Liquid Mass Distribution Research Articles

A computational study of a two-fluid atomizing coaxial jet: Validation against experimental back-lit imaging and radiography and the influence of gas velocity and contact line model

Numerical simulations of liquid atomization in a two-fluid coaxial geometry have been performed using a geometric Volume-of-Fluid method. Experimental measurements have been obtained using visible light back-lit imaging and X-ray radiography. Simulations are validated against experiments, using the same geometry and fluid injection rates of air and water, by showing excellent agreement in quantities such as liquid mass distribution in the spray formation region and the liquid jet length statistics and temporal dynamics. At the nozzle exit, the coflowing liquid and gas streams are separated by a cylindrical splitter plate. The liquid is laminar and modeled using a Poiseuille flow while the gas inflow model and the contact line model are varied. For the gas velocity models, the vorticity thickness is shown to have a strong influence on the downstream liquid distribution; the difficulty of its modeling and routes to overcome them are discussed. For the contact line model, pinning the interface to the inner wall of the splitter plate leads to an initial increase in the diameter of the liquid jet just downstream of the nozzle exit. In contrast, pinning to the outer wall of the splitter plate or allowing for a free moving contact line results in a monotonic decrease in the diameter of the liquid jet as the downstream distance is increased, in agreement with the experimental observations and measurements. A sub-grid scale contact line model based on a static contact angle is introduced. The static contact angle is varied in the model, showing that the liquid remains intact longer as the static contact angle is increased.

Evaluation of the Parameters of the Dispersed Stream Generated by Various Types of Water Nozzles

Aim: The purpose of the research was to determine the parameters of the micro- and macro-structure of the streams generated by nozzles of different types, and to identify potential applications of the tested water nozzles, including firefighting and air pollution removal. Introduction: TF6 FCN, TF6 V, NF 15 and CW 50 water nozzles were tested. At supply pressures of 0.2 MPa, 0.4 MPa and 0.6 MPa, the basic parameters of micro- and macrostructure of the streams were measured and determined: flow rate, spray angle, mass distribution of liquid on the surface (spray intensity), non-uniformity of spray density distribution, and average droplet diameters and spray spectrum. A sputter spectrum analyser, using the photoelectric method, was used to determine the microstructural parameters of the stream. Project and methods: Badaniom poddano dysze wodne TF6 FCN, TF6 V, NF 15 oraz CW 50. Przy ciśnieniu zasilania równym 0,2 MPa, 0,4 MPa oraz 0,6 MPa zmierzono i wyznaczono podstawowe parametry mikro- i makrostruktury strumieni: natężenie przepływu, kąt rozpylenia, rozkład masowy cieczy na powierzchni (intensywność zraszania), nierównomierność rozkładu gęstości zraszania oraz średnie średnice kropel i widmo rozpylenia. Do określenia paramentów mikrostrukturalnych strumienia zastosowano analizator widma rozpylenia, wykorzystujący metodę fotoelektryczną. Results: The tested nozzles generated dispersed streams with different parameters. Among the analysed nozzles, the highest degree of dispersion was obtained for the TF 6 FCN sample, whose average Sauter mean diameter (SMD) reached a value of 217.3 μm. In comparison, for the NF15 nozzle this parameter was 945 μm. The spray spectra indicate a high homogeneity of water dispersion in the stream produced by the nozzles TF 6 FCN and CW 50. From the distribution of mass sprinkling density, the CW 50 nozzle shows the greatest uniformity of spraying. At the same time, however, it reports a small amount of water, since the value of the spray density for this product did not exceed 100 g/( m2 · s), while for the NF 15 nozzle it was more than 2,700 g/( m2 · s). The obtained spray angles were close to those declared by the nozzle manufacturer. In the tests of all samples, a slight effect of supply pressure on the values of this parameter was observed. Conclusions: Among other things, the tests made it possible to conclude that in the range of supply pressures of 0.2÷0.6 MPa, the values of disperse angle and spray area of the analysed nozzles were constant or the recorded differences were insignificant. In addition, it was determined that in the case of nozzles with full spray cones, an increase in supply pressure (within the range of declared operating values) has little effect on changing the parameters of the micro- and macro-structure of the stream. The conducted tests showed the potential use of two nozzles (TF6 FCN, CW 50) in low-pressure fog extinguishing systems producing fog with SMD droplet diameters > 200 μm. For the absorption of hazardous substances, it is recommended to use nozzles with a large spray angle and a full spray cone, which, as tests have shown, produce uniform streams with small droplet diameters. Keywords: water nozzles, water spray, spray spectrum, mass spray density, water mist

