Lithium Niobate Substrate Research Articles

A Tunable Transparent Graphene Absorber with Multifrequency Resonance

AbstractThe demand for multinarrowband absorber has attracted increasing interest among researchers in recent years. However, integrating multifrequency absorption, tunability, and high optical transparency into an absorber remains a crucial challenge. In this study, a multiband, tunable, and transparent microwave meta‐absorber is theoretically proposed and experimentally demonstrated. This meta‐absorber is composed of resonant patterns made from graphene and indium tin oxide (ITO), placed on a substrate of lithium niobate (LN). By introducing P‐type doping to reduce the resistance of monolayer graphene to around 300 Ω, the impedance matching of the absorber is promoted, consequently manifesting ten absorption points within 40 GHz. The electric field distribution analysis and an equivalent circuit model are employed to elucidate the physical mechanisms of the multiband absorber. Additionally, the lithium niobate dielectric layer possesses a substantial dielectric constant and exhibits phase transition characteristics with temperature changes. When the temperature increases to 250 °C, a comprehensive tuning range of more than 5.49 GHz within 40 GHz range is realized. The maximum tuning range for a single frequency point is 1.33 GHz. With the broadening of the band, the meta‐absorber can provide multiple tunable ranges, making it more favorable for practical applications in optical modulator and sensor.

Versatile Metamaterial: Exploring the Resonances of Symmetry‐Protected Modes for Multitasking Functionality

AbstractIn this work, an experimental study supported by numerical modeling that demonstrates the possibility of exciting Symmetry Protected‐Bound states In the Continuum (SP‐BICs) in a 1D silicon grating fabricated on a lithium niobate substrate is presented. bBoth transverse electric and magnetic polarization states are investigated, leading to the excitation of four quasi‐ Bound states In the Continuum (quasi‐BIC) resonances, exhibiting distinct behaviors. Under standard illumination conditions (plane of incidence perpendicular to the 1D grating lines), two of these resonances are highly sensitive to illumination conditions, while the other two resonances involving unconventional illumination directions (plane of incidence parallel to the grating lines) are more robust to the angle of incidence, but just as sensitive to external stresses in terms of resonance wavelength and quality factor. Additionally, temperature detection is experimentally demonstrated with a Sensitivity of ST = 0.81∼nm °C−1, a state‐of‐the‐art value achieved due to significant electromagnetic field enhancement inside the lithium niobate substrate at the quasi‐BIC resonance. These findings pave the way for their use in various sensing applications (such as biology, electromagnetic, and temperature sensing), as well as nonlinear applications like second harmonic generation, and electro‐ and acousto‐optic modulation.

A route to an all direct laser written integrated FTS (SWIFTS) in the 3.39–4.1 μm range

This work aims to present the building blocks for an all direct laser written integrated spectrometer in the mid-infrared (3.39–4.1 μm range) based on the SWIFTS (Stationary Wave Integrated Fourier Transform Spectrometer) principle. In a SWIFTS-Gabor configuration, the light from the source interferes with itself in the middle of a channel waveguide, creating a stationary wave. This interferogram is then sampled through scattering centers placed on top of the waveguide that radiate the light they extract onto a detector placed directly on the sample. Finally, the spectrum of the source is retrieved through a Fourier transform. To implement a SWIFTS, two main photonic functions are required: the waveguide and the scattering centers. In this work, both functions have been created using Direct Laser Writing (DLW), a versatile technique, allowing to easily access 3D configurations and to reduce fabrication time. DLW focuses a femtosecond laser onto a sample so as to locally change the crystal lattice, resulting in its structural modification. The waveguides presented here are surface half-circular cladding structures made through type II modifications in the sample, and the scattering centers are surface damage tracks (also referred to as grooves). These surface tracks are creating dielectric discontinuities in the evanescent part of the stationary wave, resulting in the light being radiated outside the waveguide. All of these are made in a z-cut lithium niobate substrate for future implementation of the electro-optic effect. We demonstrate that we have functional waveguides in the mid-IR and that our grooves are extracting the stationary wave as expected, showing promising results for future implementation of a complete mid-IR SWIFTS using DLW.

