Petroleum Gas Research Articles

Intensified biogas to liquid (IBGTL) Process: Experimental validation and modeling analysis

The Intensified Biogas to Liquid (IBGTL) process aims to overcome traditional economy-of-scale barriers in biogas-to-liquid fuel production by integrating bi-reforming and Fischer-Tropsch synthesis (FTS) in a single IBGTL reactor. This reactor operates at uniform pressure with different optimized temperatures across two zones for efficient conversion, utilizing multifunctional bi-reforming catalysts and high-temperature FTS catalysts.Bench scale experiments were carried out using landfill gas (LFG) in a single pass process, and the yield data from these experiments were fed into process scale-up design and techno-economic analysis (TEA) across four scenarios: (1) a single pass process, (2) a process with material recycling, (3) a process with liquefied petroleum gas (LPG) co-product recovery, and (4) a process with electricity generation from the fuel gas produced. TEA identified Scenario 2 as the most cost-effective, achieving a Minimum Fuel Selling Price (MFSP) of $4.59 per gallon, competitive with the current national diesel price of $4.7 per gallon. However, comparison with the conventional two-reactor system highlights the need for catalyst performance improvements.Sensitivity analysis emphasized the importance of manufacturing cost, liquid fuel yield, and biogas flow rate. Further analysis determined that the IBGTL process must achieve a diesel mass yield beyond 11.7% to surpass the economic viability of the conventional TriFTS (Tri-reforming followed by Fischer-Tropsch Synthesis) process. If the IBGTL process attains the TriFTS yield of up to 17%, the resulting MFSP could be approximately 31% lower than the current TriFTS MFSP. Renewable energy credits and carbon credits can further enhance the economic viability of BGTL processes.

Characterization of fresh biowastes for biogas production and environmental health in Niger Delta, Nigeria

BackgroundEnvironmental pollution is a public health problem in Niger Delta, Nigeria. Therefore, the aims of the present study were to: identify the major fresh biowastes in Bayelsa State, Niger Delta; quantify the biogas yields from mono-digestion and co-digestion of identified biowastes; determine the first day of biogas production during hydraulic retention time; assess pH variations during anaerobic digestion; and evaluate biogas flame colours.MethodsFifteen communities in Bayelsa State were randomly selected, and on-the-spot assessment and quantification of the biowastes found in each community were carried out daily per week. Mono-digestion of 20 kg of each biowaste and co-digestion of 10 kg of animal waste with 10 kg of plant waste were carried out respectively under anaerobic conditions. Cumulative biogas yield and pH were measured using a pH meter and weighing scale respectively. Biogas flame colours during combustion were visually assessed.ResultsExactly 120.61 metric ton of fresh biowastes was found to be generated per week in Bayelsa State, Niger Delta. Industrial biowastes were the highest [47.6 tonnes, (39.46%)], followed by abattoir biowastes [33 tonnes (27%)], market and roadside sellers biowastes [25.5 tonnes (21.14%)], and farm biowastes [14.51 (12.03%)]. Biogas yields (kg) were: 0, 0, 0, 0, 0, 17, 14, 2, 18, 16, 17, 15 and 1 kg for palm oil mill effluent (POME), orange fruit waste (OFW), pineapple peels (PP), plantain peels, cassava mill effluent (CME), rumen digesta (RD), cow dung, sewage, PP-RD, plantain peels-cow dung, POME-rumen digesta, OFW-cow dung, and CME-sewage respectively. The first day of biogas production for RD, cow dung, sewage, PP-RD, plantain peels-cow dung, POME-RD, OFW-cow dung, and CME-sewage was on the 6th, 32nd. 56th, 1st, 26th, 18th, 25th, and 60th day of hydraulic retention time respectively. A dominant blue flame colour mixed reddish yellow or orange flames were found during biogas combustion. A slight increase in pH was found in all the biodigester media.ConclusionsIn the present study, a variety of biowastes yielding various quantities and qualities of biogas were identified in Bayelsa State, Niger Delta. The study’s findings have provided evidence-based data that might be explored as a road map and catalyst for policy creation against inadequate biowaste management and as sustainable alternatives to the expensive liquefied petroleum gas. The potential of current research study to be scaled up for commercial use is implicated in the present study.

