Liquid Desiccant Air Conditioning Research Articles

Investigating the performance of direct contact membrane distillation for liquid desiccant regeneration and freshwater production: A CFD-based study

Liquid desiccant air conditioning (LDAC) systems offer a promising solution for enhancing indoor thermal comfort, air quality, humidity control, and energy efficiency. This study focuses on the critical aspect of regenerating liquid desiccants in LDAC systems, which has the potential to enhance system efficiency and performance significantly. Using computational fluid dynamics (CFD) to model direct contact membrane distillation (DCMD) for liquid desiccant regeneration and freshwater production, this research paves the way for improving the performance of LDAC systems. The DCMD process, which involves mass transfer across a membrane driven by a temperature gradient between the permeate and feed channels, is a key area of exploration in this study. The findings of this study have significant implications for the design and operation of LDAC systems. The impact of feed inlet velocity and temperature on vapor flux for liquid desiccant regeneration is substantial, with increasing the feed inlet temperature leading to a fourfold increase in water vapor flux. Similarly, increasing the feed inlet velocity boosts flux due to enhanced convective heat transfer. Membrane characteristics, such as porosity and thickness, are key determinants of system performance. These findings underscore the importance of optimizing these parameters for efficient liquid desiccant regeneration and freshwater production in LDAC systems, thereby enhancing their overall performance and energy efficiency. Finally, a mathematical model for water vapor flux was developed to investigate water vapor flux as a function of key factors such as inlet temperature, velocity, liquid desiccant concentration, and membrane characteristics.

Novel DABCO-Derived Ionic Liquids for Liquid Desiccant Air Conditioning

Novel DABCO-Derived Ionic Liquids for Liquid Desiccant Air Conditioning

Design of ionic liquids as a desiccant for the liquid desiccant type air conditioning system

Abstract Recently, liquid desiccant air conditioners (LDACs) have gained rapidly growing interest as an important candidate for an energy-efficient air conditioner. By enabling moisture absorption from the air, ionic liquids (ILs) can serve as a novel desiccant source for LDACs. For insights into the design and optimization of ILs to this end, we herein present a survey of studies on dehumidification and other relevant properties of ILs and offer some molecular perspective on their feasibility as a desiccant.

Boosting mold aerosol reduction and dehumidification performance in liquid desiccant systems using airborne ultrasound: An experimental study

Indoor mold exposure in hot-humid regions poses considerable risks to public health and food security. Ensuring safe, durable, and energy-efficient air disinfection is crucial for the air-conditioning field. While liquid desiccant air-conditioning (LDAC) systems eliminate condensation-related mold proliferation, their capability to combat airborne mold spores is limited due to the spores' robust resistance. This paper explores a novel airborne ultrasound-assisted liquid desiccant air-conditioning (US-LDAC) system. Experiments were conducted using culture-based methods to compare the system's disinfection capacities against Aspergillus niger spores, a desiccant-resistant species, under ventilation, liquid desiccation dehumidification, and airborne ultrasound-assisted liquid desiccant dehumidification modes. Moreover, the viability and morphological changes of mold spores exposed to airborne ultrasound, with and without liquid desiccants, were analyzed to verify the disinfection effectiveness and extrapolate the improving mechanisms. The results show that irradiating low-intensity airborne ultrasound (∼127 W, harmless mechanical waves) into the dehumidifier significantly increased the disinfection efficiency by 50 % and the dehumidification rate by over 90 % when airflow passed through the dehumidifier (∼0.4 s). The enhanced disinfection is attributed to ultrasonic cavitation, which facilitates the rupture of the desiccant-captured spores through microstreaming-induced shear forces. Notably, the improvements were more pronounced in humid air and with dilute desiccant solutions, suggesting that efficiency can be maintained with lowered desiccant concentrations. The US-LDAC system was particularly adept at removing mold aerosols (2.1–3.3 μm) which are easily inhaled. These findings propose a promising avenue for retrofitting existing LDAC systems to effectively reduce airborne molds and enhance dehumidification, thereby protecting indoor air quality.