Distribution of Liquid Mass in Transient Sprays Measured Using Laser-Plasma-Driven X-Ray Tomography

We report, the use of laser-plasma-driven x rays to reveal the three-dimensional (3D) structure of a highly atomizing water spray. Soft x rays approximately 5 keV are generated by means of a laser-plasma accelerator. Transmission radiography measurements are performed at different angles, by rotating a multihole injector. Using computer tomography, the local liquid volume distribution and its spatial variation are retrieved in 3D, showing up to 55% liquid fraction at the nozzle outlet, which decreases to below 7% within only 1 mm. The resolution of the liquid volume fraction is 0.5% while the spatial resolution of the radiographic images is $11.5\phantom{\rule{0.2em}{0ex}}\ensuremath{\mu}\mathrm{m}$. The x-ray source used here provides successful measurements of liquid mass distribution over a relatively large volume and is very promising for the analysis of a variety of challenging transient spray systems, e.g., the injection of liquid synthetic and biofuels used for future clean-combustion applications.

Dynamic behavior of jet-swirl spray under resonance condition with external excitation

Gas-centered swirl coaxial (GCSC) injectors are used in many liquid propellant rocket engines to improve combustion efficiency. In this study, fluctuation of the mass flow rate is analyzed to investigate influence of external excitation in gas feed line on the mass flow rate distribution of sprays. Water and air are used as simulants for the liquid kerosene and gas oxygen, respectively. With external excitation (354 and 1062 Hz), atomization processes changes and periodic breakup phenomenon of a spray occurs. Liquid film thickness at the exit of the injector shows that the width of liquid mass flow rate wave is reserved when the instability mode changes. However, behavior of the liquid droplets captured with a structured laser illumination planar imaging (SLIPI) system for laser diagnostics indicates that time domain concentration of liquid mass becomes more severe with the second instability mode outside the injector. This study can provide a reference for liquid mass distribution with external excitation on gas and imply that resonance in injector feeding systems is one of the important factors in combustion instability.

X-RAY RADIOGRAPHY AND PHASE-CONTRAST IMAGING OF THE ENGINE COMBUSTION NETWORK SPRAY B SPRAYS AND INJECTION

X-ray measurements of diesel sprays from two of the Engine Combustion Network (ECN) Spray B injectors are described. Measurements in these three-hole nozzles complement both visible light measurements of these sprays and previous x-ray measurements of the axial single-hole ECN Spray A injectors. Both axial and lateral motions of the injector needle valve were measured with x-ray phase contrast imaging. The liquid mass distribution in room temperature sprays at elevated ambient pressure was determined with x-ray radiography. Measurements of both needle valve motion and spray distribution were performed at both the standard Spray A/B conditions and with selected variations of injection pressure, ambient density, and injection timing. The needle valve motion for the Spray B injectors is quite similar to that of the Spray A injectors, though little lateral motion is seen in either Spray B injector. Compared to the sprays from the Spray A injectors, the sprays from Spray B penetrate more slowly in the near-nozzle region, demonstrate a broader, more uniform distribution in the transverse direction, and are significantly more variable with respect to time. These differences demonstrate the importance of studies with multi-hole nozzles to provide insight into applied diesel combustion.

4D spatiotemporal evolution of liquid spray using kilohertz-rate x-ray computed tomography.

Four-dimensional (x,y,z,t) x-ray computed tomography was demonstrated in an optically complex spray using an imaging system consisting of three x-ray sources and three high-speed detectors. The x-ray sources consisted of high-flux rotating anode x-ray tube sources that illuminated the spray from three lines of sight. The absorption, along each absorption path, was collected using a CsI phosphor plate and imaged by a high-speed intensified CMOS camera at 20kHz. The radiographs were converted to a quantitative equivalent path length (EPL) of liquid using a variable attenuation coefficient to account for beam hardening. The EPL data were then reconstructed using the algebraic reconstruction technique into high-speed time sequences of the three-dimensional liquid mass distribution.

