Line Shape Research Articles

Polarization spectroscopy of 87Rb-D2 line using structured light: controlling the line shape of closed hyperfine transition

Polarization spectroscopy of 87Rb-D2 line using structured light: controlling the line shape of closed hyperfine transition

Branching ratios and CP asymmetries of the quasi-two-body decays Bc→K0∗(1430,1950)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow \\ K^{*}_0(1430,1950) D_{(s)} \\rightarrow K \\pi D_{(s)} $$\\end{document} in the PQCD approach

In this paper, we investigate the quasi-two-body decays Bc→K0∗(1430,1950)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1430,1950) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document} within the perturbative QCD (PQCD) framework. The S-wave two-meson distribution amplitudes (DAs) are introduced to describe the final state interactions of the Kπ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K\\pi $$\\end{document} pair, which involve the time-like form factors and the Gegenbauer polynomials. In the calculations, we adopt two kinds of parameterization schemes to describe the time-like form factors: one is the relativistic Breit–Wigner (RBW) formula, which is usually more suitable for the narrow resonances, and the other is the LASS line shape proposed by the LASS Collaboration, which includes both the resonant and nonresonant components. We find that the branching ratios and the direct CP violations for the decays Bc→K0∗(1430)D(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1430) D_{(s)}$$\\end{document} obtained from those of the quasi-two-body decays Bc→K0∗(1430)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1430) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document} under the narrow width approximation (NWA) can be consistent well with the previous PQCD results calculated in the two-body framework by assuming that K0∗(1430)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K^*_0(1430)$$\\end{document} is the lowest lying q¯s\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\bar{q} s$$\\end{document} state, which is the so-called scenario II (SII). We conclude that the LASS parameterization is more suitable to describe the K0∗(1430)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K_0^{*}(1430)$$\\end{document} than the RBW formula, and the nonresonant components play an important role in the branching ratios of the decays Bc→K0∗(1430)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1430) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document}. In view of the large difference between the decay width measurements for the K0∗(1950)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K_0^{*}(1950)$$\\end{document} given by BaBar and LASS collaborations, we calculate the branching ratios and the CP violations for the quasi-two-body decays Bc→K0∗(1950)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1950) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document} by using two values, ΓK0∗(1950)=0.100±0.04\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Gamma _{K^*_0(1950)}=0.100\\pm 0.04$$\\end{document} GeV and ΓK0∗(1950)=0.201±0.034\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Gamma _{K^*_0(1950)}=0.201\\pm 0.034$$\\end{document} GeV, besides the two kinds of parameterizations for the resonance K0∗(1950)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K^*_0(1950)$$\\end{document}. We find that the branching ratios and the direct CP violations for the decays Bc→K0∗(1950)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1950) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document} have not as large difference between the two parameterizations as the case of decays involving the K0∗(1430)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K^*_0(1430)$$\\end{document}, especially for the results with ΓK0∗(1950)=0.201±0.034\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Gamma _{K^*_0(1950)}=0.201\\pm 0.034$$\\end{document} GeV. The effect of the nonresonant component in the K0∗(1950)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K^*_0(1950)$$\\end{document} may be not so serious as that in the K0∗(1430)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K^*_0(1430)$$\\end{document}. The quasi-two-body decays Bc+→K0∗+(1430)D0→K0π+D0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B^+_c \\rightarrow K^{*+}_0(1430) D^{0} \\rightarrow K^0 \\pi ^+ D^{0}$$\\end{document} and Bc+→K0∗0(1430)D+→K+π-D+\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B^+_c \\rightarrow K^{*0}_0(1430) D^{+} \\rightarrow K^+ \\pi ^- D^{+}$$\\end{document} have large branching ratios, which can reach to the order of 10-4\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$10^{-4}$$\\end{document} and are most likely to be observed in the future LHCb experiments. Furthermore, the branching ratios of the quasi-two-body decays Bc→K0∗(1950)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1950) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document} are about one order smaller than those of the corresponding decays Bc→K0∗(1430)D(s)→KπD(s)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B_c \\rightarrow K_0^{*}(1430) D_{(s)} \\rightarrow K \\pi D_{(s)}$$\\end{document}.

