Quasi-logarithmic combinatorial structures are a class of decomposable combinatorial structures which extend the logarithmic class considered by Arratia, Barbour and Tavaré (2003). In order to obtain asymptotic approximations to their component spectrum, it is necessary first to establish an approximation to the sum of an associated sequence of independent random variables in terms of the Dickman distribution. This in turn requires an argument that refines the Mineka coupling by incorporating a blocking construction, leading to exponentially sharper coupling rates for the sums in question. Applications include distributional limit theorems for the size of the largest component and for the vector of counts of the small components in a quasi-logarithmic combinatorial structure.