Light Pulse Shape Research Articles

Characterization of a novel polyurethane-based plastic scintillator for neutron and gamma detection in mixed radiation fields

We present studies of a novel plastic scintillator branded M600, which was developed and provided by Target Systemelektronik. This new material is, in contrast to other solid organic scintillators offered by commercial providers, based on a polyurethane matrix complemented with scintillating and wavelength-shifting additives. This paper covers measurements of absolute light output, LO, (photons per 1 MeV-γ), γ-non-proportionality (NP), light pulse shapes, and neutron-gamma (n/γ) discrimination. The measurements were carried out either using standard calibration gamma sources (LO, NP) or in a mixed field of neutron and γ radiation from an intense (∼4 × 105 neutrons/s/4π) AmBe source (n/γ discrimination). The measured light output was 9650 ± 1000 ph/MeV and the PSD's figure of merit (FoM) was found as 2.2 ± 0.1 at ∼1000 keVee for ∅2.54 cm × 2.54 cm M600 sample. The bigger sample (∅5.08 cm × 5.08 cm) exhibits about 25% lower LO and poorer FoM when compared to the ∅2.54 cm × 2.54 cm M600, due to self-absorption.

Design solutions for the hodoscope of the magnetic proton recoil neutron spectrometer of the SPARC tokamak.

A new 14MeV neutron spectrometer utilizing the magnetic proton recoil (MPR) technique is under development for the SPARC tokamak. This instrument measures neutrons by converting them into protons, whose momenta are subsequently analyzed using a series of magnets before detection by an array of scintillators known as the hodoscope. In this work, we explore various solutions for the hodoscope detectors through laboratory tests with radioactive sources and simulations. We present findings on light collection and pulse shape discrimination based on detector types, as well as optimal solutions for photo-detectors studying the differences between SiPM and PMT. Our results also led to the determination of a better optimized design for the hodoscope detectors, consisting of a 0.7cm width and a 13cm length EJ276D scintillation rod.

Investigation of scintillation properties of a CsI(Tl) crystal at low temperature for dark matter search

The Korea invisible mass search (KIMS) experiment used CsI(Tl) crystals coupled with photomultiplier tubes (PMTs) to detect signals from weakly interacting massive particles (WIMPs) at room temperature. It is expected that combining CsI(Tl) crystals with silicon photomultipliers (SiPMs) will enhance the detection performance. However, SiPMs must operate at low temperatures to reduce the dark count rate. In this study, we examined the temperature dependence of CsI(Tl) crystal properties, including light yield, α/β ratio, decay time, and pulse shape discrimination, before integrating it with a SiPM. The CsI(Tl) crystal was placed in a low-temperature chamber with a radiation source, and scintillation photons were detected by a PMT positioned outside the chamber. The response of CsI(Tl) to α-particles and γ-rays was examined across temperatures ranging from 10 K to 300 K.

Understanding the Nonlinear Response of SiPMs.

A systematic study of the nonlinear response of Silicon Photomultipliers (SiPMs) was conducted through Monte Carlo (MC) simulations. The MC code was validated against experimental data for two different SiPMs. Nonlinearity mainly depends on the balance between the photon rate and the pixel recovery time. Additionally, nonlinearity has been found to depend on the light pulse shape, the correlated noise, the overvoltage dependence of the photon detection efficiency, and the impedance of the readout circuit. Correlated noise has been shown to have a minor impact on nonlinearity, but it can significantly affect the shape of the SiPM output current. Considering these dependencies and a previous statistical analysis of the nonlinear response of SiPMs, two phenomenological fitting models were proposed for exponential-like and finite light pulses, explaining the roles of their various terms and parameters. These models provide an accurate description of the nonlinear responses of SiPMs at the level of a few percentages for a wide range of situations.

