Liquid Research Articles

Development of a Method for Utilization of Quarry Drainage Waters of a Limestone Mine to Ensure Environmental Safety

A method has been developed for the disposal of quarry drainage waters, which ensures that they are not discharged into an open reservoir and reduce their anthropogenic impact on the environment. The direction of drainage waters from the limestone quarry into the technological process of preparing the raw charge reduces the consumption of circulating soda solutions and ensures higher extraction of potassium sulfate from soda solutions. The average increase in the yield of potassium sulfate from an increase in the content of sulfates in the liquid phase of the raw nephelinelimestone-soda charge is 4.0 tons per day or 1,460 tons per year.

Characterization of Electron Beam Effects in Liquid Phase TEM Study of Chemical Processes

Characterization of Electron Beam Effects in Liquid Phase TEM Study of Chemical Processes

Discovering Nanoparticle Formation Mechanisms and Molecular Intermediates with Liquid Phase Electron Microscopy and Reaction Networks

Discovering Nanoparticle Formation Mechanisms and Molecular Intermediates with Liquid Phase Electron Microscopy and Reaction Networks

Evaluating a green liquid phase plasma discharge process and working mechanism for remediating cobalt contamination in water

Cobalt is a toxic heavy metal contaminant in water and wastewater causing health concerns and on the other hand, a valuable element to recycle. In this study, performance of a novel and green continuous liquid phase plasma discharge (CLPD) process was investigated for removal and recovery of cobalt from aqueous solution without use of any catalysts or chemicals. The CLPD reactor design features two conductive channels and stable electric discharge at the orifice of two dielectric plates sandwiched among the electrodes. The effects of operating factors of the CLPD process were evaluated with liquid flow rate (25–100 mg/L) and applied power (200–300 W), and the highest removal efficiency of cobalt (93 %) was obtained within 25 min at a 50 ml/min liquid flow rate and 300 W applied power. The CLPD energy efficiency for cobalt removal under this condition was 27.44 g kW-1h−1. Reaction kinetics with scavenger tests revealed that oxidative reactive species, i.e., hydroxyl radical and superoxide radicals, produced at the discharge zone were responsible for cobalt removal from water by producing cobalt oxide particles and the reaction pathways were proposed. The CLPD process not only allowed for the efficient removal of cobalt (II) from water but also synthesized cobalt oxides particles with averaged size of 2.75 µm, which can be applied as catalyst. The overall results indicated that the novel CLPD is a robust and highly effective process to remove and recover cobalt from water.

New Approaches Towards Visualization of Biological Samples by the Means of Liquid Phase TEM

New Approaches Towards Visualization of Biological Samples by the Means of Liquid Phase TEM

Few-layer NbTe2 nanosheets-based saturable absorber for generating 176 fs pulse at 1 μm in ultrafast fiber laser

Ultrafast fiber lasers play an increasingly vital role in diverse fields of science and industry. In this study, a novel NbTe2 nanosheet-based saturable absorber (SA) was prepared by using liquid phase exfoliation and flame brush technology for the first time. Using a twin balance measurement system, the nonlinear optical absorption property was checked. It was found that the fabricated NbTe2 nanosheets-based SA has excellent saturable absorption properties with a large modulation depth of 5.3 %, a very high saturation intensity of 1.11 GW/cm2, and a low non-saturation loss of 63.6 %. After inserting the NbTe2 nanosheets-based SA into a ring-cavity ytterbium-doped fiber laser (YDFL), a stable soliton mode-locking state was achieved. A 176-fs ultrafast soliton pulse train was successfully generated at 1029.76 nm with the repetition rater of 3.097 MHz. Thanks to the unique and very high saturation intensity of NbTe2 nanosheets, the proposed YDFL system achieved a maximum peak power of 96.3 kW and a single pulse energy of 14.09 nJ under 370 mW pump power. These findings indicate that NbTe2 nanosheets have great potential for generating ultra-short optical pulses with higher peak power in mode-locked fiber lasers.

