Light Path Research Articles

Dual-Function Wearable Hydrogel Optical Fiber for Monitoring Posture and Sweat pH.

In recent years, wearable devices have been widely used for human health monitoring. Such monitoring predominantly relies on the principles of optics and electronics. However, electronic detection is susceptible to electromagnetic interference, and traditional optical fiber detection is limited in functionality and unable to simultaneously detect both physical and chemical signals. Hence, a wearable, embedded asymmetric color-blocked optical fiber sensor based on a hydrogel has been developed. Its sensing principle is grounded in the total internal reflection within the optical fiber. The method for posture sensing involves changes in the light path due to fiber bending with color blocks providing wavelength-selective modulation by absorption changes. Sweat pH sensing is facilitated by variations in fluorescence intensity triggered by sweat-induced conformational changes in Rhodamine B. With just one fiber, it achieves both physical and chemical signal detection. Fabricated using a molding technique, this fiber boasts excellent biocompatibility and can accurately discern single and multiple bending points, with a recognition range of 0-90° for a single segment, a detection limit of 0.02 mm-1 and a sweat pH sensing linear regression R2 of 0.993, alongside great light propagation properties (-0.6 dB·cm-1). With its extensive capabilities, it holds promise for applications in medical monitoring.

Stray light analysis and suppression of high-resolution camera line-of-sight variation real-time monitoring system (LoS Var RTMS)

Due to environmental disturbances during emission and operation processes, the line-of-sight of a high-resolution camera is highly prone to variation, resulting in a significant decrease in image positioning accuracy. To address this issue, we propose a line-of-sight variation real-time monitoring system (LoS Var RTMS). A full-link active optical monitoring system is established using laser, and a high-resolution camera is coupled to a star tracker, thereby enhancing the on-orbit calibration and image positioning accuracy of the camera. However, the high-resolution camera LoS Var RTMS belongs to a high stray light sensitivity system. Stray light entering the star tracker from the high-resolution camera through the relay reflective system can significantly affect the imaging of the star tracker, leading to the failure of the monitoring system. Therefore, a comprehensive and accurate analysis of the stray light propagation path in the monitoring system is necessary to ensure its normal operation. In response to this issue, this article proposes a stray light analysis method based on the surface subdivision method, and utilizes inverse ray tracing to meticulously analyze the propagation path of stray light. Additionally, to address the impact of stray light on laser light in the LoS Var RTMS, an inner baffle polarization filtering system is designed to effectively suppress the influence of external strong stray light on the monitoring system. The results demonstrate that the stray light analysis method based on the surface subdivision method not only enhances the integrity and accuracy of the analysis of stray light propagation paths within the monitoring system, but also significantly improves the precision of stray light analysis. It provides a reference for the analysis of stray light in high stray light sensitive systems. Moreover, the design of the inner baffle polarization filtering system effectively distinguishes between lasers and stray light, suppressing stray light within the high-resolution camera LoS Var RTMS and ensuring its normal operation.

Simultaneous measurement of 13C-,18O-, and 17O- isotopes of CO2 using a compact mid-infrared hollow waveguide gas sensor

A compact gas sensor has been developed for the first time employing a quantum cascade laser (QCL) with a central wavelength of 4.32 μm, combined with direct absorption spectroscopy technology and a hollow waveguide. The sensor could measure the concentrations of four isotopic molecules (16O12C16O, 18O12C16O, 16O13C16O, and 17O12C16O) in CO2 gas simultaneously, thereby obtaining the relative isotope ratios of δ13C, δ18O, and δ17O. By adjusting the incident light path, the anomalous absorption peaks in the system have been effectively suppressed, and a compact feedback function generator has been integrated to ensure control of the laser output wavelength to eliminate the loss of measurement precision caused by wavelength fluctuations. Under the two conditions of free-running and wavelength-controlled, a standard CO2 sample with a concentration of 5 % was measured continuously. The results showed that under wavelength-controlled conditions, the precision of the four isotopic molecule concentration measurements was improved by a minimum of 1.8 times, and the measurement precision could be further improved after filtering. According to the Allan variance analysis, the detection precision for δ13C, δ18O, and δ17O were 0.7 ‰, 0.62 ‰, and 1.58 ‰, respectively, at the optimal integration time of 98 seconds. This study has the potential for respiratory diagnosis to detect simultaneously the values of δ13C, δ18O, and δ17O in exhaled samples.