A hybrid solar-driven membrane distillation-assisted liquid desiccant air conditioning system: Mathematical modeling and feasibility analysis

Membrane distillation (MD) is a promising method for liquid desiccant (LD) regeneration as it can mitigate LD carryover and produce freshwater as a by-product. Previous research on MD regeneration was mainly focused on performance evaluation and optimization of the regenerator itself. This paper proposed a hybrid solar-driven direct contact MD (DCMD) regeneration-assisted liquid desiccant air conditioning (LDAC) system for air dehumidification, cooling, and freshwater production. A mathematical model for the DCMD regenerator was first developed by considering both temperature and concentration polarizations. This model was validated against the experimental data in terms of the outlet channel temperature and LD solution concentration in the feed tank with relative deviations of ± 9.8 % and ± 0.5 %, respectively. The DCMD model was further integrated into an LDAC system with a batch-wise operation. To investigate the technical feasibility of the proposed system, a one-week simulation was conducted in a residential house during summer in a tropical climate area of Australia. The results showed that the latent heat load was effectively removed from the process air and the regenerated liquid desiccant solution can meet the dehumidification requirement with a concentration over 30.0 wt%. The dehumidification rate and regeneration rate were at 0.49–1.25 kg/h and 0.95–4.25 kg/h, respectively. Solar energy contributed to 52 %-78 % of the total system thermal energy consumption. Furthermore, this system can produce 11.0–12.8 kg of water daily.

Effect of Air Parameters on LiCl-H2O Film Flow Behavior in Liquid Desiccant Systems

The wettability and stability of a solution’s film on the filler surface are the key factors determining heat and mass transfer efficiency in liquid desiccant air conditioning systems. Therefore, this study investigates the effects of different air parameters on the flow behavior of a lithium chloride solution’s film. The effects of air velocity, air flow pattern, and pressure on the wettability and critical amount of spray are discussed. The results show that the main mechanism by which the air velocity affects the wettability is that the shear stress generated by the direction of the air velocity disperses the direction of the surface tension and weakens its effect on the liquid film distribution. In addition, in the counter flow pattern, the air flow blocks the liquid film from spreading longitudinally and destroys the stability of the liquid film at the liquid outlet, which increases the critical amount of spray. The pressure distribution is similar under different operating pressures when the flow is stable; thus, pressure has little effect on wettability. The simulation results under 8 atm are compared with the experimental results. It is found that the sudden increase in the amount of moisture removal when the amount of spray changes from 0.05 to 0.1 m3/(m·h) in the experiment is caused by the change in the liquid film flow state. In addition, the results show that within the range of air flow parameters for the liquid desiccant air conditioning system, air flow shear force is not the main factor affecting the stability of the solution’s film, and there is no secondary breakage of the solution’s film during the falling-film flow process.

Solar driven liquid desiccant dehumidification system: Measurements and annual system simulations

Liquid desiccant air conditioning (LDAC) systems are used for dehumidification of air to low dew point temperatures. In the presented study a TRNSYS model of a LDAC unit is developed and validated with laboratory measurements. This model is coupled with a solar thermal system that provides heating water for the regeneration process. With this model dynamic annual system simulations can be carried out to simulate the dehumidification of a building. The solar fraction is evaluated for various infiltration rates of the building and solar collector areas with an internally cooled as well as an adiabatic absorption process.The simulation results reveal that high solar fractions of 70% to 81% can be achieved when dimensioning the solar thermal system to cover the regeneration heat demand on a good summer day. This is due to the good correlation of solar irradiance and dehumidification load. Without internal cooling of the absorption process (adiabatic conditions), the solar fraction is reduced by about 10percent points for the same size and operating conditions.

