Liquid Water Content Research Articles

Satellite-Based Estimation of the Role of Cloud-Radiative Interaction in Accelerating Tropical Cyclone Development

Abstract Recent modeling studies have suggested a potentially important role of cloud-radiative interactions in accelerating tropical cyclone (TC) development, but there has been only limited investigation of this in observations. Here, we investigate this by performing radiative transfer calculations based on cloud property retrievals from the CloudSat Tropical Cyclone (CSTC) dataset. We examine the radius–height structure of radiative heating anomalies, compute the resulting radiatively driven circulations, and use the moist static energy variance budget to compute radiative feedbacks. We find that inner-core midlevel ice water content and anomalous specific humidity increase with TC intensification rate, resulting in enhanced inner-core deep-layer longwave warming anomalies and shortwave cooling anomalies in rapidly intensifying TCs. This leads to a stronger radiatively driven deep in-up-and-out overturning circulation and inner-core radiative feedback in rapidly intensifying TCs. The longwave-driven circulation provides radially inward momentum fluxes and upward moisture fluxes, which benefit TC development, while the shortwave-driven circulation suppresses TC development. The longwave anomalies, which dominate the inner-core positive radiative feedback, are mainly generated from cloud-radiative interactions, with ice particles dominating the deep-layer circulation and liquid droplets and water vapor contributing to the shallow circulation. Moreover, the variability in ice water content, as opposed to the variability in liquid water content and the effective radii of ice particles and liquid droplets, dominates the uncertainty in TC-radiative interaction. These results provide observational evidence for the importance of cloud-radiative interactions in TC development and suggest that the amount and spatial structure of ice water content are critical for determining the strength of this interaction. Significance Statement The limited investigation of tropical cyclone (TC)-radiative interaction in observations impedes our understanding of TC development. This study aims to quantitatively show the spatial variation in radiation in TCs and their effect on TC development by using a set of satellite-based observations. We relate TC-radiative interaction to TC intensification and emphasize the inner-core features. Moreover, we quantitatively demonstrate the relative contribution from clouds, liquid droplets, ice particles, and water vapor to TC-radiative interaction as well as the source of the variation in radiative properties. These results provide an additional observational foundation for the importance of cloud-radiative interactions in TC development and support a quantitative validation for numerical modeling.

Prediction of rain erosion damage progression using disdrometer rain data: The importance of liquid water content

Wind turbine blade erosion poses a significant challenge to the durability and performance of wind turbines. Modeling of rain erosion damage, considering atmospheric conditions, improves our understanding of the progression of leading-edge erosion on wind turbine blades. In this study, we investigate the impact of varying raindrop characteristics on rain erosion damage development. We analyse 2.5 years of data from a disdrometer, which measures the size and velocity of falling rain droplets, at Risø campus. Various post-processing methods of the disdrometer data are used for estimating representative droplet diameters and fall velocities for each rain event. We compare measured droplet fall velocities with theoretical terminal velocities, revealing a necessity for revising theoretical approaches to raindrop fall velocity for erosion damage modeling. The measured rain rates and representative fall velocities are used to calculate the liquid water content in the air. We introduce a bin-wise summation method for estimating the liquid water content, circumventing the need for representative droplet assumptions. As this method provides the most accurate input for the damage model, we benchmark the other post-processing methods against it and employ it to evaluate bias estimates of associated damage predictions. The largest bias (22%) in accumulated damage is found with an arithmetic mean droplet diameter approach and the smallest bias (-2%) with the median volume estimation method for damage model input. Furthermore, we demonstrate that, for a given rainfall volume, smaller droplets contribute to larger accumulated damage compared to larger droplets.