Automated LPG Monitoring and Rebooking System using IoT- A Review

LPG (Liquified Petroleum Gas) has become an essential requirement in daily life, as many people rely on it for cooking, fueling vehicles, and more LPG offers a portable, clean, and efficient alternative to traditional fossil fuels, making it especially valuable for rural and urban areas in India. By replacing wood, coal, and other traditional fuels, LPG enhances health, air quality, and overall comfort. To simplify the LPG rebooking process for domestic and commercial use, various applications have been developed. This study presents a brief overview of existing research on LPG monitoring systems and proposes a method for automatic rebooking by monitoring LPG consumption in real-time and triggering an automatic refill request when the gas level reaches a predefined threshold. The system also provides users with notifications and updates about the status of the LPG, further enhancing convenience and reliability.

Experimental concerning the influence upon gaseous emissions by using HHO addition to an LPG powered Otto engine

Abstract Because of the increased pollution regulations imposed on internal combustion engines across the world as well to preserve the air quality, effective solutions for new and older cars must be found in reference to their emission levels. This paper focuses on the impact of adding oxyhydrogen (HHO) fueled into an Otto engine working with liquefied petroleum gas (LPG), in reference to the emission concentration values. HHO is produced using a water electrolytic conversion technique that works in tandem with the Otto engine. The electrolytic convertor can generate 1,800 litters of HHO gas from 1 liter of water. Due to this addition, the total calorific power of the fuel mixture is growing by around 30 % in comparison to only LPG fueled situation, considered as basic one. All measurements were conducted in a laboratory with accredited and approved gas analyzers and measuring devices. The study presents comparative results of the basic measurements, at an engine speed of 800 rotations per minute (RPM) and respectively at 2,000 RPM, when using an LPG as fuel, respectively a mixture LPG and HHO. As conclusion, one proves that the addition of HHO can generate as effect the decreased of particular emission values.

3D hollow mesoporous α-Fe2O3 sensor detecting liquified petroleum gas and humidity for diagnosing sleep hypopnea-apnea syndrome

Sensors utilizing mesoporous materials have garnered significant interest; however, they are primarily designed for detecting a single analyte. In this study, we successfully synthesized a three-dimensional (3D) hollow mesoporous α-Fe2O3 using a nanocasting process for the purpose of sensing LPG and humidity. The α-Fe2O3 obtained in this study maintained the cubic framework structure of MCM-48, demonstrating a mesoporous and hollow architecture. The Liquified Petroleum Gas (LPG) sensing characteristics of mesoporous α-Fe2O3 were examined at different operating temperatures (170–210 °C). The gas sensing response was optimized 99.3 % at 190 °C and the response/recovery time comes out to be 11.79 s & 0.84 s respectively. The humidity sensor's traits were evaluated at room temperature, with relative humidity (RH%) ranging from 11 % to 98 %, using mesoporous α- Fe2O3. The response/recovery time of mesoporous α-Fe2O3 as a humidity sensor comes out to be 6.3 s & 7.2 s respectively. The highly sensitive nature of the sensor along with negligible hysteresis, excellent repeatability and considerable stability for 30 days makes it a promisable candidate for real-time subtle respiration monitoring. Meanwhile, mesoporous α-Fe2O3 humidity sensor is also utilized for evaluation of sleep hypopnea-apnea syndrome.

Investigating the Consequence s of Energy Transitions in Protracted Displacement Settings: Solid Fuel Dependency and IDPs’ Readiness

Abstract Looking beyond cooking energy provision in humanitarian response, interventions define the course of the internally displaced people’s (IDPs) livelihood. Energy transition in displacement settings often puts the bar high as the outputs are aimed to provide full use of low emission, healthy, clean cooking energy sources. By gathering data from protracted temporary settlements inhabited since 2012 by those affected by the Mount Sinabung eruption in Karo Regency, Indonesia, the purpose of this study is to look into how Internally Displaced Persons (IDPs) are switching to greener energy sources for cooking. A framework for determining energy choice at the household size was employed to depict the overview of energy use in cooking, taking into account the effects of the transition. The case of Sinabung displacement offered a perspective of the prolonged IDPs on humanitarian energy interventions and the national ecosystem toward clean energy behaviour. Even though Liquid Petroleum Gas (LPG) penetration is subsidized, a protracted displacement situation in Sinabung still reveals solid fuel dependencies. The LPG subsidy program, which was poorly planned, and the lack of readiness of IDPs to purchase and use new alternative cooking energy were the biggest obstacles to the overall transition process and caused the fuel stacking phenomenon to persist.