Investigating the Potential of Perovskite Nanocrystal-Doped Liquid Scintillator: A Feasibility Study

Liquid scintillators are extensively employed as targets in neutrino experiments and in medical radiography. Perovskite nanocrystals are recognized for their tunable emission spectra and high photoluminescence quantum yields. In this study, we investigated the feasibility of using perovskites as an alternative to fluor, a substance that shifts the wavelengths. The liquid scintillator candidates were synthesized by doping perovskite nanocrystals with emission wavelengths of 450, 480, and 510 nm into fluor PPO with varying nanocrystal concentrations in a toluene solvent. The several properties of the perovskite nanocrystal-doped liquid scintillator were measured and compared with those of a secondary wavelength shifter, bis-MSB. The emission spectra of the perovskite nanocrystal-doped liquid scintillator exhibited a distinct monochromatic wavelength, indicating energy transfer from PPO to the perovskite nanocrystals. Using a 60Co radioactive source setup with two photomultiplier tubes (PMTs), the light yields, pulse shape, and wavelength shifts of the scintillation events were measured. The light yields were evaluated based on the observed Compton edges from γ-rays, and compared across the synthesized samples. A decrease (or increase) in area-normalized PMT pulse height was observed at higher perovskite nanocrystal (or PPO) concentrations. The results demonstrated the sufficient potential of perovskite nanocrystals as an alternative to traditional wavelength shifters in a liquid scintillator.

Impact of temperature on light yield and pulse shape discrimination of polysiloxane-based organic scintillators formulated with commercial resins

This work investigates how increased temperature affects neutron/γ discrimination and light yield (LY) in several different polysiloxane-based scintillators doped with either 9,9-dimethyl-2-phenylflourene (PhF) or 2,5-diphenyloxazole (PPO) as a primary fluorophore and 9,9-dimethyl-2,7-di((E)-styryl) fluorene (SFS) as the secondary fluorophore. The polysiloxane matrices were prepared from the commercial resins Wacker Lumisil 579 or Shin-Etsu KER-6000. Control scintillators were prepared from poly(vinyltoluene) (PVT), the industry standard matrix, as a reference point for LY and pulse shape discrimination (PSD) measurements. Samples with PhF and PPO dopant concentrations of 1 wt% and 5 wt% in the polysiloxanes and 3 wt% and 5 wt% in the PVT samples were tested at 20 °C, 35 °C, and 50 °C. In the polysiloxane samples, the KER-6000 resin outperformed the Wacker 579 and PhF proved to be a better dopant than PPO in both LY and PSD capabilities. Polysiloxane scintillators showed slight decreases in LY and increases in neutron/γ discrimination at increased temperatures, while PVT scintillators showed a similar LY decrease with little to no improvement in neutron/γ discrimination at increased temperatures. Overall, polysiloxane scintillators may not require recalibration in applications where temperatures increase up to 50 °C.

Optogenetic Generation of Neural Firing Patterns with Temporal Shaping of Light Pulses

The fundamental process of information processing and memory formation in the brain is associated with complex neuron firing patterns, which can occur spontaneously or be triggered by sensory inputs. Optogenetics has revolutionized neuroscience by enabling precise manipulation of neuronal activity patterns in specified neural populations using light. However, the light pulses used in optogenetics have been primarily restricted to square waveforms. Here, we present a detailed theoretical analysis of the temporal shaping of light pulses in optogenetic excitation of hippocampal neurons and neocortical fast-spiking interneurons expressed with ultrafast (Chronos), fast (ChR2), and slow (ChRmine) channelrhodopsins. Optogenetic excitation has been studied with light pulses of different temporal shapes that include square, forward-/backward ramps, triangular, left-/right-triangular, Gaussian, left-/right-Gaussian, positive-sinusoidal, and left-/right-positive sinusoidal. Different light shapes result in significantly different photocurrent amplitudes and kinetics, spike-timing, and spontaneous firing rate. For short duration stimulations, left-Gaussian pulse results in larger photocurrent in ChR2 and Chronos than square pulse of the same energy density. Time to peak photocurrent in each opsin is minimum at right-Gaussian pulse. The optimal pulse width to achieve peak photocurrent for non-square pulses is 10 ms for Chronos, and 50 ms for ChR2 and ChRmine. The pulse energy to evoke spike in hippocampal neurons can be minimized on choosing square pulse with Chronos, Gaussian pulse with ChR2, and positive-sinusoidal pulse with ChRmine. The results demonstrate that non-square waveforms generate more naturalistic spiking patterns compared to traditional square pulses. These findings provide valuable insights for the development of new optogenetic strategies to better simulate and manipulate neural activity patterns in the brain, with the potential to improve our understanding of cognitive processes and the treatment of neurological disorders.