Study on influence of turbulence intensity on blade airfoil icing mass & aerodynamic performance

Wind is an emerging renewable energy resource, but more useful in cold regions. With the increasing threat of climate change and global warming, the unpredictability of wind energy patterns has been affected. With continual threats from extremes and uncertainties, icing on wind turbines has been noted to grow affecting aerodynamic performance. The effect of turbulence intensity at its impact on aerodynamic performance was numerically done using ANSYS Fluent and FENSAP ICE software. Conditions considered for the study included turbulence intensities, median volume diameter (MVD), liquid water content (LWC), angle of attack, and ambient temperature for 180 min. The study's conditions aimed at providing a wide range of effects covering the in-cloud icing and freezing drizzle. The mass of ice increased with an increase in LWC when it increased from 0.05 g/m3 to 0.3 g/m3, and MVD with 1000 μm compared to 40 μm, but when temperature decreased led to an increase from −1 °C to −15 °C. Increasing the angle of attack led to reduced aerodynamic performance with stall angle occurring at α = 0–18°. An increase in the turbulence intensity from 0.01 % to 50 % resulted in decreased CL/CD.

Exploring the statistical characteristics of coastal winter precipitation measured using a Parsivel2 disdrometer: A case study in North Carolina

A drop size distribution (DSD) of a precipitation event is a key characteristic and plays a critical role in quantitative precipitation estimation. In this study, DSD datasets were collected by a Parsivel2 disdrometer in Elizabeth City, North Carolina, U.S. from October 2021 to April 2022. The microphysical and statistical characteristics of the DSD were examined. For this period, the contribution of small raindrops (< 1 mm) to the total number concentration (Nt) was the largest, while the contribution of large raindrops (3―8 mm) to Nt was the smallest. As expected, large raindrops had the largest impact on rain rate (R), liquid water content (W), and radar reflectivity factor (Z), while small raindrops had the least. The shape of the averaged DSDs was similar for different rain rates while the width of the raindrop concentration spectrum increased as rain rates increased. The average mass-weighted diameter Dm (log10Nw, generalized intercept parameter) value for all rain events was found to be 1.11 mm (4.54), while for stratiform rains Dm was 1.18 mm (4.65), and for convective rains, it was 0.89 mm (4.17). The empirical relationships between rain intercept parameter (N0) vs shape factor (μ), μ vs slope factor (Λ), log10Nw vs median volume diameter (D0), D0 vs R, R vs kinetic energy (KE), and Z―R relationship were also derived. These findings are useful for design of rainfall simulators and for better understanding erosive properties of rainfall that contribute to contaminant fate and transport.

Photo-Oxidation of α-Pinene Oxidation Products in Atmospheric Waters - pH- and Temperature-Dependent Kinetic Studies.

The atmospheric α-pinene oxidation leads to three carboxylic acids: norpinonic acid (NPA), pinic acid (PA), and 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA). In this study, the OH radical kinetics in the aqueous phase of these carboxylic acids were investigated at different temperatures and pH values of solutions. Activation parameters and the corresponding atmospheric lifetimes of the acids in the troposphere were derived. The overall second-order rate constants for the individual speciation forms of the acids (AH and A- for NPA; AH2, AH- and A2- for PA; and AH3, AH2-, AH2- and A3- for MBTCA) were determined. At 298 K, the rate constants for reactions of protonated forms (AHx) of NPA, PA, and MBTCA with •OH, were (1.5 ± 0.2) × 109 L mol-1 s-1, (2.4 ± 0.1) × 109 L mol-1 s-1, and (4.1 ± 0.6) × 108 L mol-1 s-1, respectively. For the fully deprotonated forms (Ax-) of studied acids, the second-order rate constants were (2.2 ± 0.2) × 109 L mol-1 s-1, (2.8 ± 0.1) × 109 L mol-1 s-1, and (10.2 ± 0.7) × 108 L mol-1 s-1 at 298 K, respectively. It was found that the reactions of NPA and PA with OH radicals are faster than with MBTCA. For MBTCA, the reaction rate depends on pH more strongly at elevated temperatures (>298 K). The atmospheric lifetimes of the acids considered due to their reactivity with •OH were calculated for different model scenarios at a temperature of 283 K and pH = 2 in the aqueous phase. For this purpose, liquid water content (LWC) was used for aerosols and clouds under storm conditions and at various aqueous-phase concentrations of OH radicals. The lifetimes decreased with increasing LWC (from 10-12 m3 m-3 in aerosol to 10-5 m3 m-3 in storms), indicating that the acids undergo significant aqueous processing under realistic atmospheric conditions. Besides, the aerosol systems appeared less effective in removing PA and NPA, with lifetimes ranging from hundreds of days to tens and hundreds of hours, respectively. Clouds were more effective, with lifetimes ranging from tens of hours to a single second or less. MBTCA, which dissolves better in water, was effectively removed in all systems, with the longest lifetime of approximately 90 min.