Sol gel fabrication of CeO2/SnO2 nanocomposite films for habilitation in optoelectronic and sensing properties

This study investigated the synthesis and characterization of CeO2/SnO2 composite powders and films by varying CeO2 concentration ranging from 2 to 10 mol%. The sol-gel process was utilized to create composites. X-ray diffraction demonstrated that the resulting CeO2/SnO2 powders were polycrystalline, whereas the composite films had amorphous structures. The morphology of the produced samples was studied with SEM and TEM. Also the specific surface area was measured using the Brunauer-Emmett-Teller (BET) technique and the optical characteristics were assessed using a UV–Vis spectrophotometer. The absorption coefficients, energy gaps, and refractive indices of the composite films were determined. Direct and indirect energy gaps were from 3.71 to 3.27 eV and 2.70 to 2.26 eV, respectively. The refractive index increases from 1.61 to 1.7 as the CeO2 concentration increases. The variation in the energy band gap and refractive index values indicate that CeO2/SnO2 nanocomposite films are a viable composite film for optoelectronic devices. The investigated films have electrical conductivity values ranging from 10−2 to 10−8 Ω−1 cm−1. The gas sensing test was studied using different gases as liquid petroleum gas (LPG), carbon monoxide (CO), and Hydrogen sulfide (H2S). CeO2/SnO2 films demonstrated the highest sensitivity for hydrogen sulfide (H2S), with a sensitivity of 0.988 % and a response time of 40 s.

WO3–TiO2 nanostructured thin film prepared by in situ hydrothermal method as the sensing material for liquid petroleum gas (LPG) detection

WO3–TiO2 nanostructured thin film prepared by in situ hydrothermal method as the sensing material for liquid petroleum gas (LPG) detection

Comparative Analysis of Gasoline and Liquefied Petroleum Gas (LPG) on Motorcycle Engine Performance

This research aims to determine the efficiency of LPG fuel performance compared to gasoline in motorcycle engines. The research method involves a brake dynamometer test with engine speed variations of 2000 rpm, 2200 rpm, and 2500 rpm. Based on the results obtained, the exhaust gas temperature (°C) at an engine speed of 2000 rpm with gasoline is 148°C and 146°C, while with LPG, it is 107°C and 108°C. The fuel consumption rate (cc/min) at 2000 rpm is 15.8 cc/min, 16.2 cc/min with gasoline, and 9.36 cc/min with LPG. At 2200 rpm, the fuel consumption is 16.2 cc/min, 22.8 cc/min with gasoline, and 10.48 cc/min with LPG. At 2500 rpm, it is 20.2 cc/min, 19.4 cc/min with gasoline, and 14.40 cc/min with LPG. In terms of fuel consumption savings, using LPG as a fuel can significantly reduce fuel usage.

Exploring the room temperature chemiresistive LPG and humidity sensing properties of MWCNT/TiO2 nanocomposite with DFT interpretations

A nano-sized multi-walled carbon nanotube/titanium dioxide (MWCNT/TiO2) composite gas sensing material was synthesized using the chemical vapor deposition method and extensively characterized through advanced techniques. Scanning electron microscopy (SEM) revealed a microporous surface featuring a cross-linked nanotube structure in the thin film. The bandgap, determined from absorption spectra, was calculated to be 3.89 eV. Electrical resistance variations in response to liquefied petroleum gas (LPG) concentrations (0.5–2 vol%) were systematically recorded over time, with the maximum %sensor response of 423.2 at 2 vol%, indicating high sensitivity. The sensor response towards humidity was found as 1.05 MΩ/%RH at room temperature. The limit of detection (LOD) for LPG by using MWCNT/TiO2 at room temperature was found to be 0.063 vol%. Ab initio density functional theory (DFT) calculations provided insights into the adsorption mechanisms of LPG and H2O on the CNT/TiO2 surface, assessing changes in ionization potential, HOMO-LUMO gap, and electronegativity upon interaction with hydroxyl and CnH2n+2 groups. This comprehensive approach highlights the development of a robust, cost-effective, and technologically advanced sensor for LPG and humidity detection.

