Light Matter Research Articles

Shaping the Infrared luminescence of Colloidal Nanocrystals Using a Dielectric Microcavity

AbstractAs they have gained maturity, colloidal nanocrystals (NCs) have also expand the spectral range over of which they could be used for photonic and optoelectronic applications. In particular, the infrared use of NCs has become of utmost interest to develop cost‐effective alternatives to current technologies. It is then critical not to let the material dictate the light–matter interaction, which is why the coupling of NCs to photonic cavities has been proposed. For infrared NCs, this approach has first been devoted to the control of absorption with in mind the increase of the signal magnitude for detectors. A Lot of efforts have been focused on the use of metallic metasurfaces. However, these generate significant optical losses and yield low quality factor. Here, this study rather focus on the coupling of infrared NCs to a dielectric mirror cavity. HgTe/CdS core‐shell NCs are used and integrated into a cavity made of aperiodic dielectric mirrors. The effect of the substrate is systematically study on spectral linewidth, carrier dynamic, and emission directivity. The cavity is shown to narrow the PL by a factor 10, while focusing the emission over a 12° angle. Monitoring the power dependence of the emission, this study shows that the cavity leads to 250 K increase in the effective electronic temperature.

Probing scalar, Dirac, Majorana, and vector dark matter through a spin-0 electron-specific mediator at electron fixed-target experiments

We discuss the thermal target curves of Majorana, Dirac, scalar, and vector light dark matter (DM) that are associated with the freeze-out mechanism via the annihilation into the e+e− pair through the electron-specific spin-0 mediator of dark matter. We also discuss the mechanism to produce the regarded DM mediator in the electron (positron) fixed-target experiments such as NA64e and LDMX. We derive the corresponding experimental reaches of NA64e and LDMX that are complementary to the DM thermal target parameter space. Published by the American Physical Society 2024

Light mass window of inert doublet dark matter with lepton portal interaction

We study phenomenology of a light scalar dark matter (DM). In the model, there is an inert doublet scalar and a singlet Dirac fermion ψ, both charged under a global Z2 symmetry. The mass of the lightest inert scalar H can be lighter than 10 GeV by imposing appropriate relations between three scalar quartic couplings. The lightest Z2 odd particle is stable and DM. In this paper, focusing on the parameter space where H is lighter than ψ and is DM, we discuss DM physics related to relic density, direct detection, indirect detection, collider searches, and other cosmological observations. We clarify differences from the case where ψ is instead DM, which has been focused on in previous works. Published by the American Physical Society 2024

Multiplication of the orbital angular momentum of phonon polaritons via sublinear dispersion

Optical vortices (OVs) promise to greatly enhance optical information capacity via orbital angular momentum multiplexing. The need for the on-chip integration of orbital angular momentum technologies has prompted research into subwavelength-confined polaritonic OVs. However, the topological order imprinted by the structure used for transduction from free-space beams to surface polaritons is inherently fixed after fabrication. Here we overcome this limitation via dispersion-driven topological charge multiplication. We switch the OV topological charge within a small frequency range (~3%) by leveraging the strong sublinear dispersion of low-loss surface phonon polaritons on silicon carbide membranes. Applying the Huygens principle, we quantitatively evaluate the topological order of experimental OVs detected by near-field imaging. We further explore the deuterogenic effect, which predicts the coexistence of multiple topological charges in higher-order polaritonic OVs. Our work demonstrates a viable method to manipulate the topological charge of polaritonic OVs, paving the way for the exploration of novel orbital-angular-momentum-enabled light–matter interactions at mid-infrared frequencies.

Light matters: Quantifiable optical interaction between near-infrared laser radiation and nano-additivated polymers in all states of matter present in laser powder bed fusion

Comprehending the interaction between light and material is crucial to the success of various laser-based processes, including laser powder bed fusion of polymers. The use of the promising near-infrared laser wavelength in laser powder bed fusion of polymers is limited by the necessity for absorption-enhancing (nano-) additives and insufficient knowledge of the (nano-) particulate impact on the material and process behavior. The present study lays the groundwork for an improved understanding of the laser-material interaction at different states of matter in laser powder bed fusion by means of thermo-optical measurements with a double integrating sphere setup. Analyses and experiments were based on polyamide 12 and its nanocomposite powder surface-coated with carbon black nanoparticles by two distinct additivation methods. The attenuation coefficient and penetration depth of each material were calculated from the measured transmittance and reflectance in all relevant states of matter. The effects of the feedstock particle size, the nano-additivation method, and the nanoparticle quantity were evaluated. The optical results of resolidified samples were validated using a commercially available spectrophotometer. Finally, the thermo-optical results were qualitatively correlated with the depth of fusion of specimens processed by powder bed fusion using an 808 nm diode laser.

