Battery Cycle Life Research Articles

Experimental assessment of high-energy high nickel-content NMC lithium-ion battery cycle life at cold temperatures

An essential element for the diffusion and environmental impact assessment of electrochemical storage systems is their lifetime. This lifetime also impacts the overall cost of the equipment in which the storage system is used. At the same time, a number of applications, e.g. electric vehicles, do not allow a temperature control of the batteries, although the performances of the latter are very strongly linked to them. The phenomena investigated, such as aging, behavior at low temperature and rapid charge for low temperature, are complex and difficult to model. Only the establishment of databases representative of the conditions of use can lead to elements of response. The exploitation of these databases by artificial intelligence tools is certainly relevant but requires a learning on data representative of the conditions of use and of the phenomena to be evaluated.The work presented in this paper is in this context and is intended to model the influence of the rapid charge at low temperature (0 °C, −10 °C, −20 °C) on the lifetime (initial capacity loss) of lithium-Ion NMC elements. The problem with data-based approaches is the large number of tests required and the development in relevant experimental designs. Faced to this challenge, a consortium of French laboratories and manufacturers has been working together since the 2000s to carry out this type of work. The paper proposes to present a test campaign and summarizes the main results to assess the service life (loss of capacity) for a fast-charging application at low temperature and position them against the manufacturer data established at 25 °C. The impact of two partial discharge processes (50 %) will also be assessed. In a last part, we show that for low temperatures, even for the nominal charge current the life time is reduced to few dozens of cycles and a mechanical destruction of the cell with no activation of the current interrupt device is achieved. This study demonstrates and quantifies the very important impact of low-temperature charging processes on the lifetime of high energy lithium-ion NMC batteries.

Li1.4Al0.4Ge0.1Ti1.5(PO4)3: A stable solid electrolyte for Li-CO2 batteries

In this study, a solid electrolyte, Li1.4Al0.4Ge0.1Ti1.5(PO4)3 (LAGTP), with a sodium superionic conductor-type crystal structure, was prepared using a facile solution-based method. LAGTP exhibited exceptional ionic conductivity (1.05 × 10−3 S cm−1) and a low activation energy (0.237 eV). The LAGTP pellet was employed as a solid-state electrolyte in a Li-CO2 battery, showcasing charge-discharge characteristics via a reversible electrochemical reaction (4Li+ + 3CO2 ↔ 2Li2CO3 + C). As-synthesized multi-walled carbon nanotubes, drop-cast on carbon cloth, were used as the cathode. The battery underwent 60 cycles with a cut-off capacity of 1000 mAh g−1 at various current densities, and a full-depth charge and discharge test was conducted at 100 mA g−1. During the charge/discharge process, the particle size of the dead lithium increased on the cathode surface, leading to the blockage of active sites for conversion. Post-cycling analyses were performed to elucidate the cathode degradation mechanism. The incorporation of LAGTP significantly enhanced battery cycle life and safety, making it a suitable candidate for use in next-generation, high-performance Li-CO2 batteries.

Quasi-Solid-State Electrolyte Induced by Metallic MoS2 for Lithium-Sulfur Batteries.

Lithium-sulfur (Li-S) batteries are a promising high-energy-density technology for next-generation energy storage but suffer from an inadequate lifespan. The poor cycle life of Li-S batteries stems from their commonly adopted catholyte-mediated operating mechanism, where the shuttling of dissolved polysulfides results in active material loss on the sulfur cathode and surface corrosion on the lithium anode. Here, we report in situ formation of a quasi-solid-state electrolyte (QSSE) on the metallic 1T phase molybdenum disulfide (MoS2) host that extends the lifetime of Li-S batteries. We find that the metallic 1T phase MoS2 host is able to initiate the ring-opening polymerization of 1,3-dioxolane (DOL), forming an integrated QSSE inside batteries. Nuclear magnetic resonance analysis reveals that the QSSE consists of ∼13% liquid DOL in a solid polymer matrix. The QSSE efficiently mediates sulfur redox reactions through dissolution-conversion chemistry while simultaneously suppressing polysulfide shuttling. Therefore, while ensuring high sulfur utilization, it avoids degradation of both electrodes, as well as the concomitant electrolyte consumption, leading to enhanced cycling stability. Under a practical lean electrolyte condition (electrolyte-to-sulfur ratio = 2 μL mg-1), Li-S pouch cell batteries with the QSSE demonstrate a capacity retention of 80.7% after 200 cycles, much superior to conventional liquid electrolyte cells that fail within 70 cycles. The QSSE also enables Li-S pouch cell batteries to operate across a wider temperature range (5 to 45 °C), together with improved safety under mechanical damage.

