THIS work contains the germs of a system of chemical climatology. It indicates a plan of testing the purity of the atmosphere of localities with regard to certain constituents of organic origin—the debris of living things—by washing the air, and determining the character and amount of the substances in solution by certain micro-chemical methods. By the systematic repetition of these testings, the possibility is foreshadowed that we may be enabled to classify such atmospheres, and actually to assign to them quantitative sanitary values. It thus points out how we may be able to estimate the difference between the vitiated air of the town and the pure air of the country. Our senses and experience tell us plainly of the existence of such differences; but chemistry has been hitherto powerless to detect them. “It seemed to many as if the eye had obtained a mysterious power of seeing what was scarcely capable of being proved to be within the domain of substance, and the smell had a power of observing what was more an influence than a positive thing.” Cavendish, nearly a century ago, asserted that chemical experiments could not distinguish the air of London from the air of the country; and in spite of the labours of Bunsen and Regnault, Frankland and Williamson, which have rendered gasometry more susceptible of refinement and accuracy than any other branch of chemical analysis, this assertion seems as true of to-day as it was of the time when uttered. Hitherto chemists, in judging of the quality of the air of any locality, have been obliged to content themselves with determining the proportion of oxygen and carbonic acid which it contains, in conformity with the practice of their ancestors of a century back. Gradually, however, they have been forced to the conclusion that such determinations have very little positive value in enabling them to assign a value to the sanitary condition of an atmosphere—that oxygen was no panacea, nor carbonic acid as deadly as strychnine; and thus we have been thrown back upon our unaided senses to distinguish between the good and the evil. Supposing that some Martin Chuzzlewit, going out to another Eden, required information respecting the sanitary condition of the settlement, the chemist could tell him something concerning the water he might have to drink, but he would be utterly unable to enlighten him respecting the air he would be compelled to breathe. Some such considerations prompted the inquiries which have resulted in this book. Dalton's assertion that he could not distinguish the air of Manchester from that of Helvellyn, or generally the air which depresses from that which cheers and invigorates, seems to have forcibly impressed the author. For upwards of forty years he has laboured to remove the stigma on chemical analysis, and in this volume he concentrates his thoughts and experimental results. “It was with the desire,” he says, “of clearing the mystery of air to some extent that I have devoted so much of my time to the subject; and now I feel that, whilst I have succeeded in doing much of that which I intended to do, I have not got beyond the limits which earlier observers attained by the mere fineness of unaided sense, and by sound reasoning without experiment. Still I hope I shall be found to have put their suspicions into plainer language, proved that which they only imagined, and given in detail that which they only in a general, and, we may add, in a vague manner, had attained.” Air and Rain. By R. A. Smith, General Inspector of Alkali Works. (Longmans, 1872.)
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