Ground-based cloud microphysical observations at Mount Lu in the East Asian monsoon region from 2015 to 2020

Ground-based cloud microphysical observations were continuously conducted at Mount (Mt.) Lu site from 2015 to 2020, which is located in the East Asian monsoon areas of eastern China. The statistical characteristics of cloud microphysics under different meteorological conditions were analyzed by using visibility, cloud droplet and raindrop size distribution data, and meteorological variables. The mean cloud droplet number concentration (Nc), liquid water content (LWC) and effective diameter (De) are 151 cm−3, 0.08 g m−3 and 11.4 μm, respectively. Nc and LWC observed at Mount Lu are lower than the observation results of cloud from other mountain stations all over the world. Broader cloud droplet spectra are correlated with higher temperatures and lower wind speeds. The clouds are classified into nonprecipitating, lightly-raining and raining clouds. Statistics show that lightly-raining and raining clouds account for 66% of all clouds. Nc and LWC of lightly-raining (drizzling) clouds are highest, while spectral width of raining clouds is largest. Spectral dispersion of raining clouds converges to the narrow range of 0.4–0.7. Notably, medium sized cloud droplets (11–40 μm) promote the formation of large cloud droplets (40–50 μm, pre-drizzle size) and drizzle drops which initiate the auto-conversion from condensation to collision-coalescence growth. This study relying on in-situ continuous cloud observation from mountain station are helpful to understand cloud microphysical structures in East Asian monsoon region, and fitting parameters also provide observational evidence for numerical models.

Effects of surface moisture flux on the formation and evolution of cold fog over complex terrain with large‐eddy simulation

AbstractThis study examines the effect of surface moisture flux on fog formation, as it is an essential factor of water vapor distribution that supports fog formation. A one‐way nested large‐eddy simulation embedded in the mesoscale community Weather Research and Forecasting model is used to examine the effect of surface moisture flux on a cold fog event over the Heber Valley on January 16, 2015. Results indicate that large‐eddy simulation successfully reproduces the fog over the mountainous valley, with turbulent mixing of the fog aloft in the valley downward. However, the simulated fog is too dense and has higher humidity, a larger mean surface moisture flux, more extensive liquid water content, and longer duration relative to the observations. The sensitivity of fog simulations to surface moisture flux is then examined. Results indicate that reduction of surface moisture flux leads to fog with a shorter duration and a lower height extension than the original simulation, as the decrease in surface moisture flux impairs water vapor transport from the surface. Consequently, the lower humidity combined with the cold air helps the model reproduce a realistic thin fog close to the observations. The outcomes of this study illustrate that a minor change in moisture flux can have a significant impact on the formation and evolution of fog events over complex terrain, even during the winter when moisture flux is typically very weak.

Seasonality of spectral radiative fluxes and optical properties of Arctic sea ice during the spring–summer transition

The reflection, absorption, and transmittance of shortwave solar radiation by sea ice play crucial roles in physical and biological processes in the ice-covered Arctic Ocean and atmosphere. These sea-ice optical properties, particularly during the melt season, significantly impact energy fluxes within and the total energy budget of the coupled atmosphere-ice-ocean system. We analyzed data from autonomous drifting stations to investigate the seasonal evolution of the spectral albedo, transmittance, and absorptivity for different sea-ice, snow, and surface conditions measured during the MOSAiC expedition in 2019–2020. The spatial variability of these properties was small during spring and increased strongly after melt onset on May 26, 2020, when liquid water content on the surface increased, largely accounting for the enhanced variability. The temporal evolution of surface albedo and sea-ice transmittance was mostly event-driven, thus containing episodic elements. Melt ponds reduced the local surface albedo by 31%–45%. Over the melting season, single ponding events increased the energy deposition of the sea ice by 35% compared to adjacent bare ice. Thus, single melt ponds may impact the summer energy budget as much as seasonal evolution over 1 month. Absorptivity and transmittance showed strong temporal and spatial variabilities independently of surface conditions, possibly due to the different internal sea-ice properties and under-ice biological processes. The differences in seasonal evolution shown for different sea-ice conditions strongly impacted the partitioning of shortwave solar radiation. This study shows that the formation and development of melt ponds, in reducing albedo by a third of bare ice sites, can notably increase the total summer heat deposition. The vastly different seasonal evolutions, different sea-ice conditions, and timing and duration of ponding events need to be considered when comparing local in-situ observations with large-scale satellite remote sensing datasets, which we suggest can help to improve numerical models.

