Abstract Based on the principle of K-edge technology and particle transport theory, the article establishes the calculation model of K-edge measurement technology, which includes key components such as the continuous X-ray light source, high-purity germanium detector, cylindrical sample, collimator, and so on. In terms of light source setting, the light source function was obtained by linear interpolation method according to the X-ray light source model formula; in terms of K-edge absorption distance, the average K-edge absorption distance calculation method was adopted to improve the concentration calculation formula. The calibration factor was obtained under the experimental conditions with 8mm diameter sample bottles. Under identical experimental conditions, the validation was tested out using samples with concentrations of 150g/L and 300g/L. The reconstructed Uranium concentrations were 148.5g/L and 294g/L, with deviations of 1% and 2% between the initial values, respectively. To further validate the correctness of the modified concentration calculation formula, the diameters of the sample bottles were altered to 6mm and 10mm, and the corresponding calibration factors were obtained respectively. Verification experiments were subsequently carried out using solutions with concentrations of 150g/L and 300g/L. The simulation outcomes validate the accuracy of the model and the modified concentration calculation formula. The calculation model constructed in the article combines with actual application scenarios to provide preliminary technical assurance for the expansion and optimization of K-edge measurement technology.
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