Liquid Layer Research Articles

Mullite Synthesis Using Porous 3D Structures Consisting of Nanofibrils of Aluminum Oxyhydroxide Chemically Modified with Ethoxysilanes

Nanocrystalline mullite was synthetized by annealing a highly porous 3D structure consisting of nanofibrous aluminum oxyhydroxides treated with ethoxysilanes. The chemical, structural, and phase transformations in the aluminosilicate nanosystem were studied in the temperature range between 100 and 1600 °C. The features of the solid-phase synthesis of mullite at the interface of crystalline alumina with a liquid silica layer are discussed. It was established that chemical modification of the alumina surface with ethoxysilanes significantly limits the interphase mass transport and delays the phase transformation of the amorphous oxide into γ-Al2O3, which begins at temperatures above 1000 °C, while the basic structural nanofibrils are already crystallized at ~850 °C. The formation of mullite was completed at temperatures ≥ 1200 °C, where the fraction of γ-Al2O3 sharply decreased.

Rayleigh wave propagation in an initially stressed orthotropic elastic solid half-space lying under inviscid liquid and viscous liquid layers

PurposeThe purpose of this article is the propagation of Rayleigh waves in a homogeneous, isotropic, initially stressed orthotropic elastic solid half-space lying under a homogeneous, viscous, inviscid liquid layer of finite thickness.Design/methodology/approachIn the presence of both viscous and inviscid liquids, it derives the phase velocity, initial stress, and wave number-dependent frequency equation for an orthotropic elastic solid. With the help of the MATLAB program, the thickness effects of liquid layers, initial stress, and viscosity on the phase velocity and attenuation coefficient of the Rayleigh wave are explained for a particular model.FindingsThe phase velocity-dependent dispersion relation of Rayleigh waves at the interface of viscous liquid and solid half-space is a function of initial stress and wave number. Rayleigh waves along the free surface of an orthotropic elastic half-space are also derived as a particular case. The classical results of an inviscid liquid are achieved when the thickness of a viscous liquid approaches zero. Well-known classical results for initially stressed orthotropic elastic solids were also derived.Originality/valueSo far, many researchers have looked into the propagation of surface waves at the interfaces of solid–inviscid liquid, solid–solid, and multilayer interfaces. But in this article, the dispersion behavior of Rayleigh wave propagation in an initially stressed homogeneous orthotropic elastic solid half-space under a double layer of viscous liquid and inviscid liquid is studied.

A biomimetic approach towards a universal slippery liquid infused surface coating.

One biomimetic approach to surface passivation involves a series of surface coatings based on the slick surfaces of carnivorous pitcher plants (Nepenthes), termed slippery liquid-infused porous surfaces (SLIPS). This study introduces a simplified method to produce SLIPS using a polydopamine (PDA) anchor layer, inspired by mussel adhesion. SLIPS layers were formed on cyclic olefin copolymer, silicon, and stainless steel substrates, by first growing a PDA film on each substrate. This was followed by a hydrophobic liquid anchor layer created by functionalizing the PDA film with a fluorinated thiol. Finally, perfluorodecalin was applied to the surface immediately prior to use. These biomimetic surface functionalization steps were confirmed by several complimentary surface analysis techniques. The wettability of each surface was probed with water contact angle measurements, while the chemical composition of the layer was determined by X-ray photoelectron spectroscopy. Finally, ordering of specific chemical groups within our PDA SLIPS layer was determined via sum frequency generation spectroscopy. The hemocompatibility of our new PDA-based SLIPS coating was then evaluated by tracking FXII activation, fibrin generation time, clot morphology, and platelet adhesion to the surface. This hemocompatibility work suggests that PDA SLIPS coatings slow or prevent clotting, but the observation of both FXII activation and the presence of adherent and activated platelets at the PDA SLIPS samples imply that this formulation of a SLIPS coating is not completely omniphobic.

