Battery Cycle Life Research Articles

Difluorobenzene as an Antisolvent for Fluorinated Electrolyte to Achieve Unparalleled Cycle Life of Lithium Metal Battery.

Electrolytes play a crucial role in enhancing the cycling stability and overall lifespan of lithium metal batteries (LMBs). However, conventional electrolytes achieve ununiform and low ionic conductivity solid electrolyte interphase (SEI), leading to uncontrolled lithium dendrite growth and dead lithium formation, rendering them inadequate for meeting the performance of high energy density LMBs. Herein, a 1,2-difluorobenzene (1,2-dFBn) is introduced as antisolvent in fluorinated electrolyte which is composed of fluoroethylene carbonate (FEC) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). The low energy level of the lowest unoccupied molecular orbital (LUMO) and the high fluorine-donating ability of 1,2-dFBn jointly modify the solvation structure and electrode/electrolyte interphase chemistry. As a result, this simple electrolyte formulation enables the Li||Li symmetric cells exhibit remarkable stability, enduring 700 h of continuous cycling under 2 mA cm-2 and Li||Cu cell achieve an impressive average Coulombic efficiency (CE) of 99.76%. Moreover, the full cell assembled with electrochemically deposited lithium capacity of 5 mAh cm-2 and LiFePO4 (LFP) as cathode achieves exceptional performance, maintaining a discharge specific capacity of 134.9 mAh g-1 while retaining 95.1% capacity at 2C after 1000 cycles. This study offers a plausible ratio design for fluorinated electrolyte, which achieving high CE and long-life LMBs.

Review and prospect on Metal-organic framework-based Separators for Lithium–Sulfur Battery

With the continuous advancement of technology, wearable smart devices and electric vehicles (EVs) have become an integral part of our daily lives. The increasing demand for energy from these devices and vehicles has driven the pursuit of high-performance rechargeable battery technology. In particular, the widespread adoption of electric vehicles has set higher standards for the energy density and cycle life of batteries. However, the energy density of the widely used lithium-ion batteries is currently limited by the theoretical capacity of commercial cathode materials, and there are certain challenges in terms of safety and cost-effectiveness. Therefore, the development of a new generation of rechargeable batteries with higher energy density, better safety, and more economical cost is particularly urgent. Lithium-sulfur batteries, due to their high energy density, high economic benefits, and high environmental friendliness, are considered to be one of the most promising successors to the widely used lithium-ion batteries. However, in practical applications, the electrochemical performance of lithium-sulfur batteries still needs to be improved. In particular, the poor conductivity of sulfur/lithium and the shuttle effect of polysulfides make the cycle life of the battery less than ideal, and lithium-sulfur batteries (LSB) are still far from achieving large-scale commercialization. The separator used in lithium-sulfur batteries plays a crucial role in its cycle performance and safety. The current commercial separator lacks the ability to effectively regulate the shuttle of polysulfides and is prone to thermal runaway at high temperatures. Therefore, to improve these issues, various functional materials have been used to modify the separator. Among them, as a new type of porous coordination polymer, metal organic frameworks (MOFs) have become a promising material for modifying separators due to their large specific surface area and highly ordered tunable nano-holes.At the same time, their rich inorganic nodes and designable organic ligands allow for the customization of pore chemistry at the molecular level, which can interact with the electroactive components in lithium-sulfur batteries in a tunable manner. This article reviews the reaction mechanism of lithium-sulfur batteries and the structural advantages of MOFs in terms of pore chemistry and morphology and briefly introduces the research progress of MOF-based interfacial layers for the functionalization of LSB separators in recent years. It elaborates on the mechanisms by which various modified separators improve electrochemical performance and provides a prospect for the development prospects of the field.

