal for electromagnetic wave-absorbing materials (EAMs) due to their strong electrical and dielectric losses with reduced thickness and weight. To enhance the electromagnetic wave absorption performance of these materials, additional components are often incorporated. However, this approach not only increases the complexity of the synthesis process but also complicates and destabilizes the control of the material properties. In this study, we successfully employed a one-step method to reduce graphene oxide and transform 2D graphene into a 3D pocket-like structure through plasma treatment. This unique 3D structure is induced by the formation of uneven defects on the surface due to plasma treatment. The distinctive pouch-like structure of the reduced graphene oxide achieved remarkable electromagnetic wave absorption properties. Specifically, the material demonstrated a minimum reflection loss of -38.65 dB at 7.14 GHz, with an effective absorption bandwidth of 5.13 GHz and a thickness of just 1.9 mm. These results highlight the potential of plasma processing as a rapid, efficient, and environmentally friendly approach for the continuous production of advanced EAMs, paving the way for greener manufacturing practices in the industry.

Bioinspired Antireflective and Antifogging Surface for Highly Efficient and Stable Inverted Solar Cells.

Photovoltaic devices are essentially solar energy collectors that convert incident photons into charge carriers. However, light reflection losses and external factors (e.g., fog) can lead to an inefficient utilization of incident photons. Therefore, the development of antifogging surface materials that can efficiently reduce reflection is a critical issue in the upgradation of photovoltaic devices. Herein, inspired by the wing scale structures of butterfly Trogonoptera brookiana, an antireflective and antifogging surface (BRFS) was prepared by a method combining biotemplate and sol-gel. Remarkably, the BRFS possesses a relatively large surface roughness and exhibits superhydrophilic property (static water contact angle of 0°), which can quickly split fog droplet film within 6.6 s to realize the antifogging effect. In addition, the final transmittance of BRFS is as high as 90.25%. Furthermore, as an application demonstration, BRFS was applied to the surface of the reverse organic solar cells. Without compromising the inherent performance of the panels, the BRFS enhances the electrical performance of the inverted solar panels by 18%. This work provides a simple and effective strategy for designing surfaces with superior antifogging and antireflective properties and offers significant potential value for the practical application of photoelectric devices.

MICROWAVE REFLECTOMETRY CIRCUITS INTEGRATION WITH COAXIAL PROBE FOR INITIAL BREAST TUMOR DETECTION

A six-port reflectometry (SPR) system was developed to predict the dielectric properties of both tumor and normal breast tissue, intended for medical diagnostic applications. Ensuring precise measurements, the SPR underwent calibration using a well-established four-step procedure, which will be briefly outlined. Afterward, the investigated coaxial probe was connected to the SPR through the calibrated measurement port. Subsequently, the exposed end of the probe aperture was immersed into synthetic samples representing both healthy and cancerous breast tissue to assess the dielectric constant, εrʹ and loss factor, εrʺ across frequencies ranging from 1.5 GHz to 3.3 GHz. The dielectric constant, εrʹ and loss factor, εrʺ were derived from the measured reflection coefficient using a closed-form equation associated with the coaxial probe. An examination was undertaken to compare the performance of a commercially available vector network analyzer (VNA) outfitted with a Keysight 85070E dielectric probe against an SPR-probe system. The comparison was based on analyzing the reflection coefficient magnitude, phase shift, dielectric constant, and loss factor of synthetic breast tissue samples. The study revealed maximum absolute errors of 0.01, 1.07°, 1.12, and 0.75 for the measured reflection coefficient magnitude, phase shift, dielectric constant, and loss factor, respectively. The calibrated reflection coefficient and predicted relative permittivity, εr can be effectively utilized to distinguish between normal (εrʹ < 50) and tumor (εrʹ > 50) breast tissue.