The aging pattern of lithium-ion batteries based on experiments at different temperatures

Abstract In this paper, we take an 18650-type LiFePO4 battery as the research object to investigate the aging mechanism of Li-ion batteries at different temperatures. The aging tests are conducted at 25°C, 35°C and 45°C. The results show that elevating the operating temperature can improve the cycle life of Li-ion batteries. The aging mechanism was analyzed by incremental capacity and electrochemical impedance spectrum analysis. The following conclusions were obtained: the aging mechanism of lithium-ion batteries mainly includes loss of lithium inventory, loss of active material, and conductivity loss, among which loss of lithium inventory and loss of active material are the main causes of Li-ion battery aging, and the contribution of conductivity loss is the smallest. Further analysis of the causes of battery aging by disassembling and testing the aging electrode sheet SEM and TEM shows that the aging of Li-ion battery is manifested by the rupture of graphite particles, the generation of SEI layer and lithium dendrite, and increasing the temperature can ease the rupture of graphite particles and the generation of lithium dendrite, thus improving the cycle life of the battery.

Analysis and Reflection on the Strategy Benchmarking of Power Battery Management in China and Europe

In 2023, the European Union (EU) enacted the Regulation on Batteries and Waste Batteries (hereinafter referred to as the New Law on Batteries), which strengthens the regulatory framework for the entire lifecycle of power batteries. This development presents both challenges and opportunities for global power battery manufacturers and operators. As a significant player in the global power battery industry chain and the world’s largest producer of electric vehicles and power batteries, China must systematically assess the impact of global battery management strategies, including the EU’s New Law on Batteries, from a lifecycle perspective. This understanding is crucial for maintaining China’s competitive edge in the global power battery market and achieving mutually beneficial outcomes in international trade negotiations. This paper constructs a strategy analysis framework based on the lifecycle approach. By summarizing the power battery management strategies of both the EU and China, it provides a comprehensive overview of strategies across different countries, highlights the key regulatory focus areas, and offers relevant strategy recommendations. The main conclusions and insights are as follows: (1) The New Law on Batteries achieves lifecycle regulation from “cradle” to “grave” and back to “cradle”. (2) China emphasizes the management of waste power batteries, with an increasingly robust strategy system at the recycling stage, yet lacks comprehensive measures for other lifecycle stages. (3) The EU has established a comprehensive lifecycle strategy management system centered on the New Law on Batteries, characterized by strong coordination and a synergistic combination of strategies across different sectors. Finally, this paper identifies three major compliance challenges posed by the New Law on Batteries, necessitating enhanced strategy development and implementation in the areas of carbon footprint management, circular economy, and digital battery passports.

Rapid Estimation of Static Capacity Based on Machine Learning: A Time-Efficient Approach

With the global surge in electric vehicle (EV) deployment, driven by enhanced environmental regulations and efforts to reduce transportation-related greenhouse gas emissions, managing the life cycle of Li-ion batteries becomes more critical than ever. A crucial step for battery reuse or recycling is the precise estimation of static capacity at retirement. Traditional methods are time-consuming, often taking several hours. To address this issue, a machine learning-based approach is introduced to estimate the static capacity of retired batteries rapidly and accurately. Partial discharge data at a 1 C rate over durations of 6, 3, and 1 min were analyzed using a machine learning algorithm that effectively handles temporally evolving data. The estimation performance of the methodology was evaluated using the mean absolute error (MAE), mean squared error (MSE), and root mean squared error (RMSE). The results showed reliable and fairly accurate estimation performance, even with data from shorter partial discharge durations. For the one-minute discharge data, the maximum RMSE was 2.525%, the minimum was 1.239%, and the average error was 1.661%. These findings indicate the successful implementation of rapidly assessing the static capacity of EV batteries with minimal error, potentially revitalizing the retired battery recycling industry.