Nanotechnology in Lithium-Sulfur Batteries: Addressing the Challenges in Battery Cycle Life and Safety

Lithium-sulfur (Li-S) batteries, with their high energy density and affordable material prices, are a viable alternative to ordinary lithium-ion batteries, especially for electric cars. Their actual application is limited by challenges such as substantial volume expansion, low electrical conductivity, and the polysulfide shuttle effect, despite their advantages. This research investigates how incorporating nanomaterials into Li-S battery cathodes, anodes, and electrolytes might improve battery performance and analyzes the potential of nanotechnology to address these problems. The application of metal oxides, graphene oxide, and carbon nanofibers to improve the stability and conductivity of sulfur cathodes is covered. Additionally, it examines anode protection strategies using nanocoating and protective layers to inhibit dendrite growth and improve safety. The incorporation of nanoparticles in electrolytes to improve ionic conductivity and reduce side reactions is also analyzed. Despite the progress, challenges such as the polysulfide shuttle effect and volume changes remain. The paper concludes with recommendations for future research to develop commercially viable Li-S batteries with higher capacity, longer lifespan, and improved safety.

Porous V2CTx MXene as a High Stability Zinc Anode Protective Coating.

Aqueous Zn batteries exhibit significant research potential owing to their environmental friendliness and high energy density. Nevertheless, the formation of dendrites on the zinc anode and the sluggish diffusion kinetics of zinc ions adversely affect the cycle life of zinc ion batteries. In this study, we employ porous V2CTx (MVMX) as a protective layer for the zinc anode. The uniform porous structure of MVMX promotes active site exposure and facilitates the transport of zinc ions. Remarkably, the Zn@Ti half-cell demonstrated an average CE of 99.7% in 1500 cycles. Furthermore, the Zn-Zn symmetric battery exhibited stable cycling for 1600 h at current densities of 5 mA cm-2 and 1 mAh cm-2. Additionally, the MVMX@Zn||V2O5 full cell exhibited a capacity of 198 mAh g-1 and retained a capacity of 124.75 mAh g-1 after 5000 cycles at 1 A g-1, demonstrating the potential of employing alternative MXenes for fabricating stable zinc anodes.

Progress of silicon and graphene composites in lithium-ion battery anodes

As society progresses, the need for high-power, long-life energy supply devices gradually increases. Lithium-ion batteries (LIBs) with large energy reserves and high power have recently become the preferred choice. The anode of LIBs plays a crucial role in battery performance, safety, and cycle life. Typically, graphite materials are used for LIBs anodes. Still, they have drawbacks such as low first-time Coulombic efficiency, capacity degradation, safety issues, short cycle life, insufficient gram capacity, and purity and side reactions, which limit the application of LIBs. Therefore, new harmful electrode materials are in demand. Graphene and silicon are both environmentally friendly and sustainable materials. They both have the advantages of high theoretical capacity and high energy density, which are critical materials for developing LIBs. Combining the two can exert a synergistic effect and jointly improve the cycle stability of the battery. In this paper, we review the preparation methods of graphene and silicon composites in recent years, including mechanical ball milling and hydrothermal and thermal reduction methods. In addition, graphene and silicon composites have been explored for LIBs applications.

Sulfide/Polymer Composite Solid‐State Electrolytes for All‐Solid‐State Lithium Batteries

AbstractThis review introduces solid electrolytes based on sulfide/polymer composites which are used in all‐solid‐state lithium batteries, describing the use of polymers as plasticizer, the lithium‐ion conductive channel, the preparation methods of solid‐state electrolytes (SSEs), including dry methods and wet methods with their advantages and disadvantages. In addition, the physicochemical stability of sulfide/polymer composite based solid‐state electrolytes is analyzed. The sulfide/polymer composite based solid‐state electrolyte can be utilized in lithium metal or lithium sulfur batteries. However, there are still many problems left to be solved in practical applications of these solid‐state electrolytes. In this review, several solutions are explored. Firstly, the ultra‐long life cycle of batteries can be achieved by thinning the composite electrolyte. Secondly, when sulfur is applied as the positive electrode, the thinning electrolyte can reduce polarization and other problems. Finally, an integrated battery is employed to reduce the interface impedance. By addressing these aspects, the review aims to provide valuable insights into the future development of high‐performance solid‐state electrolytes in lithium battery technology.