2 inch molecular organic glass scintillator for neutron–gamma discrimination

In this manuscript we report on the scintillation properties and pulse shape discrimination (PSD) performance of new organic glass scintillator. Two cylindrical samples with dimensions of 2 × 2 inches were tested. Additionally, this two samples were used in stack configuration in order to measure the PSD characteristics of a sample with a size of 2 × 4 inches. The study covers the measurements of neutron/gamma discrimination capability, emission spectra, photoelectron yield and analysis of the light pulse shapes originating from events related to gamma-rays and fast neutrons. The results were compared to data recorded previously using an EJ-276 plastic scintillator, an EJ-309 liquid scintillator and a stilbene single crystal.

Study on NaI(Tl) crystal at −35 [formula omitted]C for dark matter detection

We present the response of a NaI(Tl) crystal in terms of the light yield and pulse shape characteristics at two different temperatures: 22 °C (room temperature) and −35 °C (low temperature). The light yield is measured using 59.54keV γ-rays from a 241Am source relative to the mean charge of single photoelectrons. At the low temperature, we measure a 4.7 ± 1.3% increase in the light yield compared to that at room temperature. A significantly increased decay time is also observed at the low temperature. The responses to nuclear recoil events are measured using neutrons from a 252Cf source and compared to those to electron recoil events. The measured pulse shape discrimination (PSD) power of the NaI(Tl) crystal at the low temperature is found to be improved in the entire energy range studied because of the increased light yield and the different scintillation characteristics. We also find a 9.23 ± 0.26% increased quenching factor of α-induced events, which is the light yield ratio of α recoil to electron recoil, at the low temperature. This supports the possibility of an increased quenching factor of the nuclear recoil events that are known to have similar processes of dark matter interaction. The increased light yield and the improved PSD power of nuclear recoil events enhance the sensitivity for dark matter detection via dark matter–nuclei interactions.

Comparison of detectors with pulse shape discrimination capability for simultaneous detection of gamma-rays, slow and fast neutrons

In this paper, five detectors (EJ-270 — single plastic scintillator, EJ-309B5 — single liquid scintillator, and 3 phoswich detectors: EJ-276+GS20, GS20+EJ-276, EJ-309+GS20) were studied in terms of simultaneous detection of gamma-rays and slow and fast neutrons. The measurements were carried out in a mixed field of neutron and gamma radiation from an intense (∼106 neutrons/s/4π) PuBe source. The PuBe neutron source was placed in an 18 cm diameter paraffin ball in order to increase the number of slow neutron detections. This paper covers the measurements of the neutron/gamma discrimination, photoelectron yield and analysis of the light pulse shapes originating from events related to gamma-rays, slow neutrons and fast neutrons. Sensitivity to slow neutrons is also briefly discussed. A comparison of n/γ discrimination for all of the tested detectors shows excellent performance of all phoswich detectors. Phoswich configurations tested within the scope of this study allow unambiguously resolve all three types of radiation and show superior performance in comparison with single loaded plastic or liquid scintillators.

Informative light pulses of indicating polymer fiber-optic piezoelectroluminescent coatings upon indentation of rigid globular particles

A mathematical model of operation of an indicating polymer coating with an embedded fiber-optic piezoelectroluminescent (PEL) sensor is developed for diagnosing multiple mechanical force actions by digital processing of an informative luminous flux at the output of the optical fiber of the sensor. Distributed force action is caused by a multipoint low-velocity impact of multiple rigid particles, e.g., hail impacts, and the indentation of particles across the outer surface of the coating. The results of the numerical modeling of the sequence of informative light pulses at the output of the optical fiber of the PEL sensor are presented. The effects of the amplitude of the control voltage at the sensor contacts and the possible intersections of the “perturbation zones” of the adjacent globular particles on the amplitude and shape of light pulses are identified via numerical analysis. The filtering of informative signals of the indicating PEL coating based on the control sensor voltage is studied to exclude the effect of insignificant (outside of the operational range) external mechanical actions on the detected informative light signal.

Temporal mode transformations by sequential time and frequency phase modulation for applications in quantum information science.

Controlling the temporal mode shape of quantum light pulses has wide ranging application to quantum information science and technology. Techniques have been developed to control the bandwidth, allow shifting in the time and frequency domains, and perform mode-selective beam-splitter-like transformations. However, there is no present scheme to perform targeted multimode unitary transformations on temporal modes. Here we present a practical approach to realize general transformations for temporal modes. We show theoretically that any unitary transformation on temporal modes can be performed using a series of phase operations in the time and frequency domains. Numerical simulations show that several key transformations on temporal modes can be performed with greater than 95% fidelity using experimentally feasible specifications.