Investigation of bubble interaction in a temporal and spatial heat flux partitioning model for subcooled flow boiling

CFD methodology for subcooled flow boiling is significantly affected by the heat flux partitioning model, which plays a crucial role in predicting the mass source term generated by wall boiling of the liquid phase. Although numerous models have been proposed, most research efforts have focused on the spatial dimensions of boiling heat transfer mechanisms, neglecting the temporal aspect. This study presents a heat flux partitioning model for subcooled flow boiling that considers both temporal and spatial dimensions. The model accounts for the contribution of heat flux from the superheated liquid layer during the bubble growth stage, liquid convection during the bubble wait stage within the bubble influence area in the temporal dimension, and heat flux from the overlapping area of bubble influence in the spatial dimension. An approach was developed to determine the bubble influence area by considering the bubble interaction based on the stochastic nature of nucleation sites on the heated wall, verified by the Monte Carlo method. The bubble dynamics parameters were experimentally derived to reduce the uncertainty associated with the boiling sub-models on the calculation. A comparative analysis of boiling curves and wall heat flux partitioning was conducted between the present model and the RPI model under various flow conditions. The results indicate that both models could reasonably predict the boiling curve. However, the RPI model tends to over-predict the proportion of evaporative heat flux, which is considered a weakness. Based on physical principles, the present model accurately captures the fundamental trend of wall heat flux partitioning. This research enhances the understanding of subcooled flow boiling and increases confidence in multiphase CFD methodology predictions.

Bulk adhesion of ice to concrete–strength

This paper presents the results of a laboratory test program designed to investigate the adhesive effects of large-scale (bulk) ice on concrete. Medium-strength concrete cylinders were sawn into discs, and attached to a sample table. Freshwater ice samples, frozen using smaller, standard-sized concrete cylinders, were adhered to the concrete with both varying bond times and added weight during bonding. Shear strength tests were conducted at a set displacement rate, under a number of temperatures. The effect of these variables on the adhesive strength of ice to concrete was examined, as well as whether there was any noticeable removal of concrete cement paste or aggregate during testing. The tests indicate that the adhesive strength is negligible when the method of adhesion is “dry” (no liquid layer at the onset of adhesion). Tests with “wet” adhesion indicated a significantly higher strength. The nominal versus the apparent contact area had significant implications for the determination of the adhesive strength of the bond between the ice and the concrete. Removal of cement paste was evident in a number of tests, however the amount was not significant. The results have relevance for design of structures in a marine environment, such as revetement dams or rubblemound breakwaters, as well as for the standardization of adhesion tests with ice and concrete.

Ground tests for a future space experiment: Evaporation rates through a centimetric square chimney by vapor interferometry and simulation

In this paper, results of preparatory tests for a space experiment “Marangoni in Films” on board International Space Station are reported. The setup is thermalized at a setpoint temperature so that (thermal) Marangoni convection is exclusively a result of evaporative cooling of the film, here composed of a Hydrofluoroether (HFE)-7100, evaporating into nitrogen at a given setpoint pressure. The present paper is entirely devoted to the evaporation rates, whereas the Marangoni convection itself will be analyzed in future studies. Apart from the temperature and nitrogen pressure, various setpoints for the initial relative saturation in HFE-7100 vapor are explored. A special design of the test cell with a square chimney surrounding a square opening of the liquid layer permits to largely stabilize the evaporation rates during a longest-lasting middle stage (beyond the initial transients and the final film dry-out). In addition, it facilitates the use of vapor (digital-holographic) interferometry for measuring the evaporation rates, the results of which are compared with independent measurements by means of the pressure evolution within our sealed cell of a fixed volume. An excellent agreement is found before the final dry-out stage for all setpoint parameter combinations tested. The study is accompanied by numerical finite-element simulations in an axisymmetrized geometry, neglecting a possible influence of the Marangoni convection and verifying certain premises used in interferometric post-processing. Even if the simulation results might somewhat over-/underpredict in each particular case, the overall dependence of the evaporation rate on the setpoint parameters is well reproduced and the role of the buoyancy convection is thereby explored.