Effect of plant extract additives on the parasitic reaction in alkaline Zn-air batteries

The battery's high energy density, economical price, and ecological sustainability of the Zn-air battery make it a bright future battery technology. However, parasitic reactions, which can diminish the battery's life cycle and efficacy, are the key challenges for potential development of Zn-air batteries. Glycyrrhiza glabra roots extract (GGRE) has been investigated as an alternative hydrogen gas evolution and corrosion inhibitor for Zn-air batteries in order to mitigate the parasitic reaction. The results obtained reveal that the inhibition capacity of the GGRE extract increases with concentration and reaches its highest level (75.6%) around 350 mg L-1 of GGRE extract. GGRE extract is a mixed type inhibitor with a predominately cathodic effect based on the polarization data. The GGRE extract adsorption on the Zn surface complies with Freundlich isotherm. In comparison to the blank Zn-KOH (354 mAh g-1), the battery containing 350 mg L-1 GGRE extract has the highest discharge capacity (533 mAh g-1) and the best cyclability (92.9% retention after 500 cycles). Overall, GGRE extract can significantly optimize the performance of Zn-air batteries.

Bifunctional electrolyte additive enabling long cycle life of vanadium-based cathode aqueous zinc ion batteries

Aqueous zinc ion batteries have received extensive attention due to their many advantages, but they still face problems such as dendrite growth and interface reaction of Zn anode and collapse of vanadium-based cathode structure. Here, a bifunctional electrolyte additive Methionine (MET) is proposed, which exhibits a unique role in inducing uniform deposition of zinc anode and inhibiting the failure of vanadium-based cathode materials. MET affects the solvated structure of the electrolyte to inhibit water activity and reduce HER and other related parasitic reactions. At the same time, it regulates the flux of Zn2+, improves the deposition kinetics of Zn2+ on the zinc anode side, and induces the preferential growth of the Zn (1 0 1) crystal plane to promote ordered Zn deposition. In particular, MET can in-situ generate a CEI containing such as ZnF2 on the surface of the vanadium-based cathode to inhibit the failure of the vanadium-based cathode, while adjusting the surface electronic state and Zn2+ diffusion behavior, and reducing the structural damage of the vanadium-based cathode caused by the Zn2+ intercalation process by inducing a strengthened surface pseudocapacitive reaction. Compared with the bare electrolyte, the capacity retention rate of the K2V8O21||Zn full-cell with OTF-M50 electrolyte increased from 10.2 % to 99.8 % after 800 cycles at a low current density of 1 A/g. Therefore, MET exhibits considerable application prospects as a bifunctional additive that can improve the stability of vanadium-based cathode and promote the stable deposition of zinc anode.

Poly(3, 4-Ethylenedioxythiophene) as Promising Energy Storage Materials in Zinc-Ion Batteries.

Benefiting from the advantages of high conductivity and good electrochemical stability, the conjugated conducting polymer poly (3, 4-ethylenedioxythiophene) is a promising energy storage material in zinc-ion batteries. Zinc-ion batteries have the advantages of high safety, environmental friendliness, and low cost, but suffer from unstable cathode material structure, poor electrical conductivity, and uncontrollable dendritic growth of zinc anodes. PEDOT, with its fast electrochemical response and wide potential window, is expected to make up for the shortcomings and enhance capacity and cycle life of zinc-ion batteries. Herein, in this review different polymerization methods of poly (3, 4-ethylenedioxythiophene) as well as their structure and properties are summarized; the progress in doping strategies related to the increasing conductivity and dispersivity of poly (3, 4-ethylenedioxythiophene) materials is discussed; specific applications of poly (3, 4-ethylenedioxythiophene)-based materials in anode, cathode, electrolyte, and binder of zinc-ion batteries are explored; and the representative advancements for improving the electrochemical performance of poly (3, 4-ethylenedioxythiophene) in zinc-ion batteries are emphasized. Finally, the current challenges of poly (3, 4-ethylenedioxythiophene) as promising materials in zinc-ion batteries and an insight into their future research directions are pointed out.