FriiTriga, a triggered controller with an optical beam shutter using a hard disk drive voice-coil actuator

We present in this article the complete setup to build a triggered controller with a mechanical optical shutter. The system is a low cost, Do-It-Yourself, and easy to implement setup with three functionalities: Manual mode, direct mode with TTL signal command and Triggered mode with a TTL signal command. Our setup is primarily intended to be integrated in optical setup where one needs to control the opening time of a light path, but can be used also for any other setup where one wants to send a TTL signal to command another subsystem (in our case the shutter is that subsystem). The shutter used here is hard disk drive voice-coil actuator, which was already demonstrated to have interesting potentialities to be a mechanical shutter.In the Manual mode, this setup achieves an opening and closing time of 3 ms. In Direct mode with TTL signal command, the setup has a delay response time of 19 ms and a minimum open pulse time of 23 ms. This low cost device which can be made with less than 50€, have similar characteristics with commercial ones which can be twenty times more expensive.

Research on the background stray light suppression method of a dim target projector based on the orthogonal polarization extinction principle

Aiming at the problem of background stray light affecting the display of dim target scenes in existing projectors, a stray light suppression optical engine based on a polarizer is proposed. First, the effect of the background stray light of traditional LCOS target projectors on the display of dim targets is analyzed with simulation, and the sources of stray light in the target projector were analyzed as well. Secondly, we theoretically analyze the causes of different stray light paths and stray light polarization states, propose the method of stray light suppression based on the polarizer, and calculate the rotation angle of the polarizer. Then, we simulate and analyze the stray light suppression effect of the polarizer-based target projector model. Finally, a dim target projector test experiment system is built to verify the actual level of stray light suppression. The simulation results show that the highest stray light energy of the target projector with the polarizer-based stray light suppression optical engine has decreased by 2.37 times compared to the conventional LCOS target projector, the stray light coefficient has decreased from the previous 2.12% to 0.60%, and the simulated contrast ratio has been improved by 2.98 times. The experimental results show that the polarizer-based stray light suppression optical engine is able to reduce the peak gray level of the background stray light energy of the projected display image of the target projector by nearly 2 times, and improve the contrast of the gray level by 2.79 times. The suppression of dim target projector background stray light and the improvement of the contrast of the projected display image are realized.

Ultra-robust informational metasurfaces based on spatial coherence structures engineering

Optical information transmission is vital in modern optics and photonics due to its concurrent and multi-dimensional nature, leading to tremendous applications such as optical microscopy, holography, and optical sensing. Conventional optical information transmission technologies suffer from bulky optical setup and information loss/crosstalk when meeting scatterers or obstacles in the light path. Here, we theoretically propose and experimentally realize the simultaneous manipulation of the coherence lengths and coherence structures of the light beams with the disordered metasurfaces. The ultra-robust optical information transmission and self-reconstruction can be realized by the generated partially coherent beam with modulated coherence structure even 93% of light is recklessly obstructed during light transmission, which brings new light to robust optical information transmission with a single metasurface. Our method provides a generic principle for the generalized coherence manipulation on the photonic platform and displays a variety of functionalities advancing capabilities in optical information transmission such as meta-holography and imaging in disordered and perturbative media.

A simple light path modifying device to reduce scattering in front-face fluorescence spectra.

This technical note presents a device to diminish scattering signal in front-face fluorescence spectra while obtaining fluorescence signal. The beam path in a commercial fluorescence spectrometer was modified by two deflecting mirrors, leading reflections away from the sensor. This light path modifying (LPM) device was tested with two fluid and three solid substances, where the scattering-to-fluorescence ratio improved by a factor of 1.7 to 7.6. The spectra obtained with the LPM were much clearer, and distortion of the fluorescence peaks was avoided. Scans of quinine sulphate complied well with reference spectra.&#xD.

