Scattered Light Intensity Research Articles

Effects of continuous phase plate on plasma corona homogeneity and laser-plasma instabilities in experiments with three target materials

Corona homogeneity and spectra of scattered light and hot electrons produced by laser-plasma instabilities inside laser-produced plastic, aluminum, and gold plasmas were investigated with and without the use of continuous phase plate (CPP) to the laser beam. Improvement of the corona homogeneity was observed for all three materials after applying CPP, while the inhibition of the intensity of backward-scattered light and the amount of emitted hot electrons was not always synchronous for different materials, which is interpreted as a result of the changes in thresholds of the stimulated Raman scattering (SRS) and the two-plasmon decay (TPD) instability before and after the application of CPP. By comparing the changes of SRS scattered light intensity with the amount of hot electrons in different kinetic energy ranges for all three target materials in our experiments, we conclude that SRS is more responsible for the diagnosed hot electrons between 50–150 keV, and those above 150 keV should be generated by TPD, which could be explained by the difference in phase velocity of electron plasma waves between SRS and TPD calculated from measured and simulated parameters of corona and laser-plasma instabilities.

Optical-depth scaling of light scattering from a dense and cold atomic Rb87 gas

We report investigation of near-resonance light scattering from a cold and dense atomic gas of $^{87}$Rb atoms. Measurements are made for probe frequencies tuned near the $F=2\to F'=3$ nearly closed hyperfine transition, with particular attention paid to the dependence of the scattered light intensity on detuning from resonance, the number of atoms in the sample, and atomic sample size. We find that, over a wide range of experimental variables, the optical depth of the atomic sample serves as an effective single scaling parameter which describes well all the experimental data.

Evidence of absorption dominating over scattering in light attenuation by nanodiamonds

We show an experimental evidence of the domination of absorption over scattering in absorbance spectra of detonation nanodiamonds. We perform the absorbance measurements on the UV-Vis spectrophotometer equipped with integrating sphere and compare them with conventional absorbance spectra. Additionally, we measure the scattering light intensity at the cuvette side wall (scattering at 90 degrees angle). The obtained experimental data were interpreted using the simulations of photon random walk in turbid media and Kubelka-Munk approach. The scattering cross sections and indicatrices were obtained by Mie theory. We discover that despite being very close to $\lambda^{-4}$ power law (like Rayleigh scattering) the light extinction by the primary 4 nm diamond crystallites is due to absorption only and scattering can be neglected. That is the reason why previously absorption and scattering contributions were confused. The scattering is governed only by the agglomerates of 100 nm and larger in size remaining in the hydrosols and their fraction can be effectively controlled by centrifugation. Only Mie theory reproduces correctly the close to $\lambda^{-2}$ scattering by the agglomerates accounting for the weird interplay between their size, fractal dimension, and dielectric properties. Finally, using the obtained absorbance spectra we estimate the fraction of non diamond phase in nanodiamonds and their agglomerates.

Sequential Extraction of Late Exponentials (SELE): A technique for deconvolving multimodal correlation curves in Dynamic Light Scattering

Abstract:In techniques such as Dynamic Light Scattering (DLS), Fluorescence Correlation Spectroscopy, and image mining, motion is tracked by the autocorrelation of a signal over logarithmic time scales. For instance the tracking signal in DLS is the scattered light intensity; it remains correlated at time scales where scant changes in the arrangement of the scattering particles occur, but decays exponentially at the time scales of their diffusion. When there are multiple time scales of motion (for instance due to scatterers of different sizes), the correlation curve has more than one exponential fall. Extracting the decay constants or hydrodynamic sizes due to each exponential fall in a multi-species field correlation curve becomes an ill-conditioned mathematical problem. We describe a new algorithm to invert a multi-modal correlation curve by Sequential Extraction of the Late Exponentials (SELE). The idea is that while the inversion of a multi-exponential equation may be ill posed, that of a single exponential is not. So we fit data windows towards to base of the correlation curve to extract the largest contribution species, remove the species contribution from the correlation curve, and repeat the process with the remnant curve. The single exponent can be robustly fitted by least-square minimization with initial guesses generated by an adapted cumutant technique (power-series) that includes stretch coefficients (measure of sample dispersity). The proposed algorithm resolves particle sizes separated by 3X, and is reliable against fluctuations in the correlation curve and to localized regions of suboptimal data. The algorithm can be used to track particle dynamics in solution in multi-species problems such as self-assembly.

