Liquid Layer Research Articles

Coupled tidal tomography and thermal constraints for probing Mars viscosity profile

Computing the tidal deformations of Mars, we explored various Mars spherically symmetric internal structures with different types of interface between the mantle and the liquid core. By assessing their compatibility with a diverse set of geophysical observations we show that despite the very short periods of excitation, tidal deformation is very efficient to constrain Mars interior. We calculated densities and thicknesses for Martian lithosphere, mantle, core–mantle boundary layers and core and found them consistent with preexisting results from other methods. We also estimated new viscosities for these layers. We demonstrated that the geodetic records associated with thermal constraints are very sensitive to the presence of a 2-layered interface on the top of the liquid core in deep Martian mantle. This interface is composed by 2 layers of similar densities but very different viscosity and rheology: the layer on the top of the core is liquid (Newtonian, NBL) and the one at the base of the mantle, overlaying the liquid one, is an Andrade layer (ABL) with a viscosity in average 10 orders of magnitude greater than the Newtonian layer. Our results also indicate that the existence of this 2-layered interface significantly impacts the viscosity profiles of the mantle and the lithosphere. More precisely, models including the 2-layered interface do not display significant viscosity contrast between the mantle and the lithosphere, preventing mechanical decoupling between a lithosphere and the mantle immediately below. Such models are in favor of a stagnant lid regime that can be supported by the current absence of an Earth-like plate tectonics on Mars. Finally, in our results, the presence of liquid Newtonian layer at the top of the liquid core is incompatible with the existence of a solid inner core.

Saturated/subcooled flow boiling heat transfer characteristics for R134a, HFE-7100 and Deionized water inside micro/mini-channels: Part Ⅱ – New CHF prediction model establishment

A new flow pattern map has been developed and presented in Part Ⅰ of this paper for R134a, HFE-7100 and Deionized water inside micro/mini-channels. To further explain the phenomenon and understand the mechanism of triggering critical heat flux (CHF), the theoretical model to predict the CHF of saturated/subcooled flow boiling inside the micro/mini-channels is proposed based on the liquid layer dry-out and Helmholtz instability (intermittent and continuous vapor blanket) theories. Both the effect of the dry-out flows and the liquid sublayer under the vapor blanket were taken into consideration. For saturated and subcooled boiling, the two mechanisms of triggering the CHF were revealed based on different flow patterns and experimental phenomena, respectively. The boiling heat transfer performance has been experimentally investigated under different liquid subcoolings, mass fluxes and geometry parameters. By analyzing the previous models and establishing a database, the comparison of new model predictions with present experimental data shows good agreement within a standard deviation of ± 10 %. Besides, prior CHF data were used to verify this new model, which also presents varying degrees of success in predicting the CHF.

Photonic defect modes in cholesteric liquid crystal resonators with embedded isotropic layers

Photonic defect modes are explored as a viable alternative to standard photonic band edge modes in photonic crystal applications, especially due to their typically high Q-factors and local density of states. For example, they can be used in nonlinearity enhancement, lasing, and cavity quantum electrodynamics. However, they are strongly dependent on any structural change and need to be well-controlled to ensure the desired resonance frequency. Here, we present a study of the photonic defect modes that appear in a structure where a layer of isotropic material is embedded between two layers of cholesteric liquid crystal (CLC), using full electrodynamics numerical simulations. We present typical transmission spectra and electric field profiles of selected defect modes and then analyze the influence of geometrical and material parameters on the eigenfrequencies and Q-factors of the modes within and around the photonic bandgap, including refractive indices and thicknesses of isotropic and liquid crystal layers, and different anchoring orientations at the boundaries of the isotropic defect layer. Additionally, a connection of such defect modes to previously extensively analyzed twist defect modes is given. Eigenmodes in asymmetric resonators are also presented, where CLC layers surrounding the intermediate isotropic layer are not equally thick, enabling biasing of specific directional light emission. More generally, this work aims to contribute to the understanding and design capability in topological soft matter photonics where defect mode lasing could be realized in CLC geometries with different singular and solitonic topological defect structures.