Features of the structure and resistive switching of titanium oxide films on Y-cut piezoelectric substrate of a LiNbO3 crystal

The difference in the structure of titanium oxide thin films deposited on fused silica substrates and the Y-cut of a lithium niobate crystal is demonstrated. In both cases, the film is amorphous; however, an insignificant amount of rutile crystallites is observed in the film formed on the Y-cut of the lithium niobate crystal. It is shown that the electrical characteristics of the films depend not only on the material of the substrate, but, in the case of the lithium niobate substrate, also on the direction of an electric field. This is caused by the deformation of the substrate due to the inverse piezoelectric effect.

Enhanced propagation of free films with fast spread-out phenomena under the influence of megahertz surface acoustic waves

In this study, a novel approach for enhancing the rapid spreading of free liquid film on lithium niobate (LiNbO3) substrate under megahertz (MHz) surface acoustic wave (SAW) excitation is presented by treating it with surfactants. Through the design of a specific interdigital transducer structure, it was discovered that exciting the SAW at a frequency of 32.3 MHz can achieve optimal spreading performance for water droplets on the surface of surfactant-treated LiNbO3 substrate. The maximum average velocity reaches 1.76 mm/s at position P2 = 1250 μm in the water film front, and the stable film spreading speed shows a 204.9% increase compared to the existing research. Simultaneously, through the investigation of the spreading experiment phenomenon of silicone oil and de-ionized water droplets at varying frequencies, we have discovered the dynamic mechanism of “reverse phase” propagation in liquid film for the first time. This entails that the advancing edge of the wetting film demonstrates a spreading motion law that is opposite to the traditional spreading phenomena, with the spreading velocity in the central exceeding that on both sides. Our research demonstrates that this microfluidic device developed by SAWs enhances the spreading efficiency of the free films, enabling rapid expansion of the target liquid to form a high-surface area film layer. This advancement holds promise for overcoming the limitations of low sensitivity and short response time in the field of rapid pathological diagnosis in contemporary medicine.

Dual-mode Shear Horizontal / Rayleigh-like surface-acoustic-wave configuration on lithium niobate 64° Y-cut

Technologies based on surface acoustic waves (SAWs) find widespread use in wireless communications, signal processing, and sensing applications. In this study, we present an innovative dual-mode SAW configuration using a 64° Y-cut lithium niobate (LN) substrate. The conventional setup, employing interdigital transducers (IDTs) oriented along the crystal X-axis, is known for generating the shear horizontal mode (SH-SAW) with in-plane polarization. Conversely, by utilizing IDTs oriented perpendicular to the X-axis, we introduce effective excitation of a Rayleigh-like SAW (R-SAW), a novel achievement in our research. Through finite element simulations and electro-mechanical analyses, we comprehensively characterize these modes in terms of frequencies, polarizations, propagation losses, and temperature coefficients. Furthermore, we investigate their interaction with liquids by analyzing damping characteristics and acoustic streaming effects using particle image velocimetry (PIV). SH-SAWs exhibit a leaky displacement during propagation with minimal damping in liquids, resulting in weak acoustic streaming—ideal for real-time sensing applications in wet environments. In contrast, non-leaky R-SAWs, characterized by a strong displacement component normal to the surface, exhibit enhanced acoustic streaming, facilitating microfluidic operations. Additionally, R-SAWs demonstrate high sensitivity to mass loading, making them optimal for real-time sensing in dry environments. The ability to generate both SAW modes on the same substrate offers the potential to develop fully electrical-driven, multifunctional integrated sensing platforms with SAW-driven microfluidic capabilities. This unique capability promises novel solutions in bio-sensing, leveraging the complementary strengths of the two acoustic modes in detection and sample handling.

Optical imaging of ferroelectric domains in periodically poled lithium niobate using ferroelectric liquid crystals

Ferroelectric liquid crystals exhibiting a chiral smectic C* phase are deposited on z cut periodically poled lithium niobate substrates and investigated by polarized optical microscopy. While the pure substrates placed between crossed polarizers and observed in transmission appear dark, uniformly aligned liquid crystal films deposited on these substrates show alternating domains with varying brightness. This effect can be attributed to the well-known coupling between the direction of the spontaneous polarization and the optical axis in the birefringent ferroelectric smectic C* phase. Quantitative measurements of the tilt angle between the local optical axis and the smectic layer normal confirm antiparallel orientations of spontaneous polarization of the liquid crystal from domain to domain, as expected by the periodic poling of the lithium niobate substrate. This effect provides a valuable non-destructive method of optical inspection of the quality of periodically poled ferroelectric substrates, which plays an important role in achieving quasi-phase-matching in non-linear optical applications.