Temperature effects on light yield and pulse shape discrimination capability of siloxane based scintillators

In this work, we report the study of temperature effects on light yield of siloxane-based scintillators and on n/gamma discrimination capability, in terms of pulse shape discrimination (PSD). The solid scintillators are composed of phenyl containing polysiloxane (PMPS100), as a base polymer, loaded with moderate amounts (6 wt%) of 2,5-diphenyloxazole (PPO) as a primary dye and Lumogen Violet (LV) as waveshifter. The samples were heated in the range of 60–150 ^circ hbox {C} and scintillation performance were tested both after annealing for 24 h and in real time during heating. Light yield of siloxane-based scintillators containing 6 wt% PPO heated at 100 ^circ hbox {C} is very close to the room-temperature value, while heating at 120 ^circ hbox {C} causes a decrease of light yield (LY) of 17%. In addition, the figure of merit (FoM) for n/gamma discrimination of the scintillator shows a sensible worsening of the discrimination performances in case of prolonged treatment at 120 ^circ hbox {C}. Similar tests are made using the commercial plastic scintillator EJ-299 (currently named EJ-276), based on polyvinyltoluene (PVT). In this case, the light yield undergoes a much more rapid deterioration with annealing temperature, and at 70 ^circ hbox {C} it is reduced to 60% of the original value. The discrimination capability of EJ-299 decreases upon heating at 70 ^circ hbox {C} as well, with a 20% reduction of FoM; meanwhile for T > 70 ^circ hbox {C} the mechanical and optical features are remarkably degraded. The mass loss of primary dye PPO from the siloxane scintillator as a function of treatment temperature and initial dye concentration has been evaluated and compared to the behaviour of EJ-299. This measurement allows to single out and characterize a series of processes occurring during heating, which are relevant to the whole performance of the system under study, such as sublimation at the interface, thermally induced photooxidation of components, diffusion of fluorophores from the polymer bulk to the surface. The variation in luminescence characteristics have been analyzed by excitation/fluorescence spectroscopy and time-resolved fluorescence spectroscopy, in order to correlate the annealing treatment with the primary dye loss by sublimation, formation of superficial aggregates and/or degradation of the scintillator components in the synthesized siloxane scintillator.

Comparative scintillation performance of EJ-309, EJ-276, and a novel organic glass

An organic glass scintillator developed by Sandia National Laboratories was characterized in terms of its light output and pulse shape discrimination (PSD) properties and compared to commercial liquid (EJ-309) and plastic (EJ-276) organic scintillators. The electron light output was determined through relative comparison of the 137Cs Compton edge location. The proton light yield was measured using a double time-of-flight technique at the 88-Inch Cyclotron at Lawrence Berkeley National Laboratory. Using a tunable broad-spectrum neutron source and an array of pulse-shape-discriminating observation scintillators, a continuous measurement of the proton light yield was performed for EJ-309 (200 keV–3.2 MeV), EJ-276 (170 keV–4.9 MeV), and the organic glass (50 keV–20 MeV) . Finally, the PSD properties of the organic glass, EJ-309, and EJ-276 were evaluated using an AmBe source and compared via a figure-of-merit metric. The organic glass exhibited a higher electron light output than both EJ-309 and EJ-276. Its proton light yield and PSD performance were comparable to EJ-309 and superior to that of EJ-276. With these performance characteristics, the organic glass scintillator is well poised to replace current state-of-the-art PSD-capable scintillators in a range of fast neutron detection applications.

Characterization of stilbene’s scintillation anisotropy for recoil protons between 0.56 and 10 MeV

The scintillation anisotropy of the single-crystal organic scintillator trans-stilbene was characterized for recoil protons between 0.56 and 10 MeV. The light output and pulse shape anisotropies were measured at 11 distinct recoil proton energies for over 168 recoil proton trajectories relative to the crystal axes. The measurements were performed using a neutron scatter kinematic measurement system and quasi-monoenergetic neutron beams produced by the tandem Van de Graaff accelerator at Triangle Universities Nuclear Laboratory (TUNL). The extensive recoil proton directional coverage enables interpolation over both energy and direction to form a complete response function of stilbene’s scintillation anisotropy for the measured energy range.