Droplet-based triboelectric devices using liquid dielectrics for self-powered sensing applications

Triboelectric nanogenerators (TENGs) have attracted great interests by exploiting the complex interplay between contact electrification and electrostatic induction. The versatility of tribo-dielectric materials offers significant advantages for environmentally adaptive device design. In this regard, liquid dielectrics provide intimate contact between filled materials and high dielectric strength. Herein, a liquid dielectric-based TENGs system featuring a charge-transfer liquid layer is presented. A multifaceted summary is presented to illustrate the relationship between liquid dielectric materials and charge transfer mechanisms. New strategies for exploiting the dielectric properties of various liquids to control their electrical properties and monitor the parameters of liquid dielectric properties are highlighted. Additionally, it contributes to the advancement of self-powered sensing technology with increased flexibility, capacitance tuning, and sensor functionality through easy modularization. These achievements contribute to the understanding of charge transfer mechanisms in liquids and highlight their potential for self-powered sensing applications.

Comparative electron microscopic visualization of the lung alveolar epithelial glycocalyx with different staining and labeling methods.

The alveolar surface of the lung is lined by an epithelium consisting of type I (AECI) and type II alveolar epithelial cells (AECII). This epithelium is covered by a liquid alveolar lining layer (ALL). Besides intra-alveolar surfactant, ALL also contains the alveolar epithelial glycocalyx on the apical side of AECI and AECII. To better understand the alveolar epithelial glycocalyx, its ultrastructural visualization by transmission electron microscopy is required. The aim of this study was to systematically re-evaluate routine cytochemical methods for visualization of the alveolar epithelial glycocalyx and specifically its glycan components. For this purpose, we used chemical fixation by vascular perfusion with aldehydes as a common routine approach in mice. After fixation, staining is needed for glycocalyx visualization. Cytochemical staining agents such as alcian blue, ruthenium red, and lanthanum nitrate were compared. In addition, SNL (Sambucus nigra lectin) and UEA1 (Ulex europaeus agglutinin I) were used for sialic acid and fucose-specific labeling. Alcian blue showed the strongest staining, with cloud-like structures, whereas ruthenium red appeared as thread-like structures. On the other hand, lanthanum nitrate did not stain the alveolar epithelial glycocalyx. For specific sialic acid and fucose labeling, both lectins presented a specific signal. In conclusion, these methods can be used routinely for assessing ultrastructural changes of the alveolar epithelial glycocalyx in experimental invivo models under different physiological and pathological conditions. In addition, cytochemical staining by tissue massage and post-embedding lectin labeling after vascular perfusion support 3R (reduction, refinement, replacement) principles of animal welfare.

The entropic origin of the enhancement of liquid diffusion close to a neutral confining surface.

It is known that, in the proximity of a neutral wall, liquids experience diffusion enhancement relative to their bulk diffusion, but the origin of this phenomenon is still unknown. We report a molecular dynamics simulation investigating the dynamics of a simple liquid in the proximity to a non-interacting smooth confining wall, which exhibits a strong diffusion enhancement within the liquid layers adjacent to the wall. We present an analysis of these results, demonstrating that the observed diffusion enhancement can be accounted for, with numerical accuracy, using the universal scaling law that relates the liquid diffusion rate to the excess entropy. These results show that the scaling law, which has so far only been used for the description of the bulk liquid diffusion, can be successfully used to describe the diffusion in liquids under nano-scale confinement.

Influence of Rotation and Viscosity on Parallel Rolls of Electrically Conducting Fluid