Anisotropy-free arrayed waveguide gratings on X-cut thin film lithium niobate platform of in-plane anisotropy

Arrayed waveguide grating is a versatile and scalable integrated light dispersion device, which has been widely adopted in various applications, including, optical communications and optical sensing. Recently, thin-film lithium niobate emerges as a promising photonic integration platform, due to its ability of shrinking largely the size of typical lithium niobate based optical devices. This would also enable multifunctional photonic integrated chips on a single lithium niobate substrate. However, due to the intrinsic anisotropy of the material, to build an arrayed waveguide grating on X-cut thin-film lithium niobate has never been successful. Here, a universal strategy to design anisotropy-free dispersive components on a uniaxial in-plane anisotropic photonic integration platform is introduced for the first time. This leads to the first implementation of arrayed waveguide gratings on X-cut thin-film lithium niobate with various configurations and high-performances. The best insertion loss of 2.4 dB and crosstalk of −24.1 dB is obtained for the fabricated arrayed waveguide grating devices. Applications of such arrayed waveguide gratings as a wavelength router and in a wavelength-division multiplexed optical transmission system are also demonstrated.

A high-power narrow-linewidth microlaser based on active-passive lithium niobate photonic integration

We demonstrate an on-chip integrated Fabry-Perot (FP) resonator laser with high output power and narrow linewidth. The laser chip is fabricated on monolithically integrated active (i.e., Er3+-doped) and passive (i.e., non-doped) thin film lithium niobate (TFLN) substrate in which the laser cavity is constructed with two Sagnac loop reflectors fabricated on the passive TFLN. The monolithically integrated FP resonator laser achieves an output power of 126.35 μW and a linewidth of 47.5 kHz.

A Dual-Mode Surface Acoustic Wave Delay Line for the Detection of Ice on 64°-Rotated Y-Cut Lithium Niobate.

Ice accumulation on infrastructure poses severe safety risks and economic losses, necessitating effective detection and monitoring solutions. This study introduces a novel approach employing surface acoustic wave (SAW) sensors, known for their small size, wireless operation, energy self-sufficiency, and retrofit capability. Utilizing a SAW dual-mode delay line device on a 64°-rotated Y-cut lithium niobate substrate, we demonstrate a solution for combined ice detection and temperature measurement. In addition to the shear-horizontal polarized leaky SAW, our findings reveal an electrically excitable Rayleigh-type wave in the X+90° direction on the same cut. Experimental results in a temperature chamber confirm capability for reliable differentiation between liquid water and ice loading and simultaneous temperature measurements. This research presents a promising advancement in addressing safety concerns and economic losses associated with ice accretion.

Surface acoustic wave actuated plasmonic signal amplification in a plasmonic waveguide

Enhancement of nanoscale confinement in the subwavelength waveguide is a concern for advancing future photonic interconnects. Rigorous innovation of plasmonic waveguide-based structure is crucial in designing a reliable on-chip optical waveguide beyond the diffraction limit. Despite several structural modifications and architectural improvements, the plasmonic waveguide technology is far from reaching its maximum potential for mass-scale applications due to persistence issues such as insufficient confined energy and short propagation length. This work proposes a new method to amplify the propagating plasmons through an external on-chip surface acoustic signal. The gold–silicon dioxide (Au-SiO2) interface, over Lithium Niobate (LN) substrate, is used to excite propagating surface plasmons. The voltage-varying surface acoustic wave (SAW) can tune the plasmonic confinement to a desired signal energy level, enhancing and modulating the plasmonic intensity. From our experimental results, we can increase the plasmonic intensity gain of 1.08 dB by providing an external excitation in the form of SAW at a peak-to-peak potential swing of 3 V, utilizing a single chip.

A passive wireless surface acoustic wave (SAW) sensor system for detecting warfare agents based on fluoroalcohol polysiloxane film