Strong light–matter interactions based on excitons and the abnormal all-dielectric anapole mode with both large field enhancement and low loss

The room temperature strong coupling between the photonic modes of micro/nanocavities and quantum emitters (QEs) can bring about promising advantages for fundamental and applied physics. Improving the electric fields (EFs) by using plasmonic modes and reducing their losses by applying dielectric nanocavities are widely employed approaches to achieve room temperature strong coupling. However, ideal photonic modes with both large EFs and low loss have been lacking. Herein, we propose the abnormal anapole mode (AAM), showing both a strong EF enhancement of ∼70-fold (comparable to plasmonic modes) and a low loss of 34 meV, which is much smaller than previous records of isolated all-dielectric nanocavities. Besides realizing strong coupling, we further show that by replacing the normal anapole mode with the AAM, the lasing threshold of the AAM-coupled QEs can be reduced by one order of magnitude, implying a vital step toward on-chip integration of nanophotonic devices.

Two-dimensional thin film lithium niobate photonic crystal waveguide for integrated photonic chips

The photonic crystal waveguide (PCW) possesses remarkable capabilities in manipulating light beams and light–matter interactions within the subwavelength range. This property renders it a highly promising structure for the miniaturization of optical devices. We delve into the mode characteristics in two-dimensional PCWs on thin film lithium niobate, establish the correlation between the single-mode region in the PCW and its photonic crystal duty cycle, and observe mode hybridization in the waveguide. A lithium niobate PCW with sidewall angles can realize single-mode transmission or mode conversion by adjusting the width of its defective waveguides, and it is theoretically and experimentally verified that a change in the width of the waveguide shifts the operating wavelength. The results of the mode analysis are useful in the design of waveguide structures for photonic crystal-based electro-optical modulators and optical sensors.

Ultrafast wavelength sweeping of surface plasmon lasing in planar metal grating with semiconductor gain

Surface plasmon (SP) lasing, characterized by strong light–matter interaction at a metal interface, can derive from SP cavities coupled with a semiconductor gain material. With this setup, we demonstrate ultrafast wavelength sweeping of SP lasing in a metal grating. When the device was optically pumped by ultrashort pulses with sufficient power, a wavelength sweep over 10 nm within 50 ps was obtained in the telecom band of 1550 nm. Based on the pump-power-dependent lasing wavelength change in combination with finite-difference time-domain simulation, we attribute the wavelength sweep to a modulation of the SP cavity that induces changes in the refractive index from changes in the carrier density. Such a refractive index change is a critical factor in determining SP cavity resonance.

Origin of discrete donor–acceptor pair transitions in 2D Ruddlesden–Popper perovskites

Two-dimensional (2D) van der Waals nanomaterials have attracted considerable attention for potential use in photonic and light–matter applications at the nanoscale. Thanks to their excitonic properties, 2D perovskites are also promising active materials to be included in devices working at room temperature. In this work, we study the presence of very narrow and spatially localized optical transitions in 2D lead halide perovskites by μ-photoluminescence and time-decay measurements. These discrete optical transitions are characterized by sub-millielectronvolt linewidths (≃120μeV) and long decay times (5–8 ns). X-ray photoemission and density-functional theory calculations have been employed to investigate the chemical origin of electronic states responsible of these transitions. The association of phenethylammonium with methylammonium cations into 2D Ruddlesden–Popper perovskites, (PEA)2(MA)n−1PbnI3n+1, particularly in phases with n≥2, has been identified as a mechanism of donor–acceptor pair (DAP) formation, corresponding to the displacement of lead atoms and their replacement by methylammonium. Ionized DAP recombination is identified as the most likely physical source of the observed discrete optical emission lines. The analysis of the experimental data with a simple model, which evaluates the Coulombic interaction between ionized acceptors and donors, returns a donor in Bohr radius of the order of ≃10 nm. The analysis of the spectral and electronic characteristics of these single donor–acceptor states in 2D perovskites is of particular importance both from the point of view of fundamental research, as well as to be able to link the emission of these states with new optoelectronic applications that require long-range optically controllable interactions.

