Hot atomic populations are an important component of the planetary exospheres. Usually, radiative transfer models describing the scattering of light by moving atoms assume that these populations have a Maxwellian velocity distribution. However, the velocity distributions of the hot populations could actually have some more extended wings. Popular velocity distributions often used in plasma physics and recently proposed to describe neutral planetary environments are Kappa velocity function distributions. In this paper, following the work of Hummer [Non-coherent scattering: I The redistribution functions with Doppler broadening. R Astron. Soc Month Not 1962;125:21] and Cranmer [Non-Maxwellian redistribution in solar coronal Lyα emission. Astrophys J 1998;508:925–39], we calculate the frequency redistribution functions of radiation scattered by moving atoms with Kappa velocity distribution. We also present a detailed study of a radiative transfer model taking into account Kappa velocity distribution functions, for integer and semi-integer values of κ. We apply this theory to a model of Jupiter hydrogen corona containing 0.1% column density of hot hydrogen to quantify the spectroscopic and imaging differences between Kappa velocity distributions and bi-Maxwellian velocity distributions. When assuming a Kappa velocity distribution with κ=2 for the hot population, intensity increases of ∼40% occur at the bright limb and ∼15% on the disk compared with the same calculations done using a Maxwellian velocity distribution. The line profile differs slightly from a Maxwellian distribution on the disk and at the bright limb, but the difference is larger above the limb. Kappa distributions used to study the Jovian atmosphere are speculative and further studies are needed to link the formation of the hot exospheric populations to the Kappa velocity distributions.
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