Study on the optical properties of Sm3+ doped bismuth silicate crystals based on first principles

Abstract This study systematically investigated the effect of Sm3+ doping on the optical properties of bismuth silicate (Bi4Si3O12, abbreviated as BSO) crystals using first principles calculations based on density functional theory (DFT). By calculating the dielectric function, reflectivity, absorption coefficient, refractive index, conductivity, and energy loss function of BSO crystals under different Sm3+ doping ratios, we found that moderate Sm3+ doping can increase the dielectric function of BSO crystals, and the real part of the dielectric function represents the material's ability to respond to the electric field, that is, the macroscopic polarization degree. Therefore, moderate Sm3+ doping enhances the polarization ability of BSO crystals. Simultaneously doping an appropriate amount can effectively enhance the conductivity and light (visible and infrared) absorption ability of BSO crystals, and reduce the energy loss between electrons in BSO crystals, thereby improving their luminescence performance. Specifically, when the Sm3+ doping ratio is 1/6, the optical properties of BSO crystals are significantly improved. These findings not only enhance the understanding of the mechanism of optical performance changes in rare earth ion doped BSO crystals, but also provide a theoretical basis for the development of new rare earth doped optical materials.

Fe-loaded two-dimensional nitrogen-doped carbon for electromagnetic wave absorption

Abstract Electromagnetic wave absorbing materials are particularly important in modern electronics, especially in the fields of stealth and communications. Carbon-based materials show great promise in the production and application of efficient wave-absorbing materials due to their rich structure, ultra-light weight, good corrosion resistance, and low cost. Among them, nitrogen-doped carbon-based two-dimensional materials have a stronger depletion effect on electromagnetic waves due to their higher specific surface area and abundant polarization states. In this article, nitrogen-doped carbon 2D flakes (NC) were successfully synthesized by a hydrothermal method. Furthermore, Fe single atoms were successfully loaded onto their surfaces, creating Fe@NC. The wave-absorbing properties of Fe@NC samples were significantly enhanced, with the minimum reflection loss (RLmin) reaching -69.22 dB at 11.48 GHz and the effective absorption bandwidth (EAB) extending to 5.79 GHz. The enhancement of electromagnetic wave absorption is attributed to the synergistic effects of magnetic loss, relaxation processes, dipole polarization, and electrical conduction loss. The successful preparation of Fe@NC offers new possibilities for the development of atomically dispersed wave-absorbing materials.

THE NO REFLECTIVE LOSS PRINCIPLE IS NOT AN OLD-FASHIONED CORPORATE LAW RELIC

Abstract Shareholders are not allowed to bring actions for damages due to a fall in share value or loss of dividend, which are “reflective” of their company’s loss. Later, this principle also found its application to “reflective” losses of employees and creditors. The Supreme Court, however, in Marex Financial v Sevilleja, unanimously held that the principle would apply only to shareholders and not to creditors. The article argues that, while the majority opinion in the Marex decision is reasonably balanced, the minority opinion went a step further by even doubting the very existence of the no reflective loss principle without properly appreciating what shareholding entails. If the minority’s position becomes the law, it will jeopardise companies’ existence as separate legal entities with the capacity to decide with respect to their assets. Further, if the protection of the principle is removed, companies’ counterparties will have to worry constantly about facing numerous direct shareholders’ actions, whether they settle the dispute with the company or not. As a result, if the minority view becomes the law, it can potentially make the company a less dependable commercial partner.

Spatial Confinement Growth Enabling MoS2@Hollow Mesoporous Carbon Spheres Microspheres with Enhanced Microwave Absorption and Corrosion Resistance.

