A differential thermal analyser has been modified and a technique developed to enable the temperature rises which occur during the setting of visible light-cured composites to be measured. Two factors are responsible for this rise: the exothermic nature of the reaction in the material, and light used to initiate the cure which is transmitted through the composite. Both have been measured for a particular combination of one light source and one composite. The increase produced by the material is comparable to that in two paste autopolymerising systems as they set, however this is all but eclipsed by heat from the light source. The rise produced by the light increases with increasing exposure time and decreasing composite thickness, to reach up to 21.4°C for the selected combination of composite and light unit (though this rise may be reduced in vivo by other factors). The modified DTA and technique are suitable for the measurement of temperature rises (of which that from the light is of prime importance) together with corresponding times. However, whilst it is possible to obtain the heat of reaction for the composite the dominance of heat from the light source reduces the accuracy of this measurement and an alternative approach should be considered for heats of reaction.
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