For the development of “Grand-Potok” spectral systems and rapid high-sensitivity scintillation atomic emission spectrometry, the “VMK-Optoelektronika” company created a new BLPP-2000 photodetector linear array. Testing of the array as part of “Grand-Potok” spectral system had shown its advantages over a BLPP-369М1 array in recording scintillations of the gold Au 267.595 nm analytical spectral line. Further studies of the BLPP-2000 detector revealed the need to increase the spectral resolution of the system. For this, a new BLPP-4000 photodetector linear array has been developed. It was expected that its use would improve the resolution of the Grand spectrometer over the entire wavelength range, but a reduction in the sensitivity of the spectrometer could be possible. The objectives of this study were to experimentally compare the resolution and signal-to-noise ratio of the “Grand-Potok” spectral system using BLPP-2000, BLPP-4000, and BLPP-369М1 photodetector linear arrays and contrast the obtained results with the characteristics of the higher-resolution Grand-1500 spectrometer with BLPP-2000, which had shown good performance in determination of noble metals in geological samples with complex matrix. The data on the intensities and widths of the spectral lines were obtained from the spectra of the standard samples of various compositions and used to compare the signal-to-noise ratio and spectral resolution of the systems. The study showed that the use of the new MAES analyzers based on BLPP-4000 linear photodetector arrays in the Grand spectrometer increased the resolution of the instrument by a factor of two, while the signal-to-noise ratio of the instrument decreased by a factor of 4-6, leading to the deterioration of the detection limits in the scintillation arc atomic-emission spectrometry. Nevertheless, Grand spectrometers based on BLPP-4000 could be used instead of higher-resolution Grand-1500 spectrometers without deterioration of the detection limits as its aperture is 5–20 times higher. In addition, the signal-to-noise ratio and the resolution in Grand spectrometers with BLPP-369M1 detector arrays used in analytical laboratories could be increased by replacing the detectors with BLPP-4000 arrays. Keywords: Grand-Potok spectral system, MAES high-speed analyzer, spectral resolution, geological samples, scintillation atomic emission spectrometry (Russian) DOI: http://dx.doi.org/10.15826/analitika.2019.23.1.005 A.A. Dzyuba 1,2 , V.A. Labusov 1,2,3 , and S.A. Babin 1,2 1 Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Koptyuga, 1, Novosibirsk, 630090, Russian Federation 2 VMK-Optoelektronika, pr. Akademika Koptyuga, 1, Novosibirsk, 630090, Russian Federation 3 Novosibirsk State Technical University, pr. K. Marksa, 20, Novosibirsk, 630073, Russian Federation
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