Light scattering study of highly absorptive, non-fractal, hematite aggregates

We present measurements of the scattered light intensity by aerosolized hematite aggregate particles. The measurements were made at a wavelength of 532 nm in the scattering angle range from 0.32° to 157°. Hematite has high values of the real and imaginary parts of the refractive index m = n + iκ = 3 + i0.5 at the studied wavelength. Scanning electron micrographs (SEM) indicated that the particles were aggregates whereas the optical microscope pictures showed that the aerosol had a bimodal distribution with effective mean diameters of roughly 1 and 10 µm. This is consistent with the light scattering results which displayed two Guinier regimes. The aggregates were composed of smaller grains with an approximate size of 200 nm. Ultra Small-Angle X-ray Scattering (USAXS) indicate that the aggregates were uniform and non-fractal. Mie calculations for a sphere equivalent to the aggregate size were compared to the experimentally observed results. The observed results showed an enhanced backscattering, whereas the Mie calculations did not due to the large imaginary part of the refractive index. Hematite aggregates were simulated by assuming they were composed of spherical monomers inside a spherical volume. Then the light scattering was calculated using the T-matrix method for these simulated aggregates. The calculated results show an enhanced backscattering. We present a dimensional analysis to estimate the extent of multiple scattering within the aggregate and find a correlation between the average number of scattering events within the aggregate and the enhancement in the backscattering.

Turbidity of Saccharomyces cerevisiae: a proposed cell quantification method

The relation between cell and turbidity (cloudiness) in suspended form is studied intensively to facilitate the estimation of the cell number. A standard curve in turbidimetry has utility to compare the turbidity reading value for the determination of Saccharomyces cerevisiae cell number and using a model. A standard curve is a prospect in this issue for the cell that has an inherent inaccuracy in the method as well as spectrophotometry. This research is conducted to obtain a model for the standard curve using analysis and diagnosis of the linear regression which was measured the relative standard error (SE) value of the dependent variable by simulation of turbidity value and verification of the applied model. We obtained the smallest relative SE from one of the five datasets that resulted in less than 10% of the relative SE on the estimated cell number. Plotting all of the bivariate data resulted in a larger error on the scattered light intensity at the higher cell number value, and this characteristic was named heteroscedasticity. Application of turbidity method for cell enumeration per mL in the media was significant equal and lower coefficient variation than the result of verification by a viable method.

Analytic solutions for the spatial character and coherence properties of light scattered from two dipole-coupled atoms

Analytic solutions for steady-state expectation values of atomic quantities and second order correlations are obtained for a fully quantum treatment of two stationary dipole-coupled atoms driven in a standard geometric configuration by a near resonant laser. Explicit expressions for the spatial and coherence properties of the far-field scattered light intensity are derived, valid for the full range of system parameters. A comprehensive survey of the steady-state scattering behaviour is given, with key features precisely characterised, including subradiant scattering, and the regime in which the dipole-dipole coupling has significant effect. A regime is also found where the incoherent scattered light develops spatial interference fringes. We examine in detail a decorrelation approximation that has potential application for larger systems of atoms that are intractable in a full quantum treatment. Finally, we introduce the concept of an effective driving field and show that it can provide a direct and intuitive physical interpretation of key aspects of the system behaviour, including subradiant scattering.

Relationship between Transparent Skin Tissue Image Shading and Skin Tissue Light Scattering Intensity

Relationship between Transparent Skin Tissue Image Shading and Skin Tissue Light Scattering Intensity

Micellization of Polystyrene-b-Polyglycidol in Dioxane and Water/Dioxane Solutions.

In this work, the self-assembly of a series of amphiphilic polystyrene-b-polyglycidol (PS-b-PGL) diblock copolymers in dioxane and dioxane/water mixtures is presented. The PS-b-PGL have an average degree of polymerization (DP) of PS block equal to 29 units and varied degrees of polymerization for the glycidol segments with DPs of 13, 42, 69 and 117. In dioxane, amphiphilic diblock copolymers form micelles with the hydrophilic PGL placed in the core. Critical micelle concentration (CMC) was determined based on the intensity of scattered light vs. concentration. The micelle size was measured by dynamic light scattering and transmission electron microscopy. Also, the behaviour of the copolymer was studied in water/dioxane solutions by following the changes of scattered light intensity with the addition of water to the system. Critical water content (CWC) of the studied systems decreased as the initial PS-b-PGL concentration in dioxane increased. This process was accompanied by a decrease in the size of aggregate formed. For a given initial copolymer concentration, the size of copolymer aggregates decreased linearly with increasing the length of the PGL block