The complex electromagnetic applications in harsh corrosive environments urgently require research into multifunctional microwave absorption (MA) materials. The core-shell structure is an effective strategy to prepare multifunctional MA materials by efficiently combining the advantages of each component. Nevertheless, it remains a tough challenge to elucidate the effect of the binding positions of each component in MA materials on the comprehensive electromagnetic performance. Herein, two types of core-shell structured composites based on hollow mesoporous carbon spheres (HMCS), HMCS@MoS2 and MoS2@HMCS, were prepared via synergistic etch growth and spatial confinement growth strategies, respectively. Compared with HMCS, HMCS@MoS2 severely destroys the connection of HMCS, therefore resulting in impedance mismatching. Comparatively, the growth of MoS2 within the HMCS reduces the disruption of the HMCS connection, enabling MoS2@HMCS with enhanced dielectric loss while optimizing the impedance matching, and therefore, it yields an optimal reflection loss of -46.91 dB at 2 mm and an effective bandwidth of 5.78 GHz at 2.4 mm mixed with polydimethylsiloxane (PDMS). In addition, the combinations of the spatial confinement effect of HMCS, corrosion resistance of MoS2, and chemical stability of PDMS resulted in minimal changes in the MA performance of MoS2@HMCS/PDMS after soaking in acidic and alkaline solutions for 14 days, proving an excellent corrosion resistance property. This inspiring work proposes an effective spatial confinement growth strategy to optimize the impedance matching and further tailor the multifunction for dielectric loss dominated MA materials.

Design and study of electromagnetic wave absorbing structure of multilayer GN/GF/EP composites

With the improvement of radar absorption performance requirements, the research of absorbing materials is an important research direction. In this paper, a graphene/glass fiber/epoxy (GN/GF/EP) structure design scheme is proposed. By measuring the electromagnetic parameters, the influence of different GN content on the absorber performance is analyzed, and the bilayer absorber material combination with the best absorber performance is determined. The double layer absorbing material was made of GN/GF/EP-1.0% (thickness 0.4 mm) and GN/GF/EP-2.5% (thickness 1.7 mm). The peak reflection loss of the double layer absorbing material is −41.55 dB, the center frequency is 10.93 GHz, and the effective absorption bandwidth is 2.86 GHz (9.34∼11.20 GHz).

Optimization of Electromagnetic-Wave Reflectivity Performance of Electromagnetic Shielding Yarn Prepared by Evaporation-Induced Sintering of Ga60.5In25Sn13Zn1.5 Alloy with Nanosilicates.

Electromagnetic interference (EMI) shielding textiles have received widespread attention, and liquid metal (LM) shows superiority in flexible and deformable electronics. Here, we introduce a novel method using nanosilicates to help sinter LM through capillary evaporation, resulting in strong adhesion to substrates. By adjustment of the amount of nanosilicates, flexible EMI shielding yarns are created using dip-coating and curing processes. The sintered LM tightly adhered to the undulating and uneven surfaces of polyurethane (PU) yarns. The as-fabricated ION/LM@PU ("ION" is abbreviation of "ionogel") has strong EMI shielding and low EM-wave reflection due to the high electrical conductivity of the LM layer and good impedance matching of P(AAm-co-AA) ionogel. The addition of an ionogel enhances EM-wave absorption and strengthens interfacial polarization, making it an effective green EMI shielding yarn for reducing secondary reflection pollution. ION/LM@PU exhibited high total electromagnetic interference shielding effectiveness (EMI SET) (∼56 dB), low reflected power coefficient (R) (∼0.153), high impedance matching (|Zin/Z0| ≈ 0.660), high tensile strength (∼23.75 MPa), and high elastic recovery (∼0.92 at 10th stretch-release cycle). The EMI shielding mechanism of ION/LM@PU ± 60° is composed of reflective loss and absorption loss (including multireflective loss, conduction loss, dipole polarization loss, and interfacial polarization loss).

Effect of anisotropy field on the resonance frequency and reflection loss shift characteristics of barium hexaferrite ceramics

Abstract For this study, a modified barium hexaferrite based microwave and radar absorbing material was used. Synthesis and characterization of BaFe(12-2x)(MnTi)xO19 (0.1 ≤ x ≤ 1.0) have been prepared by solid state reaction method. The X-ray diffraction patterns reveal that all samples only crystallized into M-type barium hexaferrite after calcination at 1200 °C. Surface morphology images show that the hexagonal flake-like particle is formed at the initial stages of the Mn-Ti substitution level. The magnetic properties measurement reveals that the variation of magnetization values may vary based on preferable site occupation of Mn4+-Ti2+ cations to replace Fe3+ cations. The significant decrease in field coercivity (Hc) from 3.18 kOe to 0.51 kOe with the increase of Mn-Ti substitution affected the lowering values of field anisotropy (Ha). The maximum reflection loss (RL) positions of BaFe(12-2x)(MnTi)xO19 compositional series are shifted to lower frequency range following the Ha trendlines. The maximum RL value equals to 98.42% microwave absorption at 10.5 GHz has been obtained in x = 1.0 (BaFe10Mn0.5Ti0.5O19) composition.

