Hydrogen as an energy carrier is a promising solution to reduce carbon emissions and fight climate change. The US Department of Energy (DOE) announced the Hydrogen Shot initiative to reach $1 per 1 kilogram of hydrogen in 1 decade (by 2031). Although millions of metric tons of hydrogen are produced each year by industry, cost-effective approaches such as steam methane reforming involve the release of carbon dioxide. Water electrolysis is one of the key technologies of producing hydrogen from renewable energy sources which has zero carbon emission, but significant and rapid innovations are required to reach the Hydrogen Shot cost target.Here we focus on low temperature proton exchange membrane (PEM) electrolyzers which have demonstrated high efficiency and high capacity recently. Successful deployment of PEM electrolyzers requires reducing cost while simultaneously improving performance and lifetime. To evaluate and project electrolyzer performance and lifetime more effectively, accelerated stress test (AST) protocols are being developed. The primary goal of this work is the identification of key stressors of degradation and their related degradation mechanisms. Parameters of interest, such as upper and lower potential limit, dynamic vs constant load, temperature, start-up/shut-down procedures, etc., are varied in different AST protocols to elucidate their effect on membrane electrode assembly (MEA) degradation.Electron microscopy offers an in-depth examination of the MEA after AST. In this presentation, we will discuss the following findings that shed light on the degradation mechanisms of electrolyzer MEAs. Firstly, the crystalline structure of the Ir oxide catalyst was compared before and after degradation, showing a structural change from amorphous Ir oxide to nano-sized crystallites. Then, through energy dispersive X-ray spectroscopy (EDS), a correlation is found between type of AST protocol, performance loss, and degree of Ir lost from the anode due to Ir dissolution and migration toward the membrane. We will also show the migration of Ir and Ti to the cathode forming Ir-coated Pt particles and Ti oxide, respectively, for long term tests. Lastly, we find that cathode degradation occurs if a start/stop protocol is employed where Pt particle coarsening and dissolution into the membrane can be observed. [1]References[1] Funding for this work was provided by U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Hydrogen and Fuel Cell Technologies Office through the H2NEW Consortium. Electron microscopy research conducted as part of a user project at the Center for Nanophase Materials Sciences (CNMS), which is a US Department of Energy, Office of Science User Facility at Oak Ridge National Laboratory.
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