AI-Augmented Chemical Engineering Models for Predictive Battery Maintenance in IoT Applications

This research presents a cutting-edge approach that combines chemical engineering principles with artificial intelligence (AI) to enhance battery maintenance in Internet of Things (IoT) applications. The study develops predictive maintenance models capable of accurately forecasting battery degradation, thereby optimizing usage patterns and extending battery life. By integrating electrochemical data with AI-driven predictive analytics, the project enables real-time monitoring of battery health, achieving over 90% accuracy in anticipating maintenance needs, which reduces unplanned downtime and lowers operational costs. Employing machine learning frameworks, data analysis tools, and chemical engineering simulation software, the focus is on lithium-ion and solid-state batteries, commonly used in IoT networks across sectors such as smart cities, agriculture, and healthcare. Key results include a 20−30% increase in battery lifespan and a 15% improvement in energy efficiency, significantly reducing electronic waste and environmental footprint. This interdisciplinary approach provides a foundation for sustainable battery technology in IoT technology, paving the way for future advancements in AI-augmented predictive maintenance and chemical engineering models for next-generation applications. The integration of AI with chemical engineering principles allows for the development of models that adapt to the unique electrochemical behavior of different battery types, such as lithium-ion and solid-state batteries. By analyzing lifecycle data and device usage patterns, predictive models can account for variables that influence battery performance over time, including temperature fluctuations and charging cycles. This project utilizes neural networks and reinforcement learning algorithms to train models capable of learning from historical data, enhancing their predictive capabilities. A significant aspect of this research involves the preprocessing of battery lifecycle data to ensure high data quality, which is critical for accurate model training and validation.

Advancing sustainable development: Introducing a novel fast charging technique for Li-ion batteries with supercapacitor integration

Li-ion batteries play a vital role in today's world for their wide range of applications in electrical vehicles, mobile phones, electronic gadgets etc. Applying fast charging to Li-ion batteries is crucial for increasing consumer convenience, productivity, energy efficiency, and stimulating technical innovation across various industries. With the wide-spread usage of Li-ion batteries, it is critical to consider the environmental degradation caused by their decomposition. Therefore, solutions for fast charging Li-ion batteries must not only be reliable but also sustainable to meet future demands. This paper presents a novel Li-ion battery fast charging technology with an integrated supercapacitor and battery, for quick charging without shortening the battery's life cycle. The advantage of the proposed charger is that the supercapacitor assists the Li-ion battery while charging, thereby fast charging and improving the efficiency and longevity of the battery. The utilization of supercapacitor-assisted charging diminishes the burden on lithium-ion batteries, enhancing their lifespan and consequently reducing environmental harm. To validate the performance of the proposed charging technology, an experimental investigation has been carried out. The obtained results through the investigation show the increased performance of 82 % efficiency and 40 % longevity more than the conventional method. The proposed supercapacitor-based fast charging technique is not only efficient but also sustainable and reliable.

Low‐Solvent‐Coordination Solvation Structure for Lithium‐Metal Batteries via Electric Dipole‐Dipole Interaction