CFD Modeling of Film Condensation from a Steam-Air Mixture in Vertical Channels

Steam condensation in the presence of a noncondensable gas is of vital importance for passive cooling containment systems. The noncondensable gas causes a significant reduction in the condensation rate and heat transfer across the containment, which is important for postulated loss-of-coolant accidents in a nuclear reactor. In this work, computational fluid dynamics models of condensation and the adjacent single-phase steam-air mixture flow are developed for laminar and turbulent flow in vertical channels by two distinct wall condensation modeling approaches using the commercial code STAR-CCM+. The first is the fluid film model available in STAR-CCM+, which solves liquid layer governing equations with connections to the adjacent gas mixture flow. The second is a user-defined wall condensation model that neglects the fluid film and instead accounts for mass, momentum, and heat transfer via user-defined volumetric sink terms adjacent to the cold wall. The condensation models are assessed by first comparing the calculated results with the numerical solution of laminar flow, solved using a complete two-phase model that solves parabolic equations based on conservation of mass, momentum, energy, and species for each phase. Next, the results of a two-dimensional analysis are compared with COPAIN experiments and existing numerical solutions from three-dimensional analyses. The comparisons include new, detailed results that have not been reported in previous analyses of a COPAIN case. These new results include local field profiles of velocity, temperature, and air mass fraction, and local mass flux.

Directional enhancement of underwater impact and bubble loads in neighbor two-phase fluid domains charge

The loading characteristics of underwater explosions and the dynamic behavior of bubbles are directly related to the charge structure. This study proposes a unique charge structure in a gas–liquid two-phase fluid domain. Numerical methods are used to investigate the effects of fluid layer thickness and gas–liquid ratio on underwater explosion shock wave load, bubble dynamics, and bubble pulsation load. The results show that the two-phase fluid layer significantly enhances the directional release of shock wave energy and bubble pulsation load. During the shock wave phase, a lagging wave effect appears in the liquid layer direction, causing a secondary high-energy shock, significantly increasing the specific impulse. The gas layer direction may form a pressure relief channel effect, enhancing the shock wave peak pressure. For the bubble motion phase, differences in the physical properties of the fluid layer medium lead to irregular bubble boundary movements, promoting bubble tearing and rupture. The gaseous medium converts the accumulated shock wave energy into the internal energy of the bubble, increasing its volume potential. Although this characteristic reduces the pulsation frequency, it significantly increases the specific impulse. Altering the fluid layer medium can control explosion loads and bubble movement, offering new insights for ocean engineering applications.

On the Role of Anions in Solid Catalysts with Ionic Liquid Layer (SCILL) for the Selective Hydrogenation of Highly Concentrated Acetylene Streams.

Electric plasma assisted pyrolysis of methane represents a highly promising greener alternative to produce ethylene from biogas and renewable energies compared to conventional steam cracking of naphtha. The mediocre performance of typical Pd-Ag catalysts for the downstream purification of the substantially higher concentrated acetylene impurities (≥15 vol.-%) in those ethylene streams via selective hydrogenation is yet limiting economic interest. Following the concept of solid catalysts with ionic liquid layer (SCILL), we have modified an intrinsically non-selective palladium catalyst with imidazolium based ionic liquids varying among 10 different anions and investigated them in this reaction. The best performing [C4C1IM][MeSO4]-SCILL reaches an outstanding average ethylene selectivity over 20 h on-stream of 82 % at full acetylene conversion without any sign of deactivation, clearly outperforming conventional Pd-Ag catalysts. By varying parameters like ionic liquid (IL) loading, temperature, feed gas composition, cations, and by using XPS for surface analysis we could gain a very comprehensive understanding of the underlying mechanisms that reduce the competing over-hydrogenation and oligomerisation side-reactions.

In air STM observation of Au(111) surface disturbance including Au magic fingers as modified by solvent choice

A widely studied surface phenomena on Au(111) is the formation of Au magic fingers, which were first discovered nearly 20 years ago. A variety of experimental conditions have been used to observe the formation of Au magic fingers with a slight preference to ultra-high vacuum and low temperature studies. With the advances in scanning probe techniques, it is possible to study these unique structures under more relevant conditions including in air and at room temperature. After exposure to a 0.1 M solvent solution, Au(111) displayed three types of surface disturbances, including the formation of Au magic fingers, based on the identity of the solvent. The type of disturbance was dependent on the solvent molecule's characteristics, specifically its total charge and its electrolytic behavior in aqueous environments. The mechanism of disturbance relied on a strong tip-surface interaction and the mass transport of Au atoms, which was modified by the solvent selected. Overall, the ability to form organized nanostructures, like Au magic fingers, in a repeated way in environments outside of UHV and without a protective liquid layer increases the utility of these structures into a wider array of fields and applied areas.