Understanding and Predicting the Thermodynamic Behavior of Fission Products Encountered Between the (U,Pu)O2 Fuel Pellet and the Cladding: Characterization and Modeling Approaches

AbstractThis study provides a comprehensive investigation of the formation and behavior of a layer enriched in fission products encountered between the (U,Pu)O2 fuel pellet and the cladding, designated as JOG (“Joint Oxyde Gaine” in French). Employing a multifaceted approach that combined thermodynamic calculations, experimental synthesis, and advanced characterization techniques, simulated JOG has been synthetized (without radioactive fission products). Using thermodynamic calculations with the TAF-ID database, the phase compositions in the JOG was assessed for various temperatures, pressures, and oxygen potential conditions, revealing insights into the environmental factors influencing JOG formation. Experimental simulation of the JOG composition, exposed to controlled conditions, confirmed the presence of key compounds such as Cs2MoO4, CsI, and PdTe, as evidenced by SEM, EDS, and XRD analyses. The results of the calculations highlighted notable differences in the nature of the phases constituting the JOG under varying pressure and oxygen potential conditions. At 873 K and oxygen partial pressure of 10–4 bar, Cs2MoO4, Pd–Te, and a gas phase rich in tellurium and CsI were predominant, contrasting with the emergence of liquid phases at 70 bar. This study offered a comprehensive understanding of JOG microstructure, and highlighting the importance of accurate characterization for reactor safety. This information lays the foundations for future studies on the chemical interaction between the JOG and the steel cladding.

Build-up formation in cement kiln preheater: qualitative and quantitative mineral characterization

Extracting more information about reactions and parameters governing the build-up formation process, in the preheater system of the clinker burning line, could be an efficient tool to better attenuate their formation. In order to control their appearance, diagnosis steps of mineralogical analysis application for process optimization (MAA-PO) are suggested. Mineralogical characterization is carried out on three samples taken from different layers of the same build-up. The qualitative and quantitative X-ray diffraction, combined with chemical analysis and IR study, shows that Ternesite is the key mineralogical phase responsible for their growth and consolidation. Its appearance is governed by solid-solid reactions promoted by the available sulfate liquid phases, mainly Ca –langbeinite, as well as C12A7 and C4AF presence. The hot powder calcination degree, SO3 amount, LSF, SR and MA are operational data that have been correlated to the build-up mineralogical analysis. Based on this correlation, it is possible to predict the reactions kinetics involving in each layer formation and to estimate the development time of each. Results showed that MAA-OP is a promised novel approach to optimize clinker production process parameters.

The effect of swirling shear blade on gas-liquid flow pattern and mass transfer performance in Venturi injector

To address the challenge of low mass transfer efficiency of gas-liquid reaction in traditional reactors, this study proposes a new method to improve the gas-liquid mass transfer efficiency by integrating swirl shear blades (SSB) into Venturi injectors. The gas-liquid flow patterns in the mixing and diffusion sections between the Swirl Venturi Injector (SVI) and the Traditional Venturi Injector (TVI) was compared, and it was found that the SSB significantly reduced the proportion of annular flow while increased the proportion of mist flow. The enhancement factor αE and the acceleration factor αA are applied to evaluate the mass transfer performance. Compared to TVI, the maximum αA of SVI was 29%, and the maximum αE was 43%. This work shows great potential in efficiently capturing gas components with low solubility in the liquid phase, thereby helping to achieve the goal of green chemical engineering.