Detecting Chirality-Induced Spin Selectivity in Randomly Oriented Radical Pairs Photogenerated by Hole Transfer.

Chirality-induced spin selectivity (CISS) has the potential to control the spin dynamics of chiral molecules for applications in quantum information science. Here we investigate the effect of CISS on the spin dynamics of radical pair formation following photodriven hole transfer in a pair of donor-chiral bridge-acceptor (D-Bχ-A) enantiomers, where D = 2,2,6,6-tetramethyl[1,3]-dioxolo[4,5-f][1,3]benzodioxole, Bχ = (R)- or (S)-2,2'-dimethoxy-4,4'-diphenyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene, and A = naphthalene-(1,4:5,8)-bis(dicarboximide). The results are compared to those obtained on the corresponding achiral D-B-A reference molecule in which B = 2″,3',5',6″-tetramethyl-1,1':4',1″:4″,1‴-quaterphenyl. Photoexcitation of A in a randomly oriented sample of D-Bχ-A in glassy butyronitrile at 85 K results in subnanosecond two-step hole transfer from 1*A to D to form D•+-Bχ-A•-, which was characterized using time-resolved electron paramagnetic resonance (TREPR) spectroscopy at X (9.6 GHz), Q (34 GHz), and W (94 GHz) bands. The spectra show line shape changes that are characteristic of a ∼38% contribution of CISS to the spin dynamics of D•+-Bχ-A•- formation. The line shape changes resulting from CISS are particularly apparent in the TREPR spectra at X-band as predicted by recent theory. These results show that (1) CISS has a significant influence on radical pair dynamics initiated by photodriven hole transfer, which is complementary to our recent electron transfer results, and (2) CISS can be detected using TREPR on radical pairs that are randomly oriented relative to an external magnetic field.

An inter-satellite laser occultation method profiling atmospheric temperature and pressure from troposphere to lower mesosphere

We propose a laser occultation method for simultaneous profiling atmospheric temperature and pressure. Measurements can be performed on the optical link between two low-orbit satellites, where frequency-stepwise laser pulses are transmitted from one to the other. These pulses, covering several oxygen absorption lines in the wavelength domain, measure the broadened atmospheric absorption optical depth along the transmission path with a spectral resolution of tens of megahertz. In this way, atmospheric temperature and pressure are obtained by analysing the retrieved shape and intensity of the spectral lines. With the motion of the two satellites, the inter-satellite optical link penetrates different atmospheric layers at various altitudes, enabling the measurement of the vertical structure of atmospheric thermodynamic parameters from the troposphere to the lower thermosphere. This paper presents an end-to-end simulation of the proposed method, including models for laser occultation beam tracing, radiative transfer, and data inversion. The simulation results reveal that with minimal satellite payload resources, this method can accurately measure temperature and pressure at a vertical resolution of 100 m from 5 km to 90 km altitude with accuracies of ±1.5 K and 5 %, respectively. As the proposed differential absorption laser occultation method is independent of the hydrostatic equilibrium hypothesis for data inversion, it can eliminate errors associated with prior data at reference altitudes. It is believed that our method has provided a promising approach to laser satellite constellation for atmospheric observation.

Hydration structure and dynamics of phosphoric acid and its anions-Ultrafast 2D-IR spectroscopy and abinitio molecular dynamics simulations.