Electrical, mechanical, and optical changes in MWCNT-doped PMMA composite films

In this study, we report the preparation of poly (methyl methacrylate)/multi-walled carbon nanotube (MWCNT) composite thin films by simple and efficient solution mixing and ultrasonic method and the electrical, optical, and mechanical characterizations. Scattered light intensity ( I sc), tensile modulus ( E), and surface conductivity ( σ) of these composites have increased with the addition of MWCNT into the composite. The observed behavior in electrical, optical, and mechanical properties of the poly (methyl methacrylate)/MWCNT composites was interpreted by site and classical percolation theory. The optical mechanical and electrical percolation thresholds of poly (methyl methacrylate)/MWCNT composites were determined as φ op = 3 wt%, φ m = 0 wt%, and φσ = 5 wt%, respectively. The optical ( t op), mechanical ( t m), and electrical ( t σ) critical exponents were calculated as 2.23, 0.43, and 0.11, respectively. Both the tensile modulus and tensile strength of poly (methyl methacrylate)/MWCNT composites were increased with increasing MWCNT content until it reaches to 10 wt%. However, above φ = 10 wt%, the mechanical properties of the composites were decreased due to the aggregation of MWCNTs, while the toughness does not show a significant change until φ = 10 wt% MWCNT content, whereas it was decreased above this value.

Detection and amplification of spin noise using scattered laser light in a quantum-dot microcavity

Fundamental properties of the spin-noise signal formation in a quantum-dot microcavity are studied by measuring the angular characteristics of the scattered light intensity. A distributed Bragg reflector microcavity was used to enhance the light-matter interaction with an ensemble of n-doped (In,Ga)As/GaAs quantum dots, which allowed us to study subtle effects of the noise signal formation. Detecting the scattered light outside of the aperture of the transmitted light, we measured the basic electron spin properties, like g-factor and spin dephasing time. Further, we investigated the influence of the microcavity on the scattering distribution and possibilities of signal amplification by additional resonant excitation.

Stopped-flow Light Scattering Analysis of Red Blood Cell Glycerol Permeability.

Stopped-Flow Light Scattering (SFLS) is a method devised to analyze the kinetics of fast chemical reactions that result in a significant change of the average molecular weight and/or in the shape of the reaction substrates. Several modifications of the original stopped-flow system have been made leading to a significant extension of its technical applications. One of these modifications allows the biophysical characterization of the water and solute permeability of biological and artificial membranes. Here, we describe a protocol of SFLS to measure the glycerol permeability of isolated human red blood cells (RBCs) and evaluate the pharmacokinetics properties (selectivity and potency) of isoform-specific inhibitors of AQP3, AQP7 and AQP9, three mammalian aquaglyceroporins allowing transport of glycerol across membranes. Suspensions of RBCs (1% hematocrit) are exposed to an inwardly directed gradient of 100 mM glycerol in a SFLS apparatus at 20 °C and the resulting changes in scattered light intensity are recorded at a monochromatic wavelength of 530 nm for 120 s. The SFLS apparatus is set up to have a dead time of 1.6-ms and 99% mixing efficiency in less than 1 ms. Data are fitted to a single exponential function and the related time constant (τ, seconds) of the cell-swelling phase of light scattering corresponding to the osmotic movement of water that accompanies the entry of glycerol into erythrocytes is measured. The coefficient of glycerol permeability ( Pgly , cm/s) of RBCs is calculated with the following equation: Pgly = 1/[(S/V)τ] where τ (s) is the fitted exponential time constant and S/V is the surface-to-volume ratio (cm-1) of the analyzed RBC specimen. Pharmacokinetics of the isoform-specific inhibitors of AQP3, AQP7 and AQP9 are assessed by evaluating the extent of RBC Pgly values resulting after the exposure to serial concentrations of the blockers.

Nonequilibrium Fluctuations of Light Scattering Intensity in the Neighborhood of the Phase Transition Temperature

Light scattering in a 3% aqueous solution of hydroxypropyl methylcellulose (metolose) is studied under nonequilibrium conditions within a temperature range of 303–353 K, i.e., in the neighborhood of the phase transition temperature (336 K). It is established that the light scattering intensity undergoes considerable fluctuations in this temperature interval. It is shown that they are caused by quasi-periodic motions (density fluctuations) appearing in the strongly nonequilibrium state of the solution.