Microphysical Characteristics of Precipitation Over Eastern China and Its Coastal Regions

AbstractMany studies have investigated the macro‐ and micro‐physical properties of precipitation, but few classified precipitation into warm‐ and cold‐topped, which affects precipitation phase and precipitation type significantly. Furthermore, the impact of moisture and dynamics on microphysical characteristics of precipitation has been less studied. Using precipitation data from the GPM 2A DPR between May and September from 2015 to 2023, this study conducts a systematic study on microphysical characteristics of precipitation over eastern China and its coastal areas. This study divides precipitation cases into 20 categories, including warm‐/cold‐topped (CTP/WTP) convective/stratiform light/moderate/heavy/extreme/the most extreme precipitation. The findings reveal distinct differences along with similarities in various precipitation categories between eastern China and its coastal regions. The convection ratio for CTP increases with higher precipitation intensity, while WTP is dominated by convective precipitation. The more CTP, the higher the solid water content. The heavier precipitation, the higher liquid water content contributes. The mass‐weighted diameter (Dm) for CTP shows three variations from high to low with little or slight decrease with altitude at upper‐layer, followed by a rapid increase at middle‐layer and finally decreasing slightly at low‐layer. The CTP Dm grows rapidly with temperature from −18.58 (−13.93)°C for convective (stratiform) precipitation and their maximum growth rate are almost located in melting layer. Dm (raindrop density) is larger (lower) over land than ocean and larger (lower) for CTP than WTP. Dm shows positive relation to vertical velocity and specific humidity, especially sensitive to the middle‐ and upper‐layers meteorological conditions.

Online headspace monitoring of volatile organic compounds using proton transfer reaction-mass spectrometry: Application to the multiphase atmospheric fate of 2,4-hexadienedial

Chemical processes in clouds have been suggested to contribute significantly to the mass of organic aerosol particles in the atmosphere. Experimental and theoretical evidence suggest that organic mass production in clouds can be substantial and depends on the concentration of organic precursor compounds available in the gas phase. The present study aims at studying the aqueous phase reactivity of one of these overlooked precursors, i.e. 2,4-hexadienedial, an important and toxic intermediate in the atmospheric oxidation of aromatic species. Cautious synthesis and purification of 2,4-hexadienedial was performed. Its effective Henry's law constant was measured using a new simple and fast method based on online flow-injection analysis. The reactivity of 2,4-hexadienedial in the aqueous phase relevant to atmospheric conditions was studied, including hydrate formation, photolysis, ∙OH- and SO4∙--oxidation as well as reaction with NH3. The results revealed a low hydration constant compared to other dicarbonyls (Khyd1 = 7 × 10−2) and no dihydrate formation, indicating in an intermediate solubility (KH = 1.0 × 104 M atm−1) and high absorption cross sections (σ278nm > 10−16 cm2 molecule−1). Compared to its gas phase photolysis, its aqueous phase photolysis showed low quantum yields (Φ290–380nm = 0.9 %), and a significant red shift of the absorbance maximum, leading to a fast aqueous photolysis kinetics (Jaq,atm = 8.7 × 10−5 s−1) under atmospheric solar radiation, but no triplet state formation was detected. Radical oxidation experiments revealed extremely rapid oxidation kinetics (k∙OH = 1.10 × 1010 M−1 s−1 and kSO4∙- = 1.4 × 109 M−1 s−1) driven by fast addition of the radicals to the unsaturated bonds. In contrast, the reaction with aqueous NH3 (kNH3 = 2.6 × 10−3 M−1 s−1) was found slower than glyoxal and 2-butenedial, likely due to the hyperconjugation of 2,4-hexadienedial. Using these new data complemented with assumed aqueous phase kinetics (for NO3, 3C* and 1O2 reactions) and previous gas-phase kinetic ones, the multiphase atmospheric fate of 2,4-hexadienedial was established under atmospheric conditions reported from previous field measurements and models. The results revealed a short day lifetime (∼1 h) and a long night lifetime (>12 h). It was shown that daytime atmospheric chemistry of 2,4-hexadienedial can be influenced by aqueous-phase reactivity during cloud events, up to ∼50 % under thick cloud conditions (Liquid Water Content >2000 g/m3), indicating that even a compound of intermediate solubility can be strongly affected by condensed-phase reactivity. Besides its fast aqueous phase reactivity towards ∙OH and photolysis, its daytime condensed-phase reactivity may be driven by reactions with dissolved triplet states (3C*), up to 35 %, highlighting the need to study further the kinetics, the nature and concentrations of dissolved 3C* under various atmospheric conditions. In addition, the molecular properties and atmospheric behavior of 2,4-hexadienedial were found different from those of glyoxal and 2-butenedial, highlighting the need for detailed atmospheric reactivity studies of polyfunctional compounds, in particular unsaturated compounds.