BimodalPS: Causes and Corrections for Bimodal Multi-Path in Phase-Shifting Structured Light Scanners.

Structured light illumination is an active 3D scanning technique based on projecting and capturing a set of striped patterns and measuring the warping of the patterns as they reflect off a target object's surface. As designed, each pixel in the camera sees exactly one pixel from the projector; however, there are multi-path situations where a camera pixel sees light from multiple projector positions. In the case of bimodal multi-path, the camera pixel receives light from exactly two positions, which occurs along a step edge where the edge slices through a pixel which, therefore, sees both a foreground and background surface. In this paper, we present a general mathematical model to address this bimodal multi-path issue in a phase-shifting or so-called phase-measuring-profilometry scanner to measure the constructive and destructive interference between the two light paths, and by taking advantage of this interference, separate the paths and make two decoupled depth measurements. We validate our algorithm with both simulations and a number of challenging real-world scenarios, significantly outperforming the state-of-the-art methods.

Modeling and experimental verification for photodegradation in a spinning disk reactor

The spinning disk reactor has been regarded as a process intensification device in photochemical processes, which decreases the light path length by the thin film formation created by centrifugal force. A reliable reactor model was indispensable for the practical application of photoreactors. Our previous studies proposed a spinning disk reactor with elliptic-cylindrical and cylindrical spoilers for photochemical process intensification, and then hydrodynamic parameters of liquid film thickness, photon absorption rate, and residence time distribution were obtained. Based on the obtained parameters, herein, a reactor model was further established for the description of photodegradation reaction in the innovative spinning disk reactor. Different non-ideal flow models were employed during the model development, including the tanks-in-series model and axial dispersion model. The apparent reaction rate constant of a spinning disk reactor with spoilers was determined by the photon absorption rate, which was in the range of 0.088–0.268 s−1. The reactor model was verified by the experiments on photodegradation of Methylene Blue under different disk configurations and operating conditions. The degradation efficiency of Methylene Blue could reach up to 89.8 % in 25 min at N = 200 r/min, Q = 60 L/h, and I0 = 8 mW/cm2. The deviation between predicted and experimental Methylene Blue degradation efficiencies was within ± 20 %, confirming the rationality of the reactor model. The developed model lays the foundation for the scaling-up and commercial applications of the novel spinning disk reactors.

Underwater Camera Calibration Based on Double Refraction

Underwater camera calibration plays a pivotal role in underwater positioning and underwater mapping reconstruction, making it crucial for achieving precise spatial measurements in underwater environments. To elevate measurement accuracy, we have refined the calibration methodology for underwater cameras. Firstly, we conducted an in-depth investigation into the intricate challenges posed by double refraction errors arising from light passing through water–glass–air interfaces. To address this issue, we established a double refraction model based on the actual underwater light paths, laying the groundwork for our calibration efforts. Furthermore, to tackle the problem of determining multiple camera parameters, we proposed a parameter optimization method based on genetic algorithms, capable of navigating the complex parameter space. Finally, compared with other algorithms, our method enables more precise determination of underwater camera parameters.

One-shot measurement of birefringence by radial analysis

Due to complexity and bulky configuration of conventionally mechanical rotation approaches, a more convenient approach is to measure the birefringence effect (phase retardation and fast axis) by nano-fabricated spatial devices. Previous literature introduced radially-polarized illumination and eliminated the need for rotation mechanics in the illumination optics but still required rotation devices in the analyzer part. This work aims to achieve a compact and one-shot birefringence measurement by introducing spatial concepts in both the modulator and analyzer. By proposing a novel birefringence measurement by the combination of radial illumination and radial analyzer, this work is the first time to integrate no-mechanical motion and one-shot birefringence measurement in a single light path. What’s more, we are the first to introduce Fourier analysis in birefringence measurement, replacing the previous average intensity calculation, which is easily influenced by light source fluctuations. Based on our one-shot & non-mechanical measurement design and Fourier analysis algorithm, our birefringence measurement achieved very stable phase retardation measurement (standard deviation < 0.3°) and high accuracy fast axis measurement (average absolute error < 0.04°).

