The local discontinuous Galerkin (LDG) method on a Shishkin mesh is studied for a one-dimensional singularly perturbed reaction-diffusion problem. Based on the discrete Green's function, we derive some improved pointwise error estimates in the regular and layer regions. For the LDG approximation to the solution itself, the convergence rate of the pointwise error in the regular region is sharp. For the LDG approximation to the derivative of the solution, the convergence rate of the pointwise error in the whole domain is optimal. We establish also optimal pointwise error estimates in the case that the regular component of the exact solution belongs to the finite element space. Numerical experiments are presented to validate the theoretical results.