Long-term monitoring of environmental warfare agengts is a challenge for chemical gas sensors. To address this issue, we developed a 433 MHz passive wireless surface acoustic wave (WSAW) gas sensor for dimethyl methylphosphonate (DMMP) detection. This WSAW gas sensor includes a YZ lithium niobate (LiNbO3) substrate with metallic interdigital transducers (IDTs) etched on it, and an antenna was placed near the IDT. A DMMP-sensitive viscoelastic polymer fluoroalcoholpolysiloxane (SXFA) film was prepared on a LiNbO3 substrate, and mode modeling coupling was used to optimize the design parameters. The sensor can function properly in an environments between −30 °C and 100 °C with humidity less than 60% RH. When the wireless transmission distance was within the range of 0–90 cm, the sensor noise increased with distance, and the stability was less than 32°/h. While optimizing the film thickness of SXFA, a relationship was observed between sensor sensitivity and film thickness. When the film thickness of SXFA reached 450 nm, the optimal value was reached. At a distance of 20 cm between the transmitting and receiving antennas, DMMP was detected at different concentrations with the developed WSAW gas sensor. The lower detection limit of DMMP was 0.48 mg/m3, the sensitivity of the sensor was 4.63°/(mg/m3), and repeatable performance of the sensor was confirmed.

Low-loss grating coupler with a subwavelength structure on a thin-film lithium niobate substrate.

We demonstrated a low-loss O-band grating coupler on an x-cut thin-film lithium niobate substrate by implementing subwavelength and apodized structures. The subwavelength gratings were used to mitigate the refractive index discontinuity between the input taper and grating region, which was the first application of such a structure for grating coupler optimization on a thin-film lithium niobate substrate. The coupling efficiency was measured to be -1.99 dB/coupler at a wavelength of 1312.8 nm, which was the lowest loss among the reported lithium niobate grating couplers that do not use metal mirrors. The proposed design does not require metal mirrors or any additional material layers and can be easily fabricated with a single-step lithography and etching processes.

Acoustically driven spin wave resonance in Ni/128° Y-cut LiNbO3 hybrid devices with the beam steering effect

We study the acoustically driven spin wave resonance (ADSWR) in a Ni film sputtered on a 128° Y-cut lithium niobate (LiNbO3) substrate under the condition that the beam steering effect exists due to the surface acoustic waves (SAWs) transmitted along several selected crystal orientations. SAW devices with that effect exhibit significantly different ADSWR spectra from devices without it. By using the magnetoelastic coupling theory and finite element simulation associated with SAW, we find that the beam steering effect of magnetoacoustic waves has an important influence on the acoustic attenuation. The relationship between its group velocity direction and the magnetization vector can be used to define the magnetoacoustic wave mode. The mode affects acoustic attenuation magnitude, which can break the fourfold symmetry. Increasing its power flow angle will significantly increase the maximum acoustic attenuation caused by magnon–phonon coupling.

Free-space coupling and characterization of transverse bulk phonon modes in lithium niobate in a quantum acoustic device

Transverse bulk phonons in a multimode integrated quantum acoustic device are excited and characterized via their free-space coupling to a three-dimensional (3D) microwave cavity. These bulk acoustic modes are defined by the geometry of the Y-cut lithium niobate substrate in which they reside and couple to the cavity electric field via a large dipole antenna, with an interaction strength on the order of the cavity linewidth. Using finite element modeling, we determine that the bulk phonons excited by the cavity field have a transverse polarization with a shear velocity matching previously reported values. We demonstrate how the coupling between these transverse acoustic modes and the electric field of the 3D cavity depends on the relative orientation of the device dipole, with a coupling persisting to room temperature. Our study demonstrates the versatility of 3D microwave cavities for mediating contact-less coupling to quantum, and classical, piezoacoustic devices.

Dynamic Strain Modulation of a Nanowire Quantum Dot Compatible with a Thin-Film Lithium Niobate Photonic Platform.

The integration of indistinguishable single photon sources in photonic circuits is a major prerequisite for on-chip quantum applications. Among the various high-quality sources, nanowire quantum dots can be efficiently coupled to optical waveguides because of their preferred emission direction along their growth direction. However, local tuning of the emission properties remains challenging. In this work, we transfer a nanowire quantum dot onto a bulk lithium niobate substrate and show that its emission can be dynamically tuned by acousto-optical coupling with surface acoustic waves. The purity of the single photon source is preserved during the strain modulation. We further demonstrate that the transduction is maintained even with a SiO2 encapsulation layer deposited on top of the nanowire acting as the cladding of a photonic circuit. Based on these experimental findings and numerical simulations, we introduce a device architecture consisting of a nanowire quantum dot efficiently coupled to a thin-film lithium niobate rib waveguide and strain-tunable by surface acoustic waves.