AbstractUnveiling inherent interactions among solvents, Li+ ions, and anions are crucial in dictating solvation‐desolvation kinetics at the electrode/electrolyte interface. Developing an electrolyte with a low ion‐transport barrier and minimal solvent coordination in its interfacial solvation structure is essential for forming an anion‐derived solid‐electrolyte interface, a key component for high‐performance Li‐metal batteries. In this study, we harness electric dipole‐dipole synergistic interactions to formulate an electrolyte with significantly reduced interfacial solvent coordination. Operando characterization and theoretical analysis reveal that 2‐fluoropyridine (FPy) with high dipole preferentially adsorbs onto the Li metal surface. The adsorbed FPy molecule squeezes succinonitrile in the primary solvation sheath through steric hindrance, leading to the formation of an inorganic‐rich interphase. Consequently, the introduction of FPy enhances the reversible capacity of the LiCoO2||Li cell, which maintains a capacity of 143 mAh g−1 after 500 cycles at a 1 C rate. Moreover, the cycle life of LiCoO2 batteries with a limited supply of lithium extends from 120 cycles to over 200 cycles. These findings offer a strategy that can be applied broadly to design interfacial solvation structures for various metal‐ion/metal‐based batteries.

BATERIAS DE CARROS ELÉTRICOS: MANUTENÇÕES E DESCARTES

The rapid growth in the adoption of electric vehicles brings to light challenges related to the maintenance and disposal of batteries, which are essential components for the operation of these vehicles. The central issue addressed is the sustainability of the battery life cycle, considering both the efficiency of their maintenance and the environmental impacts resulting from inadequate disposal. The context involves the transition to a greener economy and the demands for clean technologies, which makes it essential to discuss appropriate practices to extend the useful life of batteries and ensure their safe disposal. The main objective of this study is to analyze the maintenance practices of electric car batteries and disposal strategies, focusing on minimizing environmental impacts and optimizing the life cycle of components. The research seeks to identify effective methods to extend the useful life of batteries, in addition to evaluating existing recycling policies and processes. The methodology used includes a literature review of current battery maintenance and disposal practices, in addition to the analysis of case studies that exemplify different approaches and results in international contexts. The research also incorporates interviews with industry experts, aiming to obtain a comprehensive and updated view of best practices and challenges faced. This work contributes to the discussion on sustainability in the automotive sector and to the formulation of more efficient policies for the management of technological waste.

Recent Progress in Liquid Electrolytes for High‐Energy Lithium–Metal Batteries: From Molecular Engineering to Applications

AbstractLithium–metal batteries (LMBs) have garnered significant interests for their promising high gravimetric energy density (Eg) ∼ 750 Wh kg−1. However, the practical application of the LMBs is plagued by the high reactivity and large volume change during charging–discharging of the lithium–metal anode (LMA), seriously deteriorating the battery safety and cycle life. Great efforts have been devoted to tailoring the electrolytes to favor the Li–metal electroplating by uniformizing the deposition morphology and by suppressing the side reactions between electrolytes and LMA. The aggressive chemistries of both the LMA and its high‐voltage counterpart give new electrolyte components more opportunities, especially designing via molecular engineering. Here, a comprehensive and in‐depth overview of the scientific challenges, fundamental mechanisms, and particularly historical strategies of designing new molecules for electrolyte components including solvents, salts, and additives. Their important roles in tuning the Li+ solvation structure, interface composition, decomposition pathways, and the resultant electrochemical performance of LMBs are also presented. Finally, novel insights and promising research directions from the practical application viewpoints are proposed for future electrolyte designs for high‐voltage LMBs.

An unsaturated chain carbonate additive contributing to high-performance LiFePO4//graphite battery at broad temperature range