Dual isotopic evidence of δ15N and δ18O for priority control of vehicle emissions in a megacity of East China: Insight from measurements in summer and winter

The source apportionment and main formation pathway of nitrate aerosols in China are not yet fully understood. In this study, PM2.5 samples were collected in Shanghai in the summer and winter of 2019. Water-soluble inorganic ions and isotopic signatures of stable nitrogen (δ15N-NO3−) and stable oxygen (δ18O-NO3−) in PM2.5 were determined. The results showed that NO3− was less important in summer (NO3−/SO42− = 0.4 ± 0.8), while it became the dominant species in winter (52.1 %). The average values of δ15N-NO3− and δ18O-NO3− in summer were + 2.0 ± 6.1 ‰ and 63.3 ± 9.4 ‰ respectively, which were significantly lower than those in winter (+7.2 ± 3.4 ‰ and 88.3 ± 12.1 ‰), indicating discrepancies between NOx sources and nitrate formation pathways. Both δ15N-NO3− and δ18O-NO3− were elevated at night, demonstrating that N2O5 hydrolysis contributed to the nocturnal nitrate increase even in summer. The contribution of the OH oxidation pathway to nitrate aerosols averaged at 70.5 ± 17.0 % in summer and N2O5 hydrolysis dominated the nitrate production in winter (approximately 80 %). On average, vehicle exhaust, coal combustion, natural gas burning, and soil emission contributed 50.7 %, 21.5 %, 15.9 %, and 11.9 %, respectively, to nitrate aerosols in summer, and contributed 56.8 %, 23.9 %, 13.6 %, and 5.7 %, respectively, to nitrate production in winter. Notably, natural gas burning is a non-negligible source of nitrate aerosols in Shanghai. In contrast to an inverse correlation between δ15N-NO3− and PM2.5, the value of δ18O-NO3− was positively correlated with nitrate concentration and aerosol liquid water content (ALWC) in winter, suggesting that explosive growth of nitrate was driven by continuous accumulation of N-depleted NOx and rapid N2O5 hydrolysis under calm and humid conditions. To continuously improve air quality, priority control should be given to vehicle emissions as the dominant source of NOx and volatile organic compounds (VOCs) in Shanghai.

Study of hydrothermal characteristics of large‐scale water conveyance trunk canals in seasonally frozen ground regions under the influence of different initial water contents