Energy storage optimal configuration in new energy stations considering battery life cycle

Energy storage optimal configuration in new energy stations considering battery life cycle

Electrochemically Dealloying Engineering toward Integrated Monolithic Electrodes with Superior Electrochemical Li-Storage Properties.

Integrated monolithic electrodes (IMEs) free of inactive components demonstrate great potential in boosting energy-power densities and cycling life of lithium-ion batteries. However, their practical applications are significantly limited by low active substance loading (< 4.0mgcm-2 and 1.0gcm-3), complicated manufacturing process, and high fabrication cost. Herein, employing industrial Cu-Mn alloy foil as a precursor, a simple neutral salt solution-mediated electrochemical dealloying strategy is proposed to address such problems. The resultant Cu-Mn IMEs achieve not only a significantly larger active material loading due to the in situ generated Cu2O and MnOx (ca. 16.0mgcm-2 and 1.78gcm-3), simultaneously fast transport of ions and electrons due to the well-formed nanoporous structure and built-in Cu current collector, but also high structural stability due to the interconnected ligaments and suitable free space to relieve the volume expansion upon lithiation. As a result, they demonstrate remarkable performances including large specific capacities (> 5.7mAhcm-2), remarkable pseudocapacitive effect despite the battery-type constitutes, long cycling life, and good working condition in a lithium-ion full cell. This study sheds new light on the further development of IMEs, enriches the existing dealloying techniques, and builds a bridge between the two.

Unraveling the relationship between the mineralogical characteristics and lithium storage performance of natural graphite anode materials

Anode materials play critical role in cycling life of lithium-ion batteries in practical applications such as electric vehicles (EVs), portable electronic devices, and large-scale power grids. Natural graphite is one of the most successful anodes for commercial lithium-ion batteries due to its high theoretical capacity and low cost and low operating voltage. The mineralogical properties of graphite minerals have an important effect on the electrochemical performance of graphite anode, while their relationship remains ambiguous. In this work, natural graphite samples from four main graphite mining areas in China were selected as the research object, and their mineralogical characteristics were characterized by XRD, SEM, Raman, ICP, SEM, FIB, BET and other test methods. The properties of crystallinity, morphology, surface/phase defects, impurities, and specific surface area of graphite were studied. The results show that the cyclic stability of graphite is mainly affected by bulk defects and crystallinity, and the initial coulombic efficiency is mainly affected by surface defects and specific surface area. Graphite samples with appropriate surface defects, fewer volume defects, appropriate crystallinity, and small specific surface area have better electrochemical performance. It is hoped that this work should guide the manufacture and modification of the natural graphite anodes and promote its wider application in lithium-ion batteries.

Review of Electrolyte Additives for Secondary Sodium Batteries

AbstractAs the energy storage sector gains prominence, sodium batteries have garnered attention due to their affordability and the abundance of raw materials. Among the methods aimed at enhancing sodium battery performance, electrolyte additives are notably cost‐effective. Despite typically comprising no more than 5% of the components, these additives play a crucial role in improving battery cycle life and overall functionality. This review begins by analyzing the factors propelling the development of sodium batteries and the diverse roles of additives, extensively examines the roles of common functional groups (fluorine(F)‐containing, sulfonyl, sulfoxide, phosphate ester, nitrogenous, boron, silyl groups, etc.) in additives. Furthermore, it categorizes the latest functional electrolyte additives into five distinct types. Lastly, the review provides an overview of the potential for designing additives that are both sustainable and efficient. This comprehensive review aims to be a valuable resource for informing the strategic selection and enhancement of electrolyte additives, thereby facilitating future progress in the field.

Enhanced battery capacity and cycle life due to suppressed side reactions on the surface of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode materials coated with Co3(PO4)2