Dynamic simulation of a novel liquid desiccant air-conditioning system for greenhouse cooling and water recovery

We present dynamic, hour-by-hour modelling of a multi-stage nanofiltration regeneration system for liquid desiccant air-conditioning (NF-LDAC) of horticultural greenhouses in 17 locations covering four climate types. Four technologies are compared: fan ventilation, evaporative cooling (EvapC), conventional air-conditioning (AC), and NF-LDAC. The comparison is based on acceptable conditions for cultivation and coefficient of performance (COP). On average, fan ventilation and EvapC achieve acceptable conditions for 2 months per year, compared to 5.4 and 10.5 months for AC and NF-LDAC respectively. The highest COP value of 7.6 for NF-LDAC is reached at Colombo (Sri Lanka), followed by 5.3 at Mecca (Saudi Arabia). The permeate of the multi-stage regenerator can be recycled for irrigation, providing water savings. The highest water saving of 63% is at Mecca. These results are inferior but more realistic than those from an earlier idealised and steady-state model, which predicted a COP of 12.4 and water savings of 100% at Mecca. Nevertheless, in hot desert climates, NF-LDAC maintains acceptable conditions for year-round cultivation and saves water that is scarce in such climates. Future advances in nanofiltration membrane fabrication could increase the COP of NF-LDAC to 12.1 at Colombo and 7.4 at Mecca.

Performance analysis and optimization of a solar assisted heat pump-driven vacuum membrane distillation system for liquid desiccant regeneration

Liquid desiccant air-conditioning (LDAC) system is one of the excellent alternatives to conventional vapor compression refrigeration system due to its great energy-saving potential. However, regeneration of diluted liquid desiccant is the main energy-consuming process, and its performance plays a significant role in LDAC system. Recently vacuum membrane distillation (VMD) is becoming an emerging and promising separation process rely on the advantage of high permeate flux and low energy losses. The interest of usage solar energy techniques for feed solution heating in VMD systems is regarded as a sustainable path for membrane distillation process. In this work, a solar-driven VMD system incorporating a vapor-compression heat pump for liquid desiccant regeneration is introduced. An adapted solar/heat pump hybrid heating strategy has been devised to establish a connection between the heat-demanding process and the solar thermal supply. A comprehensive multicriteria assessment of energy, exergy, and environmental evaluation is conducted, and the influences of crucial parameters on both key components and system performance are evaluated to ensure a systematic examination. Results show that both the COP and STEC decrease obviously with the growth of the inlet solution temperature, whereas SEEC is improved abviously from 410.6 kW·h/m3 to 566.1 kW·h/m3 due to the effect of heat pump. The exergy analysis indicates that exergy losses in solar collector and stratified heat storage tank accounted for over 80 % of the total exergy losses. Additionally, single-objective optimization and multi-objective optimization are employed to explore the optimum operating conditions of key componets and whole system. Results show the ideal optimal solution can be obtained with a COP of 19.92 and a SEEC of 142.89 kW·h/m3 when the weights of COP and SEEC are taken as [0.5, 0.5].

A proposed method of solar-driven spray flash evaporation assisted by MPCM applied to solution regeneration with experimental analysis

Solution regeneration belongs to a separation and purification technology for multi-component liquid systems, which is involved in many fields such as liquid desiccant air-conditioning, desalination, and sewage treatment. Solar-driven evaporation technology has enormous energy-saving potential in solution regeneration, but it has the disadvantages of instability and slow regeneration rate. In this work, the method of solar-driven spray flash evaporation assisted by microencapsulated phase change material (MPCM) is proposed for solution regeneration. The spray flash evaporation experimental platform working with NaCl-MPCM suspension is constructed, and the spray characteristics and heat and mass transfer characteristics of NaCl-MPCM suspension are examined under different operating parameters. The results show that the addition of MPCM to the solution can significantly improve its equivalent specific heat capacity, which mitigates dispersed and discontinuous defects of solar energy. Furthermore, it can effectively reduce the severe temperature drop of the solution during the flash evaporation process, which ensures a high driving potential difference between the solution and flash evaporation environment. It is worth mentioning that under the same operating conditions, the regeneration amount per unit mass flow rate of the NaCl-MPCM suspension (wMPCM = 10 wt%) is 24.8 g/kg, which is about 19 % higher than that of the NaCl solution. Additionally, the flash performance of the NaCl-MPCM suspension can be further improved by reducing the initial fluid velocity at the nozzle or the flash evaporation pressure. This study aims to provide guidance for the efficient utilization of solar-driven flash evaporation assisted by MPCM.

