Bi-continuous nano-porous metallic glasses (MG) synergize the outstanding properties of MGs and open-cell nano-porous materials. The low-density and high-specific-surface-area of bi-continuous nano-porous structures have the potential to enhance the applicability of MGs in catalysis, sensors, and lightweight structural designs. Here, we report molecular dynamics simulations of tensile loading deformation and failure of bi-continuous nano-porous Cu64Zr36 MG with 55% porosity and 4.4 nm ligament size. Results indicate an anomalous mechanical behavior featuring delocalized plastic deformation preceding ductile failure. The deformation follows two mechanisms: i) Necking of ligaments aligned with the loading direction and ii) progressive alignment of randomly oriented ligaments. Failure occurs at 0.16 strain, following successive necking and rupture events. This work indicates that a bi-continuous nano-porous design is able to effectively delocalize strain localization in a MG due to a combination of size effect on the ductility of MGs resulting in nano-ligaments necking and progressive asynchronous alignment of ligaments.
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