Rayleigh–Bénard convection is a fundamental fluid dynamics phenomenon that significantly influences heat transfer in various natural and industrial processes, such as geophysical dynamics in the Earth’s liquid core and the performance of heat exchangers. Understanding the behavior of conductive fluids under the influence of heating, rotation, and magnetic fields is critical for improving thermal management systems. Utilizing the Boussinesq approximation, this study theoretically examines the nonlinear convection of a planar layer of conductive liquid that is heated from below and subjected to rotation about a vertical axis in the presence of a magnetic field. We focus on the onset of stationary convection as the temperature difference applied across the planar layer increases. Our theoretical approach investigates the formation of parallel rolls aligned with the magnetic field under free–free boundary conditions. To analyze the system of nonlinear equations, we expand the dependent variables in a series of orthogonal functions and express the coefficients of these functions as power series in a parameter ϵ. A solution for this nonlinear problem is derived through Fourier analysis of perturbations, extending to O(ϵ8), which allows for a detailed visualization of the parallel rolls. Graphical results are presented to explore the dependence of the Nusselt number on the Rayleigh number (R) and Ekman number (E). We observe that both the local Nusselt number and average Nusselt number increase as the Ekman number decreases. Furthermore, the flow appears to become more deformed as E decreases, suggesting an increased influence of external factors such as rotation. This deformation may enhance mixing within the fluid, thereby improving heat transfer between different regions.

Liquid Gallium-Assisted Pyrolysis of MOF Affording CNT Non-Hollow Frameworks in High Yields for High-Performance Sodium-Ion Battery Anode.

Carbon materials have great potential for applications in energy, biology, and environment due to their excellent chemical and physical properties. Their preparation by carbonization methods encounters limitations and the carbon loss during pyrolysis in the form of gaseous molecules results in low yield of carbon materials. Herein a low-energy (600°C) and high-yield (82wt.%) carbonization strategy is developed using liquid gallium-assisted pyrolysis of metal-organic frameworks (MOFs) affording the N-doped carbon nanotube (CNT) non-hollow frameworks encapsulating Co nanoparticles. The liquid gallium layer offers protection against air, promotes heat transfer, and limits the escape of small carbonaceous gaseous molecules, which greatly improve the yields of the pyrolysis reaction. Experimental and theoretical results reveal that the synergistic interaction between CNTs and N/O-containing groups gives a non-hollow framework composed of N/O-enriched and open CNTs (NOCNTF-15, 15 denotes the 15mm thickness of the liquid gallium layer during the pyrolysis) with high specific capacity (185mAhg-1 at 10Ag-1) and ultra-stable cyclability (stable operation at 10Ag-1 and 50°C for 20000 cycles). This study provides a unique approach to carbonization that facilitates the practical application of low-cost CNTs and other MOFs-derived carbon materials in high-performance sodium-ion batteries (SIBs).

A novel coarse-grained modeling and simulation for microstructure and shear evolution of induced dipole dominant electrorheological fluid

Induced dipole dominant electrorheological fluid (ID-ERF) is a new type of ERF. After high energy ball milling (HEBM) process, dielectric particles produce a large number of oxygen vacancies, and the dipoles formed by the polarization of these oxygen vacancies provide excellent ER properties. ID-ERF has the advantages of high shear stress, low current density, long service life, anti-sedimentation, simple preparation method, etc. It should be a new generation of ERF material suitable for practical application. In this work, facing at the shortcomings of traditional particle MD simulation of ERF system, a coarse-grained molecular dynamics (CGMD) model is constructed. The evolution of ID-ERF is simulated under the conditions of no electric field and 5 kV/mm electric field. Proves that there is an adsorption layer of carrier liquid on the surface of ER particles, and shows BCT lattice arrangement under electric field. The sinusoidal shear strain is applied to the model, and calculate the variation of strain amplitude, loss factor, storage modulus and loss modulus. In addition, we prepared ID-ERF and tested its performance to compare with the simulation results.

Tiny bubble triboelectric nanogenerator functionalized by liquid film rupture

As an important energy carrier, bubble commonly exists in undersea and liquid-gas two-phase systems. Efficiently utilizing the bubble energy is critical for potential applications in energy harvesting and sensing in two-phase environment. However, the micro liquid layer inhibits the complete contact and restricts the performance. Herein, we proposed strategies for tiny bubble triboelectric nanogenerator (TB-TENG) featuring liquid film rupture to eliminate the screen between bubble and dielectric layer. We carried out optimization design by invasively rupturing the liquid film, achieving stable open-circuit voltage peak and transferred charge of 8.3 V and 3 nC by a 110-μL bubble, with a high peak power density yielding the existing tube-based studies. Additionally, for noninvasive and spontaneous liquid film rupture, a scalable bubble regulator was fabricated, which integrated the irregularly dispersed bubbly flow into slug flow. We demonstrated the self-powered undersea gas leakage detection system combining the TB-TENG with the bubble regulator. Assisted with the good bubble regulation adaptability, the total leakage gas volume and rate were measured based on the voltage signal, with a varied leakage rate of 0.72–6 mL/min. The strategy provides insights for the related research in liquid-gas two-phase systems in nature and industry.