Multi-stage nanofiltration for brine concentration: experimental and modelling study

Multi-stage nanofiltration (NF) has been proposed in several configurations for brine concentration applications where reverse osmosis (RO) is impractical due to high osmotic pressures. For example, the nNF-RO configuration, comprising several NF stages followed by a RO stage, has been proposed for liquid desiccant air-conditioning (LDAC). The RO-nNF configuration, comprising a RO stage followed by several NF stages, has been proposed for zero liquid discharge (ZLD). Previous theoretical investigations of nNF-RO and RO-nNF were based on idealised assumptions. Here, a two-stage system has been constructed and tested. By accounting for energy and pressure losses, more accurate models were developed. Experimental and model results agreed within 11%. The models were extended to four-stage systems, representing 3NF-RO and RO-3NF, and applied to two cases: LDAC using MgCl2 for greenhouses and ZLD using NaCl brine approaching crystallisation. A range of feed concentrations, energy recovery devices, and solution temperatures were modelled. The four-stage systems have SECel of 45–140 and 4–40 kWhel/m3 in LDAC and ZLD, respectively. In comparison, their thermal alternatives require 120 and 25 kWhel/m3, respectively. Thus, compared to thermal brine concentration, multistage NF is consistently more energy efficient in LDAC and more efficient at feed concentrations below 90 g/L in ZLD.

Response surface modeling and optimization scheme of an internally cooled liquid desiccant air conditioning system

Applying an internally cooled liquid desiccant air conditioning system (LDAC) is a promising energy-saving and emission-reduction scheme for hot and humid areas. This research investigates the application of an internally cooled LDAC for performance enhancement in hot and humid areas like Hong Kong. The combined system integrates liquid desiccant dehumidification (LDD) and regenerative indirect evaporative cooling (RIEC) without a power-intensive compressor. The internally cooled LDD removes latent heat from the hot and humid air before the RIEC cools it. To ensure efficient energy utilization, the LDD captures the exhaust air to assist in the dehumidification and initial cooling of the fresh air, which alleviates the efficiency deterioration of the desiccant. An all-fresh air system is used for better indoor air quality. To optimize the performance of a system with many influencing parameters, the response surface method (RSM) and multi-objective optimization are used to optimize and assess the potential and performance of the system. The system cooling capacity (C), latent heat removal rate (Qd), and dehumidification efficiency (ηd) are used as the optimization objectives. The response surface model and desirability function approach optimize six critical parameters, achieving a 7.6% improvement in dehumidification performance with low airspeed (1.5 m/s) and high desiccant concentration (40%) during high-humidity months. Increasing the extraction ratio of the RIEC by 20% in warmer months enhances the peak cooling capacity by 23.6%. This research contributes to implementing internally cooled LDAC systems and provides insights into optimizing monthly operation patterns in hot and humid regions.

Scalable and high-efficiency lignocellulose sponge-based evaporators for solar-driven desalination and desiccant regeneration

Liquid desiccant air conditioning systems (LDAC) have attracted increasing interest for the high efficiency of temperature and humidity control. Improving the regeneration performance with low-grade energy could make LDAC systems more competitive. In this work, by combining Chinese ink and lignocellulose sponge, we developed an inexpensive, efficient and large-scale evaporator that allows regeneration of desiccant via solar energy. Results show that the evaporator exhibits remarkable salt-resistance capacity, rendering it suitable for effective seawater desalination and regeneration of high-concentration desiccant. Even for the 40 wt% desiccant at about 22 °C, the regeneration rate can reach 0.63 kgm−2 h−1 under 1-sun irradiation. The outdoor experiments further confirmed the high regeneration rate of the evaporator. Additionally, concentrated desiccant presents an alternative means of solar energy storage. Considering the high efficiency, easy preparation, and remarkable salt resistance, the lignocellulose sponge-based evaporators could advance the practical application of solar heat localization for seawater desalination and desiccant regeneration.

