Light-duty Engine Research Articles

Novel low temperature NOx storage-reduction catalysts for diesel light-duty engine emissions based on hydrotalcite compounds

A series of Pt and Pt,Cu supported catalysts were prepared by wet impregnation of Mg–Al supports obtained from hydrotalcite-type (HT) precursor compounds. These novel NOx storage-reduction (NOxSR) catalysts show improved performances in NOx storage than Pt,Ba/alumina NOxSR catalysts at reaction temperatures lower than 200°C. These catalysts show also improved resistance to deactivation by SO2. The effect is attributed to the formation of well dispersed Mg(Al)O particles which show good NOx storage properties. The promoted low temperature activity is explained by the lower basicity of the Mg(Al)O mixed oxide in comparison to BaO, which induces on one hand a lower inhibition on Pt activity (NO to NO2 oxidation and/or hydrocarbon oxidation) due to electronic effect, and on the other hand a lower thermal stability of the stored NOx. The presence of Cu slightly inhibits activity at low temperature, although improves activity and resistance to deactivation at 300°C. On these catalysts FT-IR characterization evidences the formation of a Pt–Cu alloy after reduction.

Atmospheric levels of formaldehyde and acetaldehyde and their relationship with the vehicular fleet composition in Salvador, Bahia, Brazil

The present work is concerned with the formaldehyde and acetaldehyde content in the gas-phase and their concentrations correlation, with the vehicular fleet, at several sites in Salvador, BA, Brazil. The samples were collected using C-18 Sep Pak cartridges coated with an acidic solution of 2,4-dinitrophenylhydrazine (DNPH). The resulting hydrazones were separated and quantified using HPLC. Samples were collected during 1 - 2 h periods at six sites located in the city of Salvador, Bahia: a bus station, a tunnel, a commercial mall parking lot, a business building parking lot a residential district and a commercial district; and at two other sites far from Salvador: Cacha Pregos and Lagoa Verde. The measured concentrations for formaldehyde and acetaldehyde ranged, respectively, from 0.20 to 88 ppbV and from 0.40 to 93 ppbV. The formaldehyde/acetaldehyde concentration ratio determined in these sites were: 0.66 (commercial mall parking lot); 0.65 (business building parking lot); 4.4 (bus station); 1.2 (tunnel); 1.0 (residential area), 1.7 (commercial area), 1.1 (Cacha Pregos) and 0.8 (Lagoa Verde). In the case of the tunnel, it represents the hole vehicular fleet of the city. Traffic counts taken during the sampling periods indicated that 82% of the vehicles at that site were light duty engines and 18% were heavy duty vehicles. A simple calculation using the tunnel fleet composition and the ratio formaldehyde/acetaldehyde at the bus station (as a diesel signature) and at the parking (as a light duty vehicles signature) revealed an expected tunnel ratio of 1.3 which is very close to the measured ratio 1.2. Indeed, the expected ratio for both the commercial area and residential area was, respectively, 1.7 and 0.62. It allows us to conclude that the atmospheric level of formaldehyde and acetaldehyde in Salvador has a close relationship with the vehicular fleet composition.

The Application of a Thermal Efficiency Maximizing Control Strategy for Ignition Timing and Equivalence Ratio on a Natural Gas-Fueled Hercules G1600

A two-dimensional optimization process, which simultaneously adjusts the spark timing and equivalence ratio of a lean-burn, natural gas, Hercules G1600 engine, has been demonstrated. First, the three-dimensional surface of thermal efficiency was mapped versus spark timing and equivalence ratio at a single speed and load combination. Then the ability of the control system to find and hold the combination of timing and equivalence ratio that gives the highest thermal efficiency was explored. NOx, CO, and HC maps were also constructed from our experimental data to determine the tradeoffs between efficiency and emissions. The optimization process adds small synchronous disturbances to the spark timing and air flow while the fuel injected per cycle is held constant for four cycles. The engine speed response to these disturbances is used to determine the corrections for spark timing and equivalence ratio. The control process, in effect, uses the engine itself as the primary sensor. The control system can adapt to changes in fuel composition, operating conditions, engine wear, or other factors that may not be easily measured. Although this strategy was previously demonstrated in a Volkswagen 1.7 liter light duty engine (Franklin et al., 1994b), until now it has not been demonstrated in a heavy-duty engine. This paper covers the application of the approach to a Hercules G1600 engine.

Predominant induction of kinetochore-containing micronuclei by extracts of diesel exhaust particulates in cultured human lymphocytes.

The aneuploidy-inducing activity of extracts of diesel exhaust particulates from light duty (LD) and heavy duty (HD) engines was investigated in cultured peripheral blood lymphocytes of 8 healthy donors using the cytokinesis-block micronucleus test with the kinetochore labelling modification. A majority of the subjects tested showed a significant kinetochore-positive micronucleus induction after treatment with the highest dose (150 micrograms/ml) of LD extract, although some subjects also showed induction of kinetochore-negative micronuclei. Only one subject had significantly increased numbers of kinetochore-positive micronuclei at a dose of 400 micrograms/ml of HD extract. These results suggest that diesel extract, at least LD extract, possesses the ability to induce whole chromosome loss (aneuploidy) preferentially, although there are also chromosome breaks.

Polar organic components in emission and immission samples from urban suspended particulates and their mutagenicity in the AMES-bioassay

Immission and emission samples of urban suspended particulates were taken from Berlin (West) aerosols, light duty engines and private coal firing. Single organic components of PAH and oxygenated PAH (= polar neutral organic components POCn) were identified by gas chromatographic analysis. All organic fractions were tested to their mutagenic activity in the Salmonella typhimurium bioassay according to AMES.