This paper proposes a new intuitionistic fuzzy best-worst method (IFBWM) for group decision making (GDM) with intuitionistic fuzzy (IF) preference relations (IFPRs). IF values (IFVs) are used to express reference comparisons of criteria. Based on the additive consistency of IFPRs, this paper proposes the definition of additive consistency of IF reference comparisons (IFRCs). Based on the deviation minimization, a linear goal programming model is established to calculate the optimal IF priority weights. By the additive consistency, the consistency index in the closed form is computed by the score function of IFVs. A new approach is devised to enhance the additive consistency of IFRCs. Thus, an IFBWM with the additive consistency of IFRCs is proposed. For GDM with IFPRs, the best criterion and the worst criterion are identified for each decision maker by constructing the score matrix of the IFPR. The individual ranking order of the criteria is obtained by using the proposed IFBWM. Then, the collective ranking order of the criteria is obtained via building a 0–1 integer programming model. Therefore, a GDM method based on the developed IFBWM with IFPRs is proposed. Four examples are analyzed to demonstrate the effectiveness and the advantages of the proposed IFBWM for GDM.