Based on hourly precipitation observations, the diurnal variation in precipitation and its seasonal evolution over the Yunnan–Guizhou Plateau (YGP) were analyzed. The results indicate that the seasonal variation in hourly rainfall in the western part of the YGP is unique. The rainfall reaches its hourly maximum during the late afternoon in spring (March–April) and during nighttime in summer (July–August), which contrasts with the pattern in most of eastern China. By further classifying the rainfall into short-duration (1–3 h) and long-duration (more than 6 h) events, the unique seasonal variations in the western YGP are found to mainly be comprised of short-duration rainfall. The long-duration rainfall shares similar diurnal peaks year-round for both the western and eastern parts of the YGP. The short-duration rainfall in the western part of the YGP shows a year-round afternoon peak, which is different from that of the eastern YGP, which peaks from midnight to early morning in spring and in the late afternoon in summer. The surface maximum daily temperature and low-level instabilities reach their annual maximum in spring over the western YGP and are also higher than in other parts of the YGP, together providing favorable conditions for convection to be triggered in spring afternoons over the western YGP.