Effect of rare earth element on H13 microscopic structure and mechanical properties

In view of the phenomenon that irregular inclusions are easy to use as crack sources, rare earth H13 steel with different gradients is designed. The results showed that ellipsoidal rare earth inclusions (Ce2O3, CeAlO3 and Ce2O2S) were formed from irregular Al2O3 inclusions with the assistance of rare earths. The carbides that precipitated from liquid phases were arranged in a network along the grain boundary, forming composite carbides that are rich in Mo and V. Along the grain boundary, the morphology of the composite carbides got finer, and MC-type carbides enclosed the modified inclusions into nuclei, facilitating their precipitation. After annealing, the microstructure revealed that the carbides were dispersed in black segregated patches along the grain boundary and were discontinuous. The average diameter of carbides decreased from 109.7 to 79.2 nm in the same region according to a statistical comparison of the number of carbides before and after the addition of rare earth elements. The carbides were distributed alongside primary carbides as tiny particles of M7C3 and M23C6 secondary carbides. Especially when the rare earth content was 0.032 wt-%, the impact toughness increased to 34%. This work offers a reference value for the practical application of rare earth in hot work die steel in addition to revealing the strengthening mechanism of ultra-high strength RE-13 steel.

Simultaneous close-contact melting on two asymmetric surfaces: Demonstration, modeling and application to thermal storage

The present study deals with melting in a geometry suitable for Latent-Heat Thermal Energy Storage (LHTES) systems, which are of importance for future industrial installations utilizing solar energy or waste heat. The intrinsically high thermal resistance of phase-change materials (PCM) can be remedied by taking advantage of close contact melting (CCM), where the solid phase is separated from a hot surface by only a thin liquid layer. The basic CCM takes place on a horizontal flat surface, but during the last decade its application in various finned LHTES units has been demonstrated experimentally and analyzed numerically.Specifically, the configuration studied in the present work is relevant to a horizontal double-pipe concentric storage unit with a longitudinally finned inner tube. While this rather simple geometry has been extensively studied in the past, the present work is completely novel in its demonstration and analysis of simultaneous close-contact melting on two generally asymmetric surfaces created by the longitudinal fins. A unique experimental apparatus is introduced, based on the so-called 'Mercedes' configuration of the fins. It is designed transparent, allowing for real-time observation of melting sequences. Close-contact melting is achieved by supplying heat to the outer shell of the unit: the solid phase is detached from the shell and moves, by translation and rotation, in the liquid phase. The results from these experiments demonstrate the feasibility of CCM on two asymmetric walls within this system, hinting at the potential for optimizing the melting rate by utilizing a larger portion of the extended surface for CCM.A key component of this study is the development of a reliable numerical approach, which goes beyond the limitations of widely-applied enthalpy-porosity method and combines the general enthalpy formulation, convective heat transfer and general rigid body motion that includes rotation. Therefore, a new numerical model has been devised, using an in-house code realized in MATLAB. A full set of the governing conservation equations is solved using a finite-difference framework, integrated with advanced numerical methods for the fluid-solid interaction and an enthalpy formulation for the phase change process. The model is validated carefully, and then numerical studies are conducted to elucidate the melting process.The present paper presents a further proof of the special role that close-contact melting (CCM) can play in properly designed thermal energy storage units and finned systems in general. It is demonstrated that the fins, when properly designed and oriented, can induce CCM in their vicinity, contributing to a very significant increase in the melting rate, which reflects charging of the unit.

Effect of current intensity on molten pool and solidification in vacuum arc remelting process of Ti60 alloy

Current intensity is a critical parameter in the vacuum arc remelting (VAR) process, significantly impacting the molten pool, solidification structure, and ultimately, the quality of the ingot. This study establishes a transient electromagnetic-fluid-thermal-solidified coupled model to examine the effects of current intensity on the shape of molten pool and the solidification process of Ti60 alloy ingots produced by VAR process. Findings indicate that with the increase in current intensity, there is a corresponding rise in the magnetic induction intensity, current density, and Lorentz force. This enhancement leads to more vigorous flow in the liquid phase, creating a vortex flow opposing to the ingot's center at the boundary, influenced by the strong current. As a consequence, the molten pool's shape tends to shift from a “V” shape to a “U” shape, and the depth of molten pool increases while the mushy zone thickness diminishes. For instance, at 17000 A, the depth of molten pool surges by 57.43%, and the mushy zone thickness contracts by 62.01% compared to 5000 A. Over time, the depth of molten pool gradually decreases, with its reduction range ( Δh) within 400 to 6000 s inversely related to current intensity. At 17000 A, Δh is 23.71% less than at 5000 A. Furthermore, elevating the current intensity results in a higher temperature gradient within the ingot and a marked reduction in local solidification time, particularly in the ingot's central area.

