Life Cycle Research Articles

Sulfuric acid treatment to control the microcrystalline structure of starch-based hard carbon for sodium storage

By treating starch with different concentrations of sulfuric acid, we investigated the effect of cross-linked starch-based hard carbon on the performance of sodium-ion batteries (SIBs) at various concentrations. After treatment, the optimal sample exhibits a spherical microstructure, which can provide effective active sites and enhance structural stability, thereby achieving high capacity and long cycle life for SIB electrodes. In subsequent electrochemical tests, after 100 cycles at low current density of 0.1 A g−1, the capacity of H40 remains of 306 mA h g−1. And under the high current density of 1 A g−1, the capacity of H40 can still maintain of 228 mA h g−1, exhibiting a high capacity retention rate of 89 %, which is higher than other samples. This study provides a promising approach for the large-scale production of biomass-derived carbonaceous SIBs anodes.

Six element high-entropy Prussian blue analogue cathode enabling high cycle stability for sodium-ion batteries

Prussian blue analogues (PBA) are promising cathode materials for sodium-ion batteries. However, the cycle life of PBA is limited due to its structure instability during cycling. Here, we successfully introduce six transition metals into N coordination site to increase the configurational entropy, significantly improving the structure stability and cycle life of PBA cathode materials. Electrochemical characterization methods are used to compare the behavior of hexa-, penta-, quadr-, and tri-metal PBA, exhibiting the characteristic of performance increasing with entropy. Time-resolved in situ X-ray diffraction confirms the “quasi-zero-strain” structure of H-PBA during desodiation/sodiation process. X-ray absorption spectroscopy and density functional theory calculations reveal that Mn, Fe, Co and Cu contribute the high capacity of H-PBA, while Ni and Zn stabilize the structure. The strategy will inspire new ideas in designing long life cathode materials with high capacity for sodium-ion batteries.

Enhanced cyclability of O3-NaNi0.33Fe0.31Mn0.36O2 by Mg and Cu synergistic doping with strengthened Mn[sbnd]O bonds

Among some practical O3-type layered oxide cathodes, NaNi1/3Fe1/3Mn1/3O2 (NFM) features a high specific capacity and moderate cyclability. However, sluggish Na+ transfer kinetics, low structural stability, and rapid capacity loss during long-term cycling, are still posing a challenge to commercial applications of this material. In this work, we propose a Mg and Cu co-doped O3-type NaMg0.02Cu0.02Ni0.33Fe0.27Mn0.36O2 (MC-NFM) with a stable structure and good cycling stability. It was found that the MnO bonds in MC-NFM are obviously reinforced by synergistic doping with small amounts of Mg and Cu, leading to enhanced structural robustness, decreased Na+ migration barrier, and delayed O3-P3 phase transition. As a result, longer cycle life and enhanced rate performance are achieved. MC-NFM can yield a specific capacity of 142.1 mAh g−1 at 0.1C and 116.0 mAh g−1 at 5C, and maintain 83.6 % of its initial capacity after 400 cycles at 1C. This work provides a promising design of O3-type cathode for sodium-ion batteries.

Cellulose-based water-in-salt ZnBr2 hydrogels with multiple functions for energy storage devices

A new simple preparation method for water-in-salt-type cellulose hydrogels filled with ZnBr2 is reported. The ZnBr2 hydrogel electrolyte can be applied to zinc-ion hybrid supercapacitors and Zn-Br interfacial batteries. The water-in-salt ZnBr2 hydrogel serves as a stable electrolyte for good electrochemical performance in zinc-ion hybrid supercapacitors without redox reactions and can participate in the charging/discharging process of the Zn‒Br interfacial battery through the redox reaction of halogen anions. The assembled zinc-ion hybrid supercapacitor exhibits a specific capacitance of 241.8 F g-1 at 0.5 A g-1. Furthermore, after a 10000-cycle-long charging/discharging test at 5 A g-1, the coulombic efficiency is found at nearly 100%. The interfacial battery reaches the highest energy efficiency of 66% at a current density of 3 mA cm-2 at 0–1.8 V and displays a good cycle life with an 88% average coulombic efficiency at 3 mA cm-2. This work expands the application of hydrogels and provides new possibilities for optimizing the high performance of electrolytes.