The hydration shells of phosphate ions and phosphate groups of nucleotides and phospholipid membranes display markedly different structures and hydrogen-bond strengths. Understanding phosphate hydration requires insight into the spatial arrangements of water molecules around phosphates and in thermally activated structure fluctuations on ultrafast time scales. Femtosecond two-dimensional infrared spectroscopy of phosphate vibrations, particularly asymmetric stretching vibrations between 1000 and 1200cm-1, and abinitio molecular dynamics (AIMD) simulations are combined to map and characterize dynamic local hydration structures and phosphate-water interactions. Phosphoric acid H3PO4 and its anions H2PO4-, HPO42-, and PO43- are studied in aqueous environments of different pH value. The hydration shells of phosphates providing OH donor groups in hydrogen bonds with the first water layer undergo ultrafast structural fluctuations, which induce a pronounced spectral diffusion of vibrational excitations on a sub-300fs time scale. With a decreasing number of phosphate OH groups, the hydration shell becomes more ordered and rigid. The 2D-IR line shapes observed with hydrated PO43- ions display a pronounced inhomogeneous broadening, reflecting a distribution of hydration geometries without fast equilibration. The AIMD simulations allow for an in-depth characterization of the hydration geometries with different numbers of water molecules in the first hydration layer and different correlation functions of the fluctuating electric field that the water environment exerts on the vibrational phosphate oscillators.

Analyzing the effect of undermining on suture forces during simulated skin flap surgeries with a three-dimensional finite element method

Skin flaps are common procedures used by surgeons to cover an excised area during the reconstruction of a defect. It is often a challenging task for a surgeon to come up with the most optimal design for a patient. In this paper, we set up a simulation system based on the finite element method for one of the most common flap types — the rhomboid flap. Instead of using the standard 2D planar patch, we constructed a 3D patch with multiple layers. This allowed us to investigate the impact of different undermining areas and depths. We compared the suture forces for each case and identified vertices with the largest suture force. The shape of the final suture line is also visualized for each case, which is an important clue when deciding on the most optimal skin flap orientation according to medical textbooks. We found that under the optimal undermining setup, the maximum suture force is around 0.7 N for top of the undermined layer and 1.0 N for bottom of the undermined layer. When measuring difference in final suture line shape, the maximum normalized Hausdorff distance is 0.099, which suggests that different undermining region can have significant impact on the shape of the suture line, especially in the tail region. After analyzing the suture force plots, we provided recommendations on the most optimal undermining region for rhomboid flaps.

Estimation of the Global Equivalence Ratio of a Swirl Combustor from a Small Number of Absorption Spectra Using Machine Learning.

A new optical diagnostic method that predicts the global fuel-air equivalence ratio of a swirl combustor using absorption spectra from only three optical paths is proposed here. Under normal operation, the global equivalence ratio and total flow rate determine the temperature and concentration fields of the combustor, which subsequently determine the absorption spectra of any combustion species. Therefore, spectra, as the fingerprint for a produced combustion field, were employed to predict the global equivalence ratio, one of the key operational parameters, in this study. Specifically, absorption spectra of water vapor at wavenumbers around 7444.36, 7185.6, and 6805.6 cm-1 measured at three different downstream locations of the combustor were used to predict the global equivalence ratio. As it is difficult to find analytical relationships between the spectra and produced combustion fields, a predictive model was a data-driven acquisition. The absorption spectra as an input were first feature-extracted through stacked convolutional autoencoders and then a dense neural network was used for regression prediction between the feature scores and the global equivalence ratio. The model could predict the equivalence ratio with an absolute error of ±0.025 with a probability of 96%, and a gradient-weighted regression activation mapping analysis revealed that the model leverages not only the peak intensities but also the variations in the shape of absorption lines for its predictions.

Dynamical theory of single-photon transport through a qubit chain coupled to a one-dimensional nanophotonic waveguide

We study the dynamics of a single-photon pulse traveling through a linear qubit chain coupled to continuum modes in a one-dimensional (1D) photonic waveguide. We derive a time-dependent dynamical theory for qubits’ amplitudes and for transmitted and reflected spectra. We show that the requirement for the photon-qubit coupling to exist only for positive frequencies can significantly change the dynamics of the system. First, it leads to the additional photon-mediated dipole-dipole interaction between qubits which results in the violation of the phase coherence between them. Second, the spectral lines of transmitted and reflected spectra crucially depend on the shape of the incident pulse and on the initial distance between the pulse center and the first qubit in the chain. We apply our theory to one-qubit and two-qubit systems. For these cases we obtain the explicit expressions for the qubits’ amplitudes and for the photon radiation spectra as time tends to infinity. Specific calculations are performed for superconducting qubits operating in GHz frequency range. For the incident Gaussian wave packet we calculate the line shapes of transmitted and reflected photons.