Exploring Wettability: A Key to Optimizing Liquid-Solid Triboelectric Nanogenerators.

Nowadays, the liquid-solid triboelectric nanogenerator (L-S TENG) has gained much attention among researchers because of its ability to be a part of self-powering technology by harvesting ultra-low-frequency vibration in the environment. The L-S TENG works with the principle of contact electrification (CE) and electrostatic induction, in which CE takes place between the solid and liquid. The exact mechanism behind the CE at the L-S interface is still a debatable topic because many physical parameters of both solid and liquid triboelectric layers contribute to this process. In the L-S TENG device, water or solvents are commonly used as liquid triboelectric layers, for which their wettability over the solid triboelectric layer plays a significant role. Hence, this review is extensively focused on the influence of the wettability of solid surfaces on the CE and the corresponding impact on the output performance of L-S TENGs. The present review starts with introducing the L-S TENG, a mechanism that contributes to CE at the L-S interface, the significance of hydrophobic materials/surfaces in TENG devices, and their fabrication methods. Further, the impact of the contact angle over the electron/ion transfer over various surfaces has been extensively analyzed. Finally, the challenges and future prospects of the fabrication and utilization of superhydrophobic surfaces in the context of L-S TENGs have been included. This review serves as a foundation for future research aimed at optimizing the L-S TENG performance and inspiring new approaches in material design and multifunctional energy-harvesting systems.

Finite element simulations of quartz crystal microbalances (QCM): from Sauerbrey to fractional viscoelasticity under water

2D finite element simulations are performed on QCM working in the thickness-shear mode and loaded with different homogeneous films. They include a purely elastic film, a viscoelastic Maxwellian liquid, viscoelastic-Voigt solid, and the fractional viscoelastic (power-law) version of each case. Unlike single-relaxation kind models, fractional viscoelasticity considers the relaxation-time spectrum often found in polymeric materials. The films are tested in air or covered with liquids of different viscosities. Two substrate thicknesses are tested: 100 nm and 500 nm, the latter being close to the condition that promotes the resonance of the adsorbed film. In all cases the simulations are compared with small-load approximation theory (SLA). The 100 nm films follow the theory closely, although significant deviations of the SLA are observed as the overtone number n increases, even in purely elastic films. We also show that it is possible to identify the viscoelastic ‘fingerprint’ of the 100 nm films in air using raw data and Sauerbrey’s equivalent thickness obtained with the QCM in the 3 < n < 13 range. These numerical data are validated by experimental measurements of crosslinked polydimethylsiloxane films with thicknesses ∼150 nm. In contrast, the 500 nm films deviate notoriously from the SLA, for all viscoelastic models and overtones, with the largest deviation observed in the elastic film. When a liquid layer covers the QCM without an adsorbed film, the only overtone that numerically reproduces the theoretical value is the fundamental, n = 1. For n > 1, strong coupling between the solid and liquid is detected, and the original vibration modes of the crystal are altered by the presence of the liquid. Finally, the numerical simulations suggest that it is possible to detect whether a viscoelastic film is formed under a liquid layer using only the information from n = 1. In these film/liquid systems we also observe the so-called missing-mass effect, although the theory and simulations exhibit different levels of impact of such effect when the liquid viscosity is high.

Cover Feature: Assessing Solid Catalysts with Ionic Liquid Layers (SCILL) from Molecular Dynamics Simulations: On the Role of Local Charge Polarization (Chem. Eur. J. 57/2024)

Cover Feature: Assessing Solid Catalysts with Ionic Liquid Layers (SCILL) from Molecular Dynamics Simulations: On the Role of Local Charge Polarization (Chem. Eur. J. 57/2024)

Relaxation dynamics of a liquid in the vicinity of an attractive surface: The process of escaping from the surface.