Analyzing the Environmental Impact of Livestock Manure Recycling Process Using Life Cycle Assessment

Objectives:This study aims to assess the environmental impact of the composting process, which constitutes 75.3% of the domestic livestock manure recycling methods, and to determine the environmental impacts of methane and nitrous oxide, the major greenhouse gases in the livestock sector, as well as ammonia, a precursor to fine particulate matter that has recently become a social issue. The analysis will focus on the categories of climate change and fine particulate matter formation to identify the most significant factors impacting the environment.Methods:This study applied the Life Cycle Assessment (LCA) methodology according to ISO 14040/14044 standards to evaluate the environmental impact of producing one bag (20kg) of livestock manure compost. The system boundary included the transportation of livestock manure and sawdust to the composting facility and the compost production process. The methodology applied for impact assessment was the ReCiPe 2016 v.1.1 Midpoint (H) method, which allows for a more global evaluation by utilizing worldwide average data.Results and Discussion:The impact assessment of livestock manure compost production revealed that producing one bag contributes 2.667 kg CO2-eq. to climate change, with electricity consumption responsible for 68.95% of emissions. Carbon dioxide (CO2) is the dominant greenhouse gas, making up 84.37% of the total. Particulate matter formation is 0.037 kg PM2.5-eq., with 91.97% resulting from emissions during the composting process. Ammonia (NH3) is the main cause of particulate matter, accounting for 92.02% of emissions.Conclusion:Based on the research, electricity consumption is the main factor affecting climate change in compost production, and ammonia is the primary cause of fine particulate matter. This study provides a case for evaluating the environmental impact of livestock manure composting and can serve as a foundational reference for developing policies and technologies to address climate change and fine particulate matter issues.

Comparative analysis of Environmental Impact of Each Building Material using Life Cycle assessment(LCA)_Focusing on Types of Construction Wood and Concrete

Objectives:The construction sector is a very important sector in achieving carbon neutrality. In modern society, construction has grown rapidly, and basic materials such as cement and concrete have contributed greatly to the development of construction. These materials emit a large amount of global warming substances during the raw material extraction and production process, causing serious environmental pollution. In order to establish a carbon reduction strategy to slow down global warming, we compared the environmental impacts of each building material and showed the current situation.Methods:The LCI DB for the construction materials used in the two-story wooden house (Building area 128.67m2, total floor area 235.73m2) located in the National Institute of Forest Science was extracted. Then, the data for LCA was processed and performed through the life cycle assessment methodology for the resources consumed from raw material collection, material production, and transportation stages. Then, based on the environmental performance labeling impact assessment method, a study was conducted on the environmental impact categories of the actual construction materials used and comparisons with other construction materials.Results and Discussion:When analyzing the environmental impact of concrete [25-21-120] and construction wood used in wooden house, the environmental impact was found to be 98.79% higher on average in the pre-manufacturing stage than in the manufacturing stage, and construction wood was confirmed to have a reduction effect of 62.21 kg CO2-eq per 1 m3 compared to concrete. Through the scenario, there was a carbon reduction effect of up to 36% when the entire area was replaced with wood. In addition, the environmental impact by major construction material was quantitatively quantified.Conclusion:When building a wooden house, reducing the amount of concrete equivalent to the amount of wood is expected to have a greenhouse gas reduction effect, so it is time to activate construction wood from the production process to the post-production stage to replace concrete. In addition, follow-up research on the development of construction technology with low environmental impact during construction should be continued. This study is expected to be used as a useful indicator for R&D and policies in the construction field in the future, as it quantitatively quantified the amount of CO2 reduction per m3 when replacing concrete with construction wood and numerically compared and analyzed six major environmental impact categories by major construction materials.

Optimization of high-entropy alloys (HEAS) for lightweight automotive components: Design, fabrication, and performance enhancement

This paper provides a comprehensive analysis of the integration and optimization of High-Entropy Alloys (HEAs) for automotive applications, emphasizing their potential to enhance vehicle performance through superior strength-to-weight ratios, thermal stability, and corrosion resistance. Drawing on methodologies from life cycle assessments (LCAs) and insights into fuel savings achieved through lightweight design, the study explores the criteria for selecting HEAs, including composition design, thermal stability, and manufacturing compatibility. It highlights the importance of advanced Computer-Aided Design (CAD) and simulation techniques in optimizing HEA components, ensuring they meet the rigorous demands of automotive applications. The paper also examines fabrication techniques such as arc melting, casting, and additive manufacturing, alongside quality control methods like Non-Destructive Testing (NDT) and mechanical performance assessments. Through case studies of HEA-based engine, structural, and safety components, the research demonstrates significant improvements in fuel efficiency, structural integrity, and safety. The discussion extends to future research directions, focusing on cost reduction, new applications in aerospace and defense, and advancements in fabrication techniques. Finally, the paper addresses sustainability considerations, including resource efficiency, recycling, and life cycle analysis, underscoring the potential of HEAs to contribute to both performance enhancement and environmental conservation in the automotive industry.