Study of cold spray and combustion stability of effervescent atomizer

In the present work, an effervescent atomization spray system has been built with plain-orifice atomizer powered by (water / diesel fuel) and air as atomizing gas in the “inside-out” gas injection configuration. The investigation shows the influence of operation and design parameters on the spray cone angle, liquid mass distribution throughout the spray, flame blow-off and flame length. The gas to liquid mass ratio (GLR) varies from 0.3% to 15%, the liquid mass flow rate varies from 0.5 to 10 g/s and the operating pressure varies from 1 to 6 bar. The results show that spray cone angles lie in the range of 15-22° for all gas to liquid ratios, length to diameter ratios and operating pressures. Liquid mass distribution at different axial distances downstream of the atomizer becomes more uniform at lower (L/D) ratio and higher gas to liquid ratio. Increasing (A/F) ratio leads to decreasing flame length. Moreover, an empirical correlation of cone angle with operating and design parameters has been developed.

Validation of a comprehensive computational fluid dynamics methodology to predict the direct injection process of gasoline sprays using Spray G experimental data

A detailed prediction of injection and air–fuel mixing is fundamental in modern direct injection, spark-ignition engines to guarantee a stable and efficient combustion process and to minimize pollutant formation. Within this context, computational fluid dynamics simulations nowadays represent a powerful tool to understand the in-cylinder evolution of spray and air–fuel charge. To guarantee the accuracy of the adopted multidimensional spray sub-models, it is mandatory to validate the computed results against available experimental data under well-defined operating conditions. To this end, in this work, the authors proposed the calibration and validation of a comprehensive set of spray sub-models by means of the simulation of the Spray G experiment, available in the context of the engine combustion network. For a suitable validation of the proposed numerical setup in addition to the baseline condition, gasoline direct injection operating points typical of early injection with homogeneous operation, late injection with high ambient density and flash boiling with enhanced fuel evaporation were also simulated. Numerical computations were validated against a wide set of available experimental data by means of an accurate post-processing analysis taking into account axial liquid and vapor penetrations, gas-phase velocity between spray plumes, droplet size, plume liquid velocity, direction and mass distribution. Satisfactory results were achieved with the proposed setup, which is able to predict gasoline spray evolution under different operating conditions.

Analysis of viscous fluid flow in a pressure-swirl atomizer using large-eddy simulation

A computational fluid dynamics study is carried out on the inner nozzle flow and onset of liquid sheet instability in a large-scale pressure-swirl atomizer with asymmetric inflow configuration for high viscosity fluids. Large-eddy simulations (LES) of the two-phase flow indicate the unsteady flow character inside the nozzle and its influence on liquid sheet formation. A novel geometric volume-of-fluid (VOF) method by Roenby et al. (2016), termed isoAdvector, is applied for sharp interface capturing. We carry out a Reynolds number sweep (420 ≤ Re ≤ 5300) in order to investigate the link between the asymmetric inner nozzle flow and liquid sheet characteristics in laminar, transitional and fully turbulent conditions. Inside the nozzle, the numerical simulations reveal counter-rotating Dean vortices, flow impingement locations, and strong asymmetric flow features at all investigated Reynolds numbers. A helical, rotating gaseous core is observed when Re ≥ 1660. For laminar flow (Re=420), an S-shaped liquid film is observed, while the gas core presence at Re ≥ 1660 results in a hollow cone liquid sheet. For the intermediate value Re=830, the numerical simulations indicate a liquid sheet of mixed type. Consequences of the inflow asymmetry and Reynolds number to the uniformity of the injected liquid mass distribution and liquid sheet instability are pointed out.

Quantitative study on the influence of bubble explosion on evaporation characteristics of flash boiling spray using UV-LAS technique

Flash boiling is an effective way to enhance both atomization and evaporation characteristics of liquid fuel spray by introducing explosion of vapor bubbles, compared with the conventional high pressure injection. However, the evaporation characteristics and mechanism of flash boiling spray, especially, that associated with the explosion of vapor bubbles at high superheat degree, is still unknown. In this study, the vapor and liquid mass distributions in flash boiling sprays were quantified by use of ultraviolet/visible laser absorption/scattering (UV-LAS) imaging technique over a broad range of superheat degree. Based on the results of macro-structure characteristics of liquid/vapor phase spray and total evaporated vapor mass, influence of bubble explosion on detailed evaporation characteristics of flash boiling spray are investigated. And, by associating with our previous work on breakup mechanism of superheated droplet and liquid jet, the effect of two evaporation regimes, namely surface evaporation and flashing evaporation, on evaporation of flash boiling spray has been successfully identified for the first time. These results provide insightful information for understanding the evaporation mechanism of a superheated liquid jet and modeling a flash boiling spray.