Contemporary roof pattern for energy efficient buildings: Air conditioning cost alleviation, CO2 emission mitigation potential and acceptable payback period

Buildings account for a significant portion of global energy use and consumption. Buildings have substantial energy consumption due to the use of heating, ventilation, and cooling systems. It is evident that the use of insulation materials and phase change materials (PCMs) in the design of buildings can effectively reduce the cost of air conditioning by reducing external heat gains and losses. Additionally, the use of environmentally friendly, cost-effective, and natural materials can be beneficial from an environmental standpoint. This paper aims to evaluate the potential for cost savings in the air conditioning of various PCMs and insulation-stuffed building roof configurations. In that respect, four types of phase change materials (HS29, HS36, FS42, and FS30) and four insulation materials (Therma cork, sawdust, aerogel, and sheep wool) were selected. The thermophysical properties of PCMs (solid and liquid state), insulation materials, and building elements were determined experimentally as per ASTM D 5334 standards. Ten various building roof models (contemporary roof pattern) are studied with four various PCMs and four various insulations. In addition, novel building roof design integrated with PCM/insulation were analysed numerically, related to environmental conditions that refer to two different scenarios in India (hot dry and composite climates). It further analyses the reduction in greenhouse gas emissions associated with different roof configurations. The aforementioned PCM/insulation materials were stuffed in the void spaces of the contemporary roof pattern. Thermo-economic analysis of novel roof design with PCM/insulation materials on air-conditioning costs, carbon dioxide emissions and payback time are compared with conventional roofs (CR) and contemporary roof patterns (CRP). The thermo-economic analysis was carried out based on the number of degree-hours of heating and cooling to determine the building's annual energy usage. HS29 PCM stuffed roof pattern (HS29RP) saved the highest total energy cost savings of 11.89/14.71 $/m2/year when compared with conventional roof and 11.35/13.89 $/m2/year compared with contemporary roof pattern for Jabalpur/Kota climatic conditions. HS29 PCM stuffed roof pattern (HS29RP) exhibits the maximum carbon emission mitigation of 215.32/275.37 kg/kWh when compared with conventional roof and 204.95/259.57 kg/kWh for climatic conditions of Jabalpur/Kota. While considering shortest payback span, sawdust stuffed roof pattern shows the minimum payback period of 0.69 and 2.15 years when compared with conventional roof and contemporary roof pattern. The findings of this research offer significant contributions to the development of energy-efficient building envelopes applicable to a wider range of buildings, including those with and without air conditioning systems.

Carbon dioxide capture by aqueous glucosamine solutions: Pilot plant measurements and a theoretical study

AbstractA comprehensive investigation of the potential of aqueous glucosamine solutions as an eco‐friendly solvent for CO2 capture was performed. It includes an experimental study in a pilot plant setup and a theoretical analysis with a rate‐based model. The model was validated against the measured column profiles of temperature and CO2 concentration in both liquid and gas phases. Model‐based parameter sensitivity studies revealed inherent challenges for an effective absorption process. A slow reaction rate and suboptimal chemical equilibrium conditions were identified as key limitations, restricting the absorption efficiency and CO2 loading capacity of the glucosamine solution. Furthermore, an analysis of the dissociation constant of this novel absorbent was performed and its significance with respect to the (limited) performance, capability, and efficiency evaluation was highlighted.

Ab Initio Prediction of Vapor Pressure for Diverse Atomic Layer Deposition Precursors.