Product management: A multi-faceted approach to successful product development

Product management plays a pivotal role in ensuring the success of products across various industries, from digital applications to financial services. This paper examines the key aspects of product management, highlighting its strategic and tactical components. It also explores the role of the product manager, who must possess knowledge in marketing, design, technology, and data analysis. These areas are critical to managing the life cycle of a product and ensuring its success in a competitive market. The paper draws on real-world examples from the experience of Iuliia Nemudrova, a product manager with extensive experience in the financial sector.

Confiscated assets into public heritage

The research, as result of an agreement with the Calabria Region, aims to consolidate a corpus of investigations developed over the years by the Landscape_inProgress Laboratory, which examines the forms produced by criminal actions in urban transformation processes by studying property confiscated from the mafias. The investigation proposes a different approach to provide the opportunity to develop strategies for urban and architectural regeneration of cities, bringing out a “third public heritage” to be “re-injected” into urban and territorial policies. A matter to be “rewritten” for new life cycles. The “Impronte a Sud_WelfareLab” project, implemented in Reggio Calabria for Consorzio Macramè on a confiscated asset, is a best practice that combines management, functional, and urban processes with an aesthetic and architectural metamorphosis.

Advances in the Application of Graphene in Lithium-ion Batteries

The search for effective energy storage options has escalated due to the rising global energy demands and environmental concerns. Lithium-ion batteries (LIBs) emerge as a key technology. However, the performance of traditional LIBs still needs to be improved. Therefore, choosing new nanomaterials for the modification of LIBs has become an effective solution. Graphene, as a nanomaterial, is an excellent candidate material for modification. This paper delves into the application of graphene in enhancing the performance of LIBs. Graphene, with its superior electrical conductivity and substantial specific surface area, offers the potential to enhance the performance of both anode and cathode materials in LIBs. This can lead to significant improvements in the overall cycle life, energy density, and power density of these batteries. This work emphasizes the application of graphene in cathode and anode materials. In cathode materials, the layered structure of graphene enables lithium-ion with high theoretical capacity. Meanwhile, graphene helps improve the electron and lithium ion mobility of anode materials. Despite the promising developments, challenges such as lithium loading capacity and coulombic efficiency still remain. The continued exploration of graphene applications is expected to drive LIBs to unprecedented performance metrics. This is in line with the global quest for sustainable and efficient energy storage technologies.

Dual roles for a tick protein disulfide isomerase during the life cycle of the Lyme disease agent.

Vector-borne diseases are a leading cause of death and illness worldwide, and more than 80% of the global population live in areas at risk from at least one major vector-borne disease. In this study, we demonstrate a dual role of a specific Ixodes tick protein disulfide isomerase (PDI) in inhibiting the ability of the Lyme disease agent to colonize ticks and also in enhancing the initial stage of spirochete infection of mice. This study represents a novel conceptual advancement that a PDI from a blood-feeding vector plays important roles in the life cycle of an extracellular pathogen.

Optimizing sustainability and resilience of composite construction materials using life cycle assessment and advanced artificial intelligence techniques

Optimizing sustainability and resilience of composite construction materials using life cycle assessment and advanced artificial intelligence techniques

Poly(3, 4-Ethylenedioxythiophene) as Promising Energy Storage Materials in Zinc-Ion Batteries.