Characterization of the external and internal flow structure of an aerated-liquid injector using X-ray radiography and fluorescence

In the present study, the internal flowfield of aerated-liquid fuel injectors is examined through X-ray radiography and X-ray fluorescence. An inside–out injector, consisting of a perforated aerating tube within an annular liquid stream, sprays into a quiescent environment at a fixed mass flow rate of water and nitrogen gas. The liquid is doped with bromine (in the form of NaBr) to create an X-ray fluorescence signal. This allows for reasonable absorption and fluorescence signals, and one or both diagnostics can be used to track the liquid distribution. The injector housing is fabricated from beryllium (Be), which allows the internal flowfield to be examined (as Be has relatively low X-ray attenuation coefficient). Two injector geometries are compared, illustrating the effects of aerating orifice size and location on the flow evolution. Time-averaged equivalent pathlength and line-of-sight averaged density ρ(y) reveal the formation of the two-phase mixture, showing that the liquid film thickness along the injector walls is a function of the aerating tube geometry, though only upstream of the nozzle. These differences in gas and liquid distribution (between injectors with different aerating tube designs) are suppressed as the mixture traverses the nozzle contraction. The averaged liquid velocity (computed from the density and liquid mass flow rate) reveals a similar trend. This suggests that at least for the current configurations, the plume width, liquid mass distribution, and averaged liquid velocity for the time-averaged external spray are insensitive to the aerating tube geometry.

Evaporation characterization of fuel spray impinging on a flat wall by laser-based measurement

It is of interest for engine combustion modeling to quantify the evaporation behaviors of fuel spray impinging on a wall as the fuel atomization, evaporation, and mixing with oxygen in the combustion chamber usually dominate the subsequent combustion processes. In this study, the vapor and liquid mass distributions in diesel-like fuel sprays were quantified using the ultraviolet-visible laser absorption scattering imaging technique. The sprays were injected from a single-hole nozzle with a common-rail injection system and impinged on a flat wall at an ambient pressure of 4 MPa and an ambient temperature of 833 K. The mass of the total fuel vapor, the spray volume covered by the vapor phase, and the air mass entrained into the spray were characterized. The results indicate that the time evolution of these parameters until shortly after the end of injection can be expressed by a power-law function, Yi = ki· ts1.5, where Yi represents the parameter like vapor mass and so on, ts is the time after start of injection, and ki is the coefficient corresponding to Yi. The physics behind this power-law function was analyzed and discussed based on the theory of atomization and evaporation, and verified using measurement data obtained under different conditions of injection quantity.

Mechanistic Assessment of Swirl Coaxial Injection by Quantitative X-Ray Radiography

Detailed x-ray radiographic experiments were conducted to evaluate the time-averaged spray characteristics of a liquid rocket swirl injector. Sprays issued from a single liquid-centered swirl coaxial element—with and without coannular gas flow—were exposed to focused, monochromatic x rays produced by a synchrotron light source. Two-dimensional attenuation data are presented at various axial stations and reveal both projected mass distribution of liquid in the injector near field and mass-weighted axial velocity integrated over time. Measurements describing spray morphology are also inferred from the x-ray data and compared with those measured through objective image processing of visible light imagery. The gas flow is observed to reduce spray cone angle up to 50% and increase liquid film thickness up to 20% in the near field. Measurements compare well with those extracted from imagery of the pressure-swirl spray; however, the x-ray technique is more robust in resolving liquid film thickness for the optically dense swirl coaxial spray.