UV laser formation of complex topologies for sensitive elements of navigation sensors based on surface acoustic waves

A method utilizing a UV laser to form complex electrode structures on the surface of the sensitive element prototype for a solid-state gyroscope (SSG) based on surface acoustic waves (SAW) was tested. The prospects of using the method are demonstrated in terms of the flexibility of changing the topology, the speed of navigation sensors prototypes manufacturing, and reducing the cost. Methods for forming surface structures on piezoelectric materials using an IR and UV laser are compared. The parameters of laser formation of a surface pattern for configuring the topology of a sensitive element by evaporation of a thin-film coating 5000 nm and 200 nm thick deposited on lithium niobate substrates are determined. The amplitude-frequency characteristics of the manufactured samples of SAW-based SSG sensing elements are obtained. Additionally a finite-element modeling was performed to obtain theoretical prediction of dependencies of the sensing element characteristics on the thickness of the metallization forming the electrodes. It was found that when using a fiber UV laser with a wavelength of 355 nm, it is necessary to impose more stringent requirements on the quality of metallization and on the calculation of laser radiation regimes for processing coatings with a thickness of 200 nm. It is shown that when using a UV laser, it is possible to manufacture more compact sensitive elements of navigation sensors on surface acoustic waves than when using IR lasers.

Antibacterial properties of lithium niobate crystal substrates

The bactericidal properties of chemically patterned lithium niobate substrates under a super-bandgap UV light source is established. UV irradiation of lithium niobate surfaces inoculated with bacteria leads to antimicrobial activity compared to a glass substrate under similar conditions, as determined by surface enhanced Raman spectroscopy and corroborated with a fluorescence-based live/dead assay. This finding may expand the possible biomedical applications of lithium niobate.

Features of spontaneous ferroelectric domain nucleation in Ti:LiNbO3 modulators

Integrated optical modulators based on lithium niobate Ti-indiffused waveguides (Ti:LiNbO3) are used extensively for broadband devices that have a high coupling efficiency with optical fibers at a 1.5 μm wavelength window. However, the ferroelectric nature of lithium niobate crystal results in some undesirable effects causing parameters fluctuations. For example, the pyroelectric effect leads to thermal dependent DC-drift and excess optical losses. Therefore, to develop effective compensation methods, it is important to understand the origin of instability. In the interelectrode gap of phase modulators we found needle-like domain defects with switched polarization along a surface layer of the monodomain X-cut lithium niobate substrate. Based on domain nucleation theory and polarization switching behavior, the spontaneous nature of domain nucleation caused by the pyroelectric field was shown and described for the interelectrode gap of the modulator along electrode edges. Considering the corona effect, models of domain nucleation and growth are proposed, and the morphology of needle-like domains is describes based on numerical simulation of the pyroelectric field distribution in the crystal volume. Experimental studies of industrial optical phase modulators characterize the shape and size of domains not only in the interelectrode gap, but also along the boundary of external electrodes proving the pyroelectric type of domain nucleation. Several methods were used for domain visualization-selective chemical etching, piezoresponse force microscopy, and electron scanning microscopy. The present work provides a theoretical and practical basis for future research on stabilization of the parameters for optical phase modulators.

Study of pure Ni, NiO, and mixture of Ni-NiO thin films on piezoelectric lithium niobate substrate by pulsed laser deposition

The crystallographic orientation plays a significant role in the modern magnetic heterostructure devices, especially in the arena of spintronics. In terms of magnetic property, domain orientation is solely dependent on structural homogeneity. This research work deals with the development of pure Ni, NiO, and mixture of Ni-NiO thin films on a single-crystalline piezoelectric lithium niobate substrate. Pulsed laser deposition technique was used at 650 °C in a reduction and oxidation atmosphere for pure Ni and NiO deposition respectively, whereas deposited NiO was reduction annealed to achieve mixture of Ni (ferromagnetic)-NiO (antiferromagnetic) thin film on a piezoelectric lithium niobate substrate. X-ray diffraction along with x-ray reflectometry was carried out for better understanding of surface nature and thickness of the film. Morphological analysis of the films was conducted using scanning electron microscopy with energy dispersive X-ray spectrum. Atomic force microscopy as well as ferromagnetic resonance were used to understand the magnetic characteristics of the thin films. Additionally, surface properties of the films with Ni and O oxidation states were investigated by X-ray photoelectron spectroscopy. Our findings indicate that Ni and mixture of Ni-NiO thin films exhibit similar dynamic magnetic characteristics, making Ni-NiO films a more attractive option for spintronic applications because of their adjustable magnetic properties.