Innovations and Challenges in Semi-Transparent Perovskite Solar Cells: A Mini Review of Advancements Toward Sustainable Energy Solutions

Amid the shift away from fossil fuels, third-generation perovskite solar cells (PSCs) have become pivotal due to their high efficiency and low production costs. This review concentrates on semi-transparent perovskite solar cells (ST-PSCs), highlighting their power conversion efficiency (PCE) and average visible transmittance (AVT). We address strategies to optimize ST-PSC performance, tackling inherent challenges, such as optical losses from reflection, parasitic absorption, and thermalization loss, which impact the operational efficiency under variable environmental conditions. ST-PSCs are distinguished by their lightweight, flexible, and translucent properties, allowing for diverse applications in urban building integration, agricultural greenhouses, and wearable technology. These cells integrate seamlessly into various settings, enhancing energy harnessing without compromising on aesthetic or structural elements. However, the scalability of ST-PSCs involves challenges related to stability and efficiency in large-scale deployments. The tropical urban landscape of Singapore provides a unique case study for ST-PSC application, blending architectural aesthetics with high solar irradiance to optimize energy efficiency. While the potential for ST-PSCs to contribute to sustainable urban development is immense, significant technological hurdles must be overcome to realize their full potential. Continued advancements in material science and engineering are essential to address these challenges, ensuring the scalability and long-term deployment of ST-PSCs in global energy solutions.

Multifunctional molecular precursor with tunable nano-microarchitecture enables exceptional electromagnetic waves absorption

Multi-component carbon is a promising candidate for electromagnetic wave (EMW) absorption materials. However, complex and non-green preparation process with low atomic utilization efficiency compromises the merits of carbon materials. Additionally, enhancing the electromagnetic wave absorption (EMWA) is highly desirable. To face the challenge, a multifunctional molecular precursor (DQSDCI) has been developed, characterized by high atom utilization efficiency (high char yield), abundant in-situ nitrogen doping, multi-sites for composite of nano-materials (e.g. CNT) or metal ion (e.g. iron) and green preparation (water solubility). The multi-component carbons derived from DQSDCI, featuring adjustable nanostructures (nanoribbons or nanosheets) and modifiable porosity, demonstrate outstanding EMWA. The multicomponent carbon of DQSDCI, iron and CNT (DQSDCI-Fe-CNT-700) demonstrated a minimum reflection loss (RLmin) of −69.57 dB and a maximum effective absorption bandwidth (EABmax) of 5.7 GHz at about 2 mm thickness, covering a wide frequency range (4–18 GHz) by controlling the thickness between 1 and 5 mm. Moreover, simulation results indicated that the derived nanosheet is very promising application for aircraft stealth in a monostatic radar system. Abundant in-situ N doping, uniform distribution of MWCNT and ferromagnetic nanoparticles, hierarchical pore structures and various heterogeneous interfaces can synergistically improve the EMW attenuation ability by forming optimal impedance matching and multi-polarization loss.