Orientation of Linear Liquid Alkane on Solid Surface of Face Centered Cubic Lattice of (100), (110) and (111)

Solid-liquid (S-L) interfaces are found in numerous engineering applications, such as lubrication and coating systems as well as thermal interface materials. Understanding the interactions between (S-L) is crucial for optimizing various engineering applications. The main objective of this study is to provide insight regarding liquid adsorption on solid surfaces using non-equilibrium molecular dynamics simulations. To achieve this goal, a liquid confined between solid surfaces will be modeled to match the real state of contact interfaces using a constant temperature as a baseline. The results highlight a significant relationship between the peak height values of the liquid adsorption layer, density profile, and radius of gyration. Specifically, the peak height density at the S-L interfaces for the crystal plane (110) is 784.756 kg/m3, followed by (100) at 801.786 kg/m3, and finally the highest is for the crystal plane (111), at 966.940 kg/m3. Whereas the radius of gyration at the S-L interfaces for crystal planes (100) and (111) is approximately 7.45 × 10-21 m2, but for crystal plane (110) it is less and measures approximately 7.06 × 10-21 m2. Conclusion, the adsorption layer of solid density near solid-liquid interfaces is significantly influenced by the peak height of the solid's density. Higher density results in a higher adsorption layer of liquid near solid-liquid interfaces. The number of solid density layers does not affect the height of adsorption layers for liquids.

Load motion on an ice cover in the presence of a liquid layer with velocity shear

The behavior of an ice cover on the surface of an ideal incompressible fluid of finite depth under the action of a pressure domain that moves rectilinearly at a constant velocity in the presence of a current with velocity shift in the upper layer is studied. It is assumed that the ice deflection is steady in the coordinate system moving with the load. The Fourier transform method is used within the framework of the linear wave theory. The critical velocities, the deflection of ice cover, and the wave forces are studied depending on the current velocity gradient, the shear layer thickness, the direction of motion, and the compression ratio.

Diurnal humidity cycle driven selective ion transport across clustered polycation membrane

The ability to manipulate the flux of ions across membranes is a key aspect of diverse sectors including water desalination, blood ion monitoring, purification, electrochemical energy conversion and storage. Here we illustrate the potential of using daily changes in environmental humidity as a continuous driving force for generating selective ion flux. Specifically, self-assembled membranes featuring channels composed of polycation clusters are sandwiched between two layers of ionic liquids. One ionic liquid layer is kept isolated from the ambient air, whereas the other is exposed directly to the environment. When in contact with ambient air, the device showcases its capacity to spontaneously produce ion current, with promising power density. This result stems from the moisture content difference of ionic liquid layers across the membrane caused by the ongoing process of moisture absorption/desorption, which instigates selective transmembrane ion flux. Cation flux across the polycation clusters is greatly inhibited because of intensified charge repulsion. However, anions transport across polycation clusters is amplified. Our research underscores the potential of daily cycling humidity as a reliable energy source to trigger ion current and convert it into electrical current.

Interface Dynamics at a Four-Fluid Interface during Droplet Impact on a Two-Fluid System.

We investigate the interfacial dynamics involved in the impact of a droplet on a liquid-liquid system, which involves the impingement of an immiscible core liquid drop from a vertical separation onto an interfacial shell liquid layer floating on a host liquid bath. The dynamics have been studied for a wide range of impact Weber numbers and two different interfacial shell liquids of varying volumes. The core drop, upon impact, dragged the interfacial liquid into the host liquid, forming an interfacial liquid column with an air cavity inside the host liquid bath. The dynamics is resolved into cavity expansion and rapid contraction, followed by thinning of the interfacial liquid. The interplay of viscous dissipation, interfacial pull, and core drop inertia influenced the necking dynamics. The viscous dissipation increases with the thickness of the interfacial layer, which depends on the volume and lateral spread over the water. The necking dynamics transitioned from inertia-dominated deep seal closure at higher spread, lower interfacial film volumes, and higher Weber numbers into inertia-capillary-dominated deep seal closure with an increase in film volumes, decrease in the spread of the interfacial fluid, or decrease in Weber number and finally into a no-seal closure at high volumes, low spread, and low Weber numbers.