AbstractIn seasonal frozen soil, freezing and thawing can change the physical and mechanical properties and affect slope stability. There are complex moisture conditions in the main water transfer canal. A study of the hydrothermal evolution of canals with different initial water contents under the action of freezing and thawing is of great importance for the prevention and control of canal slope slides. Hydrothermal coupling models are the key to revealing the canal's hydrothermal evolution. As some of the modeling parameters in the current hydrothermal coupling model are based on empirical values, particularly those in the van Genuchten equation, which are not necessarily related to soil properties, they are not suitable for analyzing the hydrothermal evolution of canals. This paper determines the soil‐water characteristic curve from the cumulative curve of particle gradation in the subsoil, and then determines the hydraulic parameters of the subsoil using the VG model, which then corrects the hydrothermal coupling model. The method of modifying the hydrothermal coupling model is original, which makes the model more realistically reflect drainage soil characteristics. During freezing and thawing of channel slopes with different initial water contents (21%, 25%, 29%, 33%, 37%, and 41%), temperature field, water field, and ice content distributions were investigated. Using the V‐G model, the optimal parameters for canal subsoil were a = 0.06, n = 1.2, and m = 0.17, and temperature distribution trends between canals with different water contents were basically similar. Water will accumulate at the bottom as the liquid water content increases at the canal boundary.

Investigation of a haze-to-dust and dust swing process at a coastal city in northern China part II: A study on the solubility of iron and manganese across aerosol sources and secondary processes

The soluble fractions of iron (FeS) and manganese (MnS) in atmospheric aerosols potentially impact human health and ocean ecosystems. This study investigated a persistent haze-to-dust process observed in winter Qingdao, a coastal city in Northern China, focusing on the aerosol sources and acidification process affecting the dissolution of Fe and Mn. It was found that FeS in PM2.5 peaked during the intermingling of dust plumes with local haze, while other species of Fe and Mn reached their maximal levels coinciding with PM10. Positive Matrix Factorization (PMF) analysis determined that aged dust was the main source of FeS in PM2.5, accounting for 44.0%, while fresh dust contributed just 1.9%. Conversely, fresh dust played a more significant role in PM10, contributing 8.9% to FeS. Similar trends were observed in the initial dust and dust swing periods, aged dust was the dominant contributor to FeS, but fresh dust accounted for a higher fraction in PM10 (11.5%) than in PM2.5 (4.9%). In contrast, MnS levels, with high solubility (%MnS), were mainly from fresh dust (27.9% and 63.2% in PM2.5 and PM10, respectively). The PMF estimated %MnS in fresh dust at 17.0% for PM2.5 and 19.4% for PM10, considerably higher than Fe solubility (%FeS) at 0.3% and 0.1% in the corresponding particulate sizes. Additionally, %FeS correlated more strongly with sulfate and nitrate per unit Fe mass (R2 = 0.68 and 0.79 in PM2.5 and PM10) than %MnS (R2 = 0.49 and 0.50), suggesting a more profound impact of acidification on Fe dissolution. Further analysis suggests liquid water content rather than pH played a more critical role during the acidification process within fine particles. This study successfully estimated the solubility of Fe and Mn within various aerosols, providing valuable information and advancing our understanding of their dissolution and potential health and ecosystem impacts.

Complex Hygroscopic Behavior of Ambient Aerosol Particles Revealed by a Piezoelectric Technique.

Understanding the complex interactions between atmospheric aerosols and water vapor in subsaturated regions of the atmosphere is crucial for modeling and predicting aerosol-cloud-radiation-climate interactions. However, the microphysical mechanisms of these interactions for ambient aerosols remain poorly understood. For this study, size-resolved samples were collected from a high-altitude, relatively clean site situated in the Western Ghats of India during the monsoon season, in order to study background and preindustrial processes as a baseline for climate functioning within the context of the most polluted region of the world. Measurements of humidity-dependent mass-based growth factors, hygroscopicity, deliquescence behavior, and aerosol liquid water content (ALWC) were made by a novel approach using a quartz crystal microbalance based on a piezo-electric sensor. The climate-relevant fine-mode aerosols (≤2.5 μm) exhibited strong size-dependent variations in their interactions with water vapor and contributed a high fraction of ALWC. Deliquescence occurred for relatively large aerosols (diameter >180 nm) but was absent for smaller aerosols. The deliquescence relative humidity for ambient aerosols was significantly lower than that of pure inorganic salts, suggesting a strong influence of organic species. Our study establishes an improved approach for accurately measuring aerosol water uptake characteristics of ambient aerosols in the subsaturated regime, aiding in the assessment of radiative forcing effects and improving climate models.