Design and control of topological Fano resonance in Kane-Mele nanoribbons for sensing applications

The concept of topological Fano resonance, characterized by an ultrasharp asymmetric line shape, is a promising candidate for robust sensing applications due to its sensitivity to external parameters and immunity to structural disorder. In this study, the vacancy-induced topological Fano resonance in a nanoribbon made up of a hexagonal lattice with armchair sides is examined by introducing several on-site vacancies, which are deliberately created at regular distances, along a zigzag chain that stretches across the width of the ribbon. The presence of the on-site vacancies can create localized energy states within the electronic band structure, leading to the formation of an impurity band, which can result in Fano resonance phenomena by forming a conductivity channel between the edge modes on both armchair sides of the ribbon. Consequently, an ultracompact tunable on-chip integrated topological Fano resonance derived from the graphene-based nanomechanical phononic crystals is proposed. The Fano resonance arises from the interference between topologically protected even and odd edge modes at the interface between trivial and nontrivial insulators in a nanoribbon structure governed by the Kane-Mele model describing the quantum spin Hall effect in hexagonal lattices. The simulation of the topological Fano resonance is performed analytically using the Lippmann-Schwinger scattering formulation. One of the advantages of the present study is that the related calculations are carried out analytically, and in addition to the simplicity and directness, it reproduces the results obtained from the Landauer-Büttiker formulation very well both quantitatively and qualitatively. The findings open up possibilities for the design of highly sensitive and accurate robust sensors for detecting extremely tiny forces, masses, and spatial positions.

Axion Minicluster Streams in the Solar Neighborhood.

A consequence of QCD axion dark matter being born after inflation is the emergence of small-scale substructures known as miniclusters. Although miniclusters merge to form minihalos, this intrinsic granularity is expected to remain imprinted on small scales in our galaxy, leading to potentially damaging consequences for the campaign to detect axions directly on Earth. This picture, however, is modified when one takes into account the fact that encounters with stars will tidally strip mass from the miniclusters, creating pc-long tidal streams that act to refill the dark matter distribution. Here we ask whether or not this stripping rescues experimental prospects from the worst-case scenario in which the majority of axions remain bound up in unobservably small miniclusters. We find that the density sampled by terrestrial experiment on mpc scales will be, on average, around 70%-90% of the average local DM density, and at a typical point in the solar neighborhood, we expect most of the dark matter to be comprised of debris from O(10^{2}-10^{3}) overlapping streams. If haloscopes can measure the axion signal with high-enough frequency resolution, then these streams are revealed in the form of an intrinsically spiky line shape, in stark contrast with the standard assumption of a smooth, featureless Maxwellian distribution-a unique prediction that constitutes a way for experiments to distinguish between pre- and postinflationary axion cosmologies.

Specific line shape of the lowest frequency Raman scattering modes of triethylene glycol.

For both dielectric spectroscopy and light scattering spectra, the relaxation modes in the microwave region have been characterized by the Debye relaxation model, which is determined by the peak frequency, or by an empirically extended model (e.g., Cole-Davidson and Kohlrausch-Williams-Watts), which has the appropriate line shape. For light scattering from glass-forming liquids, the general line shape is a broader high frequency side in comparison with Debye relaxation. However, for triethylene glycol (TEG) in liquid form at room temperature, the lowest frequency Raman scattering (LFR) mode shows a peak at about 3.0GHz, which is narrower than that expected for the Debye relaxation. With increasing temperature, this peak exhibits a significant blueshift and begins to resemble the Debye relaxation shape, indicating that the LFR mode of TEG is also a relaxation mode. The narrowing of the LFR mode of TEG is suggested to be caused from the increased non-whiteness of the fluctuation correlations due to increased hydrogen bonding. This is a consequence of breaking the Debye relaxation model's approximation of the overdamping and narrowing limits in the GHz region, which was found in this study by analyzing the relaxation modes of Raman scattering using the multiple random telegraph model for evaluating thermal bath correlation. The analysis results show that the LFR relaxation times of TEG and the main dielectric relaxation overlap only by 333K. However, the second LFR mode and β-relaxation at higher frequencies coincide over a wide temperature range, suggesting that they are corresponding modes.