Enhanced Electromagnetic Wave Absorption in Hexaferrite/LSMO Bilayers: Optimization of Structural Design Using a High Frequency Software Simulation

In this study, the electromagnetic (EM) wave absorption properties of a two-layered structure composed of La<sub>0.7</sub>Sr<sub>0.3</sub>MnO<sub>3</sub>-epoxy (10 wt.%) (LSMO) and SrFe<sub>9.5</sub>Co<sub>1.25</sub>Ti<sub>1.25</sub>O<sub>19</sub>-epoxy (10 wt.%) (SFCTO), both exhibiting distinct high-frequency magnetic and dielectric properties, were investigated using a High Frequency Simulation Software (HFSS) simulation tool. LSMO had a high dielectric constant (ε' >30) within the measurement range (0.1-18 GHz), indicating that dielectric loss mechanisms primarily contribute to EM wave absorption. In contrast, SFCTO is a material capable of significantly absorbing EM waves near 10 GHz due to ferromagnetic resonance (FMR). The simulations were validated by comparing the measured and simulated reflection losses (RL) of an unpatterned LSMO/SFCTO bilayer. The RL spectra were examined by varying the layer thickness and pattern size in three configurations: a continuous LSMO/SFCTO structure, a cross-patterned LSMO on SFCTO, and a square-patterned LSMO on SFCTO. In the continuous LSMO/SFCTO structure, tunable absorption frequency bands were achieved by adjusting the layer thickness. However, it was difficult to achieve broadband absorption due to the reflective characteristics of the high dielectric LSMO layer. The cross-patterned LSMO structure on SFCTO demonstrated broader bandwidth absorption, with layer thickness being more influential than pattern width. The square-patterned LSMO on SFCTO exhibited the best broadband EM wave absorption (max Δ<i>f</i> = 7.39 GHz). These results suggest that broader absorption is achievable by partially covering the high-dielectric layer with patterns on a hexaferrite sheet.

A Developed Approach for Synthesizing Novel Fe3O4/FeO/BaCl2 Composites with Broadband and High-Efficiency Microwave Absorption Performance.

Designing high-performance microwave absorbing materials that are thin and exhibit strong absorption capabilities across a wide frequency range is critical for mitigating electromagnetic pollution through a simple, highly adaptable, and cost-effective approach. However, achieving these three targets remains a significant challenge. In this research a simple approach suitable for large-scale production of microwave absorbing materials, namely, Fe3O4/FeO/BaCl2 composites, is proposed, which includes the processes of chemical coprecipitation and calcination. The above approach can adjust the mass ratio of Fe3O4/FeO while prompt the formation of BaCl2 with mesoporous structure on the surface of Fe3O4/FeO, meeting the need for desirable microwave absorbing performance. Subsequently, the impacts of varying mass ratios of the Fe3O4/FeO/BaCl2 composites on microstructures, magnetic properties, and microwave absorption properties were examined. Based on this investigation, a mass ratio close to 3.5:5.5:1 was determined to be optimal. At this ratio, the Fe3O4/FeO/BaCl2 composites realize an effective absorption bandwidth of 6.70 GHz at only 1.16 mm thickness, covering the whole Ku-band, and the maximum reflection loss can be close to -46.8 dB at 1.4 mm. The robust microwave absorption performance of Fe3O4/FeO/BaCl2 composites can be attributed to heterostructured multi-interface structural design, the comprehensive effects of multiple reflections and dielectric/magnetic losses induced by BaCl2 with mesoporous structure as well as the aggregated Fe3O4/FeO particles. This work may offer insights into designing and preparing effective microwave absorption materials.

Ultralight SiO2 Nanofiber-Reinforced Graphene Aerogels for Multifunctional Electromagnetic Wave Absorber.

The high-efficiency utilization of two-dimensional (2D) graphene layers for developing durable multifunctional electromagnetic wave (EMW) absorbing aerogels is highly demanded yet remains challenging. Here, renewable, low-density, high-strength, and large-aspect-ratio ceramic silicon dioxide (SiO2) nanofibers were efficiently prepared to assist in the preparation of ultralight yet robust, highly elastic, and hydrophobic graphene aerogels using facile, scalable freeze-drying followed by a carbonization approach. The ceramic nanofibers efficiently prevent the agglomeration of graphene and enhance interfacial interactions, significantly promoting mechanical strength. In addition to the high conduction loss capability derived from the interconnected graphene network, high interfacial polarization derived by abundant heterogeneous interfaces is accomplished for the three-dimensional (3D) hybrid aerogels. The hybrid aerogels thus showcase excellent EMW absorption performance, involving a minimum reflection loss of -74.5 dB at 1.8 mm and an effective absorption bandwidth of 5.7 GHz, comparable to those of the best EMW absorbers. Furthermore, the integration of one-dimensional SiO2 and 2D graphene into 3D hybrid aerogels enables remarkable photothermal antibacterial, photothermal oil absorption, and thermal insulation performances. This work thus provides a type of ultralight ceramic/graphene aerogel with a high-efficiency utilization of graphene for accomplishing high-performance multifunctional applications.