This study explores a strategy to mitigate capacity fading in secondary batteries, which is primarily attributed to side reactions caused by residual Li impurities (LiOH or Li2CO3) on the surface of Ni-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) layered cathode materials. By applying a 1.5 wt% Co3(PO4)2 coating, we successfully formed a thin and stable LiF cathode-electrolyte interface (CEI) layer, which resulted in decreased battery resistance and enhanced diffusion of Li+ ions within the electrolyte. This coating significantly improved the interface stability of NCM811, leading to superior battery performance. Specifically, the discharge capacity of uncoated NCM811 was 190 mA h g−1 at a charge of 4.3 V and a rate of 0.1C, whereas the 1.5Co3(PO4)2/NCM811 exhibited an increased capacity of 213 mA h g−1. Furthermore, the Co3(PO4)2 coating effectively reduced the levels of LiOH and Li2CO3 on the NCM811 surface to only 0.1 %, thereby minimizing adverse side reactions with the electrolyte salt (LiPF6), cation mixing between Ni2+ and Li+, and defects at the NCM811 interface. As a result, battery lifespan was significantly extended. This study presents a robust approach for enhancing battery stability and performance by efficiently reducing residual Li+ ions on the surface of NCM811 through strategic Co3(PO4)2 coating.

Hierarchical Ni3V2O8@N-Doped Carbon Hollow Double-Shell Microspheres for High-Performance Lithium-Ion Storage.

Transition metal oxides (TMOs) are highly dense in energy and considered as promising anode materials for a new generation of alkaline ion batteries. However, their electrode structure is disrupted due to significant volume changes during charging and discharging, resulting in the short cycle life of batteries. In this paper, the hierarchical Ni3V2O8@N-doped carbon (Ni3V2O8@NC) hollow double-shell microspheres were prepared and used as electrode materials for lithium-ion batteries (LIBs). The utilization efficiency and ion transfer rate of Ni3V2O8 were improved by the hollow microsphere structure formed through nanoparticle self-assembly. Furthermore, the uniform N-doped carbon layer not only enhanced the structural stability of Ni3V2O8, but also improved the overall electrical conductivity of the composite. The Ni3V2O8@NC electrode has an initial discharge capacity of up to 1167.3 mAh g-1 at a current density of 0.3 A g-1, a reversible capacity of up to 726.5 mAh g-1 after 200 cycles, and still has a capacity of 567.6 mAh g-1 after 500 cycles at a current density of 1 A g-1, indicating that the material has good cycle stability and high-rate capability. This work presents new findings on the design and fabrication of complex porous double-shell nanostructures.

A Case Study of a Tiny Machine Learning Application for Battery State-of-Charge Estimation

Growing battery use in energy storage and automotive industries demands advanced Battery Management Systems (BMSs) to estimate key parameters like the State of Charge (SoC) which are not directly measurable using standard sensors. Consequently, various model-based and data-driven approaches have been developed for their estimation. Among these, the latter are often favored due to their high accuracy, low energy consumption, and ease of implementation on the cloud or Internet of Things (IoT) devices. This research focuses on creating small, efficient data-driven SoC estimation models for integration into IoT devices, specifically the Infineon Cypress CY8CPROTO-062S3-4343W. The development process involved training a compact Convolutional Neural Network (CNN) and an Artificial Neural Network (ANN) offline using a comprehensive dataset obtained from five different batteries. Before deployment on the target device, model quantization was performed using Infineon’s ModusToolBox Machine Learning (MTB-ML) configurator 2.0 software. The tests show satisfactory results for both chosen models with a good accuracy achieved, especially in the early stages of the battery lifecycle. In terms of the computational burden, the ANN has a clear advantage over the more complex CNN model.

Comparative analysis of electrochemical behaviors of lithium-ion batteries using the dual potential MSMD battery models: case studies on various thermal conditions

The high energy density and long cycle life of lithium-ion batteries make them a preferred option for electric vehicles. The efficiency and life span of lithium-ion batteries are particularly sensitive to temperature; thus, it becomes essential to maintain an ideal temperature range. In this context, we concentrated on two widely used electro-chemistry (Equivalent Circuit Model and NTGK) models of a single cell of a dual potential MSMD Lithium-ion Battery while taking into account two significant methods of heat transfer under varying C-rates (0.25C, 1C, 2C, and 5C). We investigated the highest temperatures that two e-chemistry models could reach in varying ambient temperatures (typical summer, winter, and room temperature). The maximum temperature-raising tendency in the ECM due to natural convection is greater than the maximum temperature-raising tendency due to radiation regardless of the environmental temperatures and various C rates (0.25C, 1C, and 2C). However, the trend line of the maximum temperature rise is different in the NTGK model, where the maximum temperature rise due to radiation is greater than the maximum temperature rise due to convection for 0.25C, 1C, and 2C rates in -5°C and 40°C environmental temperatures. In the NTGK model, at 0.25C, 1C, and 2C rates for winter and summer temperatures, the maximum temperature rise owing to radiation is larger than that due to convection. The NTGK model, however, produced somewhat superior findings for the radiation mode of heat transfer at ambient temperature. Therefore, it can be said that convection is a better thermal condition than natural convection in the NTGK model.