Controlling a Virtual Structure Involving a UAV and a UGV for Warehouse Inventory

A control system based on the control paradigm of virtual structure is here proposed for a multi-robot system involving a quadrotor and a ground vehicle, operating in an automated warehouse. The ground robot can either provide extra power to the quadrotor, thus increasing its autonomy, or receive data from it. Therefore, the quadrotor is tethered to the ground robot through flexible cables, thus justifying the adoption of the virtual structure control paradigm, which allows controlling the two vehicles simultaneously. The control approach adopted aims at guiding the virtual vertical line joining the two robots to allow the quadrotor to produce an inventory of goods in an automated warehouse. Therefore, the two robots should visit a sequence of known positions, in front of cabinets of vertically arranged shelves. In each of them the quadrotor should read QR codes, bar-codes or RFID cards corresponding to the stored boxes, to produce the inventory. Therefore, the control objective, the focus of this paper, is to keep the shape of the virtual vertical line linking the two robots while moving. However, when an obstacle appears in the route, such as a box or other robot in the floor or another aerial robot, the formation changes its shape accordingly, to avoid the obstacle. An experiment in lab scale, mimicking a real situation, is run, whose results allow claiming that the proposed system is an effective solution for the problem of controlling a multi-robot system to produce an inventory in an automated warehouse.

The Far-INfrarEd Spectrometer for Surface Emissivity (FINESSE) – Part 1: Instrument description and level 1 radiances

Abstract. The Far-INfrarEd Spectrometer for Surface Emissivity (FINESSE) instrument combines a commercial Bruker EM27 spectrometer with a front-end viewing and calibration rig developed at Imperial College London. FINESSE is specifically designed to enable accurate measurements of surface emissivity, covering the range 400–1600 cm−1, and, as part of this remit, can obtain views over the full 360° angular range. In this part, Part 1, we describe the system configuration, outlining the instrument spectral characteristics, our data acquisition methodology, and the calibration strategy. As part of the process, we evaluate the stability of the system, including the impact of knowledge of blackbody (BB) target emissivity and temperature. We also establish a numerical description of the instrument line shape (ILS), which shows strong frequency-dependent asymmetry. We demonstrate why it is important to account for these effects by assessing their impact on the overall uncertainty budget on the level 1 radiance products from FINESSE. Initial comparisons of observed spectra with simulations show encouraging performance given the uncertainty budget.

Elucidating phonon dephasing mechanisms in layered perovskites with coherent Raman spectroscopies.

Organic-inorganic hybrid perovskite quantum wells exhibit electronic structures with properties intermediate between those of inorganic semiconductors and molecular crystals. In these systems, periodic layers of organic spacer molecules occupy the interstitial spaces between perovskite sheets, thereby confining electronic excitations to two dimensions. Here, we investigate spectroscopic line broadening mechanisms for phonons coupled to excitons in lead-iodide layered perovskites with phenyl ethyl ammonium (PEA) and azobenzene ethyl ammonium (AzoEA) spacer cations. Using a modified Elliot line shape analysis for the absorbance and photoluminescence spectra, polaron binding energies of 11.2 and 17.5meV are calculated for (PEA)2PbI4 and (AzoEA)2PbI4, respectively. To determine whether the polaron stabilization processes influence the dephasing mechanisms of coupled phonons, five-pulse coherent Raman spectroscopies are applied to the two systems under electronically resonant conditions. The prominence of inhomogeneous line broadening mechanisms detected in (AzoEA)2PbI4 suggests that thermal fluctuations involving the deformable organic phase broaden the distributions of phonon frequencies within the quantum wells. In addition, our data indicate that polaron stabilization primarily involves photoinduced reorganization of the organic phases for both systems, whereas the impulsively excited phonons represent less than 10% of the total polaron binding energy. The signal generation mechanisms associated with our fifth-order coherent Raman experiments are explored with a perturbative model in which cumulant expansions are used to account for time-coincident vibrational dephasing and polaron stabilization processes.