Understanding the saturated vapor pressure (Pvap) is vital for evaluating atomic layer deposition (ALD) precursors, as it directly influences the ALD temperature window and, by extension, the processability of compounds. The early estimation of vapor pressure ranges is crucial during the initial stages of novel precursor design, reducing the reliance on empirical synthesis or experimentation. However, predicting vapor pressure through computer simulations is often impeded by the scarcity of suitable empirical force fields for molecular dynamics simulations. This challenge is further compounded by the diverse chemical substances and the introduction of new elements into modern ALD processes, necessitating robust force fields that can accommodate metals, organics, and halides. In response, this study introduces a novel approach utilizing a quantum mechanically derived force field for the prediction of vapor pressure across a wide spectrum of potential ALD precursors. This approach enables the creation of system-specific force fields through parametrization based on ab initio calculations for a single molecule. We develop a comprehensive workflow to simulate both liquid and gaseous equilibrium phases, allowing the calculation of vapor pressure across a wide temperature range. Our methodology has been validated with a diverse set of ALD precursors, demonstrating its robustness in predicting Pvap at specified temperatures. The approach yields a Pearson's correlation coefficient (R2) greater than 0.9 on a logarithmic scale and a root-mean-squared deviation in self-solvation-free energies as low as 1.3 kcal mol-1. This innovative workflow, which does not require any prior experimental data, marks a significant advancement in the computer-aided design of novel ALD precursors, paving the way for accelerating developments in technology.

A Cartridge Structure Facilitates Clinical Mass Spectrometry Pretreatment and Can be Integrated Into a High‐Throughput Instrument

ABSTRACTLiquid chromatography–triple quadrupole mass spectrometry (LC–MS/MS) is becoming an increasingly essential analytical technique in many fields, such as food, environmental, biochemical, pharmaceutical, and clinical chemistry. The testing matrices, such as plasma and serum, cannot usually be sent directly to the LC–MS/MS system because of the large number of unrelated substances in addition to target analytes in samples, such as cells, tissues, and proteins. Protein precipitation (PPT) is the most utilized pretreatment method in clinical analysis because of its ease of use; its performance always involves the separation of the liquid phase from the solid phase, in which the most commonly used manipulation is centrifugation. However, there is an upper limit of throughput for centrifugation, and the cost and difficulty of integrating centrifugation into automatic equipment are usually high. To solve the drawbacks of the current PPT method, we developed a cartridge structure that can omit the centrifugation step in PPT, which, in turn, can facilitate the incorporation of the PPT method into an automatic clinical pretreatment procedure for LC–MS/MS. We used vitamin D analysis as a representative application in our endeavor to develop a centrifugation‐free PPT method that can be easily applied to a new automatic clinical pretreatment procedure.

Wafer Level Vacuum Packaging of MEMS-Based Uncooled Infrared Sensors

This paper introduces a cost-effective, high-performance approach to achieving wafer level vacuum packaging (WLVP) for MEMS-based uncooled infrared sensors. Reliable and hermetic packages for MEMS devices are achieved using a cap wafer that is formed using two silicon wafers, where one wafer has precise grating/moth-eye structures on both sides of a double-sided polished wafer for improved transmission of over 80% in the long-wave infrared (LWIR) wavelength region without the need for an AR coating, while the other wafer is used to form a cavity. The two wafers are bonded using Au-In transient liquid phase (TLP) bonding at low temperature to form the cap wafer, which is then bondelectrical and Electronics d to the sensor wafer using glass frit bonding at high temperature to activate the getter inside the cavity region. The bond quality is assessed using three methods, including He-leak tests, cap deflection, and Pirani vacuum gauges. Hermeticity is confirmed through He-leak tests according to MIL-STD 883, yielding values as low as 0.1 × 10−9 atm·cc/s. The average shear strength is measured as 23.38 MPa. The package pressure varies from 133–533 Pa without the getter usage to as low as 0.13 Pa with the getter usage.