Sustainable Prelithiation Strategy: Enhancing Energy Density and Lifespan with Ultrathin Li‐Mg‐Al Alloy Foil

AbstractPrelithiation is a well‐established strategy for enhancing battery energy density. However, traditional prelithiation approaches have primarily addressed compensating for the initial active lithium loss (ALL) while overlooking the ALL during extended cycling. In response, a novel method is introduced by increasing the prelithiation degree and pre‐storing stable LiCx within the anode. This innovation facilitates sustainable lithium replenishment, resulting in a significant improvement in battery cycle life and energy density. Moreover, challenges associated with using pure Li foils to realize this strategy in contact prelithiation are revealed, such as difficulties in thinning to less than 5 µm, and the loss of the electronic pathway during prelithiation, resulting in low lithium utilization rates and numerous residues. Additionally, the significantly accelerated capacity fading caused by these residues, typically emerging after hundreds of cycles, has been overlooked. To overcome these challenges, an ultrathin Li‐Mg‐Al alloy foil is developed with significantly improved mechanical properties and delithiation behavior. During prelithiation, the 96Li2Mg2Al alloy maintains a complete film structure with numerous micropores, avoiding randomly distributed debris. This structure ensures high utilization, unimpeded electronic pathways, and efficient electrolyte filtration. By employing a 5‐µm 96Li2Mg2Al foil for sustainable prelithiation, a substantial improvement in energy density is achieved and tripled the battery's lifespan.

Recent Advances in Catalyst Design and Performance Optimization of Nanostructured Cathode Materials in Zinc-Air Batteries.

This review focuses on the advanced design and optimization of nanostructured zinc-air batteries (ZABs), with the aim of boosting their energy storage and conversion capabilities. The findings show that ZABs favor porous nanostructures owing to their large surface area, and this enhances the battery capacity, catalytic activity, and life cycle. In addition, the nanomaterials improve the electrical conductivity, ion transport, and overall battery stability, which crucially reduces dendrite growth on the zinc anodes and improves cycle life and energy efficiency. To obtain a superior performance, the importance of controlling the operational conditions and using custom nanostructural designs, optimal electrode materials, and carefully adjusted electrolytes is highlighted. In conclusion, porous nanostructures and nanoscale materials significantly boost the energy density, longevity, and efficiency of Zn-air batteries. It is suggested that future research should focus on the fundamental design principles of these materials to further enhance the battery performance and drive sustainable energy solutions.

Triazine and hydroxyl covalent organic framework modified separator for Zn-ion fast and Selective transport and dendrite-free deposition in zinc–iodine battery

Aqueous zinc–iodine (Zn–I) batteries show a great development potential in the field of energy storage due to their advantages of low cost, high safety and ecological friendliness. However, Zn dendrite growth and shuttle effect of polyiodide seriously aggravate the self-discharge behavior and thus decrease the cycle life of batteries. Therefore, controlling the diffusion of zinc ion and inhibiting soluble polyiodide in the separator are the most effective strategy to extend the lifespan of batteries. Herein, we design and prepare a multifunctional Janus separator composed of a covalent organic framework (COF) layer, a commercial glass fiber (GF) substrate and a graphene (Gr) layer to achieve durable Zn–I batteries. The COF layer features abundant polar groups and uniform open-channel mesopores enabling homogeneous Zn2+ flux and simultaneously inhibiting polyiodide species migration. The highly conductive Gr layer can not only load iodide but also effectively activate the redox kinetics of iodine species. The full cell assembled with the TTA-DHTPA-COF@GF@Gr Janus separator demonstrated a recorded energy density of up to 6.4 mA h·cm−2 at a high current density of 20 mA cm−2 in aqueous Zn–I batteries. The design of the multifunctional Janus separator provides a new insight into separator engineering for durable Zn-ion batteries.