Field evidence of brown carbon absorption enhancement linked to organic nitrogen formation in Indo-Gangetic Plain

Atmospheric brown carbon (BrC), a short-lived climate forcer, absorbs solar radiation and is a substantial contributor to the warming of the Earth's atmosphere. BrC composition, its absorption properties, and their evolution are poorly represented in climate models, especially during atmospheric aqueous events such as fog and clouds. These aqueous events, especially fog, are quite prevalent during wintertime in Indo-Gangetic Plain (IGP) and involve several stages (e.g., activation, formation, and dissipation, etc.), resulting in a large variation of relative humidity (RH) in the atmosphere. The huge RH variability allowed us to examine the evolution of water-soluble brown carbon (WS-BrC) diurnally and as a function of aerosol liquid water content (ALWC) and RH in this study. We explored links between the evolution of WS-BrC mass absorption efficiency at 365 nm (MAEWS-BrC-365) and chemical characteristics, viz., low-volatility organics and water-soluble organic nitrogen (WSON) to water-soluble organic carbon (WSOC) ratio (org-N/C), in the field (at Kanpur in central IGP) for the first time worldwide. We observed that WSON formation governed enhancement in MAEWS-BrC-365 diurnally (except during the afternoon) in the IGP. During the afternoon, the WS-BrC photochemical bleaching dwarfed the absorption enhancement caused by WSON formation. Further, both MAEWS-BrC-365 and org-N/C ratio increased with a decrease in ALWC and RH in this study, signifying that evaporation of fog droplets or bulk aerosol particles accelerated the formation of nitrogen-containing organic chromophores, resulting in the enhancement of WS-BrC absorptivity. The direct radiative forcing of WS-BrC relative to that of elemental carbon (EC) was ∼19 % during wintertime in Kanpur, and ∼ 40 % of this contribution was in the UV-region. These findings highlight the importance of further examining the links between the evolution of BrC absorption behavior and chemical composition in the field and incorporating it in the BrC framework of climate models to constrain the predictions.

Water management and mass transport of a fractal metal foam flow-field based polymer electrolyte fuel cell using operando neutron imaging

Metal foam flow-fields (MFFs) exhibit immense potential for enhancing the performance of polymer electrolyte fuel cells (PEFCs) owing to their advantageous pore connectivity and abundant gas pathways. Nevertheless, challenges remain with the conventional MFF concerning reactant homogeneity and water management. To address these concerns, this study incorporates a fractal manifold into the MFF design. By employing operando neutron imaging, device-level testing, and electrochemical impedance spectroscopy (EIS), a comprehensive understanding of mass transfer and water management characteristics across the fractal manifold MFF is obtained. This novel design delivers better cell performance and lower mass transport resistance compared to the conventional MFF under all experimental conditions investigated. Notably, neutron imaging reveals that the fractal manifold MFF consistently exhibits a reduced liquid water content and more uniformly distributed liquid water compared to the conventional MFF. These superior characteristics of the design contribute to a substantial ∼15% increase in maximum power density compared to the conventional MFF-based PEFC. The results indicate the potential for further performance improvement by optimizing manifold parameters.

Size-resolved water-soluble organic carbon and its significant contribution to aerosol liquid water

Size-segregated aerosols collected in Beijing from 2021 to 2022 were used to investigate the contribution of organic aerosols to the aerosol liquid water content (ALWC), the influencing factors of ALWC, and the concentrations and size distribution characteristics of water-soluble organic carbon (WSOC) after clean air actions. The results showed that the concentration of WSOC in particulate matter (PM)1.8 was 3.52 ± 2.43 μg/m3 during the sampling period. Obvious changes were observed in the size distribution of WSOC after clean air actions, which may be attributed to the enhancement of atmospheric oxidation capacity and the decrease in PM concentration. The contribution of organic aerosols to the ALWC in fine PM was 18.1 % during the sampling period, which was more significant at lower particles concentration and smaller particle size ranges. The ambient relative humidity (RH) and the ratio of NO3−/SO42− had an apparent influence on ALWC. The continuous increase in the nitrate proportion significantly reduced the deliquescence point of the aerosols, making them prone to hygroscopic growth at lower RH. Analysis of the relation among nitrogen oxidation ratio (sulfur oxidation ratio), ALWC and PM1.8 mass concentrations suggests that organic matter has a significant effect on the formation of secondary inorganic aerosols in the initial phase of pollution formation and plays a crucial role in aerosol pollution formation in Beijing. These results are conducive to understanding the formation mechanism of aerosols and provide scientific data and theoretical support for the formulation of more effective emission-reduction measures.