Formation of Ag nanowires in the presence of tannic acid

Silver nanowires (AgNWs) have received considerable attention from both research in industry and academia due to their exceptional practicable applications in various electronic devices. In this work, pure AgNWs in the absence of nanoparticles are synthesised through chemical reduction method at low temperature 80 °C. AgNWs are produced based on the reaction of a reducing agent of tannic acid and a capping agent of polyvinylpyrrolidone (MW ≈ 1,200,000). The purity of the as-prepared AgNWs is improved in the presence of both chemical reactants. The controllable morphologies and sizes make the AgNWs grown steadily up to ∼30±2 μm in length with up to ∼58±1.8 nm in diameter. To enhance the yield of AgNWs, variations in the silver nitrate precursor (AgNO3) concentration in the synthesis of AgNWs are highlighted. The properties of the synthesised AgNWs are characterised through scanning electron microscopy (SEM), photoluminescence spectroscopy and UV–visible absorption spectroscopy. The overall properties of the AgNWs in terms of scattered light intensity and the transmittance of optical responses were largely improved as compared to other reported studies.

Multiple aperture underwater imaging algorithm based on polarization information fusion

Underwater optical imaging is the key technology to explore the underwater mystery. However, due to the absorption and backscattering effects of the media in the underwater environment, the image acquired by the detector will be severely degraded. In order to obtain the effective underwater scene information, it is necessary to restore the acquired underwater image. The restoration technology based on differential polarization is one of the main methods of restoring the underwater images, which can suppress the background scattered light by the common-mode suppression between orthogonal polarization graphs, thus realizing the restoration of underwater image. However, the relevant research shows that the restoration effect of this method is general for the underwater non-uniform light field. The main reason is that the estimation errors of polarization degree and background scattering intensity under the condition of the non-uniform underwater light field are large. Out of the above problem, in this paper we present the multiple aperture underwater imaging technology of fused polarization information. The method uses the camera array to realize the large virtual aperture imaging system, thus obtaining the wide-angle light field information, and then to fuse the depth information of the scene to realize the accurate estimation of background scattering light intensity and polarization degree under the condition of underwater non-uniform light field. The estimated parameter value can better reflect the global characteristics of the scene. Through the imaging experiments on the targets with different polarization degrees in the turbid underwater environment, comparing with the current advanced restoration algorithm, the results show that the proposed method can effectively solve the problems of background scattering and polarization degree significant estimation error caused by non-uniform underwater light field, and obtain high-quality restoration results. Through the contrast imaging experiment of the target in the underwater environment with different turbidity concentrations, the results show that with the increase of turbidity concentration of the water, the image recovery effect of the method in this paper is gradually weakened. However, it still has a good restoration effect at a large concentration. At the same time, imaging experiments are conducted on targets in underwater environments with different sediment concentrations. The results show that the method proposed in this paper can also obtain a better restoration image in the turbid water environment containing sediment.

Analysis of light scattering ability of the cornea before and after endothelial keratoplasty

To evaluate light scattering ability of the cornea before and after Descemet's stripping automated endothelial keratoplasty (DSAEK) and Descemet's membrane endothelial keratoplasty (DMEK) endothelial keratoplasty. The study included 70 patients (70 eyes) who had undergone DSAEK and DMEK (35 patients, 35 eyes in each group). In addition to standard ophthalmological examinations before and during the one-year follow-up after surgery, the patients had their central corneal thickness, stromal thickness, thickness of the interface area and the graft measured with optical coherence tomography (Optovue, U.S.A.). Intensity of light scattering by corneal structures was evaluated using Pentacam HR (Oculus, Germany) topographer with proprietary software and algorithms for calculation of corneal transparency. Comparison of the outcomes revealed that indices of general integral and stromal light-scattering were higher in patients after DSAEK. Integral light scattering in the interface and graft areas in the DMEK group was significantly lower than in the DSAEK group during the whole follow-up period. The reason for decrease of visual acuity after endothelial keratoplasty, regardless of the surgery type, may be higher light-scattering ability of patient's corneal stroma due to residual opacifications. Better visual acuity outcomes after DMEK in comparison to DSAEK are associated with higher transparency of the interface and graft areas. The suggested new method of assessing the intensity of light-scattering allows more precise evaluation of the influence of light-scattering ability of the stroma, interface and corneal graft after different modifications of endothelial keratoplasty, considering the respective layer thickness and excluding the influence of light scattering on the air-epithelium interface.