Pushing the Limit of Photo-Controlled Polymerization: Hyperchromic and Bathochromic Effects.

The photocatalyst (PC) zinc tetraphenylporphyrin (ZnTPP) is highly efficient for photoinduced electron/energy transfer reversible addition-fragmentation chain transfer (PET-RAFT) polymerization. However, ZnTPP suffers from poor absorbance of orange light by the so-called Q-band of the absorption spectrum (maximum absorption wavelength λmax = 600 nm, at which molar extinction coefficient εmax = 1.0×104 L/(mol·cm)), hindering photo-curing applications that entail long light penetration paths. Over the past decade, there has not been any competing candidate in terms of efficiency, despite a myriad of efforts in PC design. By theoretical evaluation, here we rationally introduce a peripheral benzo moiety on each of the pyrrole rings of ZnTPP, giving zinc tetraphenyl tetrabenzoporphyrin (ZnTPTBP). This modification not only enlarges the conjugation length of the system, but also alters the a1u occupied π molecular orbital energy level and breaks the accidental degeneracy between the a1u and a2u orbitals, which is responsible for the low absorption intensity of the Q-band. As a consequence, not only is there a pronounced hyperchromic and bathochromic effect (λmax = 655 nm and εmax = 5.2×104 L/(mol·cm)) of the Q-band, but the hyperchromic effect is achieved without increasing the intensity of the less useful, low wavelength absorption peaks of the PC. Remarkably, this strong 655 nm absorption takes advantage of deep-red (650-700 nm) light, a major component of solar light exhibiting good atmosphere penetration, exploited by the natural PC chlorophyll a as well. Compared with ZnTPP, ZnTPTBP displayed a 49% increase in PET-RAFT polymerization rate with good control, marking a significant leap in the area of photo-controlled polymerization.

Selective Enhancement of Viewing Angle Characteristics and Light Extraction Efficiency of Blue Thermally Activated Delayed Fluorescence Organic Light-Emitting Diodes through an Easily Tailorable Si3N4 Nanofiber Structure.

We selectively improved the viewing angle characteristics and light extraction efficiency of blue thermally activated delayed fluorescence (TADF) organic light-emitting diodes (OLEDs) by tailoring a nanofiber-shaped Si3N4 layer, which was used as an internal scattering layer. The diameter of the polymer nanofibers changed according to the mass ratio of polyacrylonitrile (PAN) and poly(methyl methacrylate) (PMMA) in the polymer solution for electrospinning. The Si3N4 nanofiber (SNF) structure was fabricated by etching an Si3N4 film using the PAN/PMMA nanofiber as a mask, making it easier to adjust parameters, such as the diameter, open ratio, and height, even though the SNF structure was randomly shaped. The SNF structures exhibited lower transmittance and higher haze with increasing diameter, showing little correlation with their height. However, all the structures demonstrated a total transmittance of over 80%. Finally, by applying the SNF structures to the blue TADF OLEDs, the external quantum efficiency was increased by 15.6%. In addition, the current and power efficiencies were enhanced by 23.0% and 25.6%, respectively. The internal light-extracting SNF structure also exhibited a synergistic effect with the external light-extracting structure. Furthermore, when the viewing angle changed from 0° to 60°, the peak wavelength and CIE coordinate shift decreased from 20 to 6 nm and from 0.0561 to 0.0243, respectively. These trends were explained by the application of Snell's law to the light path and were ultimately validated through finite-difference time-domain simulations.