Investigation of AcXO3 (X = Al, Ga) perovskites for energy harvesting applications: a DFT approach

Full potential linearized augmented plane wave (FP-LAPW) based computational study is presented for AcAlO3 and AcGaO3. Tolerance factor (τG) is 0.93 for AcAlO3 and 0.90 for AcGaO3 which reveal the stability of proposed perovskite oxides in cubic phase. The calculated band structures for both materials reveal the nonmagnetic semiconductive nature with energy band gaps of 3.98 and 2.75 eV for respective Al and Ga based perovskites. Total, and partial density of states (DOS) are computed for meaningful understanding of semiconducting behavior of the proposed perovskites. The partially filled O-2p and Ac-6d states are observed to lie in the vicinity of Fermi level. Furthermore, various parameters of optical spectra have also been computed to study the light matter interaction. Moreover, thermoelectric (TE) properties of both materials have been investigated by using semiclassical Boltzmann theory with constant relaxation time approximation. Calculated figure of merit (ZT) values for AcAlO3 and AcGaO3 are 0.23 and 0.20 at 800 K, respectively. Overall, computational study for titled perovskites indicate that these materials have application in UV sensors, photovoltaic and thermoelectric devices.

Design and analysis of Si photonic NaCl sensors based on suspended microdisk resonators

In this paper, two optical refractive index sensors, respectively based on a suspended microdisk resonator (SMDR) and a sub-wavelength Bragg grating suspended microdisk resonator (SWG-SMDR) have been designed on a silicon on insulator (SOI) platform, and their optical and sensing performances have been analyzed using the three-dimensional finite-difference time-domain method. It has been shown that the Bragg grating increases the optical confinement factor in the sensing region and, consequently, improves the light–matter interaction and sensitivity. Considering concentrations of 0 to 25% for the NaCl dissolved in the deionized water, the enhanced sensitivity and FOM of the SWG-SMDR sensor with the miniaturized optimal geometrical dimensions are 163.77 nm RIU−1 and 10.81 RIU−1, respectively. This compact optical sensor enhances the sensitivity and FOM by combining effects of the Bragg grating and suspension configuration in improving the light–matter interaction.

Molecular scale nanophotonics: hot carriers, strong coupling, and electrically driven plasmonic processes

Abstract Plasmonic modes confined to metallic nanostructures at the atomic and molecular scale push the boundaries of light–matter interactions. Within these extreme plasmonic structures of ultrathin nanogaps, coupled nanoparticles, and tunnelling junctions, new physical phenomena arise when plasmon resonances couple to electronic, exitonic, or vibrational excitations, as well as the efficient generation of non-radiative hot carriers. This review surveys the latest experimental and theoretical advances in the regime of extreme nano-plasmonics, with an emphasis on plasmon-induced hot carriers, strong coupling effects, and electrically driven processes at the molecular scale. We will also highlight related nanophotonic and optoelectronic applications including plasmon-enhanced molecular light sources, photocatalysis, photodetection, and strong coupling with low dimensional materials.

Physics-assisted machine learning for THz time-domain spectroscopy: sensing leaf wetness

Signal processing techniques are of vital importance to bring THz spectroscopy to a maturity level to reach practical applications. In this work, we illustrate the use of machine learning techniques for THz time-domain spectroscopy assisted by domain knowledge based on light–matter interactions. We aim at the potential agriculture application to determine the amount of free water on plant leaves, so-called leaf wetness. This quantity is important for understanding and predicting plant diseases that need leaf wetness for disease development. The overall transmission of 12,000 distinct water droplet patterns on a plastized leaf was experimentally acquired using THz time-domain spectroscopy. We report on key insights of applying decision trees and convolutional neural networks to the data using physics-motivated choices. Eventually, we discuss the generalizability of these models to determine leaf wetness after testing them on cases with increasing deviations from the training set.