Utilization of cow dung for biogas to improve livestock breeders and MSME entrepreneurs' economy

Sriwulan Village, located in Limbangan District, Kendal Regency, is home to both cattle farmers and several Micro, Small, and Medium Enterprises (MSMEs). The village has a farmer group named Ngudi Kawruh, managing around 20 cows. However, cow dung in the area has become a source of air pollution, and the four MSMEs still rely on Liquefied Petroleum Gas (LPG) for production. One effective solution to this issue is converting cow dung into biogas, which offers both environmental and economic benefits. This community service program aims to introduce appropriate technology for processing cow dung into biogas using biodigesters. The biogas is stored in portable containers, such as truck inner tires, while the biodigester output, in the form of slurry, is utilized as solid organic fertilizer. The program provides education on these concepts through posters, videos, demonstrations, and YouTube links to ensure broad community understanding. By implementing this technology, the program not only addresses environmental concerns and reduces dependence on LPG but also significantly enhances the economic potential of both the villagers and MSME entrepreneurs, promoting sustainable development.

Development of Liquefied Petroleum Gas (LPG) Safety Risk Prediction Model for Hotel Sector in Sri Lanka

Development of Liquefied Petroleum Gas (LPG) Safety Risk Prediction Model for Hotel Sector in Sri Lanka

Hydrothermally Grown Globosa-like TiO2 Nanostructures for Effective Photocatalytic Dye Degradation and LPG Sensing.

The rapid expansion of industrial activities has resulted in severe environmental pollution manifested by organic dyes discharged from the food, textile, and leather industries, as well as hazardous gas emissions from various industrial processes. Titanium dioxide (TiO2)-nanostructured materials have emerged as promising candidates for effective photocatalytic dye degradation and gas sensing applications owing to their unique physicochemical properties. This study investigates the development of a photocatalyst and a liquefied petroleum gas (LPG) sensor using hydrothermally synthesized globosa-like TiO2 nanostructures (GTNs). The synthesized GTNs are then evaluated to photocatalytically degrade methylene blue dye, resulting in an outstanding photocatalytic activity of 91% degradation within 160 min under UV light irradiation. Furthermore, these nanostructures are utilized to sense liquefied petroleum gas, which attains a superior sensitivity of 7.3% with high response and recovery times and good reproducibility. This facile and cost-effective hydrothermal method of fabricating TiO2 nanostructures opens a new avenue in photocatalytic dye degradation and gas sensing applications.

The pH-dependent properties of cuprous oxide thin films prepared by electrochemical deposition for liquid petroleum gas sensing

Efficient liquid petroleum gas sensing was investigated by modulating the pH level (8, 9, 10, 11, and 12) of electrochemically deposited nanostructured cuprous oxide thin films in a lactate bath. The synthesized films were characterized by surface contact angle, XRD, SEM, UV–Vis absorption, Mott-Schottky, and AC impedance spectroscopy measurements. These displayed a unique initial increment or decrease followed by a persistent decrement or increment at pH 9–10. This turning pH point exhibited the least wetting polycrystalline Cu2O growth with the smallest crystallite size of ∼ 45 nm, the highest dislocation density of ∼50 µm−2, and a strain of 0.03 according to X-ray diffraction. SEM micrographs identified ∼ 1 µm-sized, closely structured grains with trigonal-prismatic shapes. The Mott-Schottky plots drawn from C-V measurements revealed a significant dependence of flat band potential and free carrier density on the deposition bath pH level. Cu2O films deposited using the lactate bath changed the conductivity at pH 9 from n-type to p-type when increasing the pH value. With the conductivity transition, films prepared at pH 9 displayed a relatively high direct band gap energy of 2.28 eV. Liquid petroleum gas (LPG) sensing at 70 °C demonstrated the most substantial gas response of 11.5 % at pH 10 Cu2O films. Cu2O thin films deposited at pH 9 emerged as the most stable and reproducible p-Cu2O LPG sensor, with response and recovery times ranging from 20 to 25 seconds. Remarkable changes in the film structures and morphologies were revealed with pH values above 9 after the gas exposure. The grain shape and distribution of pH 9 remained unchanged, assuring the stability of the sensing platform.