Influence of inverted pyramid texturization on front metallization and performance of crystalline silicon solar cells

The silicon surface texturing is an essential part for the fabrication of crystalline silicon solar cells to increase the conversion efficiency. By adjusting the etching texturing condition, inverted pyramid (IP) and upright pyramid (UP) texturization were prepared on crystalline silicon substrates for fabrication of PERC solar cells. The surface morphology not only affects the light trapping but also impacts electrode shading loss and front electrode contact interface. The IP texturization presents better anti-reflective performance due to more common light paths and narrower silver grids owing to less flow of Ag paste on concave blocked structure, both of which results in the higher short-circuit current density (Jsc). Yet in terms of front Ag/Si contact interface, the IP texturization causes more Ag crystallites and more surface recombination under the present condition suitable for UP texturization because of more edges on the upper part of IP, which leads to the lower open-circuit voltage (Voc). The final conversion efficiency of IP solar cells (23.61 %) is 0.06 % higher than that of UP solar cells (23.55 %). An improvement about 0.07 mA/cm2 of Jsc was achieved with IP samples and Voc has a decrease of 0.3 mV caused by the surface recombination on IP texturization. In summary, the structural characteristics of IP results in lower reflectivity and less electrode shading, while Ag/Si contact interface could be optimized by adjusting the processing condition, ultimately promising the higher efficiency.

A violet light-emitting diode-based gas-phase molecular absorption device for measurement of nitrate and nitrite in environmental water

A simple and sensitive device for the detection of nitrite and nitrate in environmental waters was developed based on visible light gas-phase molecular absorption spectrometry. By integrating a detection cell (DC), semiconductor refrigeration temperature-controlling system (SRTCY), and nitrite reactor into a sequential injection analysis system, trace levels of nitrite and nitrate in complex matrices were successfully measured. A low energy-consuming light-emitting diode (violet, 400–405 nm) was coupled with a visible light-to-voltage converter (TSL257) to measure the gas-phase molecular absorption. To reduce the interference of water vapor, an SRTCY was used to condense the water vapor on-line before the gas-phase analyte entered the DC. The DC was radiatively heated by the SRTCY to avoid water vapor condensation in the light path. As a result, the obtained baseline noise reduced 3.75 times than that of without SRTCY. Under the optimized conditions, the device achieved limits of detection (3σ/k) of 0.055 and 0.36 mmol/L (0.77 and 5.04 mg N/L) for nitrite and nitrate, respectively, and the linear calibration ranges were 0.1–15 mmol/L (R2 = 0.9946) and 1–10 mmol/L (R2 = 0.9995), respectively. Precisions of 5.2 % and 9.0 % were achieved for ten successive determinations of 0.3 mmol/L nitrite and 1.0 mmol/L nitrate, and the analytical times for nitrite and nitrate determination were 5 and 13 min, respectively. This method was validated against standard methods and recovery tests, and it was applied to the measurement of nitrite and nitrate in environmental waters. Moreover, a device was designed to enable the field measurement of nitrite and nitrate in complex matrices.

Effect of DC poling on transparency and photoluminescence in Pr:PMN-PT transparent ceramics

Electric poling could significantly influence the transparency and the photoluminescence (PL) intensities in transparent ferroelectric PL ceramics. This work applied direct current (DC) poling on a highly transparent 0.75PMN-0.25PT:0.015Pr3+ ceramic, observed the domain configurations in a direction perpendicular to poling direction. Lamellar domains perpendicular to electric field were observed after poling and decreased the transmittance by changing the propagation path of incident light. Besides, the enhancement of PL intensities by poling was found as high as 62 %, mainly due to the following reasons: the change of light propagation path by the lamellar domains is supposed to increase the absorption of exciting light; and the reduced crystal symmetry may increase the PL efficiency. This work revealed the effects of DC poling on transparency and PL properties in transparent ferroelectric PL ceramics.

High-throughput fluorescence quantification method based on inner filter effect and fluorescence imaging analysis

The application of the inner filter effect (IFE) in fluorescent substance determination is gaining popularity. In this paper, a theory of the fluorescence distribution along with the excitation light path is derived from our previous research about the spatial micro-element method. According to the relationship between the summation of fluorescence intensities along the vertical direction at a certain position on the excitation light path and the position, a high-concentration and wide-range fluorescent substance quantification method based on the IFE and fluorescence imaging analysis is proposed. Correspondingly, a high-throughput fluorescent substance quantification detection system is constructed. In order to validate the method, solutions of rhodamine B in different concentrations are used for principle validation, concentration prediction, and experimental investigation on the influence of integration time and lens distortion. The high-throughput system enables the simultaneous measurement of six samples, realizing the high-concentration and wide-range quantification of rhodamine B (100–600 mg/L) with high precision (R2 = 0.9992, MRE = 2.34 %). By setting the filter wheel, the system can measure the concentration of fluorescent substances with different emission wavelengths. The improvement of experimental device is expected to reduce the single sample capacity to tens of microliters and increase the overall sample quantity to tens or even hundreds. The proposed method and system are beneficial to fluorescence measurement in fields such as biomedicine and dye research and to the improvement of high-throughput fluorescence quantitative PCR instruments.