We analyze the displacements of the particles of a glass-forming molecular liquid perpendicular to a confining solid surface using extensive molecular dynamics simulations with atomistic models. In the vicinity of an attractive surface, the liquid molecules are trapped. Transient localization of liquid molecules near the surface introduces a relaxation process related to the escape of molecules from the surface into the dynamics of the interfacial liquid layer. To describe this process, we analyze several dynamical observables of the confined liquid. The self-intermediate scattering function and the mean-squared displacement of the particles located in the interfacial layer are dominated by the process of escaping from the surface. This relaxation process is also associated with a strong heterogeneity in the mobility of the interfacial particles. The studied model liquid is hydrogenated methyl methacrylate. For the confining wall, we consider different models, namely a periodic single layer of graphene and a frozen amorphous configuration of the bulk liquid (frozen wall). Near graphene, where the liquid molecules form a layered structure and adopt parallel-to-surface orientation, a clear separation between small-scale movements of the molecules near the surface and the process of escaping from the surface is observed. This is reflected in the three-step relaxation of the interfacial layer. However, near the frozen wall, where the liquid molecules do not have a preferential alignment, a clear three-step relaxation is not seen, even though the dynamical quantities are controlled by the process of escaping from the surface.

Orthogonal Phase Transfer of Oppositely Charged FeII 4L6 Cages.

Coordination cages and their encapsulated cargo can be manoeuvred between immiscible liquid layers in a process referred to as phase transfer. Among the stimuli reported to drive phase transfer, counterion exchange is the most widespread. This method exploits the principle that counterions contribute strongly to the solubility preferences of coordination cages, and involves exchanging hydrophilic and hydrophobic counterions. Nevertheless, phase transfer of anionic cages remains relatively unexplored, as does selective phase transfer of individual cages from mixtures. Here we compare the phase transfer behaviour of two FeII 4L6 cages with the same size and geometry, but with opposite charges. As such, this study presents a rare example wherein an anionic cage undergoes phase transfer upon countercation exchange. We then combine these two cages, and demonstrate that their quantitative separation can be achieved by inducing selective phase transfer of either cage. These results represent unprecedented control over the movement of coordination cages between different physical compartments and are anticipated to inform the development of next-generation supramolecular systems.

Liquisolid Technique for Solubility Enhancement of Poorly Soluble Drug - A Brief Review.

Most of the newly discovered drug candidates are lipophilic and poorly water-soluble, making it a significant challenge for the pharmaceutical industry to formulate suitable drug delivery systems. This review gives insight into an overview of the liquisolid technique (LST) and summarizes the progress of its various applications in drug delivery. This novel technique involves converting liquid drugs or drugs in a liquid state (such as solutions, suspensions, or emulsions) into dry, nonadherent, free-flowing, and readily compressible powder mixtures by blending or spraying a liquid dispersion onto specific powder carriers and coating materials. In Liquisolid systems, the liquid medication is absorbed into the interior framework of carriers. Once the carrier's interior is saturated with liquid medication, a liquid layer forms on the surface of the carrier particles, which is instantly adsorbed by the fine coating material. As a result, a dry, free-flowing, and compressible powder mixture is formed. Compared to other solubility enhancement techniques, s.a. micronization, inclusion complexation, microencapsulation, nanosuspension, and self-nano emulsions, LST is relatively simple to prepare and may offer a cost-effective solution to enhance the solubility of poorly water-soluble drugs enhancing its bioavailability in drug formulation and delivery.

Critical radius deviated from Leidenfrost state of droplets on liquid layer

The levitation of Leidenfrost droplets on liquid pool is fascinating, but its final stage is lack of understanding. Here, we found that a droplet levitated on liquid layer eventually deviated from Leidenfrost state once its radius was lower than a critical radius due to evaporation. The critical radius of ethanol droplet deviated from Leidenfrost state on silicone oils with a thickness ranging from 2.0 to 15.0 mm was determined by experiment. The influences of the initial radius of droplet, viscosity, and thickness of liquid layer on critical radius were analyzed. In addition, the critical radius decreases with increase in superheat for ΔT lower than 25.0 °C, whereas it does not significantly vary after ΔT exceeding 25.0 °C. The bottom temperature Tb of droplet does not approach to saturation temperature even under a high superheat. The experiment found that Marangoni convection existed inside droplet. Based on a theoretical model considering Marangoni convection, the reason for droplet deviated from Leidenfrost state was explained. These findings are helpful for understanding the final state of Leidenfrost droplet on liquid layer and would provide a potential practical application such as extinction of oil pool fires with liquids.