Vinylene carbonate (VC) electrolyte additive can extend the cycle life of lithium-ion batteries (LIBs) by the polymerization of CC bonds and ring opening at the electrode/electrolyte interface. However, the interface film produced by VC exhibits extremely high impedance at low temperatures (LT), leading to a rapid deterioration in battery performance. In this work, butyl 2-acetylene 1, 4-diethoxycarbonate (BAEC) additive, a chain carbonate with CC bond, is designed for the first time to overcome the fatal low-temperature defect of VC. The higher unsaturation CC bond endows BAEC with an elevated REDOX activity for film forming. When BAEC is collaborated with VC which has better cathodic compatibility, the LiFePO4//Graphite pouch cells demonstrate an ultrahigh capacity retention of 105.8 % after 300 cycles at 0 °C and 101.2 % after 130 cycles at −10 °C. In contrast, the VC system fails only after 10 cycles at 0 °C and cannot achieve normal charge and discharge at −10 °C. Moreover, BAEC + VC system exhibits an enhanced capacity retention of 85.7 % at the 500th cycle at 45 °C. Deep exploration reveals that in addition to the intrinsic factors of the higher unsaturation which are the guarantee of reactivity and uniformity for film generation, BAEC can regulate the initial Li+ solvation structure through steric hindrance and interaction with the solvent which contributes to preeminent interface film stability and conductivity. This work proves that unsaturated chain carbonates are worthwhile additives which can promote the development of LIBs with strong environmental adaptability.

Analysis of Impact of Control Strategies on Integrated Electric Propulsion System Performance During Icebreaking Process

Developing an efficient power system is an important way for icebreakers to respond to high maneuverability and strong fluctuation loads under icebreaking conditions. The performance of power systems under short-period, regularly fluctuating load-sea conditions has been intensively studied. However, the performance of the power system in the face of a long-period, stochastic multi-frequency fluctuation icebreaking process has not been fully explored, especially the parameter uncertainty and battery cycle life. In this study, an integrated electric propulsion system with an optimal control strategy is suggested for improving the power system’s dynamic performance and battery cycle life. First, an energy flow model with a diesel–electric unit as the main body and coupled energy storage system/hybrid energy storage system has been constructed. A comparative analysis of rule-based and optimization-based energy management strategies has been performed, and an optimized strategy with dynamic programming as global regulation at the upper level and model predictive control at the lower level is suggested to integrate the slow and fast dynamic powers and achieve adaptability to strong fluctuation loads. In this control strategy, the uncertainties of energy storage system/hybrid energy storage system parameters have been introduced to eliminate their impact on the system performance. Then, the icebreaking process with multi-frequency fluctuation has been simulated, and the hybrid energy storage system with battery and supercapacitor is recommended to reach multi-objective with the lowest power fluctuation of diesel–electric unit, highest efficiency, and the minimum battery degradation. Finally, the fuel oil consumption and emissions of the hybrid energy storage system have been discussed, and the optimized strategy can save fuel oil by up to 5.33% and reduce the CO2 emission by 22% during the icebreaking process, exhibiting great potential in the environmental friendliness and significant advantages in terms of low fuel oil consumption.

Effect of Battery Level During Successive Charging Cycles on the Performance of Certified and Low-cost Uncertified Light-curing Units Available on E-commerce.

To evaluate the influence of battery level on power (mW), emission spectrum (mW/cm2/ nm), and light distribution on the active tip (mW/ cm2) of certified (FDA/ANVISA) and low-cost uncertified light-curing units (LCUs) purchased through e-commerce. Seven LCUs, three certified: VALO Grand (Ultradent); Radii Xpert (SDI); and LED.B (Woodpecker); and four uncertified: 1 Sec; BS 300; LED curing light; and VAFU (VRN, AZDENT), were used. The LCUs were evaluated by calculating the power (mW) after each sequential five exposure cycles of 20 seconds and the emission spectrum (mW/cm2/nm) in the initial and final cycles, using an integrating sphere during three battery charging cycles. Beam profiling was used to check the light distribution on the LCU tip after every 50 exposure cycles until the battery fully discharged. Data were analyzed by linear regression between power and the number of exposure times (R2). The certified LCUs VALO Grand (R2=0.005), LED.B (R2=0.02), and Radii Xpert (R2=0.09) and the uncertified LCU VAFU (R2=0.002) had no significant power reduction during the three battery charging cycles. The uncertified LCUs BS 300 (R2=0.87), 1 Sec (R2=0.60), and LED curing light (R2=0.83) showed significant power reduction, decreasing the emission spectrum (mW/cm2/nm) at the end of the battery charging cycle. The light distribution on the active tip across the level battery was modified significantly with successive exposure times. The certified LCUs (VALO Grand, Radii Xpert, and LED.B) and uncertified LCU (VAFU), maintained power, emission spectrum, and light distributions during the tested battery life cycles. Low-cost certified LCU LED.B exhibited inhomogeneous light concentrated at the center of the tip. Low-cost uncertified LCUs-BS 300, 1 Sec, and LED curing light-had significant power reductions during the battery cycles and increased inhomogeneous light distribution along the successive exposure times.