Evaluation of X-ray sources for quantitative two- and three-dimensional imaging of liquid mass distribution in atomizing sprays

Quantitative measurement of liquid mass distribution is demonstrated in an impinging-jet atomizing spray using a broadband, ∼80keV X-ray tube source for 2-D radiography and 3-D computed tomography (CT). The accuracy, precision, and sensitivity of these data are evaluated using narrowband, ∼10keV, synchrotron radiation from the Argonne National Laboratory Advanced Photon Source (APS) at the same flow conditions. It is found that the broadband X-ray tube source can be used for 2-D measurement of the equivalent path length (EPL) and 3-D CT imaging of liquid mass distribution with typical error of 5–10%. Data are compared for cases with and without the use of potassium iodide (KI), which at 15% concentration by mass increases the attenuation coefficient eightfold and enables 2-D and 3-D measurement of EPL with a signal-to-noise ratio (SNR) of 5:1 down to 15μm. At this concentration, the effects of energy-dependent attenuation (i.e., spectral beam hardening) are negligible for EPL up to 5mm. Hence, the use of broadband X-ray tube sources is feasible for many practical engineering sprays with a dynamic range in EPL of ∼330:1. The advantages and limitations of using broadband and narrowband X-ray sources are discussed, and recommendations for improving performance are presented.

Development and application of a computational fluid dynamics methodology to predict fuel–air mixing and sources of soot formation in gasoline direct injection engines

A detailed understanding of the air–fuel mixing process in gasoline direct injection engines is necessary to avoid soot formation that might result from charge inhomogeneities or liquid fuel impingement on the cylinder walls. Within this context, the use of multidimensional models might be helpful to better understand how spray evolution in cylinder charge motions and combustion chamber design affects the mixture quality at spark-timing. In this work, the authors developed and applied a computational fluid dynamics methodology to simulate gas exchange and air–fuel mixture formation in gasoline direct injection engines. To this end, a suitable set of spray submodels was implemented into an open-source code to properly describe the evolution of gasoline jets emerging from multihole atomizers. Furthermore, the complete liquid film dynamics was also considered. For a proper assessment of the approach, a gasoline direct injection engine running at full load was simulated and effects of spray targeting and engine speed were studied. A detailed postprocessing of the computed data of liquid film mass, homogeneity index and equivalence ratio distributions was performed and correlated with experimental data of particulate emissions. Satisfactory results were achieved, proving the effectiveness of the proposed methodology in predicting the effects of injection system and operating conditions on soot formation.

MASS DISTRIBUTION STUDIES IN EFFERVESCENT SPRAYS

An experimental study on liquid mass distribution in effervescent sprays using water and air as working fluids is presented in this paper. Optical patternation and techniques of image processing are employed for analyzing the spray. The flow regime inside the effervescent atomizer largely dictates the mass distribution patterns. The patterns are seen to vary from concentrated, poorly atomized liquid lumps to uniformly distributed, fine droplets as the flow regime changes from bubbly flow to annular flow. A large variety of instantaneous spray patterns are observed in bubbly flow regime indicating a highly unsteady atomization process. However, relatively better consistency in spray patterns is observed at higher gas flow rates. Thus, the degree of unsteadiness gradually diminishes as gas flow rate is increased. The axial evolution of the spray in annular mode shows good mixing of liquid and gas across the interface.

Effects of primary breakup modeling on spray and combustion characteristics of compression ignition engines

Abstract Injector flow dynamics and primary breakup processes are known to play a pivotal role in determining combustion and emissions in diesel engines. In the present study, we examine the effects of primary breakup modeling on the spray and combustion characteristics under diesel engine conditions. The commonly used KH model, which considers the aerodynamically induced breakup based on the Kelvin–Helmholtz instability, is modified to include the effects of cavitation and turbulence generated inside the injector. The KH model and the new (KH-ACT) model are extensively evaluated by performing 3-D time-dependent simulations with detailed chemistry under diesel engine conditions. Results indicate that the inclusion of cavitation and turbulence enhances primary breakup, leading to smaller droplet sizes, decrease in liquid penetration, and increase in the radial dispersion of spray. Predictions are compared with measurements for non-evaporating and evaporating sprays, as well as with flame measurements. While both the models are able to reproduce the experimentally observed global spray and combustion characteristics, predictions using the KH-ACT model exhibit closer agreement with measurements in terms of liquid penetration, cone angle, spray axial velocity, and liquid mass distribution for non-evaporating sprays. Similarly, the KH-ACT model leads to better agreement with respect to the liquid length and vapor penetration distance for evaporating sprays, and with respect to the flame lift-off location for combusting sprays. The improved agreement is attributed to the ability of the new model to account for the effects of turbulence and cavitation generated inside the injector, which enhance the primary breakup. Results further indicate that the combustion under diesel engine conditions is characterized by a double-flame structure with a rich premixed reaction zone near the flame stabilization region and a non-premixed reaction zone further downstream. This flame structure is consistent with the Dec’s model for diesel engine combustion (Dec, 1997) [1] , and well captured by a newly developed flame index based on the scalar product of CO and O2 mass fraction gradients.