Long-term colloidal stability of graphene oxide aqueous nanofluids

The use of nanofluids for industrial applications depends on its stability during transport and use. In this work, we demonstrate that graphene oxide (GO)-based aqueous nanofluids can remaining stable for as many as 90 days. The structural and morphological analyses showed that the GO samples have an average thickness of two graphitic layers with interlayer spacing of 1 nm. The long-term colloidal stability of the nanofluids was monitored for 90 days using three different techniques: UV-vis, zeta potential (ζ) and DLS, which confirmed this stability. The observed ζ value (average of −64.8 ± 1.81 mV) at 200 ppm of GO is the highest negative value reported at pH = 4. The particle size distribution after 90 days of storage presented a major population with diameter of (530 ± 40) nm that represented 98% of the scattered light intensity.

Extension of complex refractive index model and analysis of scattering properties of charged submicron spheres

In the optical measurement of submicron particle properties, extra scattering generated by excess surface charges is no longer negligible as that in micron particles. When the surface charge density exceeds a certain threshold, the scattering behavior of the particles will be jointly dominated by the particles themselves and the surface charges. In this paper, the complex refractive index model is extended to be appropriate for both electrically neutral particles and electrically charged particles, and the mechanism is explained how surface charges affects elastic scattering. Taking the Mie theory of charged submicron spherical droplets of water with salt as an example, the influence of the surface charges on the complex refractive index and the scattering properties is discussed. Further, a threshold of the surface charge density is confirmed, above which extra scattering cannot be ignored. By calculating a angular distribution of the scattered light intensity, it is found that electrically charges have a magnifying effect on forward and backscattering of the particles d < 0.5 µm. This effect is helpful to extend the lower limit of measurement of visible light scattering and is of great significance to understanding the interaction between charged particles and electromagnetic or optical waves.

Electrical, optical and mechanical properties of chitosan biocomposites

In this work, chitosan/graphene nanoplatelets (CS/GNP) and chitosan/multi-walled carbon nanotube (CS/MWCNT) biocomposite films were prepared using a simple, eco-friendly and low-cost method. The electrical, optical and mechanical properties of these composite films were investigated. The optical, mechanical and electrical properties of the biocomposites were significantly improved, which make them promising materials for food packaging, ultraviolet protection and biomedical applications. With the increase of carbon filler content (GNP or MWCNT) in CS biocomposites, the surface conductivity ( σ), the scattered light intensity ( I sc) and the tensile modulus ( E) increased significantly. This behaviour in the electrical, optical and mechanical properties of the CS/carbon filler biocomposites was explained by percolation theory. The electrical percolation thresholds were determined as R σ = 25.0 wt.% for CS/GNP and R σ = 10.0 wt.% for CS/MWCNT biocomposites, while the optical percolation thresholds were found as R op =12.0 wt.% for CS/GNP and R op = 2.0 wt.% for CS/MWCNT biocomposites. Conversely, the mechanical percolation thresholds for both CS/GNP and CS/MWCNT biocomposites were found to be negligibly small ( R m = 0.0 wt.%). The electrical ( β σ), optical ( β op) and mechanical ( β m) critical exponents were calculated for both CS/carbon filler biocomposites and found compatible with the applied percolation theory.

Partially disordered TiO2 nanotube photonic crystal: randomness characterization and tuning of reflected scattering light

Introducing disorder into a periodic nanostructure can lead to specific optical behaviors. We present a method of anodic oxidation by adjusting the applied voltage and process time to introduce disorder to TiO2 nanotubes. The surface morphology of TiO2 was numerically investigated according to the morphologies measured with a scanning electron microscope by imaging processing and a statistical method. TiO2 nanotubes obtained under different fabrication conditions have various tube radii ranging from 20–40 nm and wall thicknesses ranging from 20–70 nm. We also evaluated the degree of disorder of the tube radius of the TiO2 nanotubes. The reflected scattering light distributions of laser sources were optically measured at different observing distances, which indicate that the presence of nanotubes enhances the scattering effect, reducing the scattered light intensity by more than 75%, and provide the relationship between the scattering effect and surface morphology of nanotubes. This discovery offers TiO2 nanotubes important application prospects in optical limiting and light confinement, such as stealth coating.