Numerical simulation of non-stationary regime of a submerged combustion setup operation

Relevance. The need to evaporate large quantities of brines at potash industry enterprises. Evaporation of brines in surface evaporators is difficult due to the encrustation of heat exchange surfaces by salt deposits. Therefore, such evaporation is most expedient to be carried out in submerged combustion apparatuses, since they do not contain heat-transmitting surfaces. However, in this type of apparatus, malfunctions may occur due to uncontrolled solid phase deposition. At the moment, the dynamics of the solid phase in submerged combustion devices is poorly studied. This study is part of a scientific program aimed at a comprehensive review of the laws of motion of solid particles in submerged combustion apparatuses. Aim. To study the hydrodynamic processes in the submerged combustion setup in the time interval corresponding to the beginning of its operation; describe the patterns of solid phase motion as a function of time. Object. Laboratory setup of submerged combustion. A simplified model of the thermal mode of operation without the subsequent transition of the liquid phase to steam is analyzed. Methods. The study was conducted by numerical experiment. The hybrid finite volume method was used in simulation in combination with the technology of the finite element method. The multiphase system was considered as two coexisting subsystems: gas–liquid and liquid–solid. Results. The paper considers the final time interval of the setup operation. It is found that during the time under consideration, a stationary mode of solid particle deposition is achieved. The authors have detected liquid flow velocity oscillations, leading to fluctuations in the mass flow rate of solid particles at the bottom of the setup. It was found that the velocity at the tip of the flue gas jet escaping from the burner nozzle, as well as the pressure at the nozzle section, have a similar form of oscillation. The authors substantiated the hypothesis about the determining influence of the instability of the jet movement of flue gases on the oscillatory behavior of the entire hydrodynamic system.

Development of an ecofriendly dispersive liquid phase microextraction method for the preconcentration of β-blockers in waste and environmental samples

Effective sample preparation is crucial in instrumental analysis to enhance selectivity, sensitivity, and instrument protection. The current trend of miniaturization in liquid–liquid extraction aims to conserve solvents and promote environmental sustainability. Liquid phase microextraction, requiring only small volumes of the extractant, facilitates sample preconcentration without the need for evaporation and reconstitution. This study presents the development of an eco-friendly dispersive liquid–liquid microextraction method employing solidification of floating organic droplets for the determination of five β-blocker drugs in waste and environmental samples. The optimization of key variables affecting extraction efficiency, including extractant type and volume, pH of the diluent, dispersion technique, vortexing, and centrifugation time, was carried out. Optimal results were achieved using 50 μL of dodecanol as the extractant, 1 min of vortexing for dispersion, followed by 2 min of centrifugation for phase separation. The sample was then subjected to a 5 min cooling in an ice bath to solidify the dodecanol before UHPLC/UV analysis. The method yielded enrichment factors within the range of 23–55. The applicability of this approach was demonstrated in laboratory waste and environmental water analysis, with acceptable % recoveries ranging from 98.07 % to 101.83 % and %RSD below 1.96. Moreover, we assessed the method’s performance and greenness with ComplexGAPI, BAGI, and carbon footprint. This method not only provides high efficiency and reliability but also aligns with the principles of sustainablility.

The myth of high-resolution liquid phase biological electron microscopy.

Cryo-electron microscopy (cryo-EM) has transformed structural biology over the past 12 years, with it now being routine rather than exceptional to reach a near-atomic level of resolution for proteins and macromolecular complexes. Samples are immobilized by vitrification and this sample can be maintained at liquid nitrogen temperatures in the vacuum of the electron microscope with negligible sublimation. Due to the low electron doses needed to avoid radiation damage, averaging over tens of thousands to hundreds of thousands of particle images is used to achieve a high signal-to-noise ratio. An alternative approach has been proposed where samples are at room temperature in the liquid state, maintained in the vacuum of the electron microscope by thin film enclosures that are relatively transparent to electrons while preventing evaporation of the liquid. A paper has argued that using this liquid-phase approach, higher resolution (3.2 Å) can be achieved than using cryo-EM (3.4 Å) when imaging and reconstructing adeno-associated virus particles. I show here that these assertions are untrue, and that basic principles in mathematics and physics would need to be violated to achieve the stated resolution in the liquid state. Thus, high resolution liquid phase EM of macromolecules remains science fiction.