Fabrication and analysis of a novel and sustainable set-up for safe and economic hydrotherapy

Hot water immersion therapy has been found a promising therapy that offers several potential benefits to the human body, including pain relief, wound healing, improved blood circulation, stress relief, and improved sleep. However, the therapy is not widely used by the general population, especially the middle-class and lower-middle-class populations. The reasons for this could be the accessibility and cost of the therapy. This article introduces an innovative hot water immersion therapy set-up designed to increase the therapy's accessibility to a broader audience. The proposed set-up is engineered for easy home fabrication and installation without requiring special tools or skills, ensuring user safety through the use of electrically leak-proof components. A significant benefit of this set-up is its integration with a standard household geyser for water heating, which obviates the need for a dedicated geyser typically associated with commercial hot water immersion therapy systems, thereby reducing the overall initial, operational, and maintenance costs. The set-up has been successfully fabricated, installed, and tested, proving its effectiveness and efficiency. Among the four modes experimentally analyzed, Mode 4, a mix of regular and hot water with a combined flow rate of 8.06 L/min, leads to minimum waiting and geyser on-time of 19.85 min. In addition to the direct benefit of reduced liquid petroleum gas consumption, choosing Mode 4 contributes to an overall lower environmental footprint. This study aims to raise awareness of hydrotherapy and make it accessible to the general public.

Design of LPG Leakage Detection Device using MQ-2 Sensor Equipped with Hazard Warning System

The use of liquefied petroleum gas (LPG) as household fuel in Indonesia has increased because it has greater heating power and equipment efficiency than other fuels. LPG is flammable and can explode if a leakage occurs and is exposed to a fire source. Therefore, explosions can be anticipated by installing a gas leakage detector equipped with a danger warning feature called Tor-G (LPG Detector) based on the NodeMCU ESP8266 microcontroller using an MQ-2 sensor with a buzzer and LED as a danger warning feature. Tor-G can detect when a gas leakage occurs and provides a danger signal in the form of a sound from a buzzer which can be heard several meters away by the homeowner so that an explosion can be anticipated quickly. This research carried out four tests: the sensor accuracy test, the sensor responsiveness test, the distance between the sensor and the leakage source test, and the responsiveness of the buzzer and LED test. The results of the tests show that the sensor only detects the LPG. The sensor readings are accurate since the value of Rs/Ro on the Tor-G is not much different from that of Rs/Ro on the datasheet, thus producing an error value in the 0% -0.08% range. The ideal installation position of the Tor-G is 75 cm from the gas cylinder and the danger warning system from the buzzer and red LED lights up within 18.88 seconds.

Effects of a liquefied petroleum gas stove intervention on biomarkers of metals exposure among pregnant women in the HAPIN trial

Effects of a liquefied petroleum gas stove intervention on biomarkers of metals exposure among pregnant women in the HAPIN trial

Early life liquefied petroleum gas intervention and pulmonary function in Guatemalan children from the Household Air Pollution Intervention Network trial

Early life liquefied petroleum gas intervention and pulmonary function in Guatemalan children from the Household Air Pollution Intervention Network trial

Impact of a liquefied petroleum gas stove and fuel intervention on glycated hemoglobin in the HAPIN trial

Impact of a liquefied petroleum gas stove and fuel intervention on glycated hemoglobin in the HAPIN trial

Propylene hydrogenation on pt/α-Al2O3, pd/α-Al2O3, pt/ZrO2, and pd/ZrO2 in the presence of H2O: experimental and modeling study

Liquefied petroleum gas (LPG) is known as clean fuel and its importance will be continued in the future. However, most of LPG is currently produced from fossil resources. Thus, producing LPG from CO2 as a renewable source is significant for achieving carbon neutrality. One possible way to produce LPG from CO2 is through an indirect pathway via methanol/dimethyl ether and propylene/butene. The final step of this pathway is the hydrogenation reaction of olefins to produce paraffins. Although H2O may coexist in this reaction, there have been few studies to investigate reaction kinetics of propylene hydrogenation in the presence of H2O. Here, we measured the propylene conversion over different four catalysts: Pt/α-Al2O3, Pd/α-Al2O3, Pt/ZrO2, and Pd/ZrO2. We varied a reaction temperature and concentrations of propylene, H2 and H2O in the feed. We found that above 200 °C the propylene conversion was negatively affected by the reaction temperature and the propylene concentration, while it was positively affected by the H2 concentration. We also found that the dependence of propylene conversion on H2O concentration depended on the catalysts. To reproduce the measured results, a kinetic model based on the Langmuir-Hinshelwood mechanism was developed over Pt/ZrO2 which showed the best reaction performance among the catalysts used. A two-dimensional reactor model consisting of mass and heat balance equations was developed for exploring the desirable reactor type. The simulations showed that the externally cooled reactor with a catalyst density gradient was the most suitable for propylene hydrogenation in terms of heat management and propylene conversion.