Charge Phenomena in the Elastic Backscattering of Electrons from Insulating Polymers.

Elastic peak electron spectroscopy (EPES) analyzes the line shape of the elastic peak. The reduction in energy of the elastic peak electrons is the result of energy transfer to the target atoms, a phenomenon known as recoil energy. EPES differs from other electron spectroscopies in its unique ability to identify hydrogen in polymers and hydrogenated carbon-based materials. This feature is particularly noteworthy as lighter elements exhibit stronger energy shifts. The energy difference between the positions of the elastic peak of carbon and the elastic peak of hydrogen tends to increase as the kinetic energy of the incident electrons increases. During electron irradiation of an insulating polymer, if the number of secondary electrons emitted from the surface is less than the number of electrons absorbed in the sample, the surface floats energetically until it stabilizes at a potential energy eVs. As a result, the interaction energy changes and modifies the energy difference between the elastic peaks of hydrogen and carbon. In this study, the charge effects are evaluated using the Monte Carlo method to simulate the EPES spectra of electrons interacting with polystyrene and polyethylene.

Application of Odd-Order Derivatives in Fourier Transform Nuclear Magnetic Resonance Spectroscopy toward Quantitative Deconvolution.

When Fourier transform (FT) spectrum peaks are overlapped, primary maxima of odd-order derivatives can be used to evaluate their independent intensities. We studied the feasibility of higher odd-order derivatives on Lorentzian peak shape and magnitude peak shape. Simulation studies for FT nuclear magnetic resonance (NMR) spectroscopy demonstrated good results toward quantitative deconvolution of overlapping FT spectrum peaks. Although it is not so desirable to deconvolute special line shapes such as Gaussian, Voigt, and Tsallis profiles, the odd-order derivatives exhibit a bright future compared to even-order derivatives. An application example of practical NMR spectroscopy with ethylbenzene isomers is presented. White Gaussian noises were added to the simulated spectra at two different signal-to-noise ratios (20 and 40). Kauppinen's denoising and smoothing algorithms can effectively remove interference of the noise and help to have good deconvoluting results using the odd-order derivatives. We compared features of our approach with popular deconvolution sharpening algorithms and conducted a comparison study with Kauppinen's Fourier self-deconvolution. Our approach has a better dynamic range of peak intensities and is not sensitive to the sampling rates. Other common deconvolution methods are also discussed briefly.

Temperature dependence of line shape parameters for N2- and O2-broadened methane lines by quantum cascade laser spectroscopy

This paper report nitrogen- and oxygen-broadening coefficients, their speed-dependencies, and the collisional narrowing parameters of lines in the ν4-band of methane. The parameters were determined from low (150 K) to high temperatures (600 K). The measurements were done with a high-resolution quantum cascade laser spectrometer coupled to specific absorption cells that allow to cool and heat the gas mixtures with a great stability. The spectroscopic parameters were determined at each temperature by fits of the experimental absorbances in a multispectrum fitting procedure using the Voigt, Speed-Dependent Voigt, Nelkin-Ghatak and Speed-dependent Nelkin-Ghatak theoretical line shape models. The temperature dependencies of the collisional half-widths, the speed-dependence of the broadening coefficients as well as the collisional narrowing parameters were studied with the empirical power law and the physics-based Gamache-Vispoel model (DPL) [Gamache and Vispoel, JQSRT, 217, 440–452, 2018]. The obtained line shape parameters and their temperature dependencies are compared, when possible, to existing data in literature. The DPL reproduces more accurately the evolution of the studied collisional parameters over the wide range of temperature considered in the study.