On-the-Fly Machine Learning Force Field Study of Liquid-Al/Solid-TiB2 Interfaces.

Using the on-the-fly machine learning force field, simulations were performed to study the atomic structure evolution of the liquid-Al/solid-TiB2 interface with two different terminations, aiming to deepen the understanding of the mechanism of TiB2 as nucleating particles in an aluminum alloy. We conducted simulations using MLFF for up to 100 ps, enabling us to observe the interfacial properties from a deeper and more comprehensive perspective. The nucleation potential of TiB2 particles is determined by the formation of various ordered structures at the interface, which is significantly influenced by the termination of the TiB2 (0001) surface. The evolution of the interface during heterogeneous nucleation processes with different terminations is described using structural information and dynamic characteristics. The Ti-terminated surface is more prone to forming quasi-solid regions compared to the B-termination. Analysis of mean square displacement and vibrational density of states indicates that the liquid layer at the Ti-terminated interface is closer in characteristics to a solid compared to the B-terminated interface. We also found that on the TiB2 (0001) surface different terminations give rise to distinct ordered structures at the interfaces, which is ascribed to their different diffusion abilities.

Performance characteristics of two-phase impulse turbines for energy recovery in thermal systems

The two-phase impulse turbine (TPIT) can improve the efficiency and economy of various thermal systems, because it can directly convert the internal energy of thermal fluids into the shaft power of the turbine with no needs of additional low-temperature sub-systems. However, current efficiency of reported TPITs is much lower than gas or water turbines, due to unknown characteristics of the two-phase flow in TPITs. This paper comprehensively analyzed the performance characteristics of a TPIT, which was used in the refrigeration system. CFD methods were employed to analyze the two-phase flow based on flashing models and validated with experimental results. Three average methods were used to derive the Euler power and compared with the output power derived by the torque on each blade, while the average method based on the modified factor can evaluate the Euler power accurately. The non-uniform flow caused by the nozzle position was significant, while the liquid film near pressure side and the shroud were also three dimensional and affected by wall effects. The liquid layer on the shroud was related to the negative torque on blade tips. Results presented in this paper are constructive for designing efficient thermal systems without additional energy recovery devices.

Tribological properties of YG8/steel friction pair in an aqueous lubrication system with an ionic liquid: Experimental results and molecular dynamics simulations

In this work, an ionic liquid (G-RIC) with excellent lubricating performance was successfully prepared, and the tribological properties as an additive in glycerol-water solutions were explored. The results indicated that 2.0 % additive content can reduced the friction coefficient to below 0.1, leading to a decline in the wear volume of 76 %. Gray cast iron corrosion tests revealed that the additive exhibited excellent corrosion resistance. Quantum chemical calculations revealed that the anion RIC has a low energy gap (ΔE = 0.034 Ha), which implies that it is more prone to undergoing tribochemical reactions with the metal substrate under frictional heat. The synergistic action of the liquid lubrication layer, adsorption film, and friction protective film created an interface that easily shears.