An experimental and numerical study on sprays injected from two-hole nozzles for DISI engines

The objective of this study is to investigate the mixture formation process of sprays injected from two-hole nozzles for direct-injection spark-ignition (DISI) engines. Spray characteristics were examined for vapor and liquid mass distributions, spray tip penetration and spray angle using the laser absorption–scattering (LAS) technique and the computational fluid dynamics (CFD) simulation. Other characteristics including: the vapor phase concentration distribution, droplet spatial distribution and pressure distribution were acquired from the CFD simulation results. Comparison of measured and calculated results showed that as the hole-axis-angle (HAA) of the two-hole nozzle decreased, the droplet coalescence increased and vapor mass decreased. The spray with the HAA of 10° had the longest spray tip penetration and the spray with the HAA of 15° had the shortest one. The two jets of the two-hole nozzle spray had a tendency of offsetting to the central region of the spray. From 10 to 15 MPa, the increase in the injection pressure increased the vaporization rate and the spray tip penetration rate very much, but no such tendency was found when the injection pressure increased from 15 to 20 MPa.

ASSESSMENT OF ATOMIZATION MODELS FOR DIESEL ENGINE SIMULATIONS

Liquid fuel injection and atomization have a significant influence on the combustion and emission characteristics of diesel engines. Using x-ray radiography, it is possible to obtain quantitative and time-resolved data in the primary breakup region close to the injector nozzle. However, most previous studies on model validations have employed optical measurements that are not applicable in this dense spray region. In the present study, atomization models, based on Kelvin-Helmholtz and Rayleigh-Taylor instabilities, are extensively validated using x-ray and optical measurements for non-evaporating sprays, as well as detailed measurements for evaporating sprays. The data include spray penetration, axial velocity, liquid mass distribution, cone angle, Sauter mean diameter, and vapor penetration. Simulations are performed using a computational fluid dynamics (CFD) code "CONVERGE", which employs an innovative grid generation technique, and state-of-the-art spray models. Postprocessing tools are developed to facilitate a detailed comparison of predictions with x-ray and optical measurements. The effect of rate of injection uncertainties on spray evolution is also quantified. Although the model globally reproduced the experimentally observed trends and the effects of various parameters on atomization and spray characteristics, it underpredicted spray dispersion, especially for non-evaporating sprays, indicating the need for further model development. In addition, the model could not capture the experimental trends in terms of the effects of nozzle orifice geometry on spray development, implying that effects of cavitation and turbulence generated inside the injector need to be included in the model.

Ice properties of single‐layer stratocumulus during the Mixed‐Phase Arctic Cloud Experiment: 2. Model results

Measurements from the US Department of Energy Atmospheric Radiation Measurement Program's 2004 Mixed‐Phase Arctic Cloud Experiment (M‐PACE) provide a unique opportunity to study poorly understood ice formation processes in mixed‐phase stratocumulus. Using meteorological, aerosol, and ice nucleus measurements to initialize large‐eddy simulations with size‐resolved microphysics, we compare predicted liquid and ice mass, number, and size distribution with observations from a typical flight. We find that ambient ice nuclei appear insufficient by a few orders of magnitude to explain observed ice, consistent with past literature. We also find that two processes previously hypothesized to explain the discrepancy, shatter of freezing drops and fragmentation during ice‐ice collisions, were not significant sources of ice based on parameterizations from existing studies. After surveying other mechanisms that have been hypothesized to explain ice formation in mixed‐phase clouds generally, we find two that may be strong enough: (1) formation of ice nuclei from drop evaporation residuals, a process suggested by sparse and limited measurements to date, and (2) drop freezing during evaporation, a process suggested only by inference at this time. The first mechanism can better explain the persistence of mixed‐phase conditions in simulations of less vigorous stratus observed during the Beaufort Arctic Storms Experiment (BASE). We consider conditions under which emission of nuclei from the ocean surface or activation through cloud‐phase chemistry could provide alternative explanations for M‐PACE observations. Additional process‐oriented measurements are suggested to distinguish among ice formation mechanisms in future field studies.