In-Situ-Generated Fluoride-Assisted Rapid Dissolution of Uranium Oxides by Ionic Liquids.

A quantitative, rapid, endothermic dissolution of U3O8 in C4mim·PF6 (1-alkyl-3-methyl imidazolium hexafluorophosphate) has been achieved within 2 h at 65 °C by in situ generated fluoride ions by pre-equilibrating the ionic liquid with suitable concentrations of nitric acid. The efficiency of the dissolution followed the trend: UO3 > UO2 > U3O8. The fluoride generation was found to increase with the concentration of nitric acid being equilibrated, the water content of the ionic liquid, and also the time of equilibration. The rate of dissolution of U3O8 followed the trend: C4mim·PF6> C6mim·PF6 > C8mim·PF6. The maximum loading observed for the present case was 200 mg mL-1 which is considered to be quite high with an ionic liquid. The effects of different acid pre-equilibration (HClO4, HCl) on F- generation and subsequent dissolution characteristics have also been investigated. The in situ F- generation, as well as U3O8 dissolution, were found to predominantly follow a pseudo-second-order rate kinetics, while the rate constants for U3O8 dissolution were found to be higher than that of F- generation. The dissolved uranium was successfully electrodeposited on a Cu plate, as confirmed by EDXRF, while the formation of UO2 was revealed from the XRD pattern of the deposit.

A parametric study on the effect of liquid water content and droplet median volume diameter on the ice distribution and anti-icing heat estimation of a wind turbine airfoil

This study uses an icing model, combining heat transfer with fluid flow and considering the roughness effect, to investigate the influence of liquid water content (LWC) and droplet median volume diameter (MVD) on the ice distribution and anti-icing heat estimation of a wind turbine blade airfoil through the numerical approach. The findings indicate that the simulated ice distribution can have excellent agreement with experimental data. Owing to variations of droplet collection efficiency and heat flux, the increase in LWC and MVD will amplify the fluctuations in ice accretion distribution, which will be prone to ice horns. Owing to high LWC increasing water film flow range, the jumping point of anti-icing heat flux is closer to the trailing edge. Owing to large MVD increasing droplet collection efficiency, the quantity of ice accumulation through solidification ascends to demand higher anti-icing heat flux. The peak anti-icing heat flux is more evidently influenced by LWC than that by MVD, due to the variations in heat flux, induced by water film evaporation and solidification. The findings offer valuable insights into the flow and heat transfer physics for wind turbine anti/de-icing design.

Impact of the tilted cloud vertical structure on a northward-progress episode of the East Asian summer monsoonal precipitation belt

Impact of cloud vertical structure (CVS) on a northward-progressing rainfall episode of the East Asian summer monsoon (EASM) is explored using the Weather Research and Forecasting model, in which CloudSat observation-based vertical structure of cloud liquid water content (LWC) can be imposed. Composite LWC anomaly from CloudSat data shows a northward tilted structure from the upper to the lower troposphere. Compared to the control simulation (without modification of LWC), the one with LWC imposed, but without tilted structure, doesn’t show significant changes. When LWC is introduced and northward tilted, the geopotential height (HGT) decreases in the north of the convective center, which increases the meridional wind and provides favorable conditions for the northward shift of the precipitation belt. When LWC is southward tilted, HGT decreases in the middle and lower troposphere in the south of the convective center and increases in the north, which slows down the northward shift of the precipitation belt. Adding cloud water leads to increase in humidity and decrease in temperature, causing significant increase in stratiform clouds and related precipitation. In the configuration of northward tilted LWC, low-temperature and high-humidity area is located on the north side of the convective center, favorable for the occurrence and northward shift of the precipitation belt. Deep convection is weakened with convective precipitation reduced, while shallow convection enhances the latent heat release in the lower troposphere. Therefore, more water vapor and energy are transported from boundary layer to free atmosphere, promoting the northward shift of the precipitation belt.