World experience of legislative regulation for Lithium-ion electric vehicle batteries considering their second-life application in power sector

Understanding and incorporating global regulatory experiences and standards related to battery management is of greatest importance, particularly when considering the rapid evolution of the electric vehicle (EV) market and its implications for energy storage and sustainability. This is especially relevant for Ukraine, where the burgeoning secondary market for EVs and a keen interest in renewable energy sources underscore the need for proactive policy-making and standardization to address the challenges of battery second life and recycling. This article delves into the role of Electric Vehicle Lithium-Ion batteries within the ambit of the circular economy, underscoring the significance of legislative frameworks across the globe with a particular focus on European initiatives in light of Ukraine's EU integration ambitions. This encompasses extending battery life through recycling and repurposing, thereby ensuring both economic viability and minimal environmental footprint. The narrative outlines the varied legislative landscapes internationally, noting the differences in strategies from Asia's technological and safety emphasis to Europe's robust regulatory directives aimed at battery lifecycle management. In Europe, the drive towards sustainable battery utilization is marked by comprehensive policies like the EU Battery Directive and the emerging Regulation on Batteries and Waste Batteries, which set forth ambitious recycling targets and introduce innovative concepts like the battery passport. Drawing from this global overview, the article posits a set of recommendations for Ukraine, suggesting the development of extensive battery management legislation, adoption of European standards to smooth the path towards EU membership, investment in recycling infrastructures, fostering of public-private partnerships, and public awareness initiatives. These recommendations are designed to elevate Ukraine's position in the sustainability, promoting environmental stewardship and economic competitiveness. The growing importance of secondary lithium-ion batteries for electric vehicles in supporting and harmonizing renewable energy sources is emphasized, and accordingly, the need for adequate legislation and standardization to support a closed-loop economy. Keywords: Lithium-Ion Batteries, Second-Life Application, EV Battery Life Cycle, Circular Economy, Repurpose, Reuse, Recycling, Standards, Regulation, Legislation.

The synergy mechanism of CsSnI3 and LiTFSI enhancing the electrochemical performance of PEO‐based solid‐state batteries

AbstractLithium metal solid‐state battery is the first choice of batteries for electromobiles and consumer electronic products because of the specific capacity of 3860 mAh g−1 and high electrochemical potential (−3.04 V) of Li metal. Flexible polymer solid electrolytes have become the optimal solution to produce high energy density lithium batteries with arbitrary size and shape. In this work, we introduce a halide perovskite, CsSnI3, into the polyethylene oxide/lithium bis‐(trifluoromethanesuphone)imide (PEO–LiTFSI) polymer matrix. The CsSnI3 could form a LixSn alloy with Li, leading to homogenization of the electric field and Li+‐flux at the interface, Sn atom also bonds with the TFSI− anion to provide more dissociated Li+. Besides that, the I atom could interact with Li to form an electronic insulation with a strong blocking effect on electron tunneling. As a proof of concept, the synergy mechanism of the PEO–LiTFSI–CsSnI3 electrolyte improves the stable cycle life of the symmetric battery to more than 500 h, and the Li+ conductivity raised to 6.1 × 10−4 S cm−1 at 60°C. The application of the “zwitter ions analog” halide perovskite in PEO–LiTFSI provides a new choice among various methods to improve the electrochemical performance of polymer solid‐state batteries.

Electroanalytical Exploration of Li Loss at the Solid Electrolyte-Anode Interface in Anode-Free Batteries with Polymer Electrolytes

Li loss during cycling at the solid electrolyte∣anode interface strongly determines the cycle life of anode-free solid-state batteries (SSBs). Here, this loss is probed electroanalytically for polymer electrolyte (PE)-based SSBs in anode-free coin cells with practical pressures. A wide range of parameters expected to impact the measured average coulombic efficiency (CE) were explored to estimate the expected range of performance. These factors include PE type, cycling profiles, current collector type, and the presence of a thin Li seed layer. Low CE values in the ∼50%–85% range are observed for all electrolytes and test conditions. Other than the electrolyte type, a strong dependence of the CE on the electrochemical cycling profile and the type of metallic current collector is observed. Compared to the anode-free setup, the presence of a thin (5 μm) Li seed layer did not improve the average CE for two out of three PEs, suggesting its presence to be a weak contributor in minimizing the Li loss. This work provides baseline data on the Li losses in low-pressure anode-free configuration cells with PEs.