Estimation of Evaporation of Water from a Liquid Desiccant Solar Collector and Regenerator by Using Conservation of Mass and Energy Principles

Solar thermal energy-powered air conditioning technologies are receiving increased attention. Among the solar energy-driven cooling technologies, open type liquid desiccant air conditioning (AC) system is emerging as a promising technology, which has a solar driven desiccant solution regenerator. In this type of system, the evaporation of water and concentrating the desiccant or regenerator performance determines the cooling performance of the AC system, which necessitates its development and experimental performance testing under actual operating conditions. The setup is made of a black painted corrugated solar collector of area 0.8 m × 1.84 m covered with glass, and a liquid desiccant solution tank and distribution system over the absorber. Solar regeneration experiments on calcium chloride–water solution were carried out on the setup and a total of five sets of meteorological, collector and solution property data were collected through concentrating the desiccant from 32.9 initially to 51.3% in five days. The evaporation of water from the regenerator was analyzed using energy and desiccant mass conservation. For a typical day, the mass of water evaporated was estimated to be 3.10 and 3.16 kg over a day, as estimated by conservation of mass and energy principles from a 34.8 kg of calcium chloride solution with initial desiccant concentration of 43.6% stored in the tank.

Performance enhancement of electrodialysis regeneration of deep eutectic solvent for liquid desiccant air conditioning systems

Despite the promising energy-saving potential of the electrodialysis regeneration technique for liquid desiccant regeneration in air conditioning systems, there are still issues that need to be resolved in electrodialysis separation systems, such as the high initial cost owing to the complexity of the cell gaps, over-limiting current, and electro-osmotic flow effects. This study utilized stereolithography (SLA) 3-D printing technology to manufacture a low-cost scalable model of an electrodialysis system. An electrodialysis system with a cell gap of 5 mm and serpentine flow feed spacers was investigated to regenerate deep eutectic solvent (DES) developed from choline chloride and ethylene glycol as a bio-friendly liquid desiccant for air conditioning systems. Ammonium chloride electrode rinsing solution with about 250 mS/cm electric conductivity was utilized to enhance the conductive properties of the system. The optimum parametric operating conditions for the system are found to be around 0.0058 m/s for the circulation flow rate, 0–4 wt.% for the concentration difference of the diluted and regenerated solutions' cells, and 6–8 V voltage supply energy input. In 60 minutes of operation, the current efficiency value of the constructed model was discovered to be as high as 65.82%. Matching the performance threshold of the commercial electrodialysis equipment described in the literature for regenerating lithium chloride conventional liquid desiccant.

Progressive development in hybrid liquid desiccant-vapour compression cooling system: A review

Over the past few decades, the air-conditioning (AC) sector has seen significant growth in liquid desiccant air-conditioning (LDAC) system technologies. The LDAC system has been considered as a viable substitute to vapour compression system (VCS) as a result of its exceptional temperature and humidity control and energy-saving ability. This study provides an overview of the developments associated with the incorporation of liquid desiccant technologies into VCS units to date. Various configurations of dehumidifiers and hybrid technologies have been compiled and analysed according to economic and environmental considerations. The operating principle of dehumidification and the regeneration process of a LDAC system are initially discussed. Afterwards, the numerous advancements in materials for liquid desiccant and dehumidifiers, which play a crucial part in the dehumidification and regeneration processes, are discussed. Numerous studies have demonstrated that by incorporating liquid desiccant systems with the VCS units, a comfort level of cooling can be achieved by employing a dehumidification process while providing 40–80% energy savings. This review article is beneficial to researchers since it identifies research gaps and explores prospective future research techniques to further enhance the performance of hybrid liquid desiccant-vapour compression systems..

A comparative study on the regeneration performance of traditional heating and heat localization methods

Liquid desiccant air-conditioning (LDAC) system is a promising alternative to the traditional vapor compression system. The most energy-consuming part of LDAC system is desiccant regeneration. An urgent issue that needs to be addressed is the inefficiency of traditional regeneration method. Solar heat localization is a novel and high-efficiency strategy for seawater desalination. However, the wide application is confined due to the low-efficient of water condensation and harvesting. In this work, the regeneration performance of heat localization method was investigated and an electric heating sheet was adopted to circumvent the effect of solar reflection. Compared with traditional heating method, the regeneration performance can be significantly improved by heat localization method. The regeneration efficiency of desiccant with 40 % concentration was significantly improved by 6 times (about 23.15 %) through heat localization method. Heat localization method allows immediate concentration of high-concentration desiccant with a low-temperature rise of regenerated desiccant. The low-temperature rise is beneficial for LDAC system due to less cooling energy is needed. This work is expected to extend the application of solar heat localization and provide some new information for liquid desiccant regeneration.