Benefiting from the advantages of high conductivity and good electrochemical stability, the conjugated conducting polymer poly (3, 4-ethylenedioxythiophene) is a promising energy storage material in zinc-ion batteries. Zinc-ion batteries have the advantages of high safety, environmental friendliness, and low cost, but suffer from unstable cathode material structure, poor electrical conductivity, and uncontrollable dendritic growth of zinc anodes. PEDOT, with its fast electrochemical response and wide potential window, is expected to make up for the shortcomings and enhance capacity and cycle life of zinc-ion batteries. Herein, in this review different polymerization methods of poly (3, 4-ethylenedioxythiophene) as well as their structure and properties are summarized; the progress in doping strategies related to the increasing conductivity and dispersivity of poly (3, 4-ethylenedioxythiophene) materials is discussed; specific applications of poly (3, 4-ethylenedioxythiophene)-based materials in anode, cathode, electrolyte, and binder of zinc-ion batteries are explored; and the representative advancements for improving the electrochemical performance of poly (3, 4-ethylenedioxythiophene) in zinc-ion batteries are emphasized. Finally, the current challenges of poly (3, 4-ethylenedioxythiophene) as promising materials in zinc-ion batteries and an insight into their future research directions are pointed out.

Human cellular restriction factors that target SARS-CoV-2 replication

Millions of people have died and a worldwide economic catastrophe has been brought on by the coronavirus disease 2019 (COVID-19) pandemic. Infections caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) may presently be treated with less than 10 antiviral drugs such as Remdesivir. The need for medical intervention due to sickness has led to unprecedented research efforts to study the biology of coronaviruses. Additionally, there is a strong likelihood that coronaviruses will cause pandemics in the future. All viruses cannot replicate optimally due to host restriction factors. Given that they are genetically more stable than viral targets and may be shared by similar viruses, these antiviral host factors provide appealing targets for antiviral treatment. The identification of antiviral host factors that are a component of human innate immunity and that prevent the completion of the SARS-CoV-2 life cycle has been made possible by the deployment of several “omics” technologies. In this review, we provide an overview of the antiviral host factors that limit the replication of SARS-CoV-2 in this, which were mostly discovered using functional genetic and interactome screening. Important cellular mechanisms for the SARS-CoV-2 life cycle are covered. Finally, we highlight host restriction factors that could be targeted by clinically approved molecules and the induction of these factors as potential antiviral therapies for COVID-19.

Sleep health across the life cycle: an unmet and neglected public health priority

Abstract The presentation will set the stage on the central role of sleep health across the life cycle. Despite the large body of evidence on the importance of poor sleep behaviors as a modifiable risk factor for several adverse health outcomes, sleep health is still an unmet and neglected issue in public health policy, especially in the European context. Sleep problems are widespread and potentially affect everyone, from childhood to adult age. In addition, sleep health disparities represent a major source of health inequities across marginalized and high-risk population subgroups, such us people from low socio-economic status, women, refugees and immigrants, shift workers, people living with physical and mental illness. There is an urgent need to promote evidence-based health promotion and public health policy to enhance sleep health both in the general population and high-risk subgroups.

Aqueous Supercapacitor with Wide-Temperature Operability and over 100,000 Cycles Enabled by Water-in-Salt Electrolyte.

Supercapacitors are crucial in renewable energy integration, satellite power systems, and rapid power delivery applications for mitigating voltage fluctuations and storing excess energy. Aqueous electrolytes offer a promising solution for low-cost and safe supercapacitors. However, they still face limitations in cycle life and wide-temperature range performance. Here, we present a symmetric supercapacitor utilizing activated carbon electrodes and a "water-in-salt" electrolyte (WiSE) based on lithium perchlorate. The WiSE electrolyte exhibits an expanded electrochemical stability window, endowing the aqueous supercapacitor with remarkable stability and long cycle life of over 100,000 cycles at 500 mA g-1 with more than 91% capacity retention. Moreover, the supercapacitor demonstrates good rate capability and wide temperature operability ranging from -20 to 80 °C. The use of high concentrations of salt in the aqueous electrolyte contributes not only to the enhancement of supercapacitor performance and cycle life but also to the temperature stability range, enabling all-season operability.