Deepest sensitivity to wavelike dark photon dark matter with superconducting radio frequency cavities

Wavelike, bosonic dark matter candidates like axions and dark photons can be detected using microwave cavities known as haloscopes. Traditionally, haloscopes consist of tunable copper cavities operating in the TM010 mode, but ohmic losses have limited their performance. In contrast, superconducting radio frequency (SRF) cavities can achieve quality factors of ∼1010, perhaps 5 orders of magnitude better than copper cavities, leading to more sensitive dark matter detectors. In this paper, we first derive that the scan rate of a haloscope experiment is proportional to the loaded quality factor QL, even if the cavity bandwidth is much narrower than the dark matter halo line shape. We then present a proof-of-concept search for dark photon dark matter using a nontunable ultrahigh-quality SRF cavity. We exclude dark photon dark matter with kinetic mixing strengths of χ>1.5×10−16 for a dark photon mass of mA′=5.35 μeV, achieving the deepest exclusion to wavelike dark photons by almost an order of magnitude. Published by the American Physical Society 2024

Analysis on dual Fano resonance in a coupled-resonator waveguide

Dual Fano resonance was demonstrated in a compact coupling system without additional large footprint tunable devices consisting of a grating-coupled waveguide and a micro-racetrack resonator on thin film lithium niobate. A multimode interference model was proposed for the dual Fano resonance system. The inverse design method was used to realize model fitting, validate our model, and analyze our model. Based on the parameters obtained by the inverse design, we further analyzed the influence of different parameters. Our research also shows that through the interaction of two Fano resonance modes, tunable line shape and enhanced extinction ratio can be realized in the transmission spectrum, which has potential applications in optical sensing.

(Keynote) Unified Quantum Theory of Electrochemical Kinetics Based on Coupled Ion-Electron Transfer

A general theory of coupled ion–electron transfer (CIET) is presented, which unifies quantum kinetics of electron transfer (ET) with classical kinetics of bond-breaking ion transfer (IT) in a general framework of non-equilibrium thermodynamics [1]. In the limit of large reorganization energy, the theory predicts Marcus kinetics of “electron-coupled ion transfer” (ECIT). In the limit of large ion-transfer energies, the theory predicts generalized Butler–Volmer kinetics of “ion-coupled electron transfer” (ICET), where the charge transfer coefficient and exchange current are connected to microscopic properties of the electrode/electrolyte interface. In the ICET regime, the reductive and oxidative branches of Tafel’s law are predicted to hold over a wide but finite range of overpotentials, bounded by the ion-transfer energies for oxidation and reduction, respectively. The probability distribution of transferring electron energies in CIET smoothly interpolates between a shifted Gaussian distribution for ECIT (as in the Gerischer–Marcus theory of ET) to an asymmetric, fat-tailed Meixner distribution centered at the Fermi level for ICET. The latter may help interpret asymmetric line shapes in x-ray photo-electron spectroscopy (XPS) and Auger electron spectroscopy (AES) for oxidized metal surfaces in terms of shake-up relaxation of the ionized atom and its image polaron by ICET. In the limit of large overpotentials, the theory predicts a transition to inverted Marcus ECIT, leading to a universal reaction-limited current for metal electrodes, dominated by barrierless quantum transitions. Uniformly valid, closed-form asymptotic approximations are derived that smoothly transition between the limiting rate expressions for ICET and ECIT for metal electrodes, using simple but accurate mathematical functions. The theory is applied to lithium intercalation in lithium iron phosphate (LFP) and found to provide a consistent description of the observed current dependence on overpotential, temperature and concentration, learned from x-ray images [2]. CIET theory thus provides a critical bridge between quantum electrochemistry and electrochemical engineering.[1] M. Z. Bazant, Unified quantum theory of electrochemical kinetics by coupled ion-electron transfer, Faraday Discussions 246, 60-124 (2023).[2] H. Zhao, H. D. Deng, A. E. Cohen, J. Lim, Y. Li, D. Fraggedakis, B. Jiang, B. D. Storey, W. C. Chueh, R. D. Braatz, and M. Z. Bazant, Learning heterogeneous reaction kinetics from X-ray movies pixel-by-pixel, Nature 621, 289-294 (2023). Figure 1