The light yields of luminescence (Glum) and the yields of excited ion production (yields of excitation, Gext) were measured for the first time for a number of trivalent lanthanide ions (Ln3+) during moving single-bubble sonoluminescence in solutions of 10-2 M Ln3+ in 70% H2SO4. The luminescence yields were determined by comparing the integrated sonoluminescence intensity of the test solution with the radioluminescence intensity of the reference light source, and the excitation yields were found from the relation Gext = Glum/φ, where φ are the photoluminescence quantum yields of Ln3+ ions in the solution, which were also measured experimentally in the work. Determined yields Glum = (0.63, 0.96, 1.8, 5.1, 0.49)´107 photon/100 eV and Gext = (0.066, 1.6, 0.7, 1.5, 0.7)´108 excited ions/100 eV for Ce3+, Eu3+, Gd3+, Tb3+ ions, Dy3+, respectively. It was confirmed that, as previously shown in the case of radiation-excited luminescence of lanthanide ions (Kazakov V.P., Sharipov G.L. Radioluminescence of aqueous solutions. M.: Nauka, 1986. p. 116), transition with a change in the principal quantum number (4f→5d, Ce3+ ion) is an order of magnitude or less lower than the excitation yield in a transition without its change (4f→4f, Eu3+, Tb3+ , and others ions).
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