Quantum simulation of an extended Dicke model with a magnetic solid

The Dicke model describes the cooperative interaction of an ensemble of two-level atoms with a single-mode photonic field and exhibits a quantum phase transition as a function of light–matter coupling strength. Extending this model by incorporating short-range atom–atom interactions makes the problem intractable but is expected to produce new physical phenomena and phases. Here, we simulate such an extended Dicke model using a crystal of ErFeO3, where the role of atoms (photons) is played by Er3+ spins (Fe3+ magnons). Through terahertz spectroscopy and magnetocaloric effect measurements as a function of temperature and magnetic field, we demonstrated the existence of a novel atomically ordered phase in addition to the superradiant and normal phases that are expected from the standard Dicke model. Further, we elucidated the nature of the phase boundaries in the temperature–magnetic-field phase diagram, identifying both first-order and second-order phase transitions. These results lay the foundation for studying multiatomic quantum optics models using well-characterized many-body solid-state systems.

Subradiant plasmonic cavities make bright polariton states dark

Abstract Nanostructured plasmonic surfaces allow for precise tailoring of electromagnetic modes within sub-diffraction mode volumes, boosting light–matter interactions. This study explores vibrational strong coupling (VSC) between molecular ensembles and subradiant “dark” cavities that support infrared quadrupolar plasmonic resonances (QPLs). The QPL mode exhibits a dispersion characteristic of bound states in the continuum (BIC). That is, the mode is subradiant or evanescent at normal incidence and acquires increasing “bright” dipole character with larger in-plane wavevectors. We deposited polymethyl methacrylate (PMMA) thin films on QPL substrates to induce VSC with the carbonyl stretch in PMMA and measured the resulting infrared (IR) spectra. Our computational analysis predicts the presence of “dark” subradiant polariton states within the near-field of the QPL mode, and “bright” collective molecular states. This finding is consistent with classical and quantum mechanical descriptions of VSC that predict hybrid polariton states with cavity-like modal character and N−1 collective molecular states with minimal cavity character. However, the behaviour is opposite of what is standardly observed in VSC experiments that use “bright” cavities, which results in “bright” polariton states that can be spectrally resolved as well as N−1 collective molecular states that are spectrally absent. Our experiments confirm a reduction of molecular absorption and other spectral signatures of VSC with the QPL mode. In comparison, our experiments promoting VSC with dipolar plasmonic resonances (DPLs) reproduce the conventional behavior. Our results highlight the significance of cavity mode symmetry in modifying the properties of the resultant states from VSC, while offering prospects for direct experimental probing of the N−1 molecule-like states that are usually spectrally “dark”.

Creating spatial doughnut-spot arrays and double-helix focal fields with prescribed characteristics

Spatially controllable focal fields play a pivotal role in light manipulation and provide significant opportunities for precisely manipulating light–matter interactions in a wide range of applications. In particular, the double-helix focal field—characterized by a distinctive helical structure—exhibits exceptional optical properties, thus differentiating it apart from conventional focal fields. However, the rapid construction of a double-helix focal field with controllable characteristics and a uniform intensity remains a challenging task. Based on the theory of pattern synthesis of an antenna array, we propose and realize the generation of three-dimensional doughnut-spot arrays and double-helix focal fields with specified characteristics in a 4π system by reverse-solving the radiation field of the virtual antenna. Numerical examples indicate that the desired novel focal fields, including features such as shape, orientation, length, and period, could be rapidly, conveniently, and flexibly customized by selecting appropriate parameters for the magnetic dipole array antennas. This method could reveal an avenue for enhanced light manipulation for applications in materials processing, optical lithography, and optical communications.