A Review of Metamaterials Cloaking for Military and Civilian Use

Metamaterials cloaking technology boasts a wide array of potential uses, spanning from military stealth applications to advancements in medical imaging. Metamaterials are specially engineered materials with unique characteristics absent in natural substances, such as negative refractive index, empowering them to manipulate electromagnetic waves in novel ways. The process of cloaking with metamaterials involves the bending of light or other electromagnetic waves around an object, effectively rendering it invisible or significantly reducing its detectability. This is accomplished through the intricate design of metamaterial structures capable of governing the flow of electromagnetic fields, diverting them away from the cloaked object. Among the most prominent applications of metamaterial cloaking is the development of invisibility cloaks. While primarily at the experimental stage, researchers have made substantial progress in crafting cloaking devices capable of concealing objects from specific wavelengths of light. These cloaks function by manipulating the path of light around an object, effectively creating the illusion of its absence. The potential applications of metamaterial cloaking encompass a broad spectrum, including invisibility, antennas and sensors, medical imaging, wireless communication, and stealth technology.

Nanometric determination of the thickness of aqueous samples for accurate molar absorption coefficients of water-soluble molecules in the mid-infrared region

Absorption spectra of aqueous samples measured by transmission need to be acquired using very thin cells (5–50 μm) when targeting the mid-infrared (mid-IR) region due to the strong background absorbance of liquid water. The thickness of the cell used controls the pathlength of the light through the sample, a value needed to transform absorption spectra into molar absorption coefficient spectra, or to determine solute concentrations from absorption spectra. The most accurate way to determine the thickness of an empty cell (i.e., filled with air) is from the period of an interference pattern, known as interference fringes, that arises when the cell is placed perpendicular to the path of light in the spectrometer. However, this same approach is not directly applicable to determine the thickness of a cell filled with an aqueous solution, due partially to the smaller amplitude of the interference fringes but fundamentally caused by its complex waveform, with a wavenumber-dependent oscillation period. Here, using Fresnel equations, we derived analytical expressions to model interference fringes in absorption spectra obtained by transmission, which are also valid for aqueous samples. We also present a novel Fourier-based analysis of the interference fringes that, in combination with the derived analytical expressions, allowed us to determine the pathlength of aqueous samples with an error below ∼ 50 nm. We implemented this novel approach to analyze interference fringes as a Live Script running in the software Matlab. As an application, we measured the absorption spectra of a 97 mM solution of MES buffer at pH 3.4 and pH 8.4 using cells of various nominal thicknesses (6, 25 and 50 μm), whose actual thicknesses were determined using the present approach. The derived molar absorption coefficient spectrum for both the acidic and basic forms of MES were virtually identical regardless of the cell, indicating that the determined thicknesses were likely very accurate. These results illustrate the utility of the present methodology in obtaining accurate molar absorption coefficient spectra of water-soluble molecules in the mid-IR region.

Ghost image analysis for pancake virtual reality systems

Pancake optics (also known as polarization-based catadioptric system) has been widely used as the imaging lens for virtual reality (VR) and mixed reality (MR) headsets because of its compact formfactor and excellent image quality. However, such a folded pancake optics not only dramatically lowers the optical efficiency to 25% because of the utilization of a half mirror, but also suffers from ghost images due to the stray light from multiple surface reflections and imperfect polarization control inside the optical system. In this paper, the origins including the light paths of the ghost images are explored by experiment and then analyzed by simulation. The effect of different incident angles on the intensity of each ghost is also investigated.