Fast neutron and gamma ray pulse shape discrimination in EJ-276 and EJ-276G plastic scintillators

In this paper, we report on the scintillation properties and pulse shape discrimination (PSD) performance of new plastic scintillators, EJ-276 and EJ-276G . Cylindrical samples with dimensions of 1×1 inch and 2×2 inches were tested. Additionally, four samples 2×2 inches in size were used in stack configurations in order to measure the PSD characteristics of large samples (up to 2×8 inches). The paper covers the measurements of neutron/gamma discrimination, emission spectra, photoelectron yield, and analysis of the light pulse shapes originating from events related to gamma-rays and fast neutrons. The results were compared to data recorded previously using plastic scintillators EJ-299-33, EJ-299-33G, EJ-299-34, EJ-299-34G, and an EJ-301 liquid scintillator.

Plastic scintillators with efficient light output and pulse shape discrimination produced via photoinitiated polymerization

ABSTRACTPoly(vinyl toluene) (PVT) overdoped with 2,5‐diphenyloxazole and using 1,4‐bis(5‐phenyloxazol‐2‐yl)benzene as a fluorescent secondary dopant can be used to detect and differentiate neutron and gamma radiation via scintillation. The low cost of PVT makes these plastic scintillators attractive for both portable and larger sized first line detection of special nuclear materials. Current fabrication methods rely on thermally initiated radical polymerization that generally requires an approximately 5‐day heating process in order to produce high quality scintillators. In this work, we report a proof‐of‐concept photopolymerization process to prepare plastic scintillators up to 20 g in size in 1 day. These plastic scintillators were comparable to standard thermally polymerized samples in terms of their physical properties and response to various radiation sources. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47381.

On the Relationship Between Scintillation Anisotropy and Crystal Structure in Pure Crystalline Organic Scintillator Materials

The scintillation anisotropy effect for proton recoil events has been investigated in five pure organic crystalline materials: anthracene, trans-stilbene, p-terphenyl, bibenzyl, and diphenylacetylene. These measurements include characterization of the scintillation response for one hemisphere of proton recoil directions in each crystal. In addition to standard measurements of the total light output and pulse shape at each angle, the prompt and delayed light anisotropies are analyzed, allowing for investigation of the singlet and triplet molecular excitation behaviors independently. This work provides new quantitative and qualitative observations that make progress toward understanding the physical mechanisms behind the scintillation anisotropy. These measurements show that the relationship between the prompt and delayed light anisotropies is correlated with crystal structure, as it changes between the pi-stacked crystal structure materials (anthracene and p-terphenyl) and the herringbone crystal structure materials (stilbene, bibenzyl, and diphenylacetylene). The observations are consistent with a model in which there are preferred directions of kinetic processes for the molecular excitations. These processes and the impact of their directional dependencies on the scintillation anisotropy are discussed.

The low temperature performance of CsI(Na) crystals for WIMPs direct searches

Previous studies showed that CsI(Na) crystals have significantly different waveforms between $$\alpha $$ and $$\gamma $$ scintillations. In this work, the light yield and pulse shape discrimination capability of CsI(Na) scintillators as a function of the temperature down to 80 K have been studied. As temperature drops, the fast component increases and the slow component decreases. By cooling the CsI(Na) crystals, the light yield of high-ionization events is enhanced significantly, while the light yield of background $$\gamma $$ events is suppressed. At 110 K, CsI(Na) crystal achieves the optimal balance between low threshold and good background rejection performance. The different responses of CsI(Na) to $$\gamma $$ and $$\alpha $$ at different temperatures are explained with self-trapped and activator luminescence centers. PSD capability of CsI(Na) reaches the peak at 110 K, which can be the optimum operating temperature for future CsI(Na)-based dark matter detector.

Cerium-doped scintillating fused-silica fibers

We report on a set of measurements made on (scintillating) cerium-doped fused-silica fibers using high-energy particle beams. These fibers were uniformly embedded in a copper absorber in order to utilize electromagnetic showers as a source of charged particles for generating signals. This new type of cerium-doped fiber potentially offers myriad new applications in calorimeters in high-energy physics, tracking systems, and beam monitoring detectors for future applications. The light yield, pulse shape, attenuation length, and light propagation speeds are given and discussed. Possible future applications are also explored.