THz graphene-integrated metasurface for electrically reconfigurable polarization conversion

Abstract Terahertz (THz) waves have been widely hailed as a key enabling technology for future sixth generation (6G) wireless networks. Dynamic modulation of their polarization states is of great attraction for high-capacity communications and anisotropic sensing. The development of such technology is, however, still in very early stage owing to the difficulties of realizing electrical reconfigurability for THz devices. Artificially constructed metasurfaces and new nanomaterials, such as graphene, have been shown to provide revolutionary platforms for manipulating and controlling the wave properties, especially at THz frequencies. This work leverages the light–matter interaction in a graphene-integrated metasurface functioning as an electrically reconfigurable THz polarization converter. A novel graphene-gold bilayer topology is applied to construct such a metasurface which enables wide-range electrical tunability of the polarization conversion. Under a y-polarized illumination, the reflected components of x- and y-polarizations are tuned dynamically through an external bias voltage across the metasurface, thereby producing an elliptically polarized wave with tuneable ellipticity and angle. By changing the voltage from 0 V to 12 V, the reflected polarization ellipticity has been tuned from −0.94 to −0.5 at around 240 GHz, featuring linear-to-circular and linear-to-elliptical polarization conversions. Meanwhile, the polarization angle has been modulated from 12° to −23° at around 236 GHz. This work provides an experimentally validated THz graphene-integrated metasurface with wide polarization modulation depths, low biasing voltages and simple configuration. It promises great potential for applications in future THz communications and sensing.

Tunable optoelectronic response in van der Waals heterojunction transistors for artificial visual recognition

Optoelectronic synaptic transistors are advantageous in in-memory light sensing for artificial neural networks. Herein, optoelectronic synaptic junction field-effect transistors (JFETs) based on a Ga2O3/MoS2 heterojunction are fabricated. The devices exhibit robust electrical performances, including a high on/off ratio of 108, a low subthreshold swing of 69 mV dec−1, and a high output current of 3.4 μA μm−1. An inverter and a NAND gate are constructed based on the dual-gated configuration, with the inverter showing a high voltage gain of 28 and the near-ideal noise margin of 90.4%. Additionally, the devices demonstrate outstanding optoelectronic performances benefiting from the strong light–matter interactions of MoS2. Typical synaptic plasticities, including short-term plasticity, long-term plasticity, and spiking-rate-dependent plasticity, are simulated by applying the light pulses. Furthermore, metaplastic excitatory postsynaptic current, metaplastic facilitation of long-term potentiation and transition from potentiation to depression are also readily demonstrated. The artificial neural network, in which neurons are interconnected through our proposed optoelectronic synaptic transistors, achieves a high accuracy of 89.8% in recognizing handwritten digits. This work provides insight into the design of an optoelectronic synapse based on JFETs.

Ultrafast atomic-scale scanning tunnelling spectroscopy of a single vacancy in a monolayer crystal

Defects in atomically thin semiconductors and their moiré heterostructures have emerged as a unique testbed for quantum science. Strong light–matter coupling, large spin–orbit interaction and enhanced Coulomb correlations facilitate a spin–photon interface for future qubit operations and efficient single-photon quantum emitters. Yet, directly observing the relevant interplay of the electronic structure of a single defect with other microscopic elementary excitations on their intrinsic length, time and energy scales remained a long-held dream. Here we directly resolve in space, time and energy how a spin–orbit-split energy level of an isolated selenium vacancy in a moiré-distorted WSe2 monolayer evolves under the controlled excitation of lattice vibrations, using lightwave scanning tunnelling microscopy and spectroscopy. By locally launching a phonon oscillation and taking ultrafast energy-resolved snapshots of the vacancy’s states faster than the vibration period, we directly measure the impact of electron–phonon coupling in an isolated single-atom defect. The combination of atomic spatial, sub-picosecond temporal and millielectronvolt energy resolution marks a disruptive development towards a comprehensive understanding of complex quantum materials, where the key microscopic elementary interactions can now be disentangled, one by one.

Electrically Active Terahertz Liquid‐Crystal Metasurface for Polarization Vortex Beam Switching

AbstractPolarized vortex waves have attracted widespread attention in investigations of light–matter interactions and the augmentation of information capacity owing to their distinctive characteristics. Nevertheless, the reconfigurable generation of vector beams, especially at terahertz (THz) frequencies, remains challenging. In this study, a tunable THz polarization vortex beam generator based on a liquid‐crystal metasurface is proposed. A unit cell featuring reconfigurable linear polarization selectivity is developed. A general methodology for designing metasurfaces to generate customized and reconfigurable polarization patterns is introduced. Furthermore, the electrically tunable generation of polarized patterns and cylinder vector beams is experimentally demonstrated. The findings of this study can open up opportunities for wireless communication and super‐resolution imaging applications.