Transition from Electric Vehicles to Energy Storage: Review on Targeted Lithium-Ion Battery Diagnostics

This paper examines the transition of lithium-ion batteries from electric vehicles (EVs) to energy storage systems (ESSs), with a focus on diagnosing their state of health (SOH) to ensure efficient and safe repurposing. It compares direct methods, model-based diagnostics, and data-driven techniques, evaluating their strengths and limitations for both EV and ESS applications. This study underscores the necessity of accurate SOH diagnostics to maximize battery reuse, promoting sustainability and circular economy objectives. By providing a comprehensive overview of the battery lifecycle—from manufacturing to recycling—this research offers strategies for effective lifecycle management and cost-effective, environmentally sustainable secondary battery applications. Key findings highlight the potential of second-life EV batteries in ESSs. The integration of the considered diagnostic methods was shown to extend battery lifespan by up to 30%, reduce waste, and optimize resource efficiency, which is crucial for achieving circular economy objectives. This paper’s insights are crucial for advancing sustainable energy systems and informing future research on improving diagnostic methods for evolving battery technologies.

In Situ Formation of Stable Dual-Layer Solid Electrolyte Interphase for Enhanced Stability and Cycle Life in All-Solid-State Lithium Metal Batteries.

All-solid-state lithium metal batteries have emerged as a promising solution to overcoming the energy density and safety challenges associated with conventional lithium-ion batteries. Solid polymer electrolytes, particularly those based on poly(vinylidene fluoride) (PVDF) and dimethylformamide (DMF), demonstrate significant potential. However, interfacial side reactions between residual DMF solvents and lithium metal present substantial challenges. In this study, we investigate the in situ formation of solid electrolyte interphase protective layers to mitigate these side reactions. By incorporating F-rich additives, such as fluoroethylene carbonate and lithium difluorophosphate, we successfully establish a dual-layer inorganic SEI structure characterized by an outer LiF layer and an inner Li2O layer. Consequently, our approach extends the cycle life of lithium symmetric batteries to 3000 h. Additionally, the Li||LiFePO4 solid-state battery demonstrates exceptional stability, enduring 400 cycles at a 1C rate with an impressive capacity retention of 84%. This strategic methodology effectively leverages the benefits of residual solvents, ensuring both enhanced battery efficiency and long-term operational stability for PVDF-based all-solid-state lithium metal batteries.

Life cycle assessment integrating the effects of recycling and reuse for battery circulation

The increasing electrification of automobiles and introduction of renewable energy facilities have resulted in a high demand for lithium-ion batteries. Recycling and reuse processes could significantly reduce CO2 emissions and resource consumption during the battery life cycle. This paper introduces a method of evaluating CO2 emissions over the life cycle of a one-generation battery without double counting the effects of recycling and reuse. The scope of the calculation includes manufacturing, collection/transportation, storage/diagnosis, reuse, recycling, and material synthesis. Horizontal battery-to-battery recycling was assumed to evaluate the effect of recycling, and the performance and lifespan of reused batteries were considered to be inferior to those of new batteries to evaluate the effects of reuse. Parameter studies using the proposed method quantitatively estimated the effectiveness of an efficient recycling process and the effect of reducing CO2 emissions by facilitating the complete utilization of long-life batteries through reuse. The proposed method is expected to guide the development of technologies for manufacturing, recycling, and reusing batteries to create a society with battery circularity.