Stability analysis of Rayleigh–Bénard–Marangoni convection in fluids with cross-zero expansion coefficient

Cross-zero expansion coefficient Rayleigh–Bénard–Marangoni (CRBM) convection refers to the convective phenomenon where thermal convection with stratified positive and negative expansion coefficients in a liquid layer is coupled with the Marangoni convection. In the Bénard convection, fluids with a cross-zero expansion coefficient contain a neutral expansion layer where the expansion coefficient (α) is zero, and the local buoyancy-driven convection is coupled with the Marangoni convection, leading to unique flow instability phenomena. This paper uses linear stability theory to analyze the CRBM convection in a horizontal liquid layer under a vertical temperature gradient and performs numerical calculations for fluids under different Bond numbers (Bd) in both bottom-heated and bottom-cooled models, obtaining the critical destabilization conditions and modes. In the bottom-heated model, different combinations of buoyancy instability mechanism (BIM), tension instability mechanism, and coupled instability mechanism (CIM) appear depending on the dimensionless temperature for the neutral expansion layer (Tα0) and the Bd. In the bottom-cooled model, two mechanisms occur according to the variation of Tα0: BIM and CIM.

Siphon-based scalable and salt-resistant multistage thermal desalination system

Recent advances in thermal localization-based passive solar desalination provide a great opportunity for the economical generation of freshwater, particularly in regions with insufficient energy and water infrastructure. Yet, the capillary-assisted passive desalination systems with a high-water productivity flux (measured in Lm−2 h−1) suffer from the issue of performance degradation due to salt accumulation and the inability to be scaled up. In this work, we propose siphon-based supply of saline water over the evaporator that enables scale up of the desalination system to a size significantly higher than the capillary rise height of the hydrophilic evaporator while preventing salt accumulation on the evaporator. The composite siphon comprises insulating fabric wick and a metallic grooved surface for localizing heat to evaporate a thin layer of saline liquid over the evaporator. We perform heat and mass transfer analysis to show that the thermal-to-vapor efficiency depends on the inlet mass flow rate and air gap between the evaporator and the condenser. We propose a methodology to passively control the mass flow rate to maximize the thermal to vapor efficiency at different input heat flux and initial concentration of the brine. A grooved condenser avoids mixing of brine and the freshwater, even at air gaps as low as 2 mm. A siphon-assisted 10-stage desalination system with a footprint area 15 cm × 15 cm and an air gap of 2 mm is shown to have a high water productivity flux of ~5.73 Lm−2 h−1 from 3.5 wt% saline water at an applied heat flux 1000 W/m2, which increases to a record high distillate flux of ~6.23 Lm−2 h−1 and thermal to water collection efficiency of ~423 % for a 15-stage system. The ability of the desalination system to maintain a high-water productivity flux even when the evaporator area is increased by 4 times demonstrates its scalability to achieve higher desalinated water productivity rate.

Impact of lattice structure on compressive performance and strength to weight ratio in continuous stereolithography

Lattice structures have emerged as a creative solution in additive manufacturing to achieve lightweight structures. Lattices offer the capability to reduce material usage, production costs, and weight while maintaining the structural integrity of a part. Due to its rise in popularity and excellent properties, lattice structures have been used in many applications, including but not limited to aerospace, bioengineering, and acoustics. This study aimed to explore the performance of different types of lattices on 3D additive manufactured parts by varying the type of unit cell. The three unit cells that were compared are body-centered cubic (BCC), face-centered cubic (FCC), and Fluorite. The lattice’s strength-to-weight ratio of different lattice unit cells when subjected to compression forces was evaluated. BCC and FCC have had considerable research while Fluorite has had far less research. This study aims to contribute new knowledge on the less studied Fluorite unit cell. The selected lattice structures were printed using continuous stereolithography (CSLA). This 3D printing process utilizes a photopolymerization reaction to solidify liquid resin layer by layer. Through this study, Fluorite demonstrated the highest strength-to-weight ratio among the three lattice structures examined, averaging 19,377 Nm/kg over five samples. Its potential for applications requiring high strength requirements is highlighted by this finding. Alternatively, BCC lattice structures had the weakest strength-to-weight ratio but exhibited remarkable structural resilience to deformation. The BCC lattice structures showed a more significant deformation before failure. Fluorite lattice structures are more suitable for high-strength applications, while BCC lattice structures can be used where high strength is not a primary parameter. This research aimed to determine the optimal lattice unit cell to implement in future choices in additive manufacturing applications.