Simulation study of membrane distillation regenerator based on reduced pressure air gap

To reduce the regeneration energy consumption and improve the regeneration effect of liquid desiccant in membrane-based liquid desiccant air conditioning (M-LDAC), this paper combines the widely used Vacuum Membrane Distillation (VMD) and Air Gap Membrane Distillation (AGMD) methods, and innovatively proposes a reduced pressure air gap membrane distillation regeneration system, and applies the control variable method to simulate the influencing factors (desiccant temperature, flow rate, and air gap side vacuum) in the system. The results showed that the desiccant temperature and air-gap side vacuum had more influence on the system membrane flux than the flow rate, and the simulation showed that there was an optimal range of vacuum, and the membrane flux reached 12.55 kg/(m2·h) when the desiccant temperature was 90 °C, the flow rate was 0.2 m/s, and the vacuum was 40 Kpa, which increased the membrane flux by 14.8% compared with 10 Kpa. The analysis proves that the use of vacuum on the air gap side can effectively improve the membrane flux, which provides a reference for the optimal design of future liquid desiccant regenerator modules.

Performance investigation of the solar direct-driven wood regenerator in liquid desiccant air-conditioning systems

Liquid desiccant air-conditioning (LDAC) systems are one of the most promising alternatives to conventional air conditioning systems due to the high energy efficiency. The most energy-consuming part of LDAS system is desiccant regeneration, while traditional regeneration methods often fail to balance the energy grade and energy efficiency. Inspired by solar heat localization for seawater desalination, the regeneration performance of this novel method has been investigated. Here, we fabricated a wood-based regenerator by drilling holes and spaying Chinese ink, which features high sunlight absorption and strong water transportation ability. Owing to the high hydraulic conductivity of drilled holes and low thermal conductivity of wood substrate, liquid desiccant can be regenerated efficiently with a low-temperature rise. Even for 40 wt% CaCl2 solution at 30 °C, the regeneration rate and efficiency can reach 0.64 kg·m−2·h−1 and 43.2 %. Comparisons between solar interfacial regeneration method and other traditional regeneration methods were also conducted. Results show that the solar interfacial method can significantly improve the regeneration rate at the same temperature. Given the low manufacturing cost and operating cost, high regeneration rate and efficiency, superior salt-rejecting property, and low-temperature rise, the wood regenerators based on solar interfacial regeneration show great potential in LDAC systems.

Design and energy analysis of 100% fresh air based hybrid liquid desiccant air conditioning system – A case study of a thermal power plant TG building

Turbine generator (TG) buildings in thermal power plants require chilled water air conditioning systems (CWAS) to control the temperature and humidity of heat dissipated rooms, which are energy-intensive and non-eco-friendly. As an alternative, a novel refrigerant-free 100% fresh air (FA)-based hybrid liquid desiccant air conditioning system (HLDAS) is proposed and presented the methodology to design it for a case study of TG building of 2X660 MW power plant in the most humid climate. The cooling and heating requirements for HLDAS are met with a cooling tower and potential waste heat from the plant. To assess the saving potential of the proposed system, annual energy consumption for the HLDAS, 10% FA-based CWAS (CWAS-1) and 100% FA-based CWAS (CWAS-2) are quantified and compared. The results revealed that HLDAS consume 55% and 31% of CWAS-1 and CWAS-2 power consumption, respectively. Low-grade potential waste heat from the plant is estimated and found to be sufficient for solution regeneration. The proposed system is extremely energy efficient for 100% FA applications where low-grade waste heat is available. In addition to this, since there are no ODP gases associated with the proposed system, the proposed HLDAS is recommendable in view of environmentally friendly technology and indoor air quality (since it is a 100% FA-based system). This work will support HVAC engineers and researchers in designing the LDAS for a given air conditioning application.