Programmable metasurface based phase-modulating reflector for 2.4GHz wireless communications

Abstract This paper presents an innovative programmable metasurface structure that achieves precise phase control within the 2 to 2.7 GHz frequency range by adjusting the state of varactor diodes embedded in the unit cells. The design employs a single diode, which simplifies the structure, reduces manufacturing costs, and minimizes reflection loss. At 2.4 GHz, the metasurface achieves 1-bit phase responses of 0° and 180°, with a reflection amplitude exceeding 0.72, demonstrating excellent reflective performance. Moreover, as the 2.4 GHz frequency is closely related to wireless communication bands, this programmable metasurface shows significant potential in the field of wireless communication encryption. By integrating dual varactor diodes, the design enables 2-bit phase control with reflection phase angles of 0°, 90°, 180°, and 270°. To validate the design, a 1-bit metasurface structure was fabricated and tested, with experimental results showing a high degree of consistency with simulations, highlighting the potential of this structure in enhancing wireless communication security.

Enhanced microwave absorption of sandwich panels with magnetized carbon fiber corrugated array reinforced PMI foam core

AbstractIntegrating periodic array structures made of metal wires or conductive inks into the foam core of electromagnetic (EM) wave absorbing sandwich panels can significantly improve broadband absorption performance. However, the complex fabrication process and poor corrosion resistance of these materials limit their practical applications. This work innovatively introduces magnetized carbon fiber (CF) into PMI foam, simultaneously achieving broadband absorption and lightweight characteristics of the sandwich structure through the design of array structure and fiber bundle geometry. Simulation analysis compared the EM absorption performance of sandwich panels with carbonyl iron powder (CIP)/CF tape and helical twisted CIP/CF rope corrugated arrays, determining the optimal array structure parameters, which were then experimentally validated. The experimental results align with the simulations, showing that CIP/CF rope corrugated arrays with an amplitude of 10 mm, a cycle length of 15 mm, and an array spacing of 15 mm provide optimal absorption performance, with a reflection loss below −10 dB across the 9–18 GHz frequency range and a maximum absorption of −33.9 dB at 17 GHz. Finally, the absorption mechanism of these sandwich structures is discussed, highlighting how the synergistic effects between the electromagnetic properties and structural morphology of CIP/CF enhance the absorption performance of the EM absorbing sandwich panel.

One-step green synthesis of multi-morphological carbon nanotube forests for superior microwave absorption and electrocatalysis

Porous carbon materials with multiscale distinctive morphologies hold significant promise in electromagnetic wave stealth/protection and catalysis; however, formidable challenges are highly verbose and resource/time-consuming fabrication processes. Here, we report a one-step solvent/template-free self-expanding carbonization strategy for rapidly fabricating porous carbon foams (Ni/CNT) with zero-dimensional (0D) nanoparticles, one-dimensional (1D) nanotube forests, and three-dimensional (3D) hollow microvesicles. Owing to the multi-morphological structure and low-density feature, the resulting porous carbon foam Ni/CNT-800 achieves a minimum reflection loss of −56.48 dB and an effective bandwidth of 5.44 GHz at a low filler loading of only 9 wt%. Moreover, altering the electronic structure and surface chemistry of carbon foam by phosphorus doping enables a highly reduced durable overpotential (η) of 275 mV for oxygen evolution reaction. This work emphasizes a straightforward strategy for the facile design and efficient fabrication of carbon-based materials with unique multiscale porous morphologies, customizable functions, and various applications.