Approaching the Multiphase Interface of Ir-Based PEM Electrolyzers Using Operando ‘Tender’ X-Ray AP-XPS

Electrochemical water splitting is a promising pathway for the renewable production of hydrogen as an alternative fuel and chemical feedstock. Yet, the process is plagued by slow kinetics of the essential oxygen evolution reaction at the anode. Further, large-scale hydrogen production from such devices will require reduced platinum group metal (PGM) loadings (often iridium-based anodes) and/or new materials due to factors such as PGM scarcity, cost and loss during operation. In the hopes of enabling progress of rational design for OER catalysts, effective characterization of the electrode-liquid interface is crucial. Synchrotron-based X-ray Photoelectron Spectroscopy (XPS) offers a versatile way to obtain surface chemical and elemental characterization of these materials. The use of X-rays in the ‘tender’ regime (~2-6 keV) allows for deeper probing than the conventional ‘soft’ x-ray (< 2000 eV) set up that is common at synchrotrons and lab-based sources. The photoelectrons generated from tender x-rays have enough energy to penetrate tens of nanometers through low density components such as a layer of liquid or polymeric electrolyte. This opens the door to access the chemistry at the interface of liquid and ionomer electrolyte-electrocatalyst materials. With the use of a fully operational two-electrode system, we are able to study these membrane electrode assemblies under active water splitting conditions.My talk will explain our specific approach, which is often crucial for successful collection of accurate data, highlighting elements of cell design and experimental setup that are helpful for this process. I will also show recent AP-XPS results on iridium-based polymer electrolyte membranes for water splitting. With application of elevated potential, we can correlate the iridium valency and surface species with the appearance of product traces in a mass spectrum. Figure 1

Chemistry and Formation of Solid-Electrolyte Interphase (SEI) at Li-Metal Potential

Li metal batteries (LMBs) have long been considered a solution to address the energy density limitations of Li-ion batteries. However, the widespread adoption of LMBs has faced challenges due to operational issues, notably safety concerns arising from the formation of Li dendrites and uncontrolled reactivity at the interfaces, leading to continuous consumption of the electrolyte. To enhance the reversibility of the Li-metal anode (LMA), a promising approach has emerged involving the development of a novel liquid electrolyte comprising an ether solvent and LiFSI salt. Notably, this electrolyte formulation has achieved impressive Coulombic efficiency (CE) values surpassing 99.5%. Despite this progress, the underlying causes of Coulombic inefficiency (CI) and its connection with the formation of a solid-electrolyte interphase (SEI) on the Li metal surface remain inadequately understood.Gaining fundamental insights into these essential processes occurring during continuous cycling of the LMA can provide valuable guidance for optimizing CE more effectively. This presentation focuses on recent advancements that systematically unravel the underlying chemistry and formation of SEI derived from FSI anions at the interface of the Li metal anode in contact with various liquid electrolytes. By employing a non-washing protocol and a Cu current collector, we successfully captured and identified crucial reaction intermediates from SEI chemistry, enabling precise determination of the decomposition pathway for FSI anions. Our discoveries unveil a dynamic scenario at the electrode/electrolyte interface, where these reaction byproducts can significantly dissolve into the liquid layer, and their relative solubility dictates their role in passivating the electrode surface. Furthermore, we demonstrate a strong correlation between faster interfacial passivation in higher-performing electrolytes and the reduced solubility of diverse inorganic species within the liquid electrolyte. These fresh insights into SEI chemistry and formation open new avenues for enhancing LMA performance by mitigating undesired side reactions at the interface.

CO Residence Time Modulates Multi-Carbon Formation Rates in a Copper Based Zero Gap CO2 Electrolyzer

Carbon dioxide (CO2) electrolysis on copper (Cu) catalysts has attracted interest for its direct production of C2+ feedstocks. Using the knowledge that CO2 reduction on copper is primarily a tandem reaction of CO2 to CO and CO to C2+ products, we show that modulating CO concentrations within the liquid catalyst layer allows for C2+ selectivity of > 80 % at 200 mA cm-2 in a membrane electrode assembly over broad conversion conditions. The importance of CO pooling is demonstrated through residence time distribution curves, varying flow fields (serpentine/parallel/interdigitated), and flow rate. While serpentine flow fields require high conversions to limit CO selectivity and maximize C2+ selectivity, the longer CO residence times of parallel flow fields reach similar selectivity over broad flow rates. Critically, we show that parts of the catalyst area are predominantly reducing CO instead of CO2 as supported by CO reduction experiments and transport modelling of the reactor. In addition, higher cation crossover from the anolyte is shown to maximize C2 + selectivity providing further evidence of cation effect on C-C coupling rates.