Biodiversity and plant-insect interactions in fragmented habitats: A systematic review

Abstract Fragmentation is threatening insect biodiversity and intricate interactions in various ecosystems. Ecological interactions – especially those involving plants and insects – are significantly impacted by fragmented habitats. Because of fragmentation, edge effects and reduced habitat connectivity and quality affect insect species diversity, abundance, behavior, movement, life cycles, and interactions with plants, e.g., pollination, herbivory, and seed distribution. To a large degree, ecosystem services or processes are mediated by these interactions. While fragmented habitats create suitable conditions for invasive alien plants (IAPs), such invasions modify native plant composition and herbivorous insect communities because they cause a decline or loss in insect biodiversity. A systematic review was conducted by reviewing eighty-eight (88) articles to gather evidence for fragmentation effects on insect biodiversity, insects’ behavior and adaptations, plant-insect interactions (i.e., pollination, herbivory, and seed dispersal), and its influence on IAP invasions. This review deduced that any change in insect community composition and diversity due to fragmentation can have cascading effects on ecosystem processes within habitats. It further contends that successful conservation and management of fragmented habitats requires an understanding of the intricate dynamics of plant-insect interactions. However, the long-term resilience and health of ecosystems can be guaranteed by supporting sustainable land use, improving connectivity, and restoring habitats. These actions may help stop and/or reduce the effects of fragmentation on insect biodiversity and support the livelihoods and well-being of millions of people.

Data quality assessment of aggregated LCI datasets: A case study on fossil‐based and bio‐based plastic food packaging

AbstractEnvironmental impacts resulting from plastic food packaging, made from both fossil‐based and bio‐based polymers, are increasingly analyzed in life cycle assessment (LCA) studies. However, the literature reveals significant variations in results for the same polymer within the same scope. To enhance the reliability of these assessments, data quality assessment (DQA) plays a relevant role. However, despite most of the LCA studies employing aggregated life cycle inventory (LCI) datasets, in the literature, DQA methods for aggregated processes are not available. To fill this gap, in this paper, a DQA for aggregated LCI datasets is proposed and demonstrated through its application to 101 aggregated LCI datasets, extracted from Ecoinvent and GaBi databases. The DQA method has been developed by adapting and integrating the pedigree matrix and the data quality ranking proposed by the recently published EC Plastic LCA method. The three data quality indicators (DQIs) used are technological, geographical, and time‐related representativeness. The application of this method exhibits an overall positive evaluation of the selected datasets with differences among the three DQIs. Moreover, it highlights the role of metadata structure in adequately supporting a robust DQA. Indeed, in the absence of a common framework that defines, assesses, and provides access to data quality information, transparency must be assured by the operator in the metadata interpretation and related assumptions along the DQA process. Finally, although the proposed DQA method was developed for the plastic sector, its application can be extended to LCI aggregated datasets relevant to other sectors, materials, and products.

Porcine reproductive and respiratory syndrome virus nonstructural protein 2 promotes the autophagic degradation of adaptor protein SH3KBP1 to antagonize host innate immune responses by enhancing K63-linked polyubiquitination of RIG-I.

Non-structural protein 2 (NSP2) of PRRSV is highly variable and plays crucial roles in the virus's life cycle. To elucidate the function of NSP2 during PRRSV infection, we identified SH3KBP1 as an NSP2-interacting host protein using mass spectrometry. Exogenous SH3KBP1 expression significantly inhibited PRRSV replication by enhancing IFN-I and related ISGs production. Conversely, SH3KBP1 knockdown promoted viral replication by downregulating IFN-I and ISGs levels. In vivo experiments revealed that Sh3kbp1-/- mice were more susceptible to VSV infection, exhibiting reduced serum IFN-β levels. Further investigation showed that SH3KBP1 enhances RIG-I signal transduction by increasing K63-linked polyubiquitination through interaction with the E3 ubiquitin ligase TRIM25. We also found that PRRSV infection and NSP2 overexpression induce the autophagic degradation of SH3KBP1, counteracting the host's innate immune response. A critical interaction site was identified within the third proline-rich motif in NSP2 (453PVPAPR458). Recombinant PRRSV lacking this motif displayed reduced virulence and decreased SH3KBP1 degradation. This study advances our understanding of how PRRSV interferes with the host immune response and offers valuable insights for development novel attenuated vaccines against PRRSV.

The Elderly Bias of the Spanish Welfare State (1958–2012)

Abstract The Spanish welfare state is strongly biased toward sustaining the elderly’s welfare, rather than children’s. We study the evolution of that bias since 1958 through National Transfer Accounts (NTA). NTA disentangle how people produce, consume, and save along their life cycle, and how resources move among generations through different mechanisms (families, markets, and governments). We extend the available NTA (2000–2012) to the past and show that Spanish social policies were biased toward the elderly since their early stages. The gradual increase in social expenditure and the aging of